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By D. R. Taylor, R. G. Goss

The use of clay granules as carriers for pesticides dates from the early 1940's and by the present day represents a business conservatively estimated at between 200 - 300 thousand tons / year in the U.S. alone. Aside from economic and specific target pest efficacy advantages, the use of clay granules as pesticide carriers also delivers a number of environmental benefits which will be reviewed. Topics to be discussed will include: 1) drift control (versus liquid sprays), 2) mobility (in the environment), 3) worker safety, and 4) transportation (spill) safety.

Jan 1, 1999

By Robert W. Carn

This paper presents the concepts which are presently being utilized in the design of coal export terminals. Criteria for selecting a viable site and establishing the terminal plan are presented. Factors affecting the design of the terminal as well as the present techniques and procedures in use today to determine the optimum use of equipment will be discussed along with the current trends in export terminal control systems. Finally capital and operating costs for a typical export terminal are reviewed.

Jan 1, 1982

By Stephen R. Holsinger

During the year of 1972 ASARCO's Silver Bell embarked upon a project that would test a modified grinding circuit using direct digital compute against the performance of its other five grinding lines, implementation and subsequent outcome of that project has been previously reported in a paper by Pitts, et al. The main purpose of the present paper will be to describe major problems incurred during the implementation of this control strategy on the remaining five primary grinding lines and their solutions. Also included will be a discussion of changes made in operating philosophy and methods used since that report was written. Description The Silver Bell concentrator is a 10,436 tonne/day copper sulfide plant supplied by ore from two separate open pits approximately 4 km. apart. As well as receiving ore from these two main pits, ore is received from several exten¬sions of both pits. The ore bodies are variable in rock type and the extensions have increased this variability. Grinding is carried out by six primary, single-stage, 3.20M x 3.66M Allis Chalmers grate discharge ball mills in closed circuit with four Krebs D20B cyclones (Fig. 1). Each of these grinding circuits is controlled by four independent but interactive control elements. These control elements are the fresh ore feed, the water added to the feed end of the mill, the water added to the ball mill discharge sump, and the cyclone feed pump speed. At the present time, instrumentation for measuring primary process variables consists of Merrick weightometers for fresh ore feed, orifice plates coupled with differential pressure transmitters (dp's) for incoming water measurements, back-pressure diaphragm coupled with a dp for estimating ball mill discharge sump level, a magnetic flowmeter for determining cyclone feed velocity and a nuclear density gauge for measuring cyclone feed density. All measuring instruments develop electrical signals that are measured as 2-10 V DC "inputs o the computer interface.

Jan 1, 1977

By M. R. Yenchek

Faulty insulators on mine trolley/track haulageways may allow the flow of leakage currents into the mine roof and ultimately result in combustion of the local roof material. The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), has devised a passive means to detect overheating insulators on direct current systems. The detector consists of a spring-loaded cartridge that ejects a reflective streamer of white Teflon tape when subjected to elevated temperatures. The cartridge assembly can be easily installed over the outer metallic shell of an existing trolley line insulator. If an insulator overheats due to ground leakage currents, the visible streamer alerts mine personnel traveling on the haulageway.

Jan 1, 1998

By Liaqat Ali, Robert Chapman, Asghar Ali, Mohammad Tahir Shah, Seema AnjumKhattak, Mohammad Farhan

Alluvial gold is abundant in the Quaternary deposits of the Kabul and Indus rivers in District Nowshera, Khyber Pakhtunkhwa, Pakistan. Understanding the provenance of alluvial gold using morphology and elemental composition could be helpful in developing an exploration strategy of regional benefit. Detailed morphological studies of gold grains revealed high flatness index values which are indicative of a distal source. Compositional studies of 58 gold grains using SEM and EMPA showed broadly similar Ag ranges (1– 15 wt%) for each sample and occasional Cu values in individual gold particles to 0.4 wt%.Whilst the Ag profile is not diagnostic, the Cu values are compatible with derivation from either porphyry systems or ultrabasic rocks. The complex geology of the drainage catchments could host gold mineralization of other styles, but larger sample suites would be required to refine the current interpretation to establish whether particles which are simple Au-Ag alloys could be derived fromorogenic or epithermal sources. This scoping study has demonstrated that the compositional and morphological studies of gold grains are useful in providing information regarding the nature and location of the source of placer gold in areas where there is limited information on the nature and location of in situ mineralization.

Oct 6, 2020

By Yushuai Xian, Youjun Tao, Fangyuan Ma

This study compared particle size distribution and density distribution of crushed products for waste printed circuit boards (WPCBs) before and after heat treatment. The crushing process for heat-treated WPCBs is a selective crushing process; more metal is concentrated in the coarse particle range of 1.0–0.5 mm and high density range of 2.8–2.96 g/cm3. WPCBs were separated using the Falcon separator to recycle useful metals. The Box-Behnken module of Design-Expert was used to obtain optimal separation parameters, namely, rotational frequency of 25 Hz, recoil water pressure of 0.025 Mpa and feed speed of 34 ml/s. On this basis, the separation indexes for WPCBs with and without heat treatment were compared. Experimental results show that the recovery effect is better for heat-treatedWPCBs than for thosewithout heat treatment. Comparedwith the non-heattreatedWPCBs, the product grade of heat-treated WPCBs is 1.95% higher, and its recovery is improved by about 14%. Finally, characteristics ofWPCBs before and after heat treatment were analyzed on the basis of stress experiments and scanning electron microscopy (SEM), respectively. Results of mechanical characterization indicate that the stress experiment for non-heat-treated WPCBs has a maximumpressure load of 212 N and displacement of 20mm, but heat-treatedWPCBs only need 140 N stress and 14 mm displacement. SEM shows that copper foil and fiberglass cloth are deformed in different directions and sizes after heat treatment to form gaps, which promote liberation of copper foil and fiberglass cloth.

Sep 10, 2020

By Mahaboob Basha Shaik, Shakuntala Tudu, Indrajit Paul, Chandra Sekhar, Neha Gupta, Amit Kumar, Srinivas Dwarapudi, Arvind Kumar Patel

In this study, the effect of colemanite and calcined colemanite (CC) addition on the properties of iron ore pellets is studied. The pellets are prepared in a lab without and with 0.2% colemanite and varying amounts of CC from 0 to 1.0 wt%in steps of 0.2%. A reference pellet is prepared under typical plant conditions, and the properties of the reference pellet are considered as the base value for improving the cold compressive strength (CCS) while maintaining the other parameters at an acceptable limit without altering the pellet. The study also aims to provide a detailed characterization of colemanite and calcined colemanite to better understand their behaviour during firing. The lab-scale results show that the CCS of pellets made with 0.2% colemanite was reduced by 222 points (60%) as compared to the reference pellets due to crack formation during firing. The results show an improvement in the CCS of the indurated pellets with CC dosage up to 0.4%, and decreasing strength is noted thereafter. It is observed that the swelling index increases with the increase in calcined colemanite dosage. To simulate plant conditions, reference pellets and pellets with optimized CC dosage were fired in a plant furnace.

Oct 16, 2020

By Mehmet Bugdayci, Onuralp Yücel, Yeliz Demiray Cucurachi, Ahmet Turan

The production of strontium (Sr) metal from its oxide via an aluminothermic process under 1–5 mbar pressure was examined in this study. SrO of 99%purity by weight was used in the experiments. The effects of stoichiometry and the duration of the process on the efficiency ratio of the metallic strontium were examined. The effects of functional additives (BaO, CaO, CaC2) were also examined. Characterization was carried out using X-ray diffraction spectrometry (XRD), atomic absorption spectrometry (AAS) and flame photometry techniques. The highest Sr efficiency ratio obtained was 96.89% in the experiment conducted at 1250 °C with 300% Al stoichiometry and 300% BaO stoichiometry.

Aug 7, 2020

By Ramiro da Conceição do Nascimento, Horst Guenter Feldhagen, Rafael Piumatti de Oliveira

Mixed hydroxide precipitate (MHP) is a nickel intermediate product that has economical benefits to downstream leaching of lateritic marginal ores. Usually, this product is subsequently processed and refined to produce nickel by hydrometallurgy, but an alternative route can be made integrating hydrometallurgy and pyrometallurgy. Assessing the overall consumption of ferroalloys to obtain stainless steel, as an increasing practice performed in China, the synergy of nickel extraction from laterites by leaching and precipitation asMHP with the production ofMHP agglomerates applied as rawmaterial to furnaces of ferronickel production is a very attractive practice. This work aims to further the technological development of an agglomerated product feasible to hydro-pyro integration. The agglomeration experiments were performed by traditional pelletizing (firing the pellets) and cold bonded pelletizing (aging the pellets by appropriate stocking). Appropriate compositionswere prepared withMHP, additives and binders for each of these routes. A specific study of binder composition was made to find an adequate melting point. The produced pellets were tested to prove their properties by crushing strength tests. The standardization applied to iron ore was followed. The best result of crushing strength was 98.52 daN/pellet. The agglomerates with approved crushing strength for use in electric furnaces were smelted to produce alloys containing nickel; the agglomerates were characterized by scanning electron microscopy. The alloy obtained was metallic ferronickel with sulphide precipitates. Therefore, MHP pellets can be precursors of nickel alloys, which have to be refined to obtain the desirable composition.

Jul 6, 2020

By Justin R. Patts, Andrew B. Cecala, A. KYLE LOUK, Emily J. Haas

The National Institute for Occupational Safety and Health (NIOSH) and the former U.S. Bureau ofMines (USBM) have given a significant effort over the past four decades in researching and developing engineering controls and interventions to reduce mine workers’ dust exposures during the bagging and palletizing of industrial minerals. Workers performing manual bagging and palletizing of 50- to 100-pound bags typically have some of the highest dust exposures of all workers at mining and mineral processing operations. This paper will provide an overview of available dust control technologies for bagging operations and present the findings of a recent case study that was conducted at four different industrial sand operations to identify the current types of bagging and palletizing technologies being used and to evaluate their effectiveness in reducing workers’ exposures to respirable crystalline silica dust. An evaluation will also be performed to determine if further reductions in respirable dust levels can be achieved by incorporating additional modifications or improvements into the existing technology.

Apr 3, 2020

By Fahimeh Dehghani, Louis Ackah, Tathagata Ghosh, Justin Godbold, Jia Liu, Meisam Peiravi, Manoj Mohanty, Azam Baharlouei

Primary economical deposits of rare-earth elements (REEs) are exhausting all over the world, and it has become necessary to find new sources and methods for their extraction. In addition, increasing the application of REEs in modern technological society has increased its demand globally. One of the important movements to compensate for the future shortages of critical metals is the recovery of REEs from recyclable materials. This paper presents a review of the classification and extraction methods, as well as general applications of REEs with emphasis on secondary sources such as coal and coal byproducts, iron ore tailings, apatite, and phosphate byproducts. An overview of the current state of knowledge on the various methods of REE beneficiation and extraction is covered. These methods include physical separation, as well as hydrometallurgical and bio-hydrometallurgical techniques. The application of these REE extraction techniques for enhanced recovery has been driven primarily by the unique industrial application of these important elements. This paper further explores the existing and potential environmental challenges associated with REE extraction. The authors have presented a wide array of literature, in-depth discussion of the subject, and a succinct summary of processes and relevant case studies.

Sep 23, 2020

By Isabel F. Barton, Matthew J. Gabriel, CARSON ROBERTS, JOHN LYONS-BARAL, LEON DUPLESSIS, Mark D. Barton

Geometallurgical assessment of orebodies in the mining industry typically relies on bench-scale or lab-based characterization techniques. In this study, we investigate drone- and tripod-based field hyperspectral imaging as a potential addition to the geometallurgy toolkit in multiple applications. This pilot study tests hyperspectral imaging for largescale mineral mapping in and around the active Lisbon Valley copper mine, including natural exposures, previously producing U-V mines, highwalls, dumps, and leaching sites. Tests include different (supervised and unsupervised) mineral data classification methods, varying mineral spectral reference libraries, comparison with ground-truth geological and spectroscopic mapping and sampling, and integration with LiDAR data. The results show that hyperspectral scans can produce spatially registered maps of the distribution of different spectrally active mineral types over dumps, highwalls, leach pads, and natural outcrops. Clays, other phyllosilicates, carbonates, and sulfates showed up particularly well. The sensor was also able to distinguish dry from lixiviant-saturated areas and map different clay types on the leach pads, and shows promise for differentiating types and health of vegetation. These results suggest that hyperspectral imaging, if coupled with robust ground-truthing, can be a useful complement to existing geometallurgical techniques in the mining industry, such as geological mapping, blast hole sampling and automated mineralogy identifications, and handheld spectrometry. In particular, hyperspectral imaging has promise for mapping the distribution of acid-consuming minerals; mapping the distribution of swelling, sliming, and heap-blinding clays; and pinpointing problem areas on heap leach pad surfaces.

Feb 10, 2021

By S. K. Samal, B. Mishra, M. K. Mohanty, S. C. Mishra

Steelmaking industries consume the majority of chromium and manganese ferroalloys to impart several properties in steel and also for other purposes. The quality of ore governs the process kinetics as well as the process economy of the ferroalloy industry. The present study demonstrates the thermal transformation behavior of chromite and manganese ores with varying compositions. Simultaneous thermal analysis (DTA/TG) is employed for such ore samples where the transformation of mineral phases is correlated with the thermogram characteristics and quantified. Phase, microstructure, and compositional analysis results of individual ores corroborated with thermal analysis are in good agreement. Chromite samples are ferruginous with goethite and gibbsite contents, whereas manganese ores vary in composition and also exhibit multiple and/or overlapping transformations.

Jan 21, 2021

By Göksel Hızlı, Selim Ertürk, Ayşegül Bilen, Raşit Sezer, Cüneyt Arslan

The carbothermic reduction of celestite is the first step in producing many strontium products. The way materials move in the rotary kiln has an essential effect on the carbothermic reduction efficiency as well as the temperature. In this study, the reduction of celestite ore and excess carbon blend in a laboratory-scale rotary kiln was investigated. In the experiments carried out at three different temperatures, the rotational speed and slope of the furnace tube were altered, and their effects on the reaction efficiency were examined. The leachability of the reduced powders and the content of the unburned coke indicated the optimal parameters for the reaction.When the speed was increased to 10 rpm, the powders weremoremobile in the stack and could react more easily with the furnace atmosphere. According to the results, celestite can be reduced by carbon at temperatures of 1000–1200 °C, at rates of between 5% and 75%. The maximumreaction yield (75%) was obtained with a slope of 2° and a rotational speed of 6 rpm at 1100 °C.

May 7, 2020

By Jianping Zuo, Chunlei Zhang, Yong Zhang, Shouyang Gao

To study the fracture evolution of overlying strata for ascending mining in a short-distance coal seam group, a two-dimensional physical simulation model was designed based on a specific geological condition. The fracture development zone was divided into the compaction zone and active zone by monitoring and analyzing the macro fracture evolution of the surrounding rock mass during the excavation of multiple coal seams. The secondary fracture development process of the overlying strata was demonstrated with a physical model. The quantity, length, and inclination of the fracture were calculated with MATLAB software, and the results were verified by geological radar. The total number of fractures between two coal seams increased with a “parabola” shape during the excavation of the lower coal seam, the crack angle was mainly vertical and horizontal, and the number of horizontal cracks first increased and subsequently decreased; the excavation of the upper coal seam caused the secondary fracture development process of the overlying strata, and the relief range and its extent increased. The mining-induced cracks from the lower and upper coal seams connected with each other, especially the permanent vertical fracture in the cutting room side and face side. Finally, the three-dimensional gas fissure was formed.

Nov 24, 2020

By Mahmut Altiner

In the present study, the use of horse residue as an alternative reducing agent in the roasting of a low-grade goethite ore containing 17.60% Fe was investigated. Additional roasting experiments were carried out with corn starch and without reducing agent for comparison. Each roasted product was characterized using X-ray diffraction (XRD) and magnetic hysteresis (MH) loops analyses. The optimum roasting conditions (roasting temperature [400, 500, and 600 °C], reducing agent/ore ratio [0.04, 0.08, and 0.12], and roasting time [10, 20, and 30 min]) were investigated based on the Taguchi approach. The magnetic susceptibilities of the roasted sample with the addition of reducing agents were higher compared to that of the roasted sample in the absence of reducing agent. Experimental findings indicate that the horse residue can be used as the reducing agent. Finally, an iron ore concentrate assaying a Fe grade of 62.12% with a recovery of 56.93% was prepared using wet magnetic separation at a magnetic intensity of 0.5 T from the ore roasted under the following roasting conditions: roasting temperature of 500 °C, reducing agent/ sample ratio of 0.08, and roasting time of 30 min.

Jun 3, 2020

By SANDEEP KUMAR JENA

This review work reports the recovery of potassiumfromdifferent rocks and mineral sources. The global demand for potassiumis rising consistently due to the growth of agricultural production. A major portion of the world potassium production is consumed in making of fertiliser; however, other uses include those in pharmaceutical, glass, ceramic, food and detergent industries. The availability of soluble potash minerals (sylvite, kainite and carnallite) in different countries like Canada, USA, Israel and Russia makes them as major potash producers, whereas agricultural-based countries like Liberia, Somalia, Central African Republic, Thailand, Indonesia and Malaysia including India meet their potassium requirement through import only. On the contrary, the availability of huge potassium-bearing rocks/minerals (like nepheline syenite, feldspar, mica, glauconitic sandstone) in these countries containing around 4–17% K2O would be a prospective for commercial production of potassium. The potassium recovery from minerals/rocks is very complicated due to the uniform distribution of potassium throughout the crystal structure. Different physico-chemical separation methods like bioleaching, chemical leaching, flotation and roast leaching have been discussed for the successful recovery of potash values from these rocks/minerals. However, the recovery of potassium from hugely available seawater using the chemical precipitation, solvent extraction,membrane separation and ionic exchangemethods is not cost-effective due to the low concentration of potassium.

Aug 31, 2020

By Ihsan Berk Tulu, Mark Alexander Van Dyke, Deniz Tuncay, Ted M. Klemetti

Bleeder entries are critically important to longwall mining for the moving of supplies, personnel, and the dilution of mine air contaminants. By design, these entries must stay open for many years for ventilation. Standing supports in moderate cover bleeder entries were observed, numerically modeled, and instrumented by researchers at the National Institute for Occupational Safety and Health (NIOSH). The measurements of the installed borehole pressure cells (BPCs), standing support load cells and convergence meters, and roof extensometers are presented in this paper in addition to the numerical modeling results and visual observations made by the NIOSH researchers in the bleeder entries. The results include the effects of multiple panels being extracted in close proximity to the instrumented site as well as over one and a half years of aging. As expected, standing supports closer to the longwall gob showed the greatest load and convergence. The roof sag appeared generally independent of the proximity to the longwall gob. The BPC readings were driven by both the proximity to the gob and the depth into the pillar. The results of this study demonstrated that the entry roof can respond independently of the pillar and standing support loading. In addition, the rear abutment stress experienced by this bleeder entry design was minimal. The closer the mine development, pillar, or supports are to the gob, the greater the applied load due to rear abutment stress.

Jan 7, 2021

By MOHAMED WAEL, ANASTASIA GOEVA, ABDULAZIZ TAWFEEQI, IHTISHAM TARIQ, S. M. ZAKIR HOSSAIN, NIAZ ALI KHAN, MUHAMMAD FAISAL IRFAN

Carbon capture and storage (CCS) is an attractive area of research in such fields as CO2 mineral carbonation, global warming and sustainable energy systems. In this study, carbonation efficiency for aqueous mineral carbonation (MC) was achieved through two steps,which include leaching of calciumfrom cement kiln dust (CKD) followed by the reaction of pure CO2 with the calcium hydroxide precipitates formed by the hydroxylation using NaOH. Response surface methodology (RSM) with a Box-Behnken design (BBD) was applied to optimize the calciumleaching yield,while the carbonation efficiency from CKD was assessed using RSMwith central composite design (CCD). Optimization of calcium leaching is highly important, as it is a rate-limiting reaction step in MC and also influences and enhances carbonation efficiency. Different parameters including acid concentration (HNO3), leaching temperature, leaching time, and dose of CKD sample were considered in order to optimize the maximum yield of Ca leaching from the CKD sample. In addition, different CO2 flow rates and temperatures were used as parameters for optimizing carbonation efficiency. Two quadratic regression models were developed for each process, i.e. calciumleaching and carbonation. For calcium leaching, a maximum of 98.55% calcium was extracted under the optimal set of acid concentration 4.13 M, 90 °C, 28 min leaching time, and 13.8 g of CKD sample. For carbonation, the maximum carbonation efficiency of 89.2% was achieved for a CO2 flow rate of 1163 cm3/min at 90 °C. Calcium leaching results indicate that the leaching yield was significantly affected by all the input parameters except leaching time. For carbonation, both factors affected the carbonation efficiency, with the effect temperature shown to be greater than that of the CO2 flow rate. Additionally, the predicted results agreed well with the experimental values for both calcium leaching and carbonation processes, with errors of less than 1% and 5%, respectively.

Jun 5, 2020

By Serdar Aktaş, Burcu Nilgün Çetiner

According to critical statistical studies, antimony is one of the rarest elements in the world, and global resources could be exhausted by 2050. In light of these observations, its extraction will be costly due to poor-quality ore, deep mining, remote locations, and high energy consumption. In the present study, an alkaline leaching process was carried out on stibnite concentrate to evaluate the effect of reaction parameters on the percentage of antimony extraction. The leaching efficiencies of different sulfur and hydroxide sources were studied and compared to one another to create a better understanding of the reaction process. Kinetic models were investigated to identify the reaction pathway and calculate the activation energy. The activation energy of the stibnite dissolution was assessed as 19.13 kJ/mol using a two-dimensional diffusion-reaction model. The value of activation energy indicates the quantity of energy necessary for a reaction to proceed. As expected, potassium hydroxide leaching was significantly more successful than was sodium hydroxide; however, in terms of economics, the use of sodium hydroxide was found to be more cost-efficient. Interestingly, this finding indicated that caustic leaching is still the most effective method for stibnite extraction.

Jul 23, 2020