Search Documents

By C. R. Austin

IN a recent paper1 the authors presented information on a refinement of the Rohn type of creep test with data on pure iron that exemplified the behavior of the apparatus. The present paper extends that work to nickel and cobalt and to the examination of the comparative high-temperature properties of two widely used commercial alloys. Careful attention has been given to the effect of plastic deformation in decreas-ing creep rate, using the elementary metals iron, nickel and cobalt for purposes of analysis. In any, endeavor to develop new materials for high-temperature service one soon encounters a real problem as to the sort of test to be employed in evaluating the commercial possibilities of the alloys. At one time it was considered satisfactory to determine the tensile strengths at elevated temperatures and to use these values as a criterion for the commercial application of the alloys. More recently the proportional limit has been used as a means of classification. Data obtained from a form of bend test has also shown promise as providing a "merit index" of high-temperature serviceability.2 Koerber and Pomp3 state that since the influence of testing time is small, the high-temperature yield point of steel furnishes sufficiently reliable and concordant values up to about 350° C. (and a maximum of

Jan 1, 1934

By Sushil Bhandari, S. S. Rathore

Controlled drilling and blasting continue to be an important method of block production and for block splitting. Drill and blast technique has disadvantage that sometimes, it produces cracks in uncontrolled manner and also produces micro cracks in the block as well as in remaining rock, if not carefully carried out. Recovery by this method is low compared to other methods. Therefore, attempts have continued to develop controlled growth of crack in desired direction. In this paper a series of tests are described using detonating fuse in marble. Economics of different methods is also compared. In comparison to conventional use when holes are lined with inexpensive cardboard or plastic liners with a slit, the cost and damage is the least and development of crack is in desired direction.

Jan 1, 2002

By Martín A. Encinas-Romero, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, Patricia Guerrero-Germán, José R. Parga-Torres, Luis S. Quiróz-Castillo, JESÚS L. VALENZUELA-GARCÍA

Pressure oxidation is a hydrometallurgical oxidative pretreatment for refractory ores, such as sulfide ores. Here, simultaneous alkaline pressure oxidation and sodium cyanide leaching treatments were carried out on a pyritic ore from the Mulatos Mine located in Sahuaripa, Sonora, Mexico. Mineral characterization, agitation leaching, hot cyanidation under atmospheric pressure conditions, simultaneous moderated pressure oxidation and leaching, and kinetic testing results are shown. The modified variables were temperature, pressure, and cyanide concentration. Characterization indicated that pyrite was the main mineral. Simultaneous pressure oxidation and leaching experiments were conducted at a temperature range of 40–80 °C, oxygen pressure of 87.5–200 psi, and cyanide concentration of 0.8–1.2 wt% in a 2-L Parr pressure reactor. A dissolution rate of 81–86% was achieved under the following conditions: 87.5 psi, 80 °C, 0.8 wt% NaCN, for 1 h.

May 7, 2020

By M. A. ENCINAS-ROMERO, G. TIBURCIO-MUNIVE, P. GUERRERO-GERMÁN, M. M. SALAZAR-CAMPOY, J. L. Valenzuela-García, L. S. QUIRÓZ-CASTILLO, J. R. PARGA-TORRES

Simultaneous alkaline pressure oxidation and sodium cyanide leaching treatments on a pyritic ore from Mulatos Mine located in Sahuaripa, Sonora, Mexico, were carried out. Mineral characterization, agitated leaching, hot cyanidation under atmospheric pressure conditions, simultaneous moderated pressure oxidation and leaching, and kinetic tests results are shown. The modified variables were temperature, pressure, and cyanide concentration. Characterization indicated that pyrite was the main mineral. Simultaneous pressure oxidation and leaching experiments were conducted in a temperature range of 40 to 80 °C, an oxygen pressure range of 87.5 to 200 psi, and cyanide concentration range of 0.8 to 1.2 weight percent in a 2-L Parr pressure reactor. Dissolution rates of 81 to 86 percent were achieved under the following conditions: 87.5 psi, 80 °C, 0.8 weight percent NaCN and processing time of one hour.

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By E Donskoi

In order to develop downstream processing routines for iron ore and to understand the behaviour of the ore during such processing, extensive mineralogical characterisation is required. To determine mineral associations, mineral liberation and grain size distribution, imaging techniques have to be used. There are two main imaging techniques used for the characterisation of iron ore, ie, Optical Image Analysis (OIA) and Scanning Electron Microscopy (SEM). In this article a QEMSCANTM system is used as an example of SEM methodology and results obtained from it are compared against results obtained by the CSIRO ‘Recognition3/Mineral3’ OIA system.Both OIA and QEMSCANTM systems have advantages and drawbacks. Even though the latest QEMSCANTM systems can distinguish between major iron oxides and oxyhydroxides, it is still problematic for QEMSCANTM to distinguish between iron ore minerals very close in oxygen content, eg haematite and hydroheamatite, or between different types of vitreous goethite.QEMSCANTM also can misidentify minerals with close chemical composition, ie haematite as magnetite and vitreous goethite as haematite. In OIA, iron minerals with slight differences in their oxidation or hydration state are more easily and directly recognisable by correlation with their reflectivity. In both methods, the presence of microporosity can result in some misidentification, but in SEM methods misidentifi cations due to microporosity can be critical. Low resolution during QEMSCANTM analysis can significantly affect the textural classifi cation of particle sections.The main conclusion of this study is that, for low iron content ores or tailings, QEMSCANTM can provide much more detailed information on the gangue minerals than OIA. However, for routine characterisation of iron ores with high iron content and containing a variety of iron oxides and oxyhydroxides, OIA is a faster, more cost-effective and more reliable method of iron ore characterisation. A combined approach using both techniques will provide the most detailed understanding of iron ore samples being characterised.

Jul 11, 2011

By M. Evertsson, K. Bhadani, E. Hulthén, M. Bengtsson

"Modelling and simulations for mineral processing plants have been successful in replicating and predicting predefined scenarios of an operating plant. However, there is a need to explore and increase the potential of such simulations to make them attractive for users. One of the tools to increase the attractiveness of the simulations is through applying optimization schemes. Optimization schemes, applied on mineral processing simulations, can identify non-intuitive solutions for a given problem. The problem definition itself is subjective in nature and is dependent on the purpose of the operating plant. The scope of this paper is to demonstrate two optimization schemes: Multi-Objective Optimization (MOO) using a Genetic Algorithm (GA) and Multi-Disciplinary Optimization (MDO) using an Individual Discipline Feasible (IDF) approach. A two stage coarse comminution plant is used as a case plant to demonstrate the applicability of the two optimization schemes. The two schemes are compared based on the problem formulations, types of result and computation time. Results show that the two optimization schemes are suitable in generating solutions to a defined problem and both schemes can be used together to produce complementary results. INTRODUCTION The comminution process for a mineral processing plant consists of multiple crushing and classification stages and aims to produce fine material to liberate ore from the minerals. The modelling and simulation of such processes are well established using static process models (King, 2001; Napier-Munn et al., 1996). A recent development in the dynamic modelling for such processes has shown further increase in fidelity compared to the static process models (Asbjörnsson, 2015). The developed simulations can be utilized to design, operate and control mineral processing plants based on the requirements of users (Bhadani et al., 2017). Typically, the requirements in the operation of the comminution process are conflicting in nature, as for instance, reduction of power draw by process units, maximization of production of fine materials, and increasing utilization of the process units. These conflicting requirements leads to a Multi-Objective Optimization (MOO) problem to operate a mineral processing plant. The MOO problems are normally referred to as non-linear problems and its fundamental understanding with respect to process behaviour is difficult to achieve."

Jan 1, 2018

By S K. Michelic, N Preisser

For certain applications, steels have to feature a very distinct and well-defined level of cleanness in terms of the number and composition of non-metallic inclusions. Therefore, one crucial aspect of steelmaking is removing and controlling said non-metallic inclusions during the process. Particle removal during ladle refining comprises three stages, namely: 1. Flotation 2. Transport through the steel/slag interface 3. Dissolution of the particle in the slag. Only if all three stages are completed the particle can be considered as fully removed from the steel melt which, in turn, leads to the slag being one of the most influential parameters for inclusion removal and control. Depending on the composition of the particles and the slag, the dissolution can be controlled by different mechanisms. This study focuses on the diffusion-controlled dissolution of solid oxidic particles in slags. For this, a model of particle dissolution has been developed. For modelling diffusion, either the differential equation following Fick’s second law can be solved, or an analytical solution to this equation valid for stationary interfaces can be used. Both approaches allow for calculations of concentration profiles of the dissolving species in surrounding slag. From this, the mass flux can be derived, which finally leads to calculating the boundary layer velocity due to considerations of mass balance. In this work, both methods as well as results of dissolution experiments using High Temperature Confocal Scanning Laser Microscopy are compared. This research aims to provide a framework for diffusion-based dissolution modelling in further expanding the understanding of particle dissolution in secondary metallurgy.

Aug 21, 2024

By F. Wendling, R. C. Nascimento, S. S. Wendling

"The objective of this research is to study the quality of blast-furnace iron ore pellets with binary basicity 1 fired on a pilot scale using the two main firing processes that are presently in use in the world and comparing them. Currently, the great majority of pellet producers use the traveling grate process because of its higher production capacity. In this study, the physical and chemical qualities of the pellet feed, limestone, anthracite and bentonite were determined and the amount of additives for a blast furnace pellet with the defined basicity was calculated. The physical properties of the green and dried pellets were determined accordingly. Produced pellets, after being fired on a pilot scale using traveling grate and grate kiln, were subjected to chemical analysis and physical testing. No significant difference was observed in the metallurgical quality — that is, reducibility index (RI), reducing disintegration index (RDI) and swelling index (SWI) — of the pellets produced by both processes. However, a comparison of cold physical tests — tumble and cold compression strength — shows improved quality of the pellets fired using the grate kiln process.IntroductionThe development of human civilization owes much to iron and steel (Sun et al., 2015). Iron is the most used metal in the world, and it is the main component of steel, which is present in materials for structural engineering, automotive and general industrial applications (Liu et al., 2014). Increased global demand has led to a decrease in the resources of ore with high iron content (Zhang et al., 2015), and currently 95 percent of the iron ore in China needs processing before smelting as its iron (Fe) content is only about 30 percent on average (Liu et al., 2014).Pelletizing is a process to economically agglomerate iron ore pellet feed into pellet form. After balling, green pellets are conveyed to the final step of the manufacturing process (Pena, 1982). The process is a multifaceted one, involving high temperatures, air flow gas turbulence and complex equipment geometry (Larsson et al., 2009). The pellets are fed into blast furnaces, which are now predominantly used in the extraction of iron. Ore processing also requires physical separation, including crushing, grinding and water removal (Sun et al., 2015).The increase in steel consumption favors the exploitation of low-concentration ores and the production of pellets (Halt and Kawatra, 2014). Pellet quality is affected by various factors, such as their physical and chemical characteristics and their temperatures and residence times in the furnace (Halt, Silva and Kawatra, 2015). Different geological settings lead to a wide range of different minerals (Graça et al., 2015).This work aims to generate important information for the pellet industry in the area of physical and metallurgical qualities of the agglomerates obtained by two processes: traveling grate and grate kiln."

Jan 1, 2017

By E M. Rykaart

The design of soil covers as part of the remediation initiatives for mine waste facilities is common practice and more and more engineers are faced with designing these facilities. The design issues associated with these soil covers are complex and requires a good understanding of unsaturated flow. More engineers are making use of numerical models to predict how cover designs would perform, and this has been necessitated by the high non-linearity associated with solving unsaturated flow problems. There are numerous numerical models available to the prospective users and they are all simplifications of reality using different assumptions. The users of these models often do not understand the limitations of the models but rather select a model based on ease of use, and that lends to increasingly erroneous designs being proposed for construction. This paper describes a comparative evaluation of a cover design using four different codes available today; SoilCover, SWIM, HYDRUS-2D and HELP. The paper does not propose to measure these codes up against each other and make statements about which is better than the other but rather illustrates how the assumptions in each code affect the outcome. The data set used for the comparative study is a well calibrated data set that that has been collected over a long period in time and that has been collected according to strict controls. The authors present the pitfalls of numerical modelling of the surface flux boundary conditions, as well as present guidelines towards appropriate use of these modelling tools.

Jan 1, 2003

By J. R. B. Lima

The present work emphasizes the selection in the separation of the apatite/calcite by the direct anionic flotation versus the double flotation, with a reverse second stage of the Jacupiranga phosphate ore. The double flotation would allow the obtaining of two concentrated solutions: one of them mainly constituted by a calcium carbonate material (CaCO3) and the other one, phosphatic (apatite). The calcium carbonate concentrated solution is used for the production of cement. The presence of phosphatic material in the calcium solution is not desirable, phosphor being a harmful element to cement. On the other hand, smaller quantities of calcite in the phosphate concentrate would represent a substantial economy in the processes of production of phosphated fertilizers. These processes make use of sulfuric acid to the solubilization of the apatite and the presence of calcium material consumes acid. Also that, when carbonates are solubilized, unwanted products are formed resulting in losses in the process and diminishing the quality of the fertilizer produced. These characteristics are discussed in the paper and are compared to another Brazilian phosphate ore, the reverse route of which can be considered more adequate. The results are discussed according to recent discoveries, and special emphasis is given to the use of corn starch and its crucial role in promoting the selection in the direct flotation process.

Jan 1, 1993

By P. N. Anyalebechi

The effects of solidification rate on the cast microstructures of aluminum alloys 6009 and 6016 have been investigated with directionally cooled laboratory-size ingots, at 0.2-10.1 K/s and 0.4- 23.1 K/s, respectively. These ranges of solidification rate are within those observed in commercial-size ingots. In both alloys, the average dendrite cell size and second phase particle size decreased with increase in average solidification rate and with a decrease in average local solidification time. However, at comparable solidification rates, the dendrite cells and second phase particles are finer in the shorter freezing range alloy 6009 than in the longer freezing range alloy 6016. This is provisionally attributed to the earlier formation of second phase intermetallics at higher temperatures during solidification and to the formation of greater amount of the relatively coarse plate-like ß -phase (Al9Fe2Si4) phases in alloy 6016. In general, in both alloys, the types and relative amounts of the second phase particles in both alloys are independent of solidification rate.

Jan 1, 2006

By Harvey P. Knudsen, Young C. Kim, Edward Mueller

Abstract-This paper describes the results of a comparative study of the geostatistical ore reserve estimation method over three conventional methods; the polygon method, the inverse of the distance squared (IDS) method, and ELIP which is similar to IDS. Each method was evaluated on its ability to accurately predict individual block grades for one bench of the Pima mine, located near Tucson, Ariz. Results at the Pima mine indicate that the geostatistical method is no better or worse in predicting block grades and total tonnage than the ELIP or IDS methods. In contrast, the polygon method is clearly inferior. All of the methods would have given better results if geology had been included in the block model. At already producing mines ELIP or IDS may be good choices since they involve substantially less cost in computer time. For prospective or new properties the geostatistical model is more attractive due to its ability to construct confidence limits on the estimates.

Jan 1, 1978

By C. Rodrigues

This investigation compares the gas adsorption behaviour and capacity of three bituminous coals from South Africa, of similar rank, by assessing the characteristics of the raw coal, as well as the resulting float and sink fractions (at 1.80 cm3/g) obtained by density separation of crushed coal samples. Calculations were also made to obtain the raw coal gas storage capacity from the weighted contribution of both float and sink fractions results, thereby permitting comparison with the analysed results of the raw coal. The study demonstrated that the clean fraction of a coal has the highest capacity to retain gas in the sorbed state, followed by raw coal, and lastly the sink fraction, and re?confirmed previous investigations that showed minerals to be inhibitors of gas adsorption and retention.

Jan 1, 2008

By Anne C. Chinellato, Alejandra T. Soria, Nelida L. del Mastro, Amanda C. S. Pereiral, Esperidiana A. B. Moura, Anibal V. Abreu

"This work presents a comparative study of the thermo-mechanical and morphological properties of sugarcane bagasse fiber/HDPE composite treated with electron-beam and gamma radiation. The composite samples obtained by extrusion and injection molding processes were irradiated at 50 and 90 kGy using either a 1.5 MeV electron beam accelerator or gamma irradiator EMI-9, at room temperature in presence of air. The irradiated and non-irradiated samples were submitted to mechanical and MPI tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), sol-gel analysis and X-Rays Diffraction (XRD) and the correlation between their properties was discussed. Improvement of the bagasse fiber/HDPE composite properties, using electron-beam or gamma radiation, was found.IntroductionResidues of sugarcane bagasse fiber are widely produced in Latin America and other countries: in Southern Africa, Egypt, South-Eastern Asia, India, China, Australia, Cuba, among other producers, as by-products of the sugar and bioethanol industry. The sugarcane industry in Brazil and Uruguay is well established and expanding with large potential to increase the production of sugarcane bagasse in the next years [1-3]. Although the major portion of the bagasse is currently burnt for energy supply in the sugarcane industry, the disposal of this byproduct is still inefficient and, consequently, it is critical for agricu1ture profitability and environmental protection. Sugarcane bagasse is a lignocellu1ose fiber mainly constituted by around 46 % cellu1ose, containing hemicellu1ose, lignin, fat and waxes, silica and other elements [3, 4]. Studies have reported that sugarcane bagasse can be used to produce thermoplastic polymeric composites with excellent properties for many applications. [5-8]. Based on this survey, the transformation of bagasse into high quality industrial products, such as bagasse-polymer composites, can provide its more effective utilization."

Jan 1, 2012

By J. R. Diehl, R. W. Lai, R. W. Hammack, S. U. M. Khan

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of a selected coal pyrite and a mineral pyrite. Surface properties of pyrite were evaluated in terms of flotation response in the presence of both an anionic fluorosurfactant and sodium hydrosulfide. The charge transfer adsorption and oxidation potential of sodium hydrosulfide were evaluated using cyclic voltammetry. Drastic differences in the flotation response have been observed between the coal pyrite and the mineral pyrite. Significant differences in the cyclic voltammograms at pyrite surfaces of these two sources were also observed. Measurements by XPS and EGA were used to determine the oxidation products and the rate of oxidation of the coal-pyrite and the mineral-pyrite surfaces.

Jan 1, 1991

By R. W. Lai

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of coal pyrite and mineral pyrite.

Jan 1, 1989

By N. A. Chapman

The effect of using conventional crushing and HPGR in combination with dry or wet milling was investigated using a base metal sulphide (sphalerite), and a PGM (platinum group minerals) ore in order to determine how these different processes affect the flotation performance. In the case of sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc. Conversely, in the case of PGMs, a similar treatment produced the poorest results. The results were investigated further by comparing the relative effects of factors such as percentage liberation, particle size, and surface properties of the samples produced by the different milling procedures as well as the concentrates and tailings obtained from the flotation tests.

Jan 1, 2013

By C. Hosten, K. V. S. Sastry, D. J. Kawulok-Englund

Since the last decade the iron ore processing industry has undergone drastic changes from supplying screened and natural ores to manufacturing tailored concentrates and pellets. Increased need for the beneficiation of lower grade iron ore deposits and the increased demand for higher grade concentrates necessitate finer grinding of iron ores before concentration. The normal filtration stations used in the past are experiencing difficulties in dewatering the finely ground concentrates to moisture levels acceptable for balling. In addition to finer grinding, applications of complex beneficiation techniques has decreased the filterability of the concentrates and create problems in filtration of iron ore concentrates. An overview of the filtration literature indicates there are few research reports on the dewatering of iron ore concentrate slurries. There exists a need to understand the principles and mechanisms involved in the filtration of iron ore concentrate slurries with a goal of developing more efficient filtration techniques. This paper presents the results from the first phase of our research program that included the development of a reproducible benchscale filtration technique and the investigation of the filtration behavior of eight iron ore concentrates.

Jan 1, 1984

By Dyego Monteiro de Souza

This study compares the wear resistance of specimens lubricated with biofluids or mineral oil. Tribological studies were performed by ball-cratering test. In these tests were used as lubricants epoxidized soybean oil, castor oil and mineral oil. The specimens used were untreated and nitrided AISI 4140, while a steel ball AISI 52100 was used as a counterbody. In order to analyze the results obtained, the worn volume was calculated and the characterization of the crater, after the test, was made using optical microscopy and SEM. Wettability was also measured for the different surface condition and lubricants. As expected both specimens showed a smaller volume worn when lubricated with mineral oil due to inherent properties of this type of lubricant. Among the vegetable oils studied, the castor oil showed a better performance in the lubrication of the specimens untreated while on the nitrided specimen have shown less wear when lubricated with epoxidized soybean oil, indicating a difference in the efficiency of oils, as lubricants, depending on the surface conditions of the mechanical components.

Jul 31, 2018