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By M Hilden, K Barbosa, M Yahyaei, C Ndimande, K Runge, V Jokovic

Classification devices provide a link between comminution and flotation. Basically, it determines which particles are diverted back for additional grinding and which ones pass to downstream flotation. Therefore, the classifiers play an important role in the performance of a mineral processing circuit. Hydrocyclones are the most common classifiers used in wet grinding, despite being associated with poor classification efficiency. Hydrocyclones are widely used due to advantages related to low maintenance as well as reduced capital and operating cost. Other classifiers, such as fine screens, have much better classification efficiency compared to hydrocyclones. The major challenge of using screens in an operation, however, is their large footprint and increased maintenance requirements relative to hydrocyclones. Some researchers have demonstrated that switching from hydrocyclones to screens, as the classifier device in a ball milling circuit, resulted in a 20 per cent increase in plant throughput and significant improvements in coarse particle recovery, resulting in a 6 per cent increase in overall flotation recovery. However, it is known that these benefits of improved classification are very much ore specific, ie depending on the ore response. Therefore, there is a need to estimate the benefits of improved classification in pilot scale testing before the plant could consider the potential classifier upgrade. This paper presents the results of two pilot-scale grinding tests where the ore sample was processed using different classifiers: a traditional hydrocyclone and hybrid classification involving the use of a semi-inverted hydrocyclone followed by a screen. The size specific energy and circulating load were used to compare the performance of the grinding circuit. The grinding product was subject to mineral liberation analysis and the impact of classification efficiency on the mineral liberation is discussed in the paper.

Aug 24, 2022

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By B Tadesse, L G. Dyer, K Ward

The Golden Mile ore deposit in Western Australia is one of the largest gold telluride deposits in the world. Approximately 20 per cent of the contained gold in the deposit is present as gold telluride minerals, the most prevalent being calaverite (AuTe2) and petzite (Ag3AuTe2). Telluride mineralogy in the Golden Mile orebody is fine grained and complex having formed due to hydrothermal deposition in the late paragenetic sequence. Nineteen tellurium bearing minerals have been identified including gold and silver as well as mercury, lead and nickel tellurides (Shackleton, Spry and Bateman, 2003). Extensive work has been completed on the flotation of gold, gold-silver alloys and gold ores however there is a lack of information detailing the difference between flotation of native gold and individual gold minerals (Dunne, 2016). Studies on the flotation behaviour of gold ores have focused primarily on the flotation of free gold and refractory sulfides (Teague, Van Deventer and Swaminathan, 1999).

Aug 24, 2022

By R W. Henley, L Knuefing, M Turner, Y Zhang, M Saadatfar, A Limaye, R Cruikshank, M A. Knackstedt, A Kingston, L Beeching, N Francois

A better understanding of ore fragmentation and the textural features of ore is a key to the energy efficient extraction of targeted minerals from low-grade ore deposits. In this study, X-ray microcomputed tomography (micro-CT) is employed to study mineral liberation during the tensile failure and onset of fragmentation of a copper ore. Our results show that X-ray micro-CT could inform new studies of ore micromechanics and fragmentation at the laboratory scale and may offer new avenues to address current challenges in the design of efficient comminution processes. We present the results of experiments based on a high-pressure apparatus enabling micromechanical studies to be carried out in situ (inside a micro-CT scanner). This platform produces high-quality 3D images of the evolution of a sample of porphyry copper ore during an in situ fragmentation test. A sequence of tomographic images enables mapping in 3D of both the deformation of mineral phases and the fragmentation process. The fragmentation occurs quasistatically through multiple stages starting with an initial tensile fracture splitting the ore diametrically, followed by tensile-activated nucleation and growth of multiple fractures producing a complex fracture network. Coupling breakage with microstructural information enables quantitative determination of the impact of ore texture heterogeneity on fracture patterns and mineral liberation. This microstructural information can be compared to key measurements of the ore mechanical behaviour such as the global deformation energy, strain deformation field and the stress relaxation response. The latter allows one to identify interesting precursor signals of the tensile failure. The copper liberation, fragment size distribution and breakage patterns are statistically characterised and related to comminution mechanisms which are clearly identified in the sequence of tomographic images. The two dominant mechanisms are rock-rock friction/compression induced by fracture closing and compression-driven fragmentation at rock-crusher contact points.

Aug 24, 2022

By K C. Corin, N Ndamase, M Tadie

Mining operations in arid regions are compelled to reduce their consumption of fresh water. Closed water circuits are an attractive solution and, in addition to reducing freshwater consumption, have the added benefit of reducing reagent consumption as well as the environmental impact by eliminating effluent discharge. Accumulating ionic species have been shown to hinder collector adsorption which reduces the recovery of valuable minerals. Numerous studies have investigated the effect of degrading water quality on collector adsorption however there is very limited understanding as to how this takes place from an electrochemical perspective. This study therefore aims to investigate how the presence of accumulating ionic species at varying concentrations affects the electrochemical adsorption of sodium ethyl xanthate onto galena. The synthetic plant water used in this study comprised of single salt solutions to isolate the effects of the ionic species of interest. The ionic strengths were varied between 0.0242 M, 0.0727 M, 0.1212 M and 0.2426 M which correspond to University of Cape Town (UCT) Centre for Minerals Research (CMR) synthetic plant waters of 1, 3, 5 and 10SPW, respectively. Mineral rest potentials indicated how changing water quality affected xanthate-mineral interactions. Microflotation observed the impact of changing water quality on mineral floatability.

Aug 24, 2022

By K Haga, G Danha, A Shibayama, L L. Godirilwe

The hydrometallurgical separation and enrichment processes provide an effective way to selectively recover metals from relatively dilute multicomponent sulfuric acid leach solutions. The multicomponent leach solution utilised in this study contained 0.3 g/L Cu, 0.34 g/L Ni, 0.13 g/L Co, and 2.96 g/L Fe, which was obtained after high-pressure oxidative acid leaching (HPOAL) of the copper-nickel smelter slag. The solvent extraction (SX), precipitation, and xanthate complexation processes were employed to recover and upgrade Cu, Ni, and Co from the leach solution. Batch SX tests were carried out using a countercurrent two-stage mixer settler extraction column, and LIX 984N (10 per cent v/v) as a copper extractant. Fundamental parameters influencing the extraction process such as pH, mixing speed, H2SO4 concentration, and organic/aqueous (O/A) phase ratio were investigated. For copper enrichment in solution, a combination of two extraction stages and two stripping stages were employed. Copper was successively separated from Fe, Ni, and Co under optimised extraction conditions (pH 2, 400 rev/min, O/A 0.25, and 20 min contacting) and stripping conditions (175 g/L H2SO4, 400 rev/min, O/A 4, and 20 min contacting). About 97 per cent of copper was extracted with low co-extraction of Fe, Ni, and Co of about 5.90 per cent, 1.47 per cent, and 2.53 per cent, correspondingly. A final Cu-rich solution containing 23 g/L Cu was obtained with a very low Fe concentration of 0.05 g/L. Additionally, for iron removal from the Ni/Co raffinate solution, more than 99 per cent of iron was precipitated at pH 4 by the addition of a calcium carbonate (CaCO3) suspension, with low co-precipitation of nickel and cobalt of around 3.68 per cent and 2.27 per cent, respectively. Furthermore, about 83.6 per cent of nickel and 99.4 per cent cobalt were co-precipitated from the solution by potassium amyl xanthate (PAX) solution at pH 6. The Ni and Co xanthate complexes were thermally decomposed and recovered as cobalt oxide (CoO) and nickel sulfide (NiS) solids.

Aug 24, 2022

By M Saghaeian, M Zare, V Sheikhzadeh, R Hejazi

High-Pressure Grinding Roll (HPGR) is one of the efficient methods for increasing the specific surface area (SSA) of iron ore concentrate for pellet feed production. HPGR grinding mechanism implies that material should compressed between the two rolls, therefore layer of material must be able to resist required pressure for achieving suitable grinding conditions. In this study, by doing SSA increasing tests with pilot HPGR, the effects of silica reduction on SSA increasing results were investigated. For this purpose, HPGR tests were performed on an Iranian magnetite concentrate before and after reverse flotation silica reduction tests. Based on the laboratory test results, silicates have been concentrated in two fraction sizes of the sample comprises coarser than 150 microns in form of quartz and finer than 7 microns in form of iron silicates. These silicates have been effected on reduction of concentrate bed pressure resistance by creating a pasty and sticky mud. In this condition, HPGR cannot work properly and operation results are not acceptable. According to flotation silica reduction tests, with 90 per cent weight recovery, concentrate Fe grade is increased from 67.8 per cent to 69.5 per cent and SiO2 content is reduced from 1.98 per cent to 0.9 per cent and especially for lower than 7 microns fraction size, as a critical fraction, SiO2 content decreased from 4.45 per cent to 2.35 per cent. HPGR tests were performed on 8 per cent moisture in 4 N/mm2 specific force and according to the results after silica reduction HPGR operation conditions are optimised. Results showed that the working gap increased from 7 to 10.5 mm and specific throughput of material raised from 180 ts/hm3 to 250 ts/hm3 , and SSA increased by 300 cm2 /gr in a single pass.

Aug 24, 2022

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

By A Yáñez, P Vallejos, R Grau, J Yianatos

In flotation cells, especially in large flotation units, froth management is a crucial variable that should be considered during the design phase or optimised to improve the performance of existing flotation circuits. This paper presents a simulation evaluation of the effect of launder design on the metallurgical performance of an industrial flotation circuit consisting of five TankCell® e630 (630 m3 ) cells in a Cu rougher duty. This analysis was carried out using a new industrial simulator, which was built on a wide database collected from many industrial concentrators. This tool is currently incorporated into HSC Chemistry® software and allows evaluation of the effect of launder design on mineral froth recovery, water recovery, entrainment, and other variables to be quantified. The industrial flotation circuit was evaluated under different launder design scenarios, considering an actual flotation circuit that includes TankCell® e630 cells for calibration and as a reference (baseline). Firstly, two different designs were evaluated in the full circuit: a standard launder design and a new launder technology. It was found that the new launder technology enabled improvement of the mineral recovery along the circuit, mainly for coarse particles, due to the improvement in froth mineral recovery. Next, the partial upgrade of the launder design along the circuit was analysed. Thus, the new launder technology was evaluated in the first and the last two cells of the bank. The results showed that upgrading the launders in different cells along the circuit delivered an increase in the final recovery with respect to the baseline, with a partial impact on the concentrate grade. However, these changes are less than those when evaluating the full upgrade scenario. A partial launder upgrade either in the first or last two cells of the bank showed similar final recoveries, but the latter enabled a slightly higher concentrate grade (about 1 per cent higher) to be achieved. Finally, the evaluation of launder design using the industrial simulator made it possible to estimate its effect on variables that are not commonly obtained from plant surveys, including froth recovery per particle size, collection recovery per particle size and liberation, gangue entrainment and bubble loading grade.

Aug 24, 2022

By A Liu, X Wang, W Peng, Q Zhang

Pulp rheology plays a critical role in fine mineral flotation. Yield stress and apparent viscosity are two important rheological parameters affecting mineral flotation recovery. In this paper, the concept of pulp rheology and its measuring method are presented. The main factors, such as particle size, pulp concentration, mineral types, pulp temperature, inorganic salts, that affect the pulp rheology are systematically reviewed, and then followed by the discussion of the relationship between pulp rheological properties and flotation performance. Generally, high pulp apparent viscosity and yield stress values have been found to have an adverse effect on flotation recovery. In addition, due to the hetero-coagulation between the valuable mineral and gangue mineral, the pulp of mixed ore shows higher viscosity than that of the single mineral slurry. This paper is expected to provide some references for the efficient upgrading of low-grade and complex ores from the perspective of pulp rheology.

Aug 24, 2022

By G R. Ballantyne, G Lane

Dry milling circuits that include high pressure grinding rolls (HPGR) or vertical roller mills (VRM) and air classification have replaced dry ball milling in cement production, but how do they compare to wet milling and classification circuits in mineral processing plants? Two case studies are presented that compare the energy efficiency, wear, liberation and capital cost of dry and wet milling circuits. In both case studies the VRM and HPGR consume half the energy of a wet tumbling mill for the same duty. However, the dry classification system tends to significantly erode the energy benefits. A number of improvement opportunities are presented that have the potential to improve the energy and capital efficiency of dry milling circuits. These improvement opportunities focus on the dry classification system that consumes significant energy in heating and fan power requirements and requires a large proportion of the footprint.

Aug 24, 2022

By G Bournival, Y Pan, S Ata

A custom-made set-up that measures bubble coalescence time and the thin film balance (TFB) technique were used to explore the role of residual xanthate (potassium amyl xanthate, PAX) and salt (NaCl) on the adsorption of two frothers (methyl isobutyl carbinol-MIBC, and di-propylene glycolDPG) at the air-water interface. This paper is primarily focused on the comparison of these two techniques in studying the interaction between the flotation reagents and salt emphasizing their capabilities and limits. The results from the coalescence rig showed that the presence of PAX improved the stability of bubbles in both frother solutions and led to a bubble coalescence inhibition at 50–500 ppm DPG. These measures were compared with the results from the TFB. Findings from the TFB were overall in good agreement with the bubble coalescence time, but a higher stability level was observed in thin films under the same condition. The effect of salt on the frother and PAX mixture was also explored, and the results showed an adverse impact of the salt on the interaction of frother and PAX with both techniques. However, variations were found between them in some cases. The TFB is much more sensitive to the presence of dissolved gas and oil droplets.

Aug 24, 2022

By X Zhang, Y Zhu, P E. Ngoepe, P P. Mkhonto, W Xiong, L Han, L Lu

The triazine molecules have not been given much attention and they are potential collectors that may positively impact the mineral processing industry. The adsorption of triazine as collectors such as sodium 2,6-dithio-4-butylamino-1,3,5-triazine (SDTBAT) on pyrite form a basis in design of flotation collectors that may be applicable in a wide range of sulfide minerals. The SDTBAT collector was compared with the sodium normal butyl xanthate (SNBX) and sodium normal butyl dithiocarbamate (SNBDTC). All collectors were adsorbed in their neutral form containing sodium on the pyrite (100) surface. The computational calculations found that the adsorption energies followed the order: SDTBAT (-300.35 kJ/mol) > SNBX (-186.10 kJ/mol) > SNBDTC (-163.78 kJ/mol). It was observed that the SNBX and SNBDTC adsorbed through the S atoms, while the SDTBAT adsorbed through the S atoms and N atoms onto Fe atoms. It is clear that the SDTBAT had a strong binding energy which is attributed to the presence of the triazine group that is electron depositing to the active S atoms compared to the SNBX which possessed the oxygen that is electron withdrawing. Moreover, the SDTBAT collector was found to bind stronger than the xanthate. This was complimented by microflotation tests that showed fast floating and higher recoveries of pyrite when using the SDTBAT collector than the xanthate and DTC. This clearly demonstrated that the SDTBAT is a potential collector to replace the xanthate collector due to its high selectivity and flotation power.

Aug 24, 2022

By M S. Manono, K C. Corin

The optimisation and process developments surrounding the beneficiation of Cu-Ni-PGM ores is of fundamental importance when considering the continued rise in global demand for these precious metals. The selective sequential flotation of these ores is accompanied with various processing challenges such as the successful separation of the Cu-Ni-PGMs from non-sulfide naturally floatable gangue and pyrrhotite. Reagents such as sodium iso-butyl xanthate (SIBX) and sodium carboxymethyl cellulose (CMC) have proven to significantly improve the selectivity of the flotation process in their respective roles. The use of recycled water with abnormal inorganic electrolyte concentrations can modify the selectivity of these reagents, as ions may adsorb onto minerals such as pyrrhotite, thereby hindering or promoting the hydrophocity and floatability of pyrrhotite. Process water quality effects on the behaviour of pyrrhotite may have negative or positive influence on the recovery and grades of the wanted Cu-Ni-PGMs as valuable minerals associated with pyrrhotite such as pentlandite may be affected in like manner. Thus, the impact of concentrator process water quality on the behaviour of pyrrhotite needs to be determined. In this study synthetic process water at various ionic strengths was investigated against various CMC dosages to understand the behaviour of pyrrhotite during the flotation of a Cu-Ni-PGM Merensky ore in a batch flotation cell. This study showed that pyrrhotite grades increased with an increase in CMC dosage for fixed ionic strengths whereas the recoveries of pyrrhotite increased with an increase in ionic strength until 3SPW, then a trend of a decrease in recoveries was seen with 5SPW resulting in the lowest pyrrhotite recoveries. Furthermore, this study showed that moderate CMC dosages of 100 g/t resulted in the highest pyrrhotite recovery for all four ionic strengths of synthetic process water tested. It can be said that to maximise value recovery from Cu-Ni-PGM ores, understanding the behaviour of pyrrhotite against degrading water quality and reagent suites could be of paramount importance given the sensitivity of pyrrhotite to oxidising chemical conditions.

Aug 24, 2022

By M Yvon, S Parkes, K P. Galvin, P Wang

Mineral liberation is critical to maximise the grade and recovery of nickel, however this objective is challenged considerably by the poor flotation kinetics, especially that of ultrafine particles (Kelebek and Tukel, 2018; Multani and Waters, 2019). High recoveries demand long cell residence times and hence a large flotation capital expenditure (Wills and Finch, 2016). However, this leads to excessive entrainment of gangue minerals, thus negating efforts to depress its recovery. This study aimed to investigate new hydrodynamic approaches to improve nickel flotation, focusing primarily on unrecovered nickel from a Western Australian tailings stream. Mechanical cell flotation experiments were conducted to understand the flotation kinetics, covering different size ranges. A novel Reflux Flotation Cell (RFC) was also used to improve the nickel recovery and reject the silicates. Future work aimed at applying the RFC to different size portions is also outlined.

Aug 24, 2022

By B McFadzean, N P. Lima, D A. Deglon

The reverse flotation of Itabirite iron ore is typically performed after a desliming step in which most of the sub-10 µm particles are removed. This is done to limit processing problems such as poor flotation recovery of SiO2 due to slime coatings and increased slurry viscosities, unmanageable froths and increased losses of hematite particles due to entrainment. However, the rejection of ultrafine particles contributes to large losses in iron recovery and may contribute to the instability of tailings dams. The aim of this study is to decouple the effects of ultrafine particles in the pulp and froth phases to better understand the processing capabilities of the fines fraction. The flotation test work was performed in a special-purpose continuously operated laboratory flotation cell that has a deep froth section to simulate plant-scale froth conditions. Five conditions of fines addition were investigated at three different froth heights and a solids concentration of 50 per cent. The behaviour of the pulp and the froth were decoupled using froth stability and froth recovery tests. This showed that, even though there is an exponential increase in froth stability at increasing fines quantities, the performance of the pulp has the overriding effect on the overall SiO2 recovery. Pulp zone, froth zone and overall SiO2 recoveries showed that overall recoveries increased by about 3.6 per cent for every 1 per cent decrease in fines content. This meant a large increase of 20 per cent in SiO2 recovery when going from undeslimed to deslimed feed. This was driven largely by increases in the pulp zone recoveries, which were about 4 per cent for every 1 per cent decrease in fines content. The froth recoveries, on the other hand, decreased by between 0.75 per cent and 2.5 per cent for every 1 per cent decrease in fines content, depending on froth height. This paper explores further insights into iron ore flotation processing at different slimes concentrations.

Aug 24, 2022

By M Saghaeian, A H. Baladastian, A Dehghani Ahmadabadi, V Sheikhzadeh, R Hejazi

This research was done to reduce silica from mixed hematite concentrate of Barfkar Iron Ore Sample and increase Fe grade using reverse flotation method (Depressing Hematite and floating Silica). The used sample in the reverse flotation tests was a mixture containing two types of hematite concentrates (Spiral cleaner concentrate and Slon-VPHGMS cleaner concentrate) with the percentage of 16 per cent and 84 per cent, respectively. Fe grade of two samples was 59.31 per cent and 57.52 per cent and SiO2 grade was 5.83 per cent and 6.71 per cent, respectively. After mixing, the Fe and SiO2 grade of the mixed sample was measured at 58.10 per cent and 6.20 per cent. For flotation tests, effect of variable operational parameters including feed size distribution (d80 = 130 microns and d80 = 53 microns), pulp solidity (25 per cent and 30 per cent w/w), pH (9.70, 10.20 and 11), Sodium silicate as a dispersant (500, 1000 and 2000 g/ton), Starch as a depressant (500, 1000, 2000 and 3000 g/ton) and EDA as a collector (180, 300, 400 and 500 g/ton) were investigated. For evaluating the influence of Sodium silicate and Starch dosage, initial flotation tests were performed on the main sample (d80 = 130 microns). These two parameters had no significant effects on the yield, Fe, and SiO2 grade of flotation concentrate based on test results. In the next step, screen analysis was carried out on the main sample for mineralogical studies. Accordingly, the suitable size distribution for releasing Fe and SiO2 particles was smaller than 53 microns. Therefore, the sample was crushed until d80 = 53 microns. Then, supplementary tests were performed on the crushed sample for studying the pH range, pulp solidity, and EDA collector dosage. After doing silica removal flotation tests based on the designed pattern and comparison of the results, the conditions consisting of size distribution d80 = 53 microns, pulp solidity 25 per cent, pH 10.20, Sodium silicate 1000 g/ton, Starch 1000 g/ton, and EDA 500 g/ton was selected as optimum values. In the last test, Fe and SiO2 grade was measured at 60.00 per cent and 3.93 per cent, respectively, and Fe recovery was obtained at 74.93 per cent.

Aug 24, 2022

By I Zh Bunin, V A. Chanturia, V G. Minenko, M V. Ryazantseva, A L. Samusev

A promising source for the extraction of rare metals and REEs in Russia is the eudialyte ores of the Lovozero deposit, which do not contain active uranium components. The eudialyte ore reserves of the Lovozero Massif are considered virtually unlimited and therefore have the potential to become a primary source of a number of rare and rare earth metals. The goal of this study was to comprehensively examine the effect of the parameters of high-power nanosecond electromagnetic pulses (HPEMP) and dielectric barrier discharge (DBD) on the leaching performance of eudialyte concentrate and the selective separation of zirconium and REEs from productive solutions. Using scanning electron microscopy and infrared spectroscopy, the mechanism behind the intensification of acidic dissolution of eudialyte as a result of pretreatment with energy impacts was described. During the HPEMP treatment, weakening and destruction of the eudialyte surface was observed, which at the substructural level is expressed in the deformation and local destruction of Si10O27, Si9MO30 resulting in formation of microcracks. During the DBD treatment, the formation of characteristic defects was observed in the form of imprints of dielectric breakdown microchannels and individual mineral fragments. Pretreatment of eudialyte concentrate using HPEMP made it possible to increase the recovery of zirconium into the pregnant solution of leaching by 3.4–4.3 per cent (from 86.6 per cent to 90.9 per cent) and by 4.1 per cent (from 86.6 per cent to 90.6 per cent) when using DBD. The increase in the total recovery of REEs was 1.2–1.8 per cent (from 87.7 per cent to 89.2 per cent). The effect of pH values, solution temperature, initial concentrations of valuable components on the successive recovery performance of zirconium and REEs from the pregnant solutions nitric from the acid leaching of eudialyte concentrate by chemical precipitation was examined. The possibility of selective separation of the zirconium product and rare earth elements with a zirconium recovery of 99.95 per cent and a REE recovery of 87.5 per cent was established. REE loss with the zirconium product was 8.0 per cent and 4.5 per cent with the spent pregnant solution.

Aug 24, 2022

By D K. Weatherley, A N. Mainza, I Govender, L M. Tavares, M S. Powell

It is understood that rocks do not instantaneously transport along a grinding mill and are consequently not perfectly mixed, but this is conveniently overlooked in mill modelling. A lack of understanding of the transport phenomenon and the difficulty of modelling realistic transport in a complex tumbling system, contribute to this. Visual observation of segregation in AG and SAG mills and measured lag time of mill response to changes in feed provide evidence of the influence of axial transport within mills. Incorporating this lag in dynamic models should underpin dynamic simulation of milling circuits for design and for model-based control. Limitations and errors in predicting the influence of increased power via mill length versus diameter, inability to predict pebble production, and a lack of the differential in residence time across rock sizes and competences, all contribute to inadequate design prediction that can be especially acute for large Autogenous mills. Examples of dramatically under – and overloaded pebble regrind circuits and the inability to predict pebble load in AG milling discouraging the application of this energy-efficient option, point to the need for predictive modelling of breakage by competence linked to transport through and out of mills. Incorporating progress in granular flow and mixing, coupled to computational advances enable models to be based on complex breakage and transport models at high spatial resolution. This allows mechanistic models to simulate thousands of times faster than real time, opening the door to more accurate mill design, including dynamics in process simulation and to live simulation for process control – all with advanced mechanistic models. The value of grasping this opportunity is not easily refuted.

Aug 24, 2022

By P G. Bourke, A Yáñez, G J. Jameson, N M. L Kupka

The kinetics of fine and ultrafine particles in conventional mechanical flotation cells are limited (Feng and Aldrich, 1999; Trahar, 1981; Wang et al, 2016). Accordingly, even limited recoveries with such machines require long residence times. Theoretical investigations into the rate of capture of fine particles by flotation, have indicated that a key parameter is the rate of shear in the fluid surrounding the bubbles and the particles. Achieving fast flotation rates of ultrafines requires a new method of bringing the particles and bubbles into contact, utilising the beneficial properties of highly dissipative flows to break through the water boundary layer. In 2010, a new type of flotation cell known as the Concorde Cell was described, in which bubbles and particles are brought together in a sonic shock wave (Jameson, 2010). Earlier research had shown that when a dispersion of fine bubbles in liquid passed through a converging nozzle at the local speed of sound, the resulting shock wave downstream generates a mass of even finer bubbles in the flow as it passes through the shock wave. The fluid within the shock wave is highly turbulent, and an environment is created that is very favourable to particle-bubble collision and capture. In this paper, we briefly describe the Concorde Flotation Cell and give examples of its use.

Aug 24, 2022