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By J. Guerrero, O. Pavez, N. Toro, A. Nazer

In the 19th century, mining in northern Chile was of great economic importance. Today, the ruinsof the copper smelters and abundant fragments of refractory bricks from their furnaces remain. Therefractory materials have not been previously studied. the origin, physical and chemical properties, and compressive strength of 10 different samples of historical refractory bricks collected on-site were investigated. The characterization results showed that the bricks are silico-aluminous, unlike the magnesium-chromium bricks used by current foundries. It was determined that 90% of them were produced in the UK and 10% were manufactured in Chile. The phases present are mullite, quartz, cristobalite, and tridymite, and the chemical composition corresponds mainly to SiO2. The compressive strength of the historical bricks is similart to those currently used,. These results may contribute to the knowledge of the 19th century mining and metallurgical historical heritage of Chile and the UK.

Jul 5, 2023

By R. Hogg

The various sub-processes which, together, make up the unit operation of froth flotation all depend on the characteristics of the feed solids, the solution phase, the air bubbles and the mechanical/hydrodynamic action of the machine. Characterization is obviously necessary for evaluation and process control, but the relationships between characteristics and process response are often unclear. A model-based characterization scheme is proposed in which material and system characteristics are evaluated in the context of simplified models for the individual subprocesses. The general basis for such an approach is discussed using the process of particle attachment and the influence of mineral liberation as examples.

Jan 1, 1989

By A. Morales

Flue dusts from a copper smelting furnace (continuous furnace), have been extensively characterized. The main phases detected have been cuprospinel, anhydrous copper sulfate (chalcocyanite), lead sulfate (anglesite) and arsenic oxides (claudetite and arsenolite). As minor phases, zinc sulfate (zincosite) and several copper or copper/iron sulfides were detected (digenite, anilite, bornite, cubanite), and also a copper oxide (tenorite). The suspension of this material in water leads to the partial dissolution of copper and zinc (chalcocyanite and zincosite) and arsenic oxides. The hydrocyclone classification of the residue makes it possible to obtain two fractions: a copper-rich coarse fraction and an arsenic-rich fine fraction. The coarse fraction can be recycled to the smelting furnace and the fine fraction can be mixed with wastewater sludge from a paper factory, to make both residues inert before disposing them to landfill.

Jan 1, 2007

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By John W. Graydon

Incineration is an attractive alternative to the disposal of MSW in landfill sites. However, the process of incineration generates fly ash which contains significant levels of leachable heavy metals - particularly cadmium, lead, and zinc - and it is essential to manage this fly ash in an environmentally sound manner. The compositions, phases, textures, morphologies and size of fly ash particles have been studied by light microscopy, scanning electron microscopy, X-ray microanalysis, and X-ray diffraction. The detailed spatial relationships and speciation of the environmentally significant constituents have received particular emphasis. The information obtained is useful in understanding how fly ash is formed during incineration, in understanding the leaching behavior of untreated fly ash if it is disposed of in a landfill and, most importantly, in guiding the development of the best treatment strategies for fly asti to mitigate its environmental impact.

Jan 1, 1992

By Carlos Mauricio Fontes Vieira, Sergio Neves Monteiro, Thiago Samarão Motta

This work has as its objective to characterize ceramic bodies formulated with ornamental rock waste and two different clays to produce ceramic paver. Specimens were made by uniaxial press-molding at 20 MPa and then fired at 950 and 1050oC respectively. The determined technological properties were: plasticity, dry bulk density, linear shrinkage, water absorption and flexural rupture strength. The results showed that the type of the clay has strong influence on the properties of interest for heavy clay ceramics. The investigated waste must be incorporated in small amounts to avoid increasing in the porosity of the ceramics.

Jan 1, 2015

By R. Hogg, M. Polat, S. Chander

A fresh dust generator was designed and built in order to study the agglomeration behavior and other characteristics of freshly generated airborne dust. The size distribution of the freshly generated quartz airborne dust produced by the generator was measured both directly in air and after dispersion in water. It was observed that same dust particles had an apparently coarser size distribution in air than in water, suggesting possible agglomeration of the dust particles. It was also observed that the size distribution obtained by a cascade impactor was very similar to the liquid dispersed size distribution, implying deagglomeration by the impactor. The agglomeration was confirmed by microscopic observations of particles in air and those collected on a microscope slide. The extent of agglomeration played a decisive role on the fraction of the dust actually becoming airborne. It was also found that contamination of the airborne dust by the rolls of the crusher was almost twice as much as that of the product.

Jan 1, 1991

By Michael Young, Rodrigo Araya, Cesar Gomez, Le Huynh, James Finch

The performance of flotation machines is closely related to the gas dispersion characteristics achieved in their operation. It is known that frothers play a major role not only in the size distribution of the generated bubble population, but also on the swarm rise velocity. A program to characterize frother effects on two-phase hydrodynamics (air-water) of Jameson cells was undertaken in a fully instrumented pilot unit installed at McGill University. Gas dispersion parameters (gas velocity, gas holdup and bubble size distributions) of the gas-liquid mixture generated in the downcomer were measured after its release into the separation chamber. The unit was operated under different conditions including gas velocity, liquid jet velocity and frother concentration (MIBC). Bubble size distributions for concentrations above the critical coalescence concentration (CCC) were narrow with Sauter mean diameter between 0.6 to 1.3 mm. The bubble size followed the general trend as encountered in other types of flotation machines, i.e., rapid decrease with increasing frother concentrations below 10 µL/L, and almost no change in size for concentrations above 30 µL/L. The CCC was between 10 and 15 µL/L. Strong correlations were found between bubble size and air-to-liquid flow ratio (APR), and between the bulk density of the aerated solution in the separation tank and the vacuum inside the downcomer. An equation is proposed to estimate gas holdup in the separation tank from vacuum and bulk density readings.

Jan 1, 2014

After several years of laboratory and field evaluations, it has been established that each frother has its own unique relationship among bubble size reduction, gas hold-up increase, froth stabilization and frother concentration. It has been shown that a frother?s hydrodynamic properties can be characterized using the relationship between the froth zone property froth height and the pulp zone property gas hold-up. The relationship is established in a bubble column run at a given air rate over a range of frother concentration. The use of relationships in frother selection and plant diagnostics is illustrated in a series of plant case studies.

Jan 1, 2009

The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of &apos;water carrying rate&apos;. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By S. J. Schatzel, P. W. Jeran, W. P. Diamond, F. E. McCall, F. Garcia, J. C. LaScola, T. P. Mucho

The National Institute for Occupational Safety and Health, Office for Mine Safety and Health Research, is investigating the geologic and mining factors influencing the migration of longwall gob gas. One goal of these studies is to optimize methane drainage strategies to reduce the volume of gob gas that reaches the underground workplace. As part of this research effort, longwall gob gas flow paths in a mine operating in the Pittsburgh Coalbed, PA, were investigated using SF6 tracer gas. Tracer gas released into the ventilation airflow underground generally stayed in the bleeder system and was vented at the associated bleeder fan shafts. Tracer gas injected into an inactive (intaking) gob gas venthole migrated to the two inby producing ventholes on the study panel, indicating that all three ventholes were in communication. The tracer gas that was injected into the gob generally stayed in the gob and only migrated to the ventilation system in response to the venthole on the study panel closest to the injection hole going off production. Tracer gas flow velocities in the longwall gob reservoir and factors influencing the production performance of gob gas ventholes in the study area are also discussed.

By Vanessa M. Torres, Renato S. Costa

This work presents the experience of Cia. Vale do Rio Doce in using Diagnostic Leaching tests to characterize refractory ores and CIP tailings. With the diagnostic leaching results of the highly refractory gold ore from Maria Preta Mine (Brazil), a process flowsheet was defined for a feasibility study of possible process modification on the existing plant. With CIP tailings from its Fazenda Brasileiro and Caué operations the amount of cyanidable gold was determined to aid plant optimization.

Jan 1, 1995

By P. Sergi

A method of characterizing gold ores with respect to processing is proposed. The method includes microscopical examinations to obtain qualitative and quantitative data that relate to processing. The main thrust, however, involves laboratory heavy liquid separation tests, laboratory amalgamation tests, and laboratory cyanidation tests to determine the proportions of gold that can be recovered in a conventional processing operation. Two different Brazilian gold ores: a quartz vein gold ore, and gold in metasediments were tested.

Jan 1, 1989

By J. F. Stenebråten, W. P. Johnson, D. R. Brosnahan

Carbonaceous materials (CM) from ores of varying preg¬robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, were characterized in terms of their functional group contents, hydrocarbon contents, elemental composi¬tions and humic acid contents. Fourier transform infrared (FT-IR) analyses did not show the presence of hydrocarbons or carboxylic, phenolic or sulfhydrolfunctionalities. The FT¬IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating the presence of oxygen as ether linkages or thiocarbonyl functionality in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between the maturity of the CM and the preg-robbing behavior, possibly due to the low resolution inherent in electron microprobe analyses. However, the atomic O/C ratios agree with other chemical analyses, indi¬cating that the organic carbon is very mature, similar to or higher than anthracite grade coal. Gas chromatography¬mass spectrometry and nuclear magnetic resonance analy¬ses corroborated the relatively featureless character of the carbon, indicating that the carbon structure is virtually completely aromatic (graphitic).

Jan 1, 2000

By J. F. Stenebråten, W. P. Johnson

Carbonaceous material (CM) from the Barrick Goldstrike Mines, NV, was characterized with respect to its gold sorption (preg-robbing) and gold recovery behavior. The breadth of graphite peaks measured by X-ray diffraction were used to calculate crystallite dimensions (002) of the CM. The (002) dimension was found to vary inversely with preg-robbing activity and directly with gold-recovery behavior, indicating that the degree of graphitization (maturation) experienced by the carbonaceous material is correlated with gold-loss during ore processing. The inverse correlation of preg-robbing activity was improved when percent preg-robbing was regressed against (002) crystallite size and carbon content. The (101) crystallite dimensions of all samples were calculated from laser Raman analysis, and were not found to correlate with preg-robbing behavior of the CM. BET surface area and micropore size distribution results were affected by grinding history, negating comparison of these characteristics between samples.

Jan 1, 2000

By J. F. Stenebråten, W. P. Johnson, D. R. Brosnahan

Carbonaceous material (CM) from ores of varying preg-robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, was characterized in terms of its functional group content, hydrocarbon content, elemental composition, and humic acid content. FT-IR analyses showed neither the presence of hydrocarbons nor of carboxylic, phenolic, or sulfhydrol functionalities. FT-IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating presence of oxygen as ether linkages in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between maturity of CM and preg-robbing behavior, possibly due to low resolution of electron microprobe analysis. However, the atomic O/C ratios agree with other chemical analysis, indicating that the organic carbon is very mature, similar to or higher in grade than anthracite coal.

Jan 1, 1999

By A. Iordanidis

Fly ash samples were collected from two large lignite-fired power plants of Ptolemais region, northern Greece. Environmental Scanning Electron Microscopy (ESEM) was applied for the characterisation of the samples. ESEM coupled with Energy Dispersive System (EDS) provided fast and accurate results on the morphology, mineralogy and chemical composition of the fly ash particles. Fly ash consists mainly of aluminosilicate glass, silicates, oxides-hydroxides, sulphates, carbonates and char. Various types of chars, spheres (e.g. ferrospheres, cenosphers, plerospheres etc.), spheroids, agglomerates and mineral crystalls were observed. The size distribution of the fly ash particles was correlated with their mineralogical and chemical composition. Possible environmental impacts and potential utilization is also discussed in this study.

Jan 1, 2005

By F. G. Caballero, J. L. Gonzalez-Carrasco, S. Barrius, H. Carreon, M. Lieblich

"The grit blasting is a low-cost technique successfully used to enhance mechanical fixation of the implants through increasing their roughness. As a result of the severe plastic surface deformation, it produces subsurface effects such as grain refinement, hardening and compressive residual stresses which are generally evaluated with destructive techniques. In this research work, non-contacting and contacting thermoelectric power measurements are performed in blasted 316L VM and Ti-6AI-4V specimens using Ah03 and Zr02 particles which yield a coarse and a fine rough surface, respectively. This study correlates the microstructural changes induced by the grit blasting treatment and the limitations and advantages of each of the nondestructive thermoelectric techniques based on the Seebeck effect used to evaluate these biomaterials.IntroductionIt is well known that surface properties play an important role in metallic materials used in bio-medical applications. Since the biological response is correlated directly with surface properties it is comprehensible the intense activity in superficial modification by physics or chemistry methods in this field. Grit blasting, one of the most popular surface modification of metallic biomaterials, enhances the mechanical fixation of the implant through the increase in roughness [1-3]. Roughening is developed by bombarding the surface with a high-velocity jet of ceramic particles, being the final roughness a function of the processing parameters (pressure, distance, time, ... ) and blasting particles (nature, shape, size). As the plastically deformed surface layer tries to expand relatively to the intact interior of the specimen, residual compressive stress gradients develops perpendicular to the surface at shallow depths with a maximum value at a depth in the range of 5 to 60 µm. This surface treatment also may cause subtle variations in the subsurface material properties, such as increased hardness and grain size refinement, which are consequences of the significant plastic deformation through cold work. Blasted affected zones may extend to a depth of up to about 200 µm. The subsurface hardening and the near-surface compressive stress gradient playa beneficial role by retarding fatigue crack nucleation and further growth, ultimately extending the fatigue life of the metallic part [4]. In this work, two non-destructive thermoelectric techniques (NDTT), the non-contacting and contacting thermoelectric power measurements were used to analyze the subsurface induced changes on blasted Ti-6AI-4V and 316L VM specimens using Al2O3 and Zr02 particles. Detailed information on the microstructural induced effects and subsurface mechanical properties were published elsewhere [5-8]. Here the nondestructive evaluation of the involved microstructural changes is used to assess the global subsurface damage. Advantages of using nondestructive techniques during manufacturing are envisaged."

Jan 1, 2012

By S. Mohammadnejad, M. Olizadeh, B. Mehrabi

A new method using a combination of comprehensive mineralogical and analytical approach which includes optical and electrical microscopy and several analytical techniques with diagnostic leaching has been used to characterize the associations and distribution of gold in a variety of minerals from the Zarshuran refractory gold ore, NW Iran. Zarshuran ore with an average of 7.9 g/t Au-grade and about 8% arsenic with gold recovery less than 20% in direct cyanidation is considered as high arsenic, high au-grade refractory gold ore. In most of the refractory ores, gold is associated with arsenopyrite and co-para genetic ore minerals, while in Zarshuran ore; gold is associated with orpiment, realgar and arsenian-pyrite. Considering its mineralogy and As content, it can be considered as the most difficult refractory ore for characterization and processing. Results from the mineralogical examination and diagnostic leaches indicate that there is only a small amount of free gold (17-19%) that is present in cyanide-soluble sulfo-arsenides compounds, predominantly orpiment and realgar. Diagnostic leaches also indicate that little gold is occluded within the silicate structure (14%). Overall, the gold is mostly included in sulfides, arsenic sulfides and sulfo-arsenides (50%). The results also have shown how the technique can be used to gain a good initial understanding of potential metallurgical problems for a refractory gold ore.

Jan 1, 2005

By Zhou Wenbin

In this paper the mechanical properties of high carbon equivalent cast iron for automobile brake discs were analyzed through thermal analysis curves. Experiment results show that the mechanical properties have a strong correlation with thermal analysis curves and an effective way to predict the mechanical properties of high carbon equivalent cast iron was proposed based on the features of thermal analysis curves.

Jan 1, 2010