Search Documents

By C. R. Everly

"The purpose of this paper is to review the most effective methods of reducing chloride transfer and chloride removal in the solution extraction and electrowinning (SX/EW) process. Elevated chlorides in electrolyte have various negative effects including a reduction in current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Historical controls that Sierrita has used to control chloride transfer, in order of effectiveness, have been chloride gasification at the EW that is directly correlated to amperage and chloride concentration in electrolyte, wash stage bleed and efficiency, width and velocity of aqueous bands, and electrolyte bleeds. Maintaining high bleed rates and high amperage settings has been a challenge with decreasing pregnant leach solution (PLS) grades, so keeping chlorides out of the electrolyte has become imperative. The effectiveness of reducing aqueous entrainment, optimizing wash stage efficiencies, and improving organic quality to reduce the transfer of chlorides to the electrolyte are illustrated in this study. INTRODUCTION The transfer of impurities from PLS feed streams to electrolyte in the Copper Solution Extraction process is a very common problem and is the reason that the wash stage exists in most SX operations. The main impurities affecting the SX process are iron, chloride, nitrate, and manganese. Elevated chlorides in the electrolyte have various negative effects including reduced current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, increased cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Freeport-McMoRan Sierrita Hydromet is unique in that a high-chloride byproduct stream from the molybdenum process is pumped into the SX raffinate solution pond. This byproduct steam accounts for the majority of chloride introduced to the circuit, and over the years has built up to a point where 4000ppm chloride is consistently in the PLS feed to the SX. Concentrations of chloride over 70 ppm in electrolyte will result in downgraded cathode, so it is important to limit chloride carryover from SX as much as possible. Historically, Sierrita has been able to manage chloride levels with reactive techniques including increasing electrolyte bleeds and rectifier amps. Decreasing copper in PLS has made high amps harder to maintain, and increasing bleed rates have a direct impact on production goals."

Jan 1, 2015

By K. V. Raj, T. Bhowmick

"Control of fugitive dust in high latitude open-pit mines is challenging due to unique atmospheric phenomenon resulting in complicated flow regimes, and atmospheric inversion due to lack of adequate solar insolation during prolonged winter seasons. In this study, two idealized (One conical and one trapezoidal) three-dimensional open-pit mine geometries are simulated for differing seasonal conditions using the CRADLE-CFD package. The airflow is modeled using Standard Kappa-Epsilon Turbulence Model solved by RANS equations. The concept of particle tracking is used to predict the flow pattern of dust particles. For various climatic conditions, and two different pit geometries, fugitive dust particles varying in size (PM0.1 to PM10) and concentration are generated at various locations of a mine and dispersed by the airflow pattern inside the open-pit mine. The amount and location of dust particles inside the pit is reported at various time intervals. The development of atmospheric inversion during the winter season significantly affected the amount of dust retention inside the open-pit domain. While during the summer, airborne dust particles were transported outside the open-pit domain in a short time. INTRODUCTIONComputational fluid dynamics (CFD) modeling of open-pit mines is challenging. In a recent paper, Bhowmick et. al. [1] presented different constraints and challenges in developing a 3-Dimensional CFD model. In order to obtain realistic results from a simulation, however, appropriate values of various inputs are required. Simulation results of a 3D non-hydrostatic model by Shi et al. [2] showed that both the mechanical and thermal forcing are important mechanisms, controlling the development of the atmosphere inside an open-pit. Alvarez et al [3] used a CFD model for predicting dust dispersions in a medium sized limestone quarry, and presented several iso-surfaces of varying dust concentrations using ANSYS CFX. A similar study by Torno et al [4] introduced a more sophisticated parameterization of the dust sources. Flores et al. [5] used an OpenFOAM CFD simulation package to simulate and predict pollutant dispersion in an idealized and an actual open-pit mine in Chile with an intense insolation condition. The model was simulated for three different conditions: (i) air advection (10 m/s) driven mechanical turbulence; (ii) surface heat flux (240 W/m2) driven thermal buoyancy; and (iii) both air advection and surface heat flux driven conditions. The results of the simulations showed that the buoyant currents contribute to the removal of a large percentage of the dust particles. The buoyant currents modify the purely mechanical-turbulence induced flow pattern and reduce the particle residence time, commonly observed in a purely mechanical turbulent flow (non-buoyant case)"

Jan 1, 2015

By T. J. Lutz, J. L. Carr, J. A. Yonkey, C. C. Jobes

"Since 1984, the date of the first recorded fatality involving a remote controlled continuous mining machine, 38 miners in the United States have been killed when they were struck by a continuous mining machine. Proximity detection is a valuable tool for preventing fatalities, and the use of these systems is expected to significantly improve safety. Proximity detection provides a means to prevent accidents like these. Researchers at the National Institute for Occupational Safety and Health (NIOSH) conducted a series of underground tests to evaluate the accuracy and repeatability of proximity detection systems under a number of conditions such as varying the orientation and height of the personal wearable device (PWD), moving the PWD close to the trailing cable, and activating the machine’s mining mode. At the 2014 SME Annual Meeting, results from tests on first-generation proximity detection systems were presented. This paper will provide results from the similar tests performed with second-generation systems. The results show that performance has improved. For example, the negative impact of PWD orientation and the trailing cable has been reduced. However, some inconsistencies remain. Notably, performance changes dramatically when mining mode is activated. INTRODUCTION Since 1984 there have been 38 fatalities involving striking and pinning of the operator and other workers by the continuous mining machine (CMM) [1]. In August 2011, the Mine Safety and Health Administration (MSHA) published a proposed regulation that would require proximity detection systems on all continuous mining machines except full-face machines [2]. Proximity detection systems are designed to stop machine motion to protect miners from striking/pinning hazards. Several MSHA-approved proximity detection systems are commercially available. MSHA estimates that of the 38 fatal striking and pinning accidents that have occurred since 1984 involving CMMs, the use of proximity detection could have been a preventative factor in at least 28 cases [1]. Furthermore, MSHA estimates that proximity detection could prevent 20% of all deaths throughout the industry [3]. NIOSH researchers have been involved in the development and testing of proximity detection technology since creating the HASARD system [4] and have recently conducted research intended to develop more advanced proximity detection technology for CMMs [5,6,7,8]. In addition, NIOSH has also conducted research investigating how the signals of a proximity detection system propagate [9,10] and have developed a novel method for determining the location of a personal wearable device (PWD) relative to the magnetic field generators [11,12]."

Jan 1, 2015

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives (HydroStar® 4208, DXG®-F7, Cyquest® N-900) using a potentiostatic technique. The current-time data obtained at 0.16V vs. SHE was analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A m-2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current-time data from the electrolyte without organic additives indicate progressive nucleation with two-dimensional (2-D) growth under diffusion control. SEM images obtained confirmed progressive nucleation with 2-D growth. 20 mg/L Cl- and 2.5 mg/L organic additives did not change the nucleation and growth mechanism, however the additives increased the number and reduced the size of copper nuclei leading to more uniform coverage of the stainless steel substrate.INTRODUCTION Electrowinning of copper is an important process in the manufacture of high purity copper metal. It is approximated that 20% of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole, and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth, and nature of the initial deposit (Sun and O'Keefe, 1992). Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature, and copper concentration, small amounts of organic smoothing agents (traditionally guar products) are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper dendrites, which leads to improved deposit quality by producing bright, smooth, and dense cathodes."

Jan 1, 2015

By K. N. Han, H. C. Cho, R. Kim

"As an extension of the work on the effect of OH- on various cations in hydrometallurgical systems, the effect of Cl-, Br-, I- and CN- on cations such as Ag+, Cd2+, Hg2+, Cu+, Cu2+, Co2+, Zn2+, Pb2+ and Sn2+ has been examined in detail. The Newton-Raphson technique has been used to determine the amounts of various metal species as a function of the concentration of anions. Some practical implications of various metal complexes in metal separation and removal from solutions have been examined and discussed.IntroductionUnderstanding the role of anions in hydrometallurgical processes often determines the success of an operation. The successful choice of concentration and type of anions not only leads to an effective extraction and removal of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2009; Al-Tarazi et al., 2004), but also to assisting effective separation of various metals, whether it is a solvent extraction, ion exchange operation or even a simple precipitation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974).This paper continues the discussion of the role of anions in hydrometallurgical systems beyond the role of OH-, which was the topic of a previous paper (Kim et al., 2014). Table 1 lists various anions that are frequently used in conjunction with metal ions to be selectively separated or precipitated. As seen in the table, many anions are used frequently in hydrometallurgical practices. Some of the more frequently used anions include OH-, SO4 2- and CO3 2-. The halogen elements, Cl-, Br- and I- , as well as CN-, are also used in hydrometallurgical applications, especially in relation to noble metal recoveries (Meng and Han, 1994; Zhang et al., 1996; Sun et al., 1996; Starovoytov et al., 2007)."

Jan 1, 2015

By M. Michael, A. Felber

"Mining activities, especially underground mining operations, create great demands on utilized haulage means which cover a variety of different horizontal and vertical distances. In the course of the continuous optimization of the haulage process, the application of textile machine elements, in particular synthetic fiber ropes, offers new opportunities. Therefore the current level of knowledge needs to be improved based on extensive analyses. For the estimation of the scope of these analyses, different fields of application and occurring environmental influences which have an impact on synthetic fiber ropes during their use in underground mining have to be evaluated. The Chair Underground Mining Methods of the TU Bergakademie Freiberg works on a scientific project concerning the use of synthetic fiber ropes in underground mining operations. This paper focuses on the potential application of synthetic fiber ropes in haulage systems in underground mining and exposes critical influences as an outcome of the working environment. These first investigations are the basis for the development of an appropriate experimental series. SYNTHETIC FIBER ROPES FOR UNDERGROUND MINING OPERATIONS The main idea is to optimize underground haulage means to develop even more economic systems. The new and lightweight design of single machine elements seems to be the first step to accomplish this goal. An example is the lightweight design of shaft hoisting ropes. The commonly used steel wire ropes are very heavy and are endangered to snap due to their own weight when reaching a distinguishing length. Thus they may not or only conditionally be used for deep mining operations utilizing shaft haulage. Ropes made of high-tech synthetic fibers weigh only an eighth of steel wire ropes while displaying the same tensile strength. This relation is shown in Figure 1, based on the comparison of fiber strength and density. This could offer new opportunities for deep mining operations, which are anticipated by many mining companies. /1/"

Jan 1, 2015

By Erika Moonin, Jim Nickerson, Claudio Cimiotti, Roberto Bono

"In response to the severe drought on the Colorado River basin and in order to preserve existing water capacity to the Las Vegas Valley, the Southern Nevada Water Authority contracted a new deep-water intake (Intake No. 3) located in Lake Mead. The current project (Contract No. 070F-01-C1) includes 5 km (3 miles) of tunnel with very difficult geological conditions and a 200- m (650-ft) deep shaft and marine works. This paper will present the current status of the design-build contract being constructed by Vegas Tunnel Constructors and the challenges and problems faced and the innovative solutions developed to handle the difficult conditions encountered during tunneling with up to 15 bars of pressure.ProjectbackgroundThe Las Vegas Valley receives the majority of its water from Lake Mead, which is located approximately 30 km (20 miles) east of the Las Vegas, NV metropolitan area. Due to the severe drought that has hit the southwest region of the United States, the water level in Lake Mead has receded from its high water level of 372 m (1,221 ft) above mean sea level (amsl) to a low of 330 m (1,076 ft) amsl in June 2015. Should the lake level continue to fall, at elevation 320 m (1,050 ft) amsl, the current water intakes will not be able to draw enough water to meet the needs of the local area. The risk of losing water capacity has prompted the construction of a new deeper intake. Not only is the new Intake No. 3 situated at a lower elevation in the lake at 262 m (860 ft) amsl, the new Intake No. 3 is also located to draw better quality (Fig. 1).Project challengesThe project has had several difficult challenges to overcome:• The work consisted of a 1.2 kt (1,300 st) structure constructed on a barge and lowered 100 m (330 ft) into Lake Mead anchored with 9,200 m3 (12,200 cu yd) of tremie concrete.• The drill-and-blast starter tunnel was impacted by three inflow events, resulting in a one-year project delay.• One of the main challenges was selecting the tunnel boring machine (TBM) and excavating the tunnel with expected hydraulic head pressure of as much as 17 bar (16 bar was the highest pressure recorded during the drive), crossing faulted areas, low rock cover and the risk of tunnel instability due to direct connection with the lake.• Extensive pre-excavation grouting with a constant head pressure ranging from 12 bar to 15 bar.• Structural repair of the cutterhead in difficult hydrogeological conditions [water inflow of approx. 800 m3/hr (4,000 gpm)].• Complete repair of the cascade sealing system for the main bearing and two replacements of the pinion bearings.• The TBM approach to the intake structure."

Jan 1, 2015

By R. L. Keiski, H. Miettunen

"The serpentinite massifs of Hitura are located in the municipality of Nivala in Central Finland. The most important sulfide minerals in the ore are pentlandite, pyrrhotite and chalcopyrite. The ore body consists of amphibolite rocks in contact with serpentinite against mica gneiss. The mean Ni grade of the ore is about 0.7%, and the highest Ni grades have been encountered in close contact. In general, the inner parts of the ore are strongly serpentinized ultramafite and some sulfides have been converted to mackinawite and valleriite. The degree of alteration varies considerably within the ore body and, correspondingly, the grain size of the sulfides varies as well. In this study, flotation tests were done with samples from different zones of the ore body. The flotation test results on the bench scale and plant scale are discussed in terms of the mineralogical features of the ore. Ores in the North Hitura zone differ from those in the South Hitura zone.IntroductionThe Hitura nickel mine, like the entire Nivala area, is part of the Bothnian Svecokarelian schist zone, where numerous Ni-Cu boulders have been discovered since the early 1930s. The Nivala area has therefore been the subject of exploration activities by the Geological Survey of Finland (GSF) and mining companies. The first period of exploration started in 1936, and the Makola nickel deposit, located 3 km south of the Hitura mine, was discovered by GSF in 1937. About 415,000 tonnes of ore were mined at Makola between 1941 and 1954. In 1937, during the exploration and development stage of the Makola mine, boulder tracing and a geophysical survey revealed a significant ultramafic body with some lowgrade Ni-Cu occurrences in the South Hitura zone.In 1961, GSF continued the exploration program in the area and discovered the North Hitura ultramafic complex and its allied Ni-Cu occurrences. In 1964, Outokumpu Oy bought the property and, after underground exploration, comprehensive mineralogical studies, process research and a feasibility study, production started in 1970 (Isohanni et al., 1985)."

Jan 1, 2015

By S. Bentley

"Everyone has a general idea what mixing means, but describing the mixing process is not so simple. The objective of any mixing process is to distribute and blend the materials with different characteristics, different quantities as evenly as possible resulting in a homogenous mixture. Introducing proportional movement with the optimal intensity into the materials achieves effective homogeneous mixing results. A simple one directional movement with inadequate acceleration of the materials would obviously not achieve the same mixing results. This would be more like stirring than mixing. The amount of relative movement that is introduced is a decisive factor. Circumstances for successful mixing involve distribution of all materials, and achieving the highest probability that all recipe particles located in a specific position at the beginning can be found at any random location in the mixing chamber at the end of the process. This is the only way to ensure that a consistent result is achieved every time mixing is repeated.THREE-PART CYCLE The mixing cycle occurs in three phases; charging the mixer, the mixing process, and discharging. The sequence in which the individual materials to be mixed are filled into the mixer can have a huge impact on the efficiency of the mixing cycle. The mixing cycle overlaps the charging process and the discharge cycle follows the mixing cycle. To achieve optimum results, effective discharging methods should be taken into consideration to avoid risks of segregation. Costs for energy and wear should be as low as possible and finally, it is very important that the mixing cycle takes place as quickly as possible. In concrete or paste backfill production, selecting the best mixing technology is crucial for both the quality of the final product to be blended and the efficiency of the production process. The optimum mixing system is one that rapidly disperses all ingredients evenly throughout the mixing trough and completely surrounds all the course or fine aggregate particles with the slurry cement particles. Specific for paste production it’s the mixers job to also break-down unconditioned tailings to achieve consistent paste viscosity or measured spread. Many paste and concrete formulas also involve small quantities of chemical additives which also must be evenly distributed effectively. The time required per mixing cycle as well as the costs of energy, wear and maintenance will determine the economy of the concrete production."

Jan 1, 2015

By P. G. Martin

"As the speed of business has continued to increase over the last decade, the focus on real-time control of the performance of both stationary and mobile assets has become an increasing priority. Traditionally the maintenance team has been focused on the management of the availability of assets while the operations team has been focused on the throughput of those same assets. Typically operations and maintenance teams worked almost independently in spite of the fact that they were both working with the same assets. Part of the problem has been their traditional performance measures which have often been diametrically opposed. Recent advancements in the area of real-time performance measures and decision support have helped to drive higher levels of collaboration between operations and maintenance leading to real-time asset performance control and higher levels of business performance. This paper will explore the forces driving the need for changes, present an effective approach to the definition of the most appropriate business performance measures, and examine the effectiveness of contextualized real-time decision support resulting in asset performance control. TRADITIONAL APPROACHES TO ASSET PERFORMANCE MANAGEMENT In most industrial operations the phrase asset performance management is synonymous with maintenance of the industrial assets. This is the way industry has viewed asset management and asset performance management for decades. This is a very limited perspective that is serving to constrain the profitability of industrial operations. As industrial organizations began to form following the Industrial Revolution, the complexity of the operations forced an organizational design based on specialization. No single person could understand all of the aspects of an industrialized operation. This was particularly true at the plant floor level where the operation and maintenance of the industrial equipment required very different skillsets and training. To accommodate the vast differences most industrial organizations set up operations teams to run the equipment and maintenance teams to keep the equipment available to the operation. Both teams were dealing with the same industrial equipment but from very different perspectives and with very different performance measures. Typically the operations team was measured on maximizing the output of the equipment – or throughput. On the other hand the maintenance team was measured on the uptime – or availability of the equipment."

Jan 1, 2015

By P. Zhang, W. D. Xiao

"A process mineralogy study was conducted to guide the development of a process for the extraction of vanadic oxide (V2O5) and aluminum compounds from bone coal and its ash as well as the production of byproducts. Results show that to extract the targeted metals at higher recovery rates, one must find a suitable agent capable of destroying the structure of the mica and breaking down the lattices in which these metal-bearing minerals occur. For such minerals, metal extraction efficiency is usually low if the approach is simply adding an oxidant that cannot destroy the structure. In this research, a byproduct fluosilicic acid (H2SiF6) at 20 percent concentration from an operating phosphate fertilizer plant was found to be powerful and effective for the leaching of vanadium-bearing minerals such as mica. This environmentally friendly process improved the leachability of valuable constituents in the bone coal significantly, with the leaching rate of V2O5 increased to 94 percent, from 83 percent, and that of aluminum oxide (Al2O3) increased to 75 percent, from 40 percent. X-ray diffraction and chemical analyses showed that the structure of mica can be destroyed using fluosilicic acid either alone or in combination with sulfuric acid. Based on the process mineralogy study, a processing flowsheet was tested, which resulted in a final V2O5 powder product with purity of 99.2 percent and an overall recovery rate of higher than 85 percent. The flowsheet consists of leaching, ion exchange and ammonium precipitation. With this process, various byproducts could also be generated, including aluminum fluoride, cryolite, aluminum sulfate, calcium sulfate, ammonium chloride, sodium chloride and cement admixtures.IntroductionVanadium is an important rare metal broadly used in the production of steel alloys and nonferrous alloys as well as in the chemical field as a catalyst. Vanadium-bearing bone coal and clays are abundant in China, and they contain other valuable metals such as aluminum. Bone coal is a type of carbonaceous shale. The vanadium-bearing minerals mainly exist in mica, kaolin, iron oxides, tourmaline and garnet. According to previous studies (Xiao, 2007; Xu, 1989; Xu and Chen, 1991; Ji and Xu, 1991; Chen and Xu, 1992; Xu and Heng, 1992), vanadium occurs from the isomorphous substitution of V3+ for Al3+ or Fe3 + in the crystal lattices of mica, tourmaline, garnet, dolomite and aluminosilicate minerals. In iron oxide and kaolin minerals, vanadium appears as an adsorption form. The isomorphous substitution of vanadium is more stable in tourmaline, garnet and silicate minerals. Therefore, vanadium in bone coal may exist in three phases: vanadium-containing kaolin and oxides, vanadium-containing mica, and tourmaline and garnet (Xu and Chen, 1993; Xu and Zhang, 1993; Xu and Wang, 1994; Feng, et al., 2005; Lin and Fan, 2001)."

Jan 1, 2015

By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By M. Noppé

"Dilution in underground coal operations can be underestimated by up to five times during Feasibility Studies, with disastrous economic consequences. Every 1% of stone waste introduced can reduce an in situ specific energy of 11,000 BTU/lb (25 MJ/kg) by some 110 BTU/lb (0.25 MJ/kg) and increases the abrasiveness of the run-of-mine coal. Where a wash plant is not in place, penalties imposed for not meeting contractual specifications alone can amount to some AU$1 million per year.This paper presents a method for monitoring, reporting and ultimately controlling dilution in an underground coal mining operation. The dilution trends before and after introducing the recommended controls in a continuous miner/longwall mine are presented over an eight year period. The additional information from such a dilution monitoring program can also be used to control mining horizons and plan longwall extraction heights across the face proactively, on a short-term scale with resulting improvements in productivity. INTRODUCTION Grade control, as practiced on any mine, is concerned with predicting routine quality and tonnage values for short- to medium-term mining operations, and the reconciliation of these predictions against “actual” results. For a longwall mine supplying steam coal, such routine parameters may include the proximate analyses, specific energy (SE), abrasiveness and sulphur, as well as float and sink analyses if the coal is beneficiated. In addition, grade control is concerned with identifying the mineable horizon (or horizons) in a selective-mining operation, together with monitoring how well these horizons have been extracted or adhered to. Close-spaced surface drilling can be costly for any mining venture, particularly for longwall mines operating in the deeper seams. For this reason, much of the data for short-term grade control requirements are acquired during actual bord-and-pillar development. The underground data are derived from so-called “channel” samples. These samples are cut or chipped from the coal seam, perpendicular to the mining horizon, with dimensions suitable for obtaining sufficient “representative” sample for analyses. For a 2m thick mining horizon, a channel sample 300 mm wide and 50 mm deep over the thickness of the horizon would provide some 4.5 kg of sample, sufficient for most of the necessary tests. To allow the information to be computer recorded, additional information such as seam thickness, sample co-ordinates, and the elevation of the seam (or horizon) roof or floor, may be required."

Jan 1, 2015

By H. Wen, X. Zhai

"The Jurassic coal fields which lay in west China are the major energy base and contain half of coal resources in China. Due to the gather and degeneration rules, the spontaneous combustion characteristic of Jurassic coal is distinguished with permo-carboniferous coal, which needs to be studied deeply. Programmed heating experiments of five Jurassic coal samples and three permo-carboniferous coal samples from different primal coal fields in West China were conducted to identify the characteristic parameters in the low temperature stage of oxidation and spontaneous combustion. The experiments were carried out under non-isothermal heating conditions up to 180? at the heating rate of 0.33?/min in an air atmosphere. The result showed that oxygen consumption rate, CO gas production rate and heating intensity of all coal samples increased with the rising of the temperature, which of the Jurassic coal was higher than that of Permian-carboniferous coal. The C2H4 gas of Jurassic coal generated earlier, more than that of Permian-carboniferous coal in the process of oxidation and spontaneous combustion. It indicated that the Jurassic coal was easier to be oxidized and spontaneous combustion and the index parameters of spontaneous combustion were different between the Jurassic coal and permo-carboniferous coal.INTRODUCTION Coal was the foundation of industry development, and occupied 70% of primary energy production and consumption structure in China. According to the data of the 3rd coalfield prediction, 39.6% of the total coal resources were located in northwest Jurassic coal field in China [1], where the quality of coal was excellent. The study of northwest Jurassic coal already dated from the 80s of the 20th century, about coal rock composition, coal metamorphism [2], coal-derived hydrocarbons, coal structure [3], etc. The results of these studies showed that the composition and properties of Jurassic coal was obviously different from Permian-carboniferous coal, as well as the characteristic of spontaneous combustion [4]. As a result, the spontaneous combustion characteristic of Jurassic coal particularly needed to be studied. Now more and more methods could be conducted to test the characteristics of coal spontaneous combustion, for example, thermal analysis technology [5-7], programmed heating experiment [8-10] and coal spontaneous combustion experiment [11,12]. In these methods, programmed heating experiment could be conducted to determine the oxygen consumption rate, CO gas production rate and heating intensity quickly."

Jan 1, 2015

By J. P. Ducarme, J. L. Carr, C. C. Jobes

"An average of 1.2 fatalities occur per year in underground coal mines in the United States when a miner is struck or pinned by a remote-controlled continuous mining machine. Proximity detection technology provides a means to prevent these types of accidents by disabling all machine motion when a miner is in close proximity. Researchers at the National Institute for Occupational Safety and Health (NIOSH) have developed the intelligent Proximity Detection (iPD) system, which continuously tracks the position of miners near the machine and disables only those machine motions that could cause a pinning accident. This system, previously demonstrated using non-permissible proximity detection hardware, has now been shown to be effective when implemented using an MSHA-approved system as a platform. Performance tests have shown accuracy, repeatability, and stop zone identification to be comparable to or better than the system demonstrated with non-permissible hardware. INTRODUCTION Underground coal mining room-and-pillar operations typically use Continuous Mining Machines (CMMs), such as the one shown in Figure 1. When CMMs first became available, they were operated from an on-board operator’s compartment that protected operators from roof falls and other hazards but severely restricted visibility and subjected them to machine vibration and high levels of dust and noise. To solve these problems, remote controls were developed to operate CMMs. Now CMM operators are free to position themselves for best visibility of each mining task and are no longer subjected to the rough motion of the CMM during mining operations or the dust and noise generated by the machine. However, this technological advance removed operators from the protection afforded by the operator’s compartment and exposed them to the hazard of being struck or pinned by the CMM or other large moving machines."

Jan 1, 2015

By K. Huttu, A. van Wageningen

"The Kittilä underground mine in northern Finland is extracting one of the largest known gold deposits in Europe. Kittilä achieved commercial production on May 1, 2009, becoming Agnico Eagle’s first mine to open outside of Canada. The Kittilä orebodies were initially mined from two openpits – Suuri and Roura – and underground operations were added in October 2010. The pits were mined out in November 2012, so mining is now entirely underground in the Suuri and Roura deposits. Additional, small openpits will mine any remaining near-surface reserves in the future.The Kittilä Mine is located in the Lapland region of northern Finland, approximately 900 km (560 miles) north of Helsinki and 150 km (93 miles) north of the Arctic Circle. With a mine life estimated through 2034, Kittilä is Agnico’s longest-life mine.The mine’s proven and probable reserves contain 32 Mt (4.7 million oz) at 4.6 g/t (0.13 oz/ st) gold. Ore has been mined from underground since 2010. The original 3 kt/d (3,300 stpd) operation underwent an expansion project to increase the throughput capacity of the mill by 1 kt/d (1,100 stpd), starting by the end of 2014.The region around the Kittilä Mine is underlain by mafic volcanic and sedimentary rocks of the Kittilä Greenstone Belt oriented nearly vertical. This greenstone belt is similar to those hosting Agnico Eagle’s Canadian deposits in Quebec’s Abitibi region and Nunavut. At the contact point between ironrich and magnesium-rich rocks lies a 100- to 200- m (330- to 660-ft) thick structural zone known as the Suurikuusikko Trend. This trend hosts the Kittilä deposit, where multiple mineralized zones have been traced over a strike length of more than 25 km (15 miles).Most of Agnico Eagle’s work has focused on a 4.5-km (2-mile) segment of the Suurikuusikko Trend that hosts the five main zones of the known gold reserves and resources. From south to north they are: Ketola, Etela, Suuri, Roura and Rimpi.The ore at the Kittilä Mine is refractory, making gold extraction relatively difficult because the gold is generally locked inside the two main sulfide minerals – arsenopyrite and arsenic-rich pyrite. Only about 4 percent is very fine-grained “free gold” (not locked in sulfide grains) and easier to extract. Most of this free gold is found in the outer, oxidized or eroded sections of the ore."

Jan 1, 2015

By H. Yen, D. E. Walsh, H. K. Lin

"Comminution circuits are widely used in nonferrous and precious metals milling. Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) fines, are unavoidably produced and report to undersize products in the classification circuit, i.e., flotation or leach feed, while tramp grinding steel (TGS) reports to classification oversize products and returns to the grinding mill, building up in the circulating load. In laboratory studies, TGS reduced grinding efficiency significantly, the impact being dependent upon the size of the TGS present in the mill. Because iron fines adsorb flotation reagents effectively, iron fines increase reagent consumption and reduce flotation recovery. Iron fines are also capable of reducing gold recovery in cyanidation circuits via a cementation reaction. When using filtered gold solution from the cyanidation circuit of an Alaskan gold mine, the gold concentration in solution was reduced by 0.2 to 2.6% over various reaction periods when iron fines were present in the solution.IntroductionComminution circuits are widely used in copper, lead, zinc, nickel, cobalt, molybdenum and precious metal mills. Flotation and leaching processes are usually preceded by comminution (crushing and grinding) circuits in order to liberate valuable minerals for effective separation, concentration or dissolution by the subsequent flotation or leaching processes.Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) powder, are unavoidably produced and report to undersize products in the classification circuit (flotation or leach feed), while tramp grinding steel (TGS) reports to oversize productions during classification and returns to the grinding mill, building up in the circulating load. Variables affecting the amount of metallic iron powder and TGS produced in a comminution circuit include ore hardness, grinding mill operating conditions, comminution circuit design and the metallurgy of the steel used for manufacturing crusher liners, mill liners and grinding media. As one example, a comminution circuit product of 80% passing 200 mesh at the Pogo Mine, AK is estimated to contain approximately 2 kg/t of metallic iron. A finer grind will generally produce a comminution circuit product with higher metallic iron fines content."

Jan 1, 2015

By J. Boisvert, E. Daniels, C. Deutsch

"INTRODUCTION Conventional mine planning is performed on a single resource model at a selective mining unit (SMU) scale deemed appropriate for the deposit and mining method. Estimation methods such as kriging and inverse distance, commonly used to construct a single model, are susceptible to histogram smoothing (Rossi & Deutsch, 2014). This can be mitigated by limiting the number of composites per estimate, therefore correctly reproducing the distribution of estimates (Boisvert & Deutsch, 2012). Search limiting techniques remedy histogram smoothing at the cost of introducing a problematic conditional bias (Isaaks, 1999) and introduces even greater spatial smoothing. Localization is an alternative, offering histogram reproduction through post processing of more robust probabilistic modeling techniques. A single localized model at the SMU scale is desirable. The correct histogram can be reproduced and a single model allows for the use of conventional mine planning and resource evaluation techniques. Despite the advertized benefits of localization, the necessary reliance on a larger panel scale as a middle step in the localization process yields unsightly “edge-effect” artifacts (Boisvert & Deutsch, 2012). Two approaches to artifact reduction are presented here. The first is a straight forward optimization approach designed to minimize an objective function that penalizes artifacts including panel edge discontinuities to generate a model free of panel edge-effects. The second approach redefines a panel in a less conventional fashion as a randomly chosen set of SMUs throughout the domain. This method produces a model void of any regular panel shape resulting in an artifact free model. Artifact reduction minimizes the obvious “edge-effect” issues of localization but local precision issues described by Boisvert & Deutsch (2012) persist. Localization is not a replacement for quantified uncertainty for comprehensive risk analysis and resource evaluation. LOCALIZATION Initially developed with Uniform Conditioning in mind, localization collapses a distribution of local uncertainty at a panel scale to an SMU scale model for mine planning (Abzalov, 2006). This process has been extended to Indicator Kriging (Hardke, 2011), Sequential Gaussian Simulation (Boisvert & Deutsch, 2012) and MultiGaussian Kriging (Daniels and Deutsch, 2014). The localization process is performed in a similar fashion regardless of which technique is chosen to create the prior model of uncertainty. Methodology There are three scales of importance considered in the localization process. The point scale, otherwise known as the data scale, is the smallest and is the scale at which experimental data is collected. The SMU or block scale is the familiar scale at which mine planning and resource evaluation takes place. Lastly, the panel scale is larger and contains a number of SMUs. Each of the three scales is illustrated in Figure 1."

Jan 1, 2015

By J. M. Ekenes, C. A. Caro

"New approaches that increase hydrometallurgical recovery from refractory minerals in below mill cutoff -grade sulfide copper ore can add significant value, improve profitability and increase ore reserves. This paper describes the development and implementation of an engineered heap (EH) approach to leaching low-grade, chalcopyritebearing ore at Freeport-McMoRan’s mine in Morenci, AZ. The technical evolution of the engineered heap concept is described together with the challenges and benefits following implementation. Introduction The Morenci ore deposit, located in eastern Arizona, has been mined for copper for 140 years. Mineralization in the Morenci district consists of sulfides and oxides. To process these ores, Morenci operates concentrator and leaching circuits. Leaching accounts for two-thirds of the copper produced in Morenci. More than one-half of this leaching-derived copper production comes from run-of-mine (ROM) stockpiles. The largest category of material moved in Morenci is destined for ROM stockpiles and waste dumps. Materials that are not economic to mill or leach are designated “waste.” However, this designation can change based on improvements in extraction technology and commodity prices. Chalcopyrite does not leach well due to its refractory nature. For predominant chalcopyrite mineralized ore, copper recovery during a typical leaching cycle may be as low as 5%. For this reason, chalcopyritedominant ores below mill cutoff grade have historically been classified as waste. By incorporating advanced leaching technology to improve metal recovery from previously leach-resistant ore types such as chalcopyrite, the Morenci Mine has been able to reclassify substantial amounts of this “waste” to “ore.” Process chemistry Chalcopyrite copper extraction is temperature, oxygen and ferric dependent. The temperature is achieved primarily by pyrite oxidation (Eq. (1)) and secondarily by oxidation of chalcopyrite itself (Eq. (2)). The regeneration of ferric in solution can be enhanced by providing the appropriate acid and oxygen levels according to Eq. (3). In the absence of microorganisms, this reaction is very slow."

Jan 1, 2015