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By W. H. Fertl, S. J. Pirson

Well logging techniques, as used successfully in oil and gas exploration, can also be used to give a detailed evaluation of drill holes through industrial mineral deposits such as sulphur. This paper describes the logging tools used gives the theory behind the well-log interpretation and discusses the application of the method in sulphur-bearing limestone and m more complex sulphur deposits.

Jan 1, 1970

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By Alfred Guenkel, Kyle Marte, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985 (Borbely, Devuyst, Ettel, Mosoiu & Schitka, 1985). Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. Though it is possible to supply sulphur dioxide (SO2) in either gas or liquid form, the majority of these SO2/air operations use sulphite-based salts as the ‘SO2’ equivalent reducing agent. This is probably due to the lower capital cost, safety concerns with, and availability of liquid SO2. Sodium metabisulphite (SMBS) is commonly employed, and its cost is an order of magnitude higher than that of sulphur. The increased capital expenditures (CAPEX) for a sulphur-burning SO2 gas plant could have a pay-back of less than two years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas inventory. Furthermore, a SO2 gas plant will not trigger the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and Boleo).This paper discusses the different processes which require SO2 as a reducing agent and compares the capital and operational costs of a SO2 gas plant to conventional process alternatives using sulphite-based salts or liquid SO2.The heart of the SO2 gas plant is the sulphur furnace. The most economical way to produce SO2 is by combustion of sulphur in air producing up to 19.5 vol% SO2. Examples of large and small sulphur furnaces are discussed in terms of design, operation, and impacts on operational costs.The SO2 gas produced in a sulphur-burning plant has to be contacted with the liquor to be reduced. The choice of gas-liquid contacting device is important, and two contacting devices are discussed: 1) Gas sparging into the bottom of leach tanks (high, nearly constant, back pressure due to liquid head) and 2) absorption columns (low gas-side pressure drop)."

Jan 1, 2014

By R. L. Every, A. G. Fonseca

"Sulphur deposition on the internal wall of a pipeline is caused by the temperature effect on the solubility of sulphur in the carrier fluid and is not due to particulate sulphur present. Deposition can be completely eliminated by proper insulation of the pipeline to prevent ""cold-spots"" and the resultant temperature gradient necessary for sulphur to precipitate from solution. Friction head losses for sulphur-condensate slurry systems are quite acceptable from a technical and economic standpoint and, in fact, are less than many present commercial slurry systems. Slurry transportation of sulphur in a hydrocarbon pipeline is a viable possibility and promises to have economic advantage over currently accepted transportation modes."

Jan 1, 1972

By R. W. Allgood

"THE world-wide shortage of elemental sulphur, which became sharply apparent in 1950, has focused attention on the commercial exploitation of sulphur-bearing materials such as pyritic ores, sour natural gas, and smelter gases. Although there •are no known commercial deposits of elemental sulphur in Canada, there are vast quantities of these sulphur-bearing materials. The International Nickel Company of Canada and Canadian Industries Limited have for many years collaborated in an effort to develop economic processes for the recovery of sulphur from the smelter gas arising from Inco's metallurgical operation at Copper Cliff, Ontario. While sulphuric acid has been •produced at Copper Cliff for over twenty years, recent developments will result in a 60 per cent increase in acid production early in 1952 and, later in the year, in commencement of the operation of the largest single unit ever erected for the manufacture of liquid sulphur dioxide.The purpose of this paper is to discuss •briefly the general factors associated with the recovery of sulphur from the Copper Cliff smelter gases and to describe the sulphuric acid operations and the liquid sulphur dioxide development.Processes for the manufacture of elemental sulphur, liquid sulphur dioxide, and sulphuric acid from sulphur-dioxide-bearing smelter gases are well known and in some cases •highly developed."

Jan 1, 1952

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By R. H. Keyes Duval

"The one point left off the table was pumping costs, i.e. the cost of pumping to the cyclones.At East Malartic 5 x 5 S R L pumps that had been used to pump the classifier overflow were used to pump the rod and ball mill discharges to the cyclones. Maintenance costs on the pumps rose from $105 in 6 months to $1000 per month. The pumps had to be operated at 1150 rpm and impellers lasted only 5 to 6 days. These pumps were replaced by 6 x 6 S R. L. pumps operating at 825 rpm, but at this speed the coarser sands settled and plugged the pipe lines and the speed was increased to 925 rpm. The maintenance cost is now $100 per m::rnth which is 0 003 cents per ton milled. The impellers now last 1 month and the casing linings 6 months.Density meters are often used on cyclone overflows and sometimes on the cyclone feed. Haliburton weighted tube density meters are used in some plants. They are cheaper than the radioactive density controller, $2500 as compared to $ 6000The angle of the discharge spray from the apex can be used to judge the quality of perform1nce of a cyclone.For ordinary metallurgical applications the inside slope of the cyclone is not too important but for fine separation steeper slopes are used.The cyclone is a versatile tool and will handle considerable variations in feed tonnage - probably up to 15%. Above this variation the number of cyclones used has to be increased or decreased or the tonnage fed to them has to be adjusted"

Jan 1, 1965

By W. N. Hamilton

Industrial minerals are plentiful in Alberta. Although exi ting in variety and in quantity, they constitute a minor segment of the province's mineral industry, which is based on oil and gas. In 1983 Alberta led all the other provinces in value of mineral production with a total of $22,2 18 million, 62 per cent of the total for Canada. Of Alberta's total, $22 million or about 3 per cent came from the indu trial minerals. Nearly two-third of this production is accounted for by sulphur, which is actually a by-product of the oil and ga industry. Alberta ranked third among the province in industrial minerals production for 1983, with about 20 per cent of the national total.

Jan 1, 1984

By Z. D. Hora

Traditionally, industrial minerals in British Columbia comprise about 10 per cent of the combined value of mineral, coal, petroleum and natural gas production. Over the years a wide variety of industrial minerals have been produced in British Columbia, often with a different level of marketing success. For some products such as building stone, common brick or expanded shale, once strong demand gradually disappeared; for others such as asbestos and barite, new discoveries or new industrial activities created demand and new markets. For yet other minerals such as fluorite, talc and perlite, wider use has been prevented by the small size, poor quality or remote locations of the deposits. Bentonite (1926 to 1944-as a by-product from coal mines) Building stone (intermittently since the mid-1800s) Chromite (1918 and 1929) Over the past years, the list of industrial minerals produced has been expanded to include several new commodities: glassgrade silica sand, magnesite, pumice and silica for ferrosilicon and silicon carbide manufacture.

Jan 1, 1984

By BARRY BANNATYNE

About 90 per cent of Manitoba's industrial minerals production is for structural materials. Most of these come from the Paleozoic rocks west of the Precarnbrian Shield, or from glacial deposits that are extensive throughout Manitoba. The major raw materials are sand and gravel, and carbonate rocks for crushed stone (and also dolomite for high-magnesia lime, high-calcium limestone for lime and Portland cement, and dolomitic limestone for Tyndall stone). Glacial lake clays are used both in cement and in lightweight aggregate. The Jurassic and Cretaceous strata exposed along or near the Manitoba Escarpment include siliceous, carbonaceous, kaolinitic and illitic shales, all of which are quarried by Red River Brick and Tile in the Pembina Mountain and Ste. Rose areas for use in a brick plant at Lockport. Non-swelling bentonite near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation is of value as an absorbent clay, and is the only commercial source in production in Canada. It has been quarried by Pembina Mountain Clays Limited since 1940. Gypsum occurs in the Jurassic Amaranth Formation and supplies much of the market for wallboard and Portland cement additive in the Prairie Provinces. Quarries are operated at Gypsumville by Domtar Construction Materials Limited, and north of Amaranth by Westroc Industries Limited. Silica sand from the Ordovician Winnipeg Formation is of glass-grade quality, and about 100,000 tonnes are produced annually by Steel Brothers Canada Limited on Black Island . It is used as a glass sand, as foundry sand, for sand blasting, and as a filter-bed sand .

Jan 1, 1984

By DONALD E. BARNETT

Since the days of early settlement ew Brunswick has produced a variety of industrial minerals but it is perhaps only the recent discoveries of significant reserves of potash that have elevated the meaning of industrial minerals in their contribution to the provincial economy. With potash production commencing in July 1983, the role of industrial minerals will increase significantly to the value of mineral production in the province.

Jan 1, 1984

By PAUL L. DEAN

Industrial mineral deposits are widespread in Newfoundland and Labrador and a variety of commodities are produced. The province has the only pyrophyllite mine in Canada and also produces asbestos, gypsum, silica, barite, limestone, gemstones, cement and other structural materials. Large reserves of these and other industrial minerals are known and several deposits are likely future producers. Most producers are wellestablished and have large tonnages of ore reserves.

Jan 1, 1984

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By D. G. Minnes

Many non-metallic minerals and structural materials are produced in Ontario to serve the needs of domestic manufacturers and export markets. In 1982 production was estimated to have a value of $765 million. Approximately 81 per cent of this was represented by structural materials, nearly 12.8 per cent by salt, and the remainder was other industrial minerals. Total mineral production in Ontario in 1982 was estimated at $3 .16 billion, down nearly $1.5 billion from 1980's high of $4.58 billion.

Jan 1, 1984

By Paul Guliov

Potash dominates the industrial mineral scene in Saskatchewan accounting for 44% of total provincial mineral production in 1981. More than 7 million tonnes of potash have been produced annualy in recent years; ten underground mines are presently (1983) active. Sodium sulphate and cement are also important mineral products. Construction aggregates, clay products, bentonite, salt, peat moss and sulphur complete the list of industrial mineral products.

Jan 1, 1984

By L. Frost

Physical Conditions Great Britain The physical conditions in the mines investigated in Great Britain are similar to those found in the mines of the Dominion Steel and Coal Corporation, with the important difference that many of the coal seams visited were interspersed by a large number of heavy faults, making the development of a continuous face operation difficult, and in many cases the life of a unit development was exceptionally short, adding to unit cost; but in spite of these difficulties, a great deal has been accomplished in the application of mechanical loading units in a number of the mines in the areas visited. The coal-bearing measures, as in Nova Scotia, consist of shales and sandstones, and in some sections mussel bands overlie the coal seams making roof conditions difficult'. In several mines, the main roof consisted of weak shale bind, being held by a coal roof of varying thickness. This shale bind had a tendency to flow when the coal roof was broken. The floor, in some cases where cutter loaders were operated successfully, consisted of weak, flaky shales with very little resistance and a tendency to disintegrate into powder when broken. The depth of cover under which these mines were operating varied from 250 feet to 2,340 feet, with an average of 1,700 feet. The coal seams varied in height from 3 feet to 8 feet 6 inches, and the gradients from level to 33 per cent. The seams vary in hardness, but all-with the exception of one seam, the 'Morrison Busty'- presented a cutting problem similar to that found in Nova Scotia. The structure and cleavage of the coal was well defined and uniform. Some of the seams visited were gassy, ?but the temperature of the workings generally was not in excess of 70°F.

Jan 1, 1948

By E. G. Joe

"This paper summarizes the main conclusions derived from twenty-two technical presentations made at the 1973 meeting of the Canadian Mineral Processors. Results of two surveys with response from over seventy mines were reported on Canadian milling practice for water re-use and on elimination of cyanide from mill effluents. Water and solution recycle in Canadian mills were detailed for copper, copper-zinc, lead-zinc-copper, nickel-copper, iron and gold mines. Cyanide elimination from mill effluents was reported under current practice and under requirements for further treatment by various other processes. Three recent process equipment entries into Canadian mills have been the on-stream particle analyzer, the new gravity concentration tables for recovery of fine tin and other heavy minerals, and solution-jet slurry equipment for reclaiming ground ore from storage. The principles of operation of this equipment were described along with the practical limitations that were found in their application to mineral processing. Capital costs and milling cost reductions were shown in some operations. Computer control of flotation mill processing was a major item on the program. Four major mining companies outlined their mill process control strategy, computer programs and on-stream analysis equipment. Some capital costs and personnel changes were presented, together with gains in concentrate grade and mill recovery. Recent development work has shown the effect of the type of grinding and of aeration on the recovery of sulphide minerals in flotation. One mining company reported a significant depressing effect on copper sulphide flotation while floating ore ground with mild-steel balls; also, pyrite appeared to be activated in the subsequent zinc flotation step. One company with extensive experience in the application of aeration to copper sulphide flotation showed significant improvement to copper recovery by pre-aeration. Both the effects of grinding and aeration were subject to the constraints of the chemical condition of the ore pulp. The metallurgy of silver recovery by combination grinding - gravity treatment and of gold recovery from a complex gold-sulphide ore were reviewed in two papers on precious metals. The latter paper further described the recovery of gold from the Cottrell collectors and the final disposal of arsenic from the dust collectors."

Jan 1, 1973

By K. Delbeke

Within the framework of the EU Existing Substance (93/793/EEC) and REACH regulations EC/1907/2006), the copper industry initiated in 2000 a comprehensive Voluntary Risk Assessment of copper and several copper compounds. The Italian Government's Istituto Superiore di Sanità, reviewed the process and reports on behalf of the European Commission. Copper exposure levels to man and the environment from production of copper anodes and cathodes, copper powders and copper chemicals as well as fabrication and use of semi-fabrication products and down stream user products were collected across Europe. Environmental and human health effects data were obtained from literature as well as novel research programs and used to deduct safe threshold

Jan 1, 2007

By D. Lessard, S. Nantel

"Surface crown pillars are important Canadian,mining structures. Mines operating in the Canadian Shield usually have several, forming a first line of protection from surface elements.Detailed technical information from twenty-four Canadian hard rock mines show that the deposits dip steeply and are generally either single or multiple veins. Considerable overburden usually cap the deposits. The rock mass is often altered and intersected by important discontinuities.The designs for these types of pillars lack basic data and are based on experience rather than a scientific approach. Regardless of the competence of the rock mass, the surface crown-pillar thickness to width ratios (an unscientific design tool used by the industry) are usually less than five. Rock bolting is, in almost every case, used as a support measure. However, there are many openings neither backfilled nor monitored.The characteristics of openings with surface crown pillars are also examined."

Jan 1, 1988

By Brad Bjornson, Geoff Stevens, Mike Ashar, Cliff Britch

"LocationThe facilities are located 30 km north of Fort McMurray, Alberta (or 470 km northeast of Edmonton, Alberta).Brief Description of OperationThe operation includes the mining of oil sands, extraction of bitumen from the oil sands, and upgrading of the hydrocarbon fraction prior to shipment via pipelines to refineries.HistorySuncor was initially called Great Canadian Oil Sands. It was started by Sun Oil of Philadelphia. Construction began in 1965, with the first production coming on September 1967.Details of Present Milling Practice (Plant 3)Plant 3 recovers bitumen from the oil sand using the Clark hot water process. The basic steps in the process are conditioning, primary recovery, secondary recovery and tailings oil recovery.Oil Sand Feed SystemThe oil sand feed from the mine is transferred to the feed bin in extraction by two conveyor systems. Oil sand analyzers on each conveyor system measure the amount of bitumen and fines in the ore. Cones at the bottom of the feed bin distribute the oil sand to five process lines. Feed flow from each cone is regulated by an apron feeder which transfers the oil sand to conveyors that discharge into the conditioning drums. Weightometers on each of these five conveyors measure the rate at which the oil sand is delivered into the drums. The oil sand feed rate to each drum can be adjusted by varying the speed of the apron feeders."

Jan 1, 2000