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By Michael Botz, Craig McKenzie

Recovery of cyanide from mill tailings can be conducted to lower the overall cost of precious metals extraction, while lowering cyanide concentrations in mill discharges and potentially eliminating the need to chemically destroy cyanide. Recent applications of cyanide recovery based on acidification­volatilization-reneutralization (A VR) technology have elimi­nated the need for cyanide destruction and substantially increased the profitability at several gold and silver operations. Recent developments in the technology permits processing of scale-prone and high percent solids pulps while generally affecting cyanide recoveries in excess of 70% to 90%.

Jan 1, 1997

By W. de Moura, R. Fueyo, M. M. Botz, J. C. Scola

The Cerro Vanguardia mine is an AngloGold Limited operation in southern Argentina that includes multiple open pits and a hybrid Merrill-Crowe and CIL circuit to recover gold and silver from oxide ore. Operations were commissioned at the site in 1998, which included a plant in the metallurgical circuit to recover cyanide from mill tailings. The cyanide recovery plant was initially configured to process tailings slurry and achieved greater than 90% cyanide recovery from tailings containing about 600 to 800 mg/L WAD cyanide (as CN). The cyanide recovery circuit was operated in this manner for approximately eight months, during which time the consumption of sulphuric acid and sodium hydroxide was relatively high, leading to high rates of scale formation in the acidification tank and stripping towers. In July 1999, several piping changes were made in the cyanide recovery system to permit its operation with clear solution, which reduced the sulphuric acid consumption and eliminated scale formation in process equipment. The cyanide recovery system currently operates with a two-stage counter-current decantation (CCD) circuit which provides clear solution for processing in the cyanide recovery plant. The cyanide recovery efficiency now averages about 90% to 92% from solution containing about 350 mg/L WAD cyanide (as CN). Recovered sodium cyanide now accounts for about two-thirds of the total cyanide added to the leaching circuit. This paper presents a description of the cyanide recovery plant and details regarding its current operating efficiency.

Jan 1, 2004

By N. D. Jagger, I. M. Arbuthnot

The recovery and destruction of cyanide in gold tailings is currently a topic of great interest for both financial and environmental reasons. The environmental problem is particularly important in the U.S.A. at present with the environmental lobby waging a campaign to eliminate the problem of migratory birds dying after drinking tailings dam wate. Tough legislation with severe fines and jail sentences for company executives have been introduced in several states for exceeding cyanide limits. To reduce cyanide levels in tailings dams chemical treatment, including acidification, alkaline chlorination, the INCO sulphur dioxide oxidation process and the Degussa hydrogen peroxide process amongst others are being. used. In addition several processes are at various stages of development for the recovery of residual cyanide from gold tailings. Among these is the process developed by Cyprus Gold and pilot tested by DSIR Industrial Development. This process uses air to strip cyanide from the acidified barren pulp and will be used at Cyprus Gold Mines Golden Cross Mine on the Coromandel Peninsula in New Zealand (Fricker & OWers 1990).

Jan 1, 1991

By Andrew Briggs, Denis Kidby

VITROKELER cyanide recovery technology has been successfully piloted at the Gabanintha and Cosmo-Howley mines by Nedpac Engineering Pty. Ltd. The pilot campaigns were designed to confirm technical and economic feasibility of the recovery process including the production of base metal concentrates and return of re-useable cyanide to the leach circuit. The capital and operating costs of full-scale plants is now able to be estimated to within ±20% on the basis of hydrometallurgical data. Firm quotes are subject to on-site test-work, and any special requirements or site peculiarities.

Jan 1, 1990

By G. Van Weert, J. F. Breedveld

Both regular and Silver Impregnated Activated Carbon (SIAC) were studied for their effectiveness in removing WAD (Weak Acid Dissociated) cyanides from solutions at pH = 10. SIAC has already been shown to be effective in the removal of free cyanide down to 30 ppb or less. The present work deals with complexed cyanides. Zinc cyanide was used to represent the WAD component. At pH=10, in either batch or column tests it was not possible to lower the total cyanide in solution from either 30 or 8 ppm to less than 1 ppm, using SIAC, regular activated carbon as received, or after grinding. Silver (metal) impregnation of the carbon was not beneficial in the removal of WAD cyanide. However, when silver is added as silver ions (nitrate), the cyanide is adsorbed as silver cyanide in preference to zinc cyanide. The latter compound converts to zinc (hydr) oxide. This way, the cyanide concentration in solution can be lowered below 1 ppm, even when zinc cyanide is already adsorbed on the carbon used. A single exploratory test with added copper ions indicated a similar effect for that system.

Jan 1, 2004

By Kambhampati C. Rao, Cecil Lue-Hing, Nabih P. Kelada, William B. Willborn

improvements in the analytical techniques for cyanide speciation can furnish useful information about the behavior of the different cyanide species in the receiving environment. This could be of help to the environmentally concerned public and the regulatory agencies in the assessment of cyanide limits for effluents, stream quality, and land disposal of cyanide bearing wastes. In addition the ability to distinguish the free cyanide and the weakly bound cyanide from the strong ULTRAVIOLET IRRADIATION UNIT (LAMP, COIU3' HOUSING) FIGURE 1 complexes, as well as transformation to thiocyanate is also needed by different industries, such as mining and metal finishing, etc., to evaluate the efficiency of several processes. Cyanide has been used for the recovery of gold since the late 19th century. Although cyanide leach solutions are mostly recovered and used again, a large quantity of cyanide bearing wastewater becomes unfit for use and has to be treated before it can be released into natural waterways.

Jan 1, 1992

By Michael R. Straka

ALPKEM A Brief History, Cyanide Questionnaire Conclusions

Jan 1, 1998

By F. W. De Vries

A review as of the date of this meeting will cover the writer's perception of eachof the areas indicated in the charts. Changes in many are occurring with enough frequency that a detailed summary would be inaccurate within a few days of writing; for this reason, only an outline is appropriate for advanced preparation.

Jan 1, 1998

By Michael J. Virnig, Keith E. Weerts

The development of heap leach technology for the treatment of low grade gold and silver ores has led to a boom in gold production in the Western United States in the last 15 years. The heap leaching process consists of stacking the mined ore on a specially prepared leach pad followed by leaching with dilute alkaline cyanide solution. Depending on the nature of the ore, it may require crushing and/or agglomeration prior to stacking on the leach pad. As the dilute alkaline cyanide solution migrates down through the stacked ore, the precious metal values along with a portion of the base metal values present in the ore are dissolved to give a pregnant leach solution which is collected at the base of the stacked ore. The precious metal values are then recovered by zinc precipitation or by adsorption on activated carbon. Once all of the economic metal values have been leached from the ore, the spent heap leach pad, the leached materials, and associated process solutions must be decomissioned. Decommissioning requires that the spent heap leach pad along with the leached materials and process solution be treated to reduce the concentration of the residual cyanide, base metal cyanide complexes, and other anionic metal species to levels where they no longer represent a long tenn liability for the environment and the operator. The levels to which these components must be reduced is dependent upon the applicable water quality standards as determined by the responsible federal, state, and local agencies. As environmental awareness has grown, these standards have become increasingly stringent. A number of treatment options have been developed for the de-toxification of the process residues. These include natural degradation which incorporates bio-degradation, fresh water rinsing, alkaline chlorination, hydrogen peroxide, and sulfur dioxide/air. Each of these options has been reviewed with regard to relative effectiveness, generation of hazardous by­products, reagent handling considerations, relative costs, and time requirements by Denton, Iverson, and Gosling I. As an outgrowth of the program to develop Henkel's guanidine based gold extractants, COGNIS, Inc., the environmental ann of Henkel, has developed the CyanoMet R process for the extraction and concentration of the various cyanide and anionic metal species from the dilute aqueous alkaline solutions generated during the process of detoxifying spent heap leach pads. This paper describes the CyanoMet R process, its application to three different feed solutions, and treatment of the concentrate generated by the process.

Jan 1, 1993

By M. C. Roberts

Metal producers are now suffering through a major downturn in prices for their products even though it has only been a few years since they were enjoying high prices. From an historical perspective, the current situation is another of the cyclical downturns that often occur every five to seven years. This paper uses time-trend decomposition techniques to identify the cycles and statistical methods to find the duration of these cycles for a variety of metal prices. Given some idea of how long and severe these cycles typically are, the mining industry can better plan to weather the downturns and take advantage of the upturns. For example, timing investments in new projects to take advantage of the cyclical upturns can dramatically improve project profitability.

Jan 1, 2003

By M. C. Roberts

Currently, mineral producers are suffering through a major downturn in prices for their products, even though it has only been a few years since they were enjoying high prices. From an historical perspective, the current situation is another of the cyclical down-turns that often reoccur every 5 to 7 years or so. This paper uses time trend decomposition techniques to identify the cycles and statistical methods to find the duration of these cycles for a variety of mineral prices. Given some idea of how long and severe these cycles typically are, the mining industry can better plan to weather the downturns and take advantage of the upturns. For example, timing investments in new projects to take advantage of the cyclical upturns can dramatically improve project profitability.

Jan 1, 2000

By W. Choi

The present study revealed that the bioleachability of a chalcopyrite flotation concentrate is influenced by the semiconductor properties of CuFeS2. The overall reaction of biooxidation,

Jan 1, 1991

By Roy A. Grancher

CYCLING WITH CEMENT "THE WHEEL IS COME FULL CIRCLE" Shakespeare's King Lear Act V, Scene 3, Line 176 The time clock of the cement industry has been turned back to the early 1950s. After the trials and tribulations of the decade of the Sixties, the hands now stand where they did just over twenty years ago. Cement shipments have steadily increased, with a record 419 million barrel level (78.8 million tons) being reached last year. Plants are operating at average utilization rates in excess of 85 percent of rated capacity. The spread between supply and demand has narrowed to where a definite shortage of cement now exists within the industry. The notable and unfortunate difference between the two periods however is that, back then, cement's returns were a respectable 14 to 18 percent, whereas today they stand at less than half those levels. Insufficient return forms the present foundation of the U.S. cement industry. This lack is destined to have a cumulative effect. Just as the industry's balance between supply and demand is returning to favorable proportions, promising a period that has historically and now should generate those profit levels required to modernize and provide for capacity addition, cement instead finds itself frozen by federal price controls into the semi-depressed condition that has existed for over a decade and from which it was just starting to emerge. Capital is not attracted to continued low returns, and increasingly restrictive pollution control measures are necessitating great non-productive expenditures be made as definite costs to stay in business. Even a clouded crystal ball would reveal that additional cement plant closings can be expected.

Jan 1, 1972

By P. R. Taylor

Recent research by the investigators has evaluated the oxidation roasting of refractory gold concentrates in the presence of hydrated lime. (Taylor, 1990, 1991, 1992, 1993). These results have indicated that it may be possible to roast concentrates in such a way as to contain nearly all of the sulfur and arsenic in the roaster calcine and that cyanidation may be possible. To further evaluate the behavior of this type of roasting system a laboratory cyclone reactor was built and operated using pyrite and hydrated lime as a .model system. Approximately 50 years ago, the principle of cyclone firing entered practical boiler construction. The appeal of the cyclone configuration was that it afforded the flash combustion process greater efficiency due to turbulence-induced increased mass transfer, heat exchange, and combustion rates.

Jan 1, 1994

By James K. Kindig

Solvent extraction as a method of purifying and concentrating metal values from solution has become a standard hydrometallurgical operation for recovery of both uranium and vanadium, and within the past two years it has been put into operation in a commercial plant for recovery of copper from leach solutions. In this first full scale solvent extraction plant for recovery of copper operated by Ranchers Exploration and Development Corporation near Miami, Arizona, a kerosene solution of an organic compound, LIX-64® is used to selectively extract the copper from the dilute acidic copper sulfate leach liquor obtained from heap leach operations. The copper is back extracted from the solvent into a stripping solution which is fed to an electrolysis circuit producing cathode copper for sale.

Jan 1, 1970

By R. Lai

This paper describes the application of a cyclonic flotation column (CFC) for coal cleaning. A CFC makes use of centrifugal force to create a density gradient in a column to augment the froth flotation process. In a CFC, a series of angular helical inserts is attached to the wall of a conventional column, and coal slurry is mixed with a series of impellers attached to a central shaft. The hydrophobic froth concentrates near the center shaft and moves upward, while the relatively heavy hydrophilic particles concentrate near the wall and are guided downward by the helical inserts. The results of pyritic sulfur removal from an Upper Freeport coal during CFC flotation are discussed.

Jan 1, 2003

By R. Lai

This paper describes the application of a cyclonic flotation column (CFC) for coal cleaning. A CFC makes use of centrifugal force to create a density gradient in a column to augment the froth flotation process. In a CFC, a series of angular helical inserts is attached to the wall of a conventional column and coal slurry is mixed with a series of impellers attached to a central shaft. The hydrophobic froth concentrates near the center shaft and moves upward, while the relatively heavy hydrophilic particles concentrate near the wall and are guided downward by the helical inserts. Results of pyritic sulfur removal from an Upper Freeport coal during CFC flotation are discussed in this paper.

Jan 1, 2000

By X. Zhou

A novel flotation device, cyclonic static micro-bubble column flotation (FCSMC), was introduced in this paper. FCSMC has been widely applied for fine coal preparation in China, and its application has been further expanded to the mineral processing industry. The FCSMC system features a unique cyclonic structure which enhances the separation performance of the column. In this paper, the cyclonic separation mechanism of FCSMC process was investigated, and corresponding kinetics equations were established to probe the separation principle of this device. Some typical examples of using FCSMC to separate different materials including coal, copper, fluorite, etc., were presented. Key words: cyclonic static micro-bubble flotation column, cyclonic separation

Jan 1, 2008

By John L. Watson

The processes of magnetic separation and cyclone classification are common in the mineral processing industry, and frequently the two are found in consecutive stages in the beneficiation of a magnetic mineral ore. The application of a magnetic field across the cyclone, to combine the two stages in treating a magnetic mineral pulp, has been investigated with a view to possible practical applications in the mineral industry The results of this research reveal that magnetic particles can be manipulated within the cyclone body by the application of a magnetic field, and that magnetic grades may be significantly upgraded with recoveries in excess of 90%.

Jan 1, 1983

By Raymond L. Jones

With the inauguration of the open pit operation in Bagdad, plans were formulated for a large scale leaching operation. Dump stockpiling was started almost immediately, but actual production was not initiated until the spring of 1961. Like all neophytes, we started something about which, on a commercial scale, we knew next to nothing, either dump preparation or leach procedure, and as a consequence, we are still paying the piper. True, we had been through an extensive laboratory pilot program, but it soon became apparent that there was considerably more to increasing solution volumes than simple multiplication. Had we initially possessed our present acumen, the Cyprus Bagdad plant could be operated more efficiently and at a better profit. During the past several years, the art of dump leaching of copper has improved in many ways, primarily because of the application of scientific principles gleaned from general mining practice. Rigid pH control and the use of atomic absorption techniques for rapid," accurate assaying have probably played a leading role in this respect, although we cannot overlook the other sophisticated electronic controls lending improvement to acid addition and pumping, better piping materials, and lastly, the more efficient use of our pregnant liquors. Thin too, the years of experience have given us a greater understanding of dump behavior in general; and, we can, to a greater extent, measure, predict, and avoid some of the idiosyncrasies inherent in every dump. However, it is my firm belief that we will still be confronted with unexplainable dump behavior as long as we are involved in leaching. We have found our dump to be a wonderful money bank, but one that is capable of yielding a wildly fluctuating profit.

Jan 1, 1975