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By C. L. Schneider, C. O. Gomes, R. P. King, J. A. Finch, D. Lin

Discussion is presented by Prof. King and Dr. Schneider of the paper by Lin, Gomez and Finch published in Trans.IMM C, vol.104, 1995, p.C155-C161. They conclude that the correction procedures used for simulated observations of simulated capped spheres are not reliable when applied to mineralogical data and that their relative ranking should not be extrapolated to other situations. Properly regularised solutions obtained with the use of appropriate kernels can be safely used for routine mineral liberation work and can be calibrated accurately against real mineralogical samples in the laboratory

Jun 19, 1905

By C. T. Aimone-Martin, V. L. Rosenhaim

The response of two structures to blast-induced ground vibrations were evaluated and compared in order to quantify the impact of different blasting operations, hard rock and soft rock blasting, upon the structures movements. The first instrumented structure was a residential type, located in the operational area of a coal mine, were blasting is conducted in soft rocks, such as siltstone and coal, with compressive strength ranging from 20 to 50 MPa. Blasting is characterized by low benches, with hole lengths averaging 5.5 m (18 ft) and low powder factors, 140 to 210 g/m3 (0.236 to 0.354 lb/yd3), resulting in very little horizontal movement of the rock during the blast. The second structure was a commercial building, located in a basalt quarry (compressive strength between 109 and 180 MPa), where blasting is conducted in 12 m (39.4 ft) benches with powder factors ranging from 200 to 350 g/m3 (0.337 to 0.590 lb/yd3). Velocity sensors were placed on the structure walls to measure wall displacements and calculate blast-induced strains in the walls, and these results were compared with the driving ground excitations. The calculated strains were compared with the limits of rupture of the cement grout used as mortar between bricks and as wall coating, considered to be the weakest material in the structure composition. The blast-induced response of existing cracks in the structures were also measured using displacement gages and compared to the daily influence of weather fluctuations, such as changes in temperature and humidity, on crack movement. The results show that for the same levels of ground motions the structures present different movement, resulting in distinct levels of induced strains on the walls depending on the geology. The influence of long-term temperature and humidity variations on crack movements on both structures is very similar, during the same seasons of the year. Crack response to long-term weather changes is 2.5 to 3.5 times greater than blast influences.

Jan 1, 2015

By R Herbert, M E. Malmstr÷, S U. Salmon

The study focuses on sulfide oxidation processes in unweathered pyrite-rich mine tailings from a soil-covered impoundment in northern Sweden. To simulate the oxygen-limited conditions in water saturated tailings two long-term column experiments were performed. Results are presented for the first 11 months of the experiments at room temperature. The tailings used in the experiments were of two different grain sizes (one coarse grained, in the range 0.02 - 0.6 mm with a grain surface area of 1.86 m2 g-1, and one fine-grained, in the range 0.0015 - 0.06 mm with a grain surface area of 10.00 m2 g-1) and with slightly different mineralogical composition. The S:Fe molar ratio in the leachates (1.0 - 1.5) indicates either that pyrrhotite is the main iron sulfide undergoing oxidation in our experiments, or, alternatively that the S:Fe molar ratio in the leachate is determined by pyrite weathering in conjunction with other processes releasing iron or immobilising sulfate. However, speciation modelling of the leachates indicates that ferrihydrite was close to saturation, suggesting that a ferric oxyhydroxide may have dissolved/ precipitated during the experimental period, thereby affecting the S:Fe molar ratio. Pyrite oxidation rates obtained from the two column experiments during æsteady-stateÆ were 2.25 + 10-13 and 8.45 + 10-14 mol m-2 s-1 in the coarse and fine tailings, respectively. Pyrrhotite oxidation rates, as an alternative, were 2.31 + 10-12 and 1.24 + 10-11 mol m-2 s-1 in the coarse and fine tailings, respectively. Natural microbial activity was confirmed in both the tailings and the leachates; therefore, the obtained oxidation rates are not strictly abiotic. It is thus concluded, based on the experimental results, that tailing heterogeneity will result in zones with different oxidation rates, related to their physical and chemical properties.

Jan 1, 2003

By M. Josick Comarmond, John J. Jeffery, John W. Bennett

Oxidation rates of sulfidic mine wastes measured at a range of size scales have been collected from a number of sources. The results suggest that well-designed laboratory columns, under controlled conditions, provide comparable information on oxidation rates to that obtained from field test piles. It has been found in the cases presented that laboratory measurements of oxidation rates of a particular material type can be applied with confidence to the same materials in the field. It is recommended that a further study be undertaken to measure the time-dependence of the oxidation rate for a range of particle sizes and different materials. This study would provide measurements against which models of oxidation rate as a function of time and particle size can be tested, to give confidence in the use of models to describe dump behaviour in the longer term.

Jan 1, 2000

By R C. Morris

Supergene lateritic iron ores are uncommon when compared with the vast tonnages of BIF-hosted microplaty haematite ores of the world or with the dominant supergene mimetic martite-goethite ores of the Hamersleys. In Australia and to a lesser extent in India and South America, mimetic replacement of gangue minerals by iron hydroxyoxides is a major factor in forming supergene iron ore from banded iron-formation (BIF) and results in the superb preservation of all of the original BIF features. This includes primary banding down to the finest inclusions, as a result of pseudomorphing of the BIF gangue at depth by goethite. The enrichment as a whole is an absolute accumulation of Fe at depth, dissolved from the surface BIF, and a removal of the gangue elements without loss of the original BIF mineral textures. Thus the ores grow upward to meet the downward destruction of the surface BIF by erosion. By contrast the supergene lateritic ores including the 'blue dust ores' are residual ores resulting from the relative accumulation of Fe. In the supergene lateritic ores derived from BIF, removal of the gangue is accompanied by repetitive solution and reprecipitation by secondary haematite and goethite. The final product of lateritisation of BIF and BIF-derived ores is typically complex, due to successive overprinting of earlier stages of alteration during the process, and because of the different precursors. This progressive lateritic modification tends to produce a varied surface complex including massive, vermiform, and botryoidal, or nodular aluminous/siliceous goethite and haematite, variously known as ferricrete, duricrust, canga, or 'hydrated zone hardcap'. The significant difference in these ores to the supergene mimetic martite-goethite ores is that they grow downward, with the total destruction of any of the parent BIF or BIF-ore textures.

Jan 1, 2009

By D. Bois, F. P. Hassani, M. Hossein

"A growing environmental awareness hos prompted the mineral industry to seek innovations in waste management and technology. It is estimated that over 500 million metric tonnes of solid waste each year are rejected by the Canadian mineral industry. This waste hos to be disposed of in the most environmentally and economically acceptable manner.An extensive study has been conducted to estimate the cost of implementing total tailings fill from a waste disposal point-of-view as an alternative to large-scale surface disposal of tailings. The cost of waste disposal at the surface (tailings pond), and underground (total tailings fill) for three Canadian mines which have taken part in Quebec Mine Survey conducted in 1992 are analyzed. Surface disposal is the most economical and common method of mine waste disposal in Canada. Total tailings backfill as a method of waste disposal is technically feasible but cannot be regarded as more economic than surface disposal in all . It is important to remember that while surface disposal costs are rising, due to tighter legislation and more environmental pressure on governments; the costs of preparing and placing total tailings backfill is still falling as the technology improves."

Jan 1, 1994

The Gympie Province is a unique tectono-stratigraphic unit which does not fit into the overall palaeogeographic pattern of the New England Fold Belt (NEFB), and part of it has been proposed as an exotic terrane more closely linked to New Zealand. From E to W the Gympie Province comprises 6 distinct units which can be evaluated as suspect or exotic terranes.

Jan 1, 1990

By Peter Fajfa, Heinz Palkowski, Jakob Kraner, Matjaž Godec

The study of asymmetric rolling on the AA 5454 aluminium alloy plates was carried out. The plates were taken directly from the industrial hot rolled sheet. They were cold rolled on the laboratory mill with different rotation speed of the upper and the lower work roller with the strains around 33 % and 44 %. To get closer to the industrial conditions the maximal dimensions of the rolled plates for laboratory rolling mill and the special industrial lubricant were used. After deformation the plates were annealed to the soft condition. This research was focused on all possible effects of asymmetric rolling: The reduction of rolling force, the increase of strain at same set roll gap, bending of workpiece, finer microstructure, more heterogeneous textures and as a consequence of that better mechanical properties. The asymmetric rolling with favourable mechanisms in the deformation zone has created the material with the homogeneous hardness in the cross section and with lower anisotropy, which is crucial for improvement of formability properties of aluminium work hardened alloys and to get closer to properties of steels. In the presented paper the general impact and different effects of speed difference of rollers was investigated on cold rolled aluminium alloy. Obtained and analysed results explain the function of asymmetry in rolling process and the options to implement the asymmetric rolling in industrial plant.

Oct 1, 2019

By Mauro F. Dobran

The use of Slot Raises has been common for many years. The following presentation will compare various methods of developing these Slot Raises and introduce two new ones.

Jan 1, 1996

By A. Casuge, D. Lee, J. A. Finch, C. C. Sui

The adsorption of copper and lead und their subsequent xanthate uptake were compared at pH 3.0, 6.0 and 9.2 on both fresh and oxidized sphalerite. The extent of adsorption and the rate of adsorption were strongly dependent on pH, with the highest adsorption of Cu and Pb being at pH 9.2. In the presence of both Cu and Pb, Cu adsorption was enhanced and Pb adsorption was suppressed. The adsorption kinetics of Cu and Pb were characterized by two- and three-stage adsorption processes, respectively. The exchange ratio of Cu to Zn was about one and that of Ph to Zn was greater than one and varied with pH. The uptake of xarlthate on "activated" sphalerite was dependent on pH. The rnaximum uptake was found to be at pH 6.0 for Cu-activated sphalerite artd at pH 9.2 for Pb-activated sphalerite. A measure of "activation strength" based on inetal ion adsorption and xanthate uptake was introduced. The activation strength of Cu to Pb was about one at acidic pH, but it was higher at neutral (pH -6) and alkaline (pH -3) conditions. The oxidation of sphalerite decreased Pb and, especially, Cu adsorption and decreased xanthate uptake.

Jan 1, 2000

By Serdar Aktaş, Özgün Küçükoğlu, Burcu Nilgün Çetiner, Mehmet Hakan Morcalı

This study compares the cementation performance of metallic iron, metallic aluminum, and metallic tin in terms of the reaction conditions and parameters in synthetic antimony chloride solutions. The effects on the antimony recovery (%) caused by the cementators’ types, stirring speed, reaction time, and temperatures were explored thoroughly. The cementation kinetics of antimony were also explored for each cementator. The activation energies were determined to be 10.99, 9.09, and 13.58 kJ mol– 1 for Al, Fe, and Sn, respectively. The results reveal that the reaction is diffusion controlled, and comparable results were obtained for each cementator. At 25 °C, 40 mg of iron powder was found to reduce all antimony ions (i.e., approx. 99% recovery), but even when 100 mg of Al and Sn cementators were used, the antimony recovery did not reach 100%. This result shows that iron is the best candidate to cement antimony out of the solution.

Jan 28, 2022

By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By Priscila Tavares de Paula, Márcia Mika Saito, Henrique Gonçalves Teixeira, Felicio de Freitas Simoões

In this paper a sample of the apatite flotation from Cajati-SP was studied. Four alternatives of depressants were analyzed: corn starch, cassava starch, sodium hexametaphosphate with corn starch and sodium silicate with corn starch. The cassava starch had a gain of 7.5% in the metallurgical recovery and a collector consumption 13.8% greater than corn starch. Alternatives with hexametaphosphate and silicate sodium had a loss of 6.7% and 7.8% in recovery respectively in comparison with corn starch.

Oct 3, 2019

By Barnes E. L S

With the introduction of diesel powered loading and hauling equipment, a number of Australian mines producing less than one million tonnes per year from shallow orebodies have been dev- eloped by decline. This method of entry has the advantage of providing both flexible access and early prod uction. However, as the depth of mining increases so does the operating cost of haulage, due to the need for more trucks. This cost, together with increased capital requirements for both equipment and infrastructure, leads to the point where the alternat- ive of shaft hoisting must be con- sidered. With an established decline it is possible to provide an ore hoisting shaft using a drilled raise with subsequent stripping to a suitable size. Using DCF techniques and known equipment operating and capital costs, an economic comparison of the two systems is made to determine the limit- ing depth to which truck haulage can be used.

Jan 1, 1973

By C. Liu, G. Zhu, Y. Liao

"The effect of particle size on the flotation kinetics of a low-rank coal was compared using air bubbles and oily bubbles. Five kinetic models were applied to the data from the tests to derive the relationships between the flotation rate constant, the ultimate recovery, and the particle size fraction. The results show that oily bubble flotation (OBF) resulted in a lower ash content and higher combustible recovery than air bubble flotation (ABF), especially for the -125 ??m size fraction. It was found that the flotation of a low-rank coal in individual size fractions using air bubbles and oily bubbles can be best described by a first-order model with rectangular distribution of tendency to float and the classical first-order model respectively. OBF yielded higher ultimate combustible and ultimate ash recoveries. The flotation rate constants for OBF were higher in all the models except for the fully mixed reactor model. The ultimate recovery values and modified rate constants first increased and then decreased as the size fraction decreased. The trend of the flotation rate constants as a function of the size fraction was similar in all the models except for the fully mixed reactor model. IntroductionFroth flotation is a physical-chemical separation method that is widely used in coal beneficiation for the separation of fine coal particles from associated minerals in water slurries. Since the cumulative recovery of a component in the concentrate is proportional to flotation time, the flotation process can be considered as a time-rate recovery process (Emad, Mohammad, and Bahram, 2010). Therefore, the general mathematical flotation models that incorporate both a recovery and a rate function can describe flotation time recovery profiles.The kinetics of coal flotation, as a measure of coal recovery as a function of time, have been studied in detail by many researchers. Different kinetic models have been proposed and published in the literature. The order and the rate constant are strongly dependent on the flotation conditions, such as the particle size and size distribution, the bubble concentration, the reagent concentrations, and the operating parameters (Zhang et al., 2013). The particle size has been reported to affect the flotation kinetics to a great extent (Yoon, Luttrell, and Asmatulu, 2002; Ntengwe and Witika, 2011). Numerous researchers have studied the aspects of flotation kinetics while paying special attention to particle size (Meftuni and Ibrahim, 1997; Rubinstein and Samygin, 1998; Graeme, 2012). However, the effect of particle size on the flotation kinetics of a low-rank coal has been relatively little discussed."

Jan 1, 2017

By Tchingis Lekhatinov, Lev Filippov, Vyacheslav Severov, Alexandre Matinin, Victor Samyguin, Inna Filippova

"Comparison of flotation efficiency of the new multi-zone flotation cell (MZFC) and different conventional cells was carried out at lab and pilot scales on the various samples: high contrast pyrite tailings and old copper containing tailings. MZFC is a cell of intensive flotation, which provides optimal hydrodynamic conditions for all flotation sub processes. Enhancing of particle attachment, creation of conditions for coalescent flotation, selection of spatially separated zones according to optimal hydrodynamic conditions for flotation sub-processes are proposed as main principles to design an MZFC. The bubbles/pulp stratification was pointed out as a limiting step in the existing intensive flotation machines. Two strategies to improve bubbles/pulp stratification in the MZFC were studied: (a) impact of pulp-bubble jet to the surface of a prismatic insert inside of cell, which provides the detachment of low hydrophobic particles from bubbles, and (b) profiling the pulp/bubbles jet from the reactors due to a specific geometry of cell walls. The new continuous MZFC devices were demonstrated similar or higher efficiency in comparison with laboratory batch flotation cells for pyrite flotation. Higher flotation efficiency (82%) with pure pyrite concentrate (51.2% of sulfur) and a recovery level of 92% was obtained in MZFC when the cell with stratification by impact was used. Similar results were obtained with old Cu-containing tailings. Although MZFC had 1.5 times greater yields of concentrate than a batch flotation cell, it provided the increase of chalcopyrite recovery by 29.4% and concentrate grade by 4.8%. An original organization of pulp/bubbles stratification in the separator part of the new intensive flotation machine using variable geometry inserts allowed the best flotation selectivity with a bubble mineral loading coefficient 1.5 fold higher than the laboratory mechanical or pilot cells."

Jan 1, 2014

By H. Cevizci

"Numerical simulation of the plaster stemming method (PSM) was performed and compared with the conventional drill cuttings stemming method (DCSM). Many earlier in situ tests have proved that PSM can use the blast energy more efficiently than DCSM. Despite PSM generating more blast vibrations, it has advantages over DCSM such as better fragmentation and lower cost per unit volume of rock blasted. In this study, numerical simulation with Autodyn software using a 2D tool was employed to prove the efficiency of plaster stemming by comparing parameters such as pressure, Y-velocity, Y-force, internal energy, acceleration-Y, and compression. For example, the maximum pressure attained at the top of explosive column was 7 395 MPa for DCSM whereas it was as high as 11 945 MPa for PSM. Most of the computed parameters were significantly higher in PSM than those obtained for DCSM. This paper is the first study elucidating the efficiency of PSM by numerical simulation. It is concluded that PSM can save substantial amounts of money and effort. IntroductionThe stemming of blast-hole collars in surface mines with an inert material redirects blasting energy to the rock more efficiently, thus the blast-induced energy is utilized more effectively in breaking rock. With proper stemming, the gases should not escape due to loose stemming material. More efficient stemming with better confinement therefore increases the blast fragmentation. In addition, the distance of scatter is increased, giving rise to a looser rock pile that can be more easily loaded and transported. In order to improve the performance of a blast, stemming is used to help maintain the gas pressure over time (Konya and Konya, 2018). Proper stemming has been shown to increase the explosive efficiency by over 41% (Snelling and Hall, 1912).The most common stemming material in open pits and quarries is drill cuttings because of their ready availability at blast sites and the drill cuttings stemming method (DCSM) is a low-cost method. However, it has a major disadvantage in that dry drill cuttings eject very easily from blast-holes during an explosion, thus a great percentage of the blast energy is wasted and lost to the atmosphere. Cevizci (2012, 2014, 2013, 2017) studied blasting parameters in open pits and obtained better results with the plaster stemming method (PSM) in many limestone, basalt, and clay quarries. Moulding plaster is preferred for stemming because of the fast hardening time of 25–30 minutes."

May 1, 2019

By F. M. Lyon, F. J. Chernosky

Research efforts have not developed techniques for the complete desulfurization of coal that is needed to reduce air pollution caused by burning coal and to reduce the sulfur in metallurgical coke. Sulfur in coal occurs in three forms and of these, the pyritic sulfur occurs as discrete mineral particles and, at least theoretically, should be subject to physical rejection. Pyrite occurring in hard rock mining is concentrated by froth flotation; therefore, the possibility of removal of pyrite from coal by flotation does exist. With this possibility in mind, the flotation and adsorption characteristics of ore and coal-pyrite were compared while using potassium ethyl xanthate as the collector.

Jan 1, 1973

By L. Gutierrez, R. Yepsen, F. Alarcón

Chile is the world's largest copper producer which is mostly in the form of sulfides for which froth flotation is the most efficient concentration process. As a result a concentrate that contains high concentrations of copper sulfides such as chalcopyrite, chalcocite and enargite is obtained. In the last decades processing of ores containing high concentrations of enargite (Cu3AsS4) has continuously increased in Chile, which is related to the fact that ore deposits nawadays are more heterogeneous and complex. Enargite is a mineral that contains arsenic and its presence in the copper concentrates implies severe penalties. In addition, the shortage of fresh water has driven the search for new alternative sources of water, among which seawater has proved to be one of the most attractive. The objective of this research is to study the behavior of the enargite in the process of flotation using seawater, and at the same time to compare its behavior with the results obtained using conventional water. The study was carried thorugh micro-flotation tests using pure samples of enargite, at pH values ranging from 4 to 11, both in fresh and seawater. PAX and MIBC were used as collector and frother respectively. Micro-flotation tests were also done at different redox potential conditions so that the effect of the surface oxidation of enargite was evaluated in seawater. The results indicate that the recovery of copper from enargite is reduced in seawater compared to fresh water, in particular at the pH values close to those of the formation of the first hydroxy complexes of Mg and Ca. In general, the experimental data indicate that the floatability of enargite is strongly affected when seawater is used, in particular at oxidizing conditions. These results suggest that Mg2+ and Ca2+ ions contained in seawater interact with the surface of enargite forming hydrophilic species.

Jan 1, 2018

By J. Killian, S. Cox

Many questions exist within the geotechnical industry as to the applicability of Strength Reduction Factor (SRF) values to the design acceptance criteria (DAC) of mining operations. There are many factors that contribute to changes in the SRF estimate, some of which are numerical (e.g. dilation angle) and some of which are geometric (e.g. model grid size)[1]. Numerous studies have confirmed equivalent values of SRF and FOS are found for soil slopes of limited height as presented in, [2] and [3]. However, significant deviation of the SRF value was observed for highly cohesive materials (rock slopes) of heights typically encountered in mining, [4]. This paper builds on the work presented in [4], providing a more rigorous examination of the modeling parameters that control the SRF estimate. The failure mechanism assumed for this study was a simple circular shear surface in a uniform material. Both LEM and numerical methods are suited well for analysis of this failure mechanism. A parametric study was completed to evaluate and test the relationships of key numerical variables that affect the estimated value of the SRF using Itasca’s Fast Lagrangian Analysis of Continua (FLACTM) software. The effect of groundwater has been tested and may be significant but is not presented as part of this body of work for brevity and simplicity of presentation.

Mar 2, 2022