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By A. D. Davis, C. J. Webb, F. W. Beaver

The proposed National Underground Science Laboratory will be housed in the former Homestake Gold Mine at Lead, South Dakota. Uses will include underground neutrino experiments that must be shielded by several thousand feet of rock, as well as ground-water research in fracture-flow environments, and investigation of the microbiology of extreme environments. The Homestake Mine has about 300 miles of underground workings. Seepage of ground water into the mine openings is approximately 500 gallons per minute. Average annual precipitation in the northern Black Hills is approximately 28 inches per year. The majority of this becomes surface-water runoff or evapotranspiration, with little ground-water recharge because of the low permeability of the Precambrian rocks in the area. Dewatering of the workings over the 125 years of operation of the mine has influenced the subsurface hydrology of the 8,000-footdeep mine.

Jan 1, 2003

By P. R. Taylor

A reaction is evaluated by which heated and pressurized water is used to precipitate metal oxides from loaded Kelex 100 complexes. Pure copper oxide (CuO) and pure nickel (Nio) in powder form, and ranging in average size from 12 to 25 micrometers, were found to precipitate from copper and nickel loaded Kelex 100/kerosene complexes, by water heated and pressurized to between 374 and 400 °c and 2170 psig (148 atm) and 3500 psig (238 atm). The precipitation is suggested to result from hydrolysis of the metal, following exchange for the hydrogen in the phenolic hydroxyl of the Kelex 100 structure, enhanced by the conditions provided by heated and pressurized water. The reaction is believed to have the characteristics of homogeneous nucleation and heterogeneous growth. The effects of temperature, pressure, initial metal concentration and seed addition on the kinetics of the process were studied. In addition, characterization studies were performed on the reaction products. A detailed discussion of the experimental results is presented.

Jan 1, 1992

By Richard B. Stein

This paper will present an overview of several hydrometallurgical processes which can be used for sea-nodule metal recovery and some simplified economics. Before going any further, here are some of the basic figures from which the economics were developed. The first is to establish a representative composition for a typical nodule feed (Slide 1). This set of chemical analysis figures can be taken as typical for a deep Pacific nodule feed and shows manganese at 30%, copper at 1.1%, cobalt at 0.2%, nickel at 13% and iron at 10% for the metals of economic interest1.

Jan 1, 1982

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975

By Wayne R. Charley

High operating costs and environmental restrictions have combined to increase smelting costs for precious metals to a level where many mining companies cannot afford to operate. The need for a hydro-metallurgical process to produce bullion with an efficient, economical and environmentally safe method is well recognized by the industry. This paper describes the research and development program conducted by Behrent Engineering Company in its investigation of the use of an acidic solution of thiourea for the extraction of precious metals from concentrates and high-grade ores. The areas discussed are: process design parameters, health and environmental aspects and economics of the process. The scope of this paper includes the leaching process, the recovery of precious metals from pregnant solutions and the production of dore'. Thiourea leaching offers a complete alternative to smelting and cyanidization for those concentrates and ores amenable to this process.

Jan 1, 1984

By Patrick R. Taylor

The hydrometallurgical fundamentals review did not arrive in time for publication in the May issue. Papers presented at the SME Annual Meeting, in Phoenix, AZ were available as preprints. The EPD Congress 1992 from The Metallurgical Society had several papers related to hydrometallurgy. Minerals Engineering 1992 was published in Minerals Engineering and contains several papers related to hydrometallurgy. In addition, a conference was held to honor Ernie Peters. The proceedings contains a large number of hydrometallurgy papers. Precious metals Gold extraction in the potassium cyanide-primene JMT sulfate-Xylene system was studied by Caravaca and Alguacil (Hydrometallurgy). Adams, Friedl and Wagner presented results on the mechanism of gold cyanide adsorption onto activated carbon (Hydrometallurgy). Adams also studied the adsorption of silver cyanide and used an IR method to evaluate adsorbed aurocyanide species on activated carbon (Hydrometallurgy).

Jan 1, 1993

By D. R. Rice

Separation of valuable constituents from a complex mineral mixture was examined. Nitric acid leaching produced a solution containing copper, zinc, iron and a large proportion of silver. The residue contained antimony, lead, the remaining silver and elemental sulfur. A caustic sodium sulfide leach dissolved the antimony from the residue, producing an insoluble, high-grade silver-lead product and a filtrate for electrolytic recovery of antimony. The pH of the primary filtrate was raised, precipitating the iron and leaving a solution containing the copper, zinc and the soluble portion of the silver, which would be recovered by conventional means.

Jan 1, 1969

By Nikhil Dhawan, Shrey Agrawal, Ashwini Kumar

The current study investigates sericite clay as an alternative source of potash and alumina. The alumina and potash content in the sericite is approximately 35 and 10%, respectively, compared with 50–55% in bauxite ore. Muscovite and illite phases are stable, and direct leaching is found to be ineffective. Here, planetary ball milling was performed, which provided dissociation of stable phases to relatively reactive phases. The milling led to a five-fold increase in the surface area, resulting in enhanced leaching kinetics even at low acid concentration. The statistical design obtained optimal conditions of 8 h of milling followed by leaching in 1.73 M HCl at 75 °C, yielding 82% alumina extraction in precipitate with 85% purity in γ-alumina form and 63% potassium dissolution in sylvinite phase. The yield of the precipitate was ~65–68%, and the acid leach residue contained primarily silica.

By K. Ueda

Lead concentrates from Kuroko (black ore) mines, which contain Cu 4 ? 7%, Pb 55%, Zn 3 - 7%, As 0.5 - 0.9% are treated by hydrometallurgical process in order to smelt the product by electric furnace smelting together with other lead resouces from Kuroko. The hydrometallurgical pretreatment involves sulfuric acid leaching at first stage, ferric leaching at second stage. This paper describes the short history of lead recovery from Kuroko and the performance of laboratory test, pilot plant and commercial operation.

Jan 1, 1982

By N. S. Kim

Silver paste including nano sized particles maintains conductivity in high temperatures without forming oxide layers. In the industry, printing process produces wasted silver paste inside the cylinder and on silk-screen. Pyrometallugical silver recycling methods have environmental problems and do not extract pure silver after removing polymer and organic materials during the extraction process. In this study a simple wet process, of recycling the waste silver paste, using ammonia, was conducted. Silver ion extraction yield was increased using oxidant in the ammonia solution. Possible extraction yields, such as pH, concentration, temperature of ammonia, oxidant concentration and the extraction time. The particles that were obtained after the extraction process will be used as porous hydrophobic catalytic and applied to AI mask and hydrophobic ink. Keywords: Waste silver paste; Ammonia; Hydrophobic porous support

Jan 1, 2009

By G. Michael Lloyd

The term phosphate beneficiation often conjures up visions of processing technologies that physically separate the phosphate rock from some impurity and do not result in a change in the chemical nature of the phosphate rock. However, when we consider hydrometallurgical processing as a phos¬phate beneficiation technique we have to include all chemical treatments that convert phosphate rock into a more useful product. With most of the phosphate rock mined being used for fertilizer pro¬duction, the best known and most widely employed hydrometallurgical process is wet process phospho¬ric acid manufacture. In general, all phosphate rocks are so insoluble that there is no physical treat¬ment that will allow the phosphate content to be used by vegetation in a timely manner. However, after chemical treatment, 100% of the phosphate is readily available for vegetation nutrition. If there is a chemical beneficiation process that could be considered the standard method of treat¬ing phosphate rock it would have to be the wet pro¬cess for phosphoric acid production. In this process finely ground phosphate is reacted with sulfuric acid to give phosphoric acid and phosphogypsum. The phosphogypsum crystals are removed from the phosphoric acid solution and discarded; the phos¬phoric acid is further processed to give the finished fertilizer product. The primary reason that this pro¬cess was adopted so widely is because the phosphogypsum solid that is formed can be easily separated from the phosphoric acid, thereby removing the calcium portion of the phosphate rock and the sul¬fate portion of the sulfuric acid. Other acids have been used to treat phosphate rock but nitric acid is the only other acid used commercially. Nitric acid gives a mixture of phos¬phoric acid and nitrates that can be further pro¬cessed into N-P fertilizers, but the range of N/P grades that can be produced is limited. Hydrochlo¬ric acid has been used to react with phosphate rock, and it can be used to generate a pure phos¬phoric acid but only after solvent extraction to separate the calcium chloride from the phosphoric acid. And then there is the problem of what to do with the calcium chloride. The acid that has received the most attention as a substitute for sulfuric acid is phosphoric acid. In this process, the phosphoric acid reacts with the phosphate rock to give a mono-calcium phosphate solution. This process does not dissolve all the impurities in the phosphate rock, and these solids can be removed from the solution before sulfuric acid is added to convert the soluble calcium to insoluble phosphogypsum. Despite all the claimed advantages, this process has not found favor. A suc¬cessful application of this process to treat some of the lower grade phosphate rocks being used today would seem to have some distinct advantages. Other beneficiation schemes have been pro¬posed or practiced on specific phosphate rocks on a limited scale. These include calcination followed by water leaching to remove lime, weak acid

Jan 1, 1999

By J. Brent Hiskey, Srini Raghavan

The physical chemistry of dissolution of silicate and complex oxide ores in aqueous lixiviants has been reviewed. Particular attention has been paid to the analysis of dissolution mechanisms and kinetic models and to the elucidation of the role of the porous nature of the materials on dissolution behavior. Importance of the physico-chemical characteristics of the leach residues on leaching efficiency has been discussed.

Jan 1, 1989

By Caelen D. Anderson

An investigation of a hydrometallurgical method for the recovery of tellurium dioxide from cadmium telluride (CdTe) thin-film manufacturing scrap was conducted. Sulfuric acid/ hydrogen peroxide lixiviation was employed to selectively leach cadmium and oxidize tellurium to tellurium dioxide (TeO2). Experimental variables included solution pH, pulp density, oxidant (H2O2) concentration, temperature, agitation rate and residence time. After one hour of lixiviation, no noticeable increase in grade or recovery occurred; thus, all experiments were performed for one hour. Leaching results showed it was possible to recover at least 74% of the tellurium, while producing a 98% pure TeO2 product. Additionally, an apparent activation energy value of 12.1 kJ/mole (2.9 kcal/mole) was determined. This value, along with results from agitation rate experiments, indicated the reaction was primarily controlled by diffusion through the product layer. During lixiviation, partial dissolution of tellurium proved inevitable. Thus, a second step: ammoniacal precipitation was introduced to recover the aqueous tellurium as a precipitate. A statistical experimental design (DOE) was used to identify the significant effects from the residual effects. Experimental variables included precipitation pH, temperature, initial tellurium tenor and agitation rate. Precipitation results showed that it was possible to produce a low-grade (46% Te) precipitate, while recovering 98% of the aqueous tellurium species. The precipitation pH and temperature (°C) were determined as the significant effects for both the grade and recovery of tellurium. Agitation rate and initial tellurium tenor were determined as the residual effects and did not influence the grade or recovery of tellurium. An illustration of tellurium recovery, as a function of the significant effects, is illustrated in Fig. 1.

May 1, 2012

By Edita Vircíková, J. B. Hiskey, Ludovít Molnár, Peter Lech, B. J. Scheiner

This paper describes the results of a study of hydrometallurgical methods of producing sodium arsenate for the glass industry from arsenic oxide wastes occurring in carbon dioxide washing. This paper addresses the following aspects: theoretical assumptions for leaching arsenic and its oxides, experimental results of As(III) oxidation to As(V) in aqueous solutions, sodium arsenate crystallization (the system As2O5-Na2O-H2O), characteristics of the crystalline product, and pilot-plant tests using sodium arsenate in the glass industry.

Jan 1, 1993

By M. Niinae, Y. Nakahiro, K. Yamaguchi, T. Wakamatsu

The rare earth magnet has a good performance and the production is increasing year by year. Two types of rare earth magnets are presently made as industrial products. One is a Nd-Fe-B intermetallic compound magnet and the other is a Sm-Co alloy magnet. The mixed scraps of Nd-Fe-B intermetallic compound and Sm-Co alloy are sometimes produced in the step of production. Therefore it is desired that a recycling system of mixed rare earth magnet scraps should be established. In the present study, hydrochloric acid leaching of the oxidizing roasted products of Nd-Fe-B intermetallic compound and Sm-Co alloy and solvent extraction of metals such as Nd, Sm, etc. are tested to obtain the fundamental data for the hydrometallurgical treatment of the mixed rare earth magnet scraps.

Jan 1, 1995

By G. Włoch, E. Rudnik

The oxide fraction of industrial zinc ash was characterized in terms of chemical and phase composition, leaching behavior in sulfuric acid solutions, and leaching thermal effect. The waste product contained about 68 percent zinc (Zn), 7 percent chlorine (Cl), 2 percent aluminum (Al) and less than 1 percent other metals, such as iron (Fe), manganese (Mn), calcium (Ca) and silicon (Si). It consisted mainly of zinc oxide contaminated with metallic zinc and zinc hydroxide chloride. The dissolution of metals from the zinc ash was determined for solid-to-liquid ratios ranging from 100 to 500 kg/m3, acid concentrations of 10 and 20 percent, and temperatures of 20 and 40 °C. The best result — 130 g/dm3 Zn(II) at 95 percent zinc recovery — was obtained at a solid-to-liquid ratio of 200 kg/m3, sulfuric acid concentration RI SHUFHQWDQGLQLWLDOWHPSHUDWXUHRI ƒ& 7KH¿QDOVROXWLRQVZHUHFRQWDPLQDWHGPDLQO\E\0Q ,, DQG)H ,,, ions, but the presence of cadmium (Cd(II)) and lead (Pb(II)) ions enabled electrowinning of zinc of about 99 percent SXULW\DWKLJKFXUUHQWHI¿FLHQF\RI WR SHUFHQW /HDFKLQJRIWKHPDWHULDOZDVDQH[RWKHUPLFSURFHVVZLWKUHDFWLRQ heat of about 520 kJ/kg

By I. H. Warren, F. A. Forward, D. E. Pickett, Ernest Peters, Alvin H. Ross, I. M. Masters, N. P. Finkelstein, R. Derry, A. W. Fletcher

In this section the chemical, physical, and mechanical principles of hydrometallurgical processes are developed and reviewed. Plant practice is not discussed other than to note the metals which are processed using the various systems that are available. These notations will permit the reader to refer to the appropriate section in Part II of the Handbook for specific details on a particular metal or mineral. The equipment used to accomplish the desired unit operation is de¬scribed. Comparative data are presented to illustrate performance characteristics of unit operations, process, and equipment. The economic efficiency of individual processes is outlined. Some of the chapters contain material that is covered in detail in other sections of the Handbook Such chapters are developed only sufficiently to indicate the specific application of the techniques to hydrometallurgical processes. In this section considerable cross-referencing to the other related sections has been done.

Jan 1, 1985

By R. J. Wesely, Corby G. Anderson, L. Ernest Krys, John B. Ackerman, A. D. Zunkel, Suzzann M. Nordwick

Processing of the refractory precious metal ore from the Sunshine Mine is done in a fully integrated hydrometallurgical facility. This operating philosophy began with the construction of an antimony plant during World War 11, and it continued with the construction of a silver-copper refinery in 1984. The antimony plant relies on an alkaline sulfide ambient pressure leach combined with antimony electrowinning and antimony compound production. This plant is the largest producer of antimony metal in the United States. The one-of-a-kind silver- copper refinery uses a nitrogen species catalyzed sulfuric acid pressure leach system. The plant contains innovative downstream silver recovery processes as well as copper solvent extraction and electrowinning. This paper presents the pertinent process chemistries and flow sheets for the two unique hydrometallurgical processing plants.

Jan 1, 1993

By Steve Kral

The Fourth International Symposium on Hydrometallurgy was organized to give those in the minerals processing field an opportunity to discuss current topics of interest in the broad field of hydrometallurgy. Held in Salt Lake City, UT Aug. 1-5, 1993, this fourth symposium also paid tribute to Milton E. Wadsworth for his many contributions in this area over the past 40 years. The science of hydrometallurgy has made great strides since the last symposium was held 10 years ago. The use of electrochemical principles and techniques has produced encouraging results. For example, the application of in situ electrode spectroscopy has helped to understand the mechanisms operating in hydrometallurgical processes. Sophisticated computer models have been developed to handle the thermodynamic properties of concentrated electrolytes. However, it is up to the hydrometallurgist to continuing working on bridging the gap between theory and practice. The successful application of solvent extraction-electrowinning (SXEW) is one illustration of the successful transfer of technology. Its widespread use in the United States during the 1980s played a significant role in the revival of the domestic copper industry. Currently, electrowon copper accounts for about 30% of total US production. Impressive developments in precious metals recovery have also occurred. Since the last symposium, carbon-in-pulp (CIP) and heap leaching have become widely used in gold recovery. And recovery of refractory precious metals ores and concentrates by pres¬sure oxidation and bio-oxidation have made significant advances. In all these examples, hydrometallurgy has played a significant role in the recovery of minerals and metals from primary sources. In addition, considerable attention has been focused on the treatment and recovery of values from secondary sources.

Jan 1, 1994

By Earl Sackett

In its 110-year history as a mining camp, the Boleo copper district of Baja California has weathered significant changes in its operation, ownership, and profitability, despite an inhospitable environment and unique ore body. For some 65 years, under the operation of Compagnie Boleo, the area ranked as the second largest copper producing district in Mexico, with over 560 km of underground workings. As its ore grade-and profitability-declined, operations continued sporadically and with varying degrees of success. Today, operations at Boleo are maintained -despite the economics -while work is underway to devise a viable metallurgical process. Lab tests on a hydrometallurgical method look encouraging and, though this may end the district's days as a mining camp, the feasibility of the process may result in an 18-kt/d full-scale operation.

Jan 7, 1980