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By R. Fedel-Moen, R. W. L. Kimber, B. D. Williams, S. R. Ragusa

The use o f cyanide to extract gold from ores is widespread. In the process of extracting gold, cyanide may form metal cyanide complexes with a variety of other metals present in the ore. This study was carried out to investigate the biodegradation of the Cu(I)-cyanide complex and tetracyanonickelate under varying pH and nutrient additions. Detailed studies using shake flask cultures and bioreactors showed that naturally occurring bacteria residing on gold-leach-pad ore uti¬lized the Cu(I)-cyanide complex (CuCN) and tetracyano-nickelate, Na2(NiCN4), as carbon and/or nitrogen sources. Ammonium-nitrogen (NH4+-N) and/or cyanate (CNO-) accumulated in solution as the metal cyanide complexes were degraded. The accumulation of cyanate as a product is a concern due to its toxicity. Degradation rates were increased if a growth substrate (peptone, 0.1%) was added to the medium or if bioreactors were primed with peptone before addition of the metal-cyanide complex. Tetracyanonickelate was degraded at pH 8 without added peptone, but it was not degraded at pH 10. The addition of peptone was required for degradation of the Cu(I)-cyanide complex at pH 8 and pH 10. At pH 8, the addition of peptone resulted in the accumulation of cyanate, whereas, at pH 10, cyanate was not detected in the cultures. Biodegradation of metal-cyanide complexes was faster (approximately 1.5 to ten times faster) in bioreactors than in shake flask cultures. The addition of peptone was not required for degradation of metal-cyanide complexes in bioreactors. However, priming the bioreaetor with peptone resulted in higher metal-cyanide degradation rates over multiple cycles.

Jan 1, 2000

By J. David Lowell

The first part of this article is a review of industry techniques and styles during the past 50 years. It is followed by my career history during the same period. The second part covers my ideas about what works in mineral exploration. These include estimates about discovery costs, thoughts about education of explorationists, organization of exploration groups and my opinions about the relative value of exploration techniques. Evolution of exploration techniques [Table 1] shows the evolution of mineral exploration techniques and styles from 1950 to 2000. During the first half of that period, there was a progressive increase in exploration drilling. During the second half, there was a decrease in prospecting and an increase in high technology, indirect exploration and a rapid increase in discovery cost.

Jan 1, 2000

By N. Kuyucak

Acid rock drainage (ARD) resulting from the natural oxidation of sulfide mineral wastes has become a major concern to the mining industry, both during the operational period and after mine closure. ARD is generally characterized by high acidity and high concentrations of dissolved metals and sulfates. If the generation of acid cannot be prevented or controlled, it must be treated to eliminate acidity and to reduce the concentration of heavy metals and suspended solids before release to the environment. Microorganisms play an important catalytic role in the generation of ARD. Several prevention, control and treatment technologies that are based on microbiological activities have been developed. The role of microorganisms and biotechnology in the generation of ARD and their role in the methods used for prevention, control and treatment are discussed in this paper. Recently developed passive and biological treatment processes that have been implemented at mine sites are emphasized in this paper. Benefits, limitations and design criteria for passive biological processes are also presented.

Jan 1, 2000

By R. A. Jankowski

Laboratory tests were conducted to evaluate the silica collection efficiency of flooded-bed scrubbers using six different filter panel designs at two operating velocities. Test results indicated that reductions in filter density negatively impacted respirable dust collection. Silica collection efficiency for the least-dense filter was as much as 33 % lower than the collection efficiency of the most-dense filter. At the low operating velocity, the least-dense filter allowed more than 40% of the respirable silica dust in the scrubber intake air to pass through the unit and back into the mine environment. Operation of the scrubber at the higher test air velocity increased silica collection efficiency regardless of the filter panel tested The density of the filter panels also impacted the quantity of air moved through the scrubber, with higher-density filters reducing scrubber airflow. For each filter, the relationship between dust-collection efficiency and air-moving capacity must be considered to determine the overall effectiveness for each mine application.

Jan 1, 2000

By R. W. Smith, M. C. Fuerstenau, G. X. Xang

Nonliving dried water hyacinth (Eichhornia crassipes (Mart.) Solms) roots were investigated for the biosorption of cadmium, lead and other heavy metal ions from aqueous solutions. Dried water hyacinth roots, when suspended in solution, strongly and rapidly sorb several different metal ions. Factorssuch as reaction time, pH, the initial concentration of metal ions, the presence of other metal ions and biomass concentration were investigated. The adsorption was shown to follow the generalized Langmuir adsorption equation. The relative affinity of the roots for lead is greater than that for cadmium. The batch sorption kinetics of the uptake of cadmium and lead can be described by an apparent first-order reversible reaction model. The roots could be regenerated after the metal ions were stripped. Successful desorption of Cd and Pb from the biomass by acidic CaCl2 solutions revealed that the metal uptake phenomenon is reversible, implying physical sorption of Cd and Pb.

Jan 1, 2000

By C. R. Euston, B. T. Field, W. E. Lindquist

Pyroprocessing applications in the minerals industry range from low-temperature drying to high-temperature reactions. Material characteristics and process requirements range over a very broad spectrum and can confuse plant engineers trying to select a pyroprocessirtg system for their plant. This paper examines the important process variables and offers empirical guidelines to assist in a user's overall process evaluation.

Jan 1, 2000

By Gennaro G. Marino

During the preliminary design stages of the Illinois Division of Natural Resources(DNR) building, it was discovered that an old coal mine was present some 70 m (220 ft) beneath the building site. The new DNR building to be constructed is 36 m (120 ft)wide and 134 m (440 ft) long. It has three stories above grade and abasement level. The building is oriented north-south and has east and west ponds next to it (Fig. 1). The building is located on the State Fairgrounds in Springfield, IL. Given the history of surface subsidence of these underground coal mines in the Springfield area, there was concern about the potential for future subsidence at the building site. Mine subsidence events in the area have resulted in more than 0.9 m (3 ft) of settlement and have caused significant structural damage.

Jan 1, 2000

By Steven Atkin, Rens Verburg, Bryony Hansen, David McWharter

The use of paste tailings as underground backfill and for surface disposal is rapidly expanding, and with it comes the requirement to understand and predict its long-term environmental stability. This paper presents the results from a kinetic testing study performed on cemented tailings paste mixtures under both subaqueous and subaerial conditions. In addition, the effects of grainsize reduction are investigated. It will be demonstrated that the long-term weathering behavior of tailings paste is controlled by its physical and chemical characteristics, as well as its placement conditions. The testing indicates that subaqueous disposal of paste inhibits acid generation, whereas the exposed samples produced acidic leachate despite the presence of cement added to meet geotechnical requirements.

Jan 1, 2000

By Christoph Wels, Michael Royle, Shannon Shaw

Intrinsic remediation is the effect of natural attenuation mechanisms - dilution, dispersion, sorption/precipitation and biodegradation - reducing contaminant concentrations in ground water to specified levels at predetermined compliance points in the aquifer. Current monitoring and modeling for post closure was used to assess the current and long-term potential of intrinsic remediation of contaminated seepage originating from a large reactive (sulfidic) tailings impoundment near Questa, New Mexico. It is concluded that the natural attenuation mechanisms of precipitation within the tailings (as a result of buffering) and dilution/dispersion within the aquifer are currently active and likely sufficient to reduce contaminant concentrations to below state standards in the long-term. Other natural attenuation mechanisms such as sorption and biodegradation within the receiving aquife4s) were not assessed here, but are likely further reducing contaminant concentrations. Active interception and recovery of the seepage water is being maintained until monitoring demonstrates that intrinsic remediation has successfully achieved the level of water quality control required.

Jan 1, 2000

By H. K. Lin

Cyclic voltammetric and potential step chronoam-perometric techniques were used to study gold dissolution in cyanide solution. Three distinct anodic and one cathodic peaks appear on the voltammogram between -0.50 and 0.80 V vs SCE. The corresponding reactions were proposed to explain the peaks and the passivations. The proposed reactions were in agreement with the effect of pH, cyanide concentration and the rotating speed of the electrode on the magnitude of the peak currents. Cyclic voltammetric tests, with various vertex potentials, were also conducted to examine the proposed reactions. Steady-state currents at various potentials were obtained by potential step chronoamperometric technique and were compared with transient currents obtained by the cyclic voltammetric technique.

Jan 1, 2000

By John C. Gathje, Gary L. Simmons

Power Point slides

Jan 1, 2000

By R. Fedors, T. Ghezzehei, D. Or

The phenomena of dripping into cavities (e.g. tunnels and drifts) within an unsaturated fractured porous medium under ventilated conditions is studied to improve estimates of dripping rates, drop sizes, and chemical composition of droplets that could affect the integrity of high-level nuclear waste packages placed in drifts. The sensitivity of dripping rates and water chemistry to ventilation is analyzed at various flow rates using analytical expressions linking flow on fracture surfaces to drop formation and evaporation. The model was tested using laboratory experiments involving machined aluminum slabs designed to represent a simplified morphology of a fracture face intersecting a cavity and using natural fracture surfaces from a welded tuff. Comparison with ten years of data on dripping in natural caves showed good agreement with model predictions. In particular, for low dripping rates, evaporation due to ventilation leads to larger drop sizes and alters drop chemistry by increasing the concentration of solutes in the drop relative to that in the water flowing on the fracture face.

Jan 1, 2000

By T. M. Barton

This paper presents several case studies in which a mechanics-based boundary-element program is used to back-calculate the surface subsidence associated with various panels at several northern Appalachian coal mines. The program used in this case study is called LAMODEL, which incorporates a frictionless, laminated overburden into a general-purpose displacement-discontinuity code primarily designed for calculating the stresses and displacements in coal mines or other thin-seam or vein-type deposits. In this paper, the program is used to calculate both the underground convergence and the resulting surface subsidence at five longwall panels and a room-and-pillar section. The fitted subsidence from the model is compared with the field measurements and analyzed. The results from this work show that the LAMODEL program is not as accurate as available empirical subsidence-predictive methods; the expected correlation between the geology and the optimum input parameters is not evident. However, for a mechanics-based program, LAMODEL does provide moderately accurate subsidence calculations, and it is one of a few programs that can even attempt to practically calculate both underground stress and convergence and the resulting surface subsidence.

Jan 1, 2000

By R. Lai

This paper describes the application of a cyclonic flotation column (CFC) for coal cleaning. A CFC makes use of centrifugal force to create a density gradient in a column to augment the froth flotation process. In a CFC, a series of angular helical inserts is attached to the wall of a conventional column and coal slurry is mixed with a series of impellers attached to a central shaft. The hydrophobic froth concentrates near the center shaft and moves upward, while the relatively heavy hydrophilic particles concentrate near the wall and are guided downward by the helical inserts. Results of pyritic sulfur removal from an Upper Freeport coal during CFC flotation are discussed in this paper.

Jan 1, 2000

By L. W. Scott, T. H. Dubaniewicz, F. T. Duda, P. G. Kovalchik

Recent research conducted by NIOSH's Pittsburgh Re¬search Laboratory showed that electrical current levels permitted under present regulations may not limit cable temperatures to less than 90°C in reeled trailing cables. Reeled cables, which are tightly wrapped with many turns and which carry current in an enclosed space, can become overheated due to poor heat transfer. This overheating can cause the cable insulation to soften, making them prone to damage. The damaged insulation reduces the life of the cable and can lead to shock, electrocution and mine fires. This paper describes a method of measuring the conductor tem¬perature of mine trailing cables during normal operation. The temperature is measured using a 50/125-, µm graded index multimode optical fiber located in the center of the metallic conductors. Distributed temperature measurements are made using an optical time domain reflectometer (OTDR). This system is capable of measuring temperatures with an accuracy of ± I °C over a length of 4 km at I -mintervals. With this unique way of measuring temperature, tests can be conducted that simulate actual mine conditions. The tests provide important data that allows MSHA's Approval and Certification Center to develop approval criteria for cycli-

Jan 1, 2000

By M. K. Larson, R. G. Wade

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying the time-dependent response of rock stressed along weakness planes. The objective is to improve mine safety by reducing the number of roof falls that cause injuries and fatalities to miners. Researchers conducted direct-shear tests on mud-stoneovercored from a coal mine roof. Results showed frictional strength weakens with displacement along the shearing planes. Results of direct-shear creep tests also showed time-dependent deformation. Test measurements were compared to classical analytical models. Results suggest that risk of roof collapse may be decreased through layout and support design to reduce creep rates and thus slow progression toward failure.

Jan 1, 2000

By B. P. Atkin, D. W. Brown

The handleability monitor has been specifically designed to provide a simple, rapid and on-site assessment of the whole or part consignment of a coal blend in its ‘as-received’ condition. Evaluation has been carried out at a number of coal-handling plants, on both metallurgical and power station coals from a variety of sources world-wide. The results which are used to predict which coals could routinely pass through a handling plant at line capacity, without causing blockage or delay, have also been correlated with moisture, ash and size analyses of the coal to develop a predictive model of handleability.

Jan 1, 2000

By M. J. Gula, S. S. Xue, E. P. Horwitz, J. T. Harvey

A study has been conducted to control iron in copper electrolyte streams using Eichrom Industries’s new Monophosphonic /sulphonic acid resin. The resin strongly and selectively extracts ferric ion over copper and cobalt from highly acidic copper electrolytes. The resin has a loading capacity of 27 g/L of iron and can be readily regenerated. In addition, the new resin can be easily synthesized using commercially available starting materials. This paper presents the experimental results for iron control in copper electrolyte streams using the new resin and discusses its potential applications to other hydro-metallurgical streams.

Jan 1, 2000

By D. Erik Spiller

A commercialized dry gravity concentrator is operating on an alluvial gold deposit in the Boludo Mining District, State of Sonora, Mexico. The technology base of the process is the Rotary Air Concentrator (a dry circular air jig) that recovers gold from the desert sand resource. An overview of the Mexican operation and the dry concentration technology is presented. Application of the dry technology to pretreat­ment of heap leach feeds and other heavy minerals is a pos­sibility.

Jan 1, 2000

By Andreas Rubo, Stephen Gos

Over the past couple of decades several endeavours have been made to develop lixiviants with the intention of replacing cyanide in gold leaching. In 1980s these endeavours were largely economically driven, due to cyanide shortages at that time. In more recent times, the driving force has shifted to occupational health and environmental considerations. It is often argued that the high acute toxicity of cyanide alone makes it worthwhile considering to replace it completely by less toxic alternative lixiviants. This has led to having to consider more criteria in the choice of any alternative lixiviants, which have often not been taken into account in the past. The intention of this paper is to review these alternative lixiviants and also review the criteria, which have ultimately led to most of these lixiviants never having found any large scale application, if they passed laboratory stage at all. It is also intended to show, that by handling and treating cyanide in a proper manner, the overall profile for the use of cyanide compared to these alternative lixiviants is very favourable. The question to really be answered is whether there is actually any chemical or process applicable to gold leaching that does not show the high toxicity potential of cyanide and that is still favourable with regard to looking at a broader spectrum of criteria and not only acute toxicity.

Jan 1, 2000