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By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached to remove base metals from a concentrate containing platinum group metals (PGMs). We investigated the atmospheric leaching process to develop a better understanding of the leaching behaviour of the base metals (Cu, Fe, and Ni) and the PGMs, in particular Ru, Ir, and Rh with respect to key process variables, acid concentration, and Cu concentration under oxidative and non-oxidative conditions. With oxidative leaching, a higher initial acid concentration resulted in higher Cu, Ni, and Fe extractions, as well as faster leaching reaction rates. A higher initial acid concentration also resulted in faster precipitation of Cu, Ru, and Ir under oxidizing conditions. Under non-oxidative conditions, Ni and Fe extraction was much slower, and the effect of initial acid concentration on Cu precipitation was less pronounced. The initial Cu concentration had a slightly smaller effect on the leaching behaviour of Fe and Ni, as well as precipitation of Ru, Ir and Rh. Moreover, a higher initial Cu concentration suppressed both Ni and Fe leaching and had a slight inhibiting effect on the precipitation behaviour of Cu, Ru, and Ir.

Nov 1, 2021

By M. B. C. Brandt

Richter magnitudes for seismic events were calibrated for use as a Local magnitude scale in the West Rand (WR), Far West Rand (FWR), and Klerksdorp–Orkney–Stilfontein–Hartebeesfontein (KOSH) gold mining areas. Richter magnitudes are currently calculated from seismograms recorded by local surface cluster networks using tabulated calibration values for Southern California, published in 1958. The Richter (1958) model is incorrect for distances of less than 30 km and should be applied only to crustal earthquakes in regions with similar attenuation properties to those of Southern California. When compared to the South African National Seismograph Network (SANSN), the cluster networks, on average, overestimate seismic event magnitudes by approximately 0.1 of a magnitude unit. A calibrated Local magnitude scale was derived by means of a multiple regression analysis between the Local magnitudes reported by the SANSN and the largest zero-to-peak trace amplitudes measured on the cluster network horizontal seismograms, after modelling the attenuation of the seismic waves as these progress from the epicentre to the station position. Magnitudes reported by individual stations for the same event show a significant scatter around the average magnitude owing to the near-surface amplifications of the seismic waves at the recordings sites. Average magnitude should be estimated using as many magnitudes of individual stations as possible to ensure an accurate estimate. Larger event magnitudes should be compared with those recorded by the SANSN.

Nov 1, 2021

By L. Roux

This review was initially motivated by the author’s own experience in attempting to reconcile run-of mine production tons with the Coal Resource and Reserve estimation of mineable, in-situ tonnages. The primary scientific measurements and observations that are collected during exploration at the beginning of the value chain will have a profound effect on the future of the mining operation. Due diligence must be exercised during the planning of a new mine and during the life of an existing mine. The comments provided by the technical and economic assessment group of Venmyn Deloitte confirmed the need for this critical review. They found the reporting of Coal Resources in South Africa to be inconsistent. This was particularly problematic in the Waterberg Coalfield in Limpopo Province. In this coalfield there are two types of coal deposit present. The first is comprised of the thick intercalated, cyclic coal and shale/mudstone sequences of the Volksrust Formation. This overlies multiple coal seams within the Vryheid Formation, each of which is thick enough to be extracted as an individual raw coal unit. On the other hand, the interbedded coal and shale seams of the Volksrust Formation require beneficiation to separate the coal from the shale. The review examines practices and methods, investigates alternatives, provides checks and balances, and tests these against actual production reconciliations. In conclusion, the best estimates of the mineable, in-situ tonnage will be obtained from the air-dry raw material density. These estimates should be adjusted afterwards to allow for free moisture content. The adjustments are derived from reconciliation data. The greatest contributing factor to the over-estimation of Reserve tonnages is the moisture content of the raw material. This fluctuates significantly under varying conditions in situ, as well as upon exposure to the natural environment. The air-dried density of the raw material includes inherent (structurally bound) moisture within the matrix. It provides credible tonnage estimations of raw material available while also providing an indication of voids within the volume of material being assessed. The calculated solids percentage can be used to adjust the specific gravity, which is determined via the Archimedes principle. This will supply a representative estimate of the material to be mined.

Nov 1, 2021

By Víctor Vázquez, Guillermo Tiburcio, Martin Encinas, Jesús L. Valenzuela, Erick Montaño, Alejandro Valenzuela, José Parga

Merrill-Crowe is the primary process used for the concentration and purification of silver in a cyanide solution. The Langmuir Adsorption model for silver recovery in a cyanide solution was used for the study. The maximum adsorption capacity was 6.19 mmol/g for silver. This model properly adjusts the experimental results of the adsorption equilibrium with high correlation coefficients, which also favors the formation of a single layer of molecules adsorbed for the silver in the electrocoagulation- generated species. The thermodynamic parameters ΔG, ΔH, and ΔS were estimated, and it was found that the adsorption process is exothermic and spontaneous. For the kinetic study, the Lagergren second-order equation was used to study the adsorption speed. To characterize the solids coming from the electrocoagulation, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) were used; the results of this study suggest that silver is present in aluminite, hydroniumjarosite, and alunogen.

Oct 30, 2021

By Atta Ur Rehman, Kwame Awuah‑Offei

This paper examines the effect of bucket geometry (cutting blade profile, floor profile, and blade thickness), speed, motor power output, and muckpile particle sizes on bucket penetration and draft for rubber tire loaders. The work uses a 1:16 scaled model of a load-haul-dump in full factorial experiments to examine the effect of the variables on penetration and maximum draft. The results show that speed and motor output are positively correlated to penetration and draft; muckpile particle size is positively correlated to penetration and negatively correlated to draft (p < 0.0014). The results show that buckets with a semi-spade cutting nose profile yield the highest penetration (mean 118.30 mm) followed by those with the spade (mean 108.88 mm), which also yield higher penetration than those straight blades (mean 95.19 mm). Bucket floor profile and blade thickness had no significant effect on penetration or draft. Also, we determined that increasing the speed and motor power output, simultaneously, can reduce bucket penetration. Thus, operators should not waste energy for no additional gain or even loss in bucket penetration. Also, the work finds speed and motor power output each combine with muckpile particle sizes to affect bucket penetration. This research furthers our understanding of the effectiveness of different bucket geometries in improving penetration and reducing draft for rubber tire loaders.

Oct 29, 2021

By Omid Asghari, Amin Mousavi, Arshad Ranjbar

Geometallurgical modeling of the production benches is an attempt to estimate the geometallurgical variables of the different ore domains, which leads to a better understanding of the ore and its properties. Having geometallurgical variables results in a more accurate prediction of ore characteristics, an improved drilling and blasting operation, and better efficiency of the processing plant. In this research, the geometallurgical variables required for the geometallurgical modeling of the extraction benches are discussed. Then, the relations between Bond work index (BWi), as one of the most important geometallurgical variables and the primary grindability index, and rock geomechanical properties are investigated based on the previously published studies. The BWi is the main parameter for measuring the resistance to the grinding of ore minerals. It represents the energy required for processing (e.g., crushing, grinding) ore rocks in the beneficiation plant. As a real case study, BWi of a production bench in Sungun Copper Mine, located in East Azarbaijan province, Iran, was estimated. The rock’s geomechanical properties were measured using laboratory tests, including uniaxial compressive strength, Brazilian tensile strength, point load strength, and hardness. Then, BWi was estimated using the proposed formulas in the literature and the results of the rock’s geomechanical properties. The selected bench consists of three ore zones and two dyke domains. The laboratory tests revealed that the first ore zone has a slightly higher compressive strength than the other two zones, while the compressive strength of the waste rocks is larger than the ore domains. Using the proposed equations in the literature, the predicted values of the BWi for the samples in ore zones are in the range of 6.36 – 14.44 (kWh/t), and therefore this wide range must be considered when the short-term production schedule is planned. In addition, variations are observed in the samples within a specific zone and between the ore zones, demonstrating heterogeneity in the selected bench. Finally, wide-open results obtained by different equations show a necessity to perform a geometallurgical program specifically for the Sungun mine.

Oct 28, 2021

By A. Halim, J. Gustafsson, A. van Wageningen, J. Johansson, · J. Lööw, K. Kocsis

A major part of the European Union’s (EU) project Sustainable Intelligent Mining System (SIMS) is investigating the development of diesel-free/carbon–neutral underground mines in order to ensure sustainable underground mining in the future. Replacing diesel machines with electric vehicles in underground hard rock mines has been widely acknowledged by the mining industry worldwide as a critical step to improve working conditions by reducing diesel exhaust–related contaminants, to reduce mine ventilation electrical power cost by reducing mine airflow quantity, and to reduce mine greenhouse gas emissions. All of these are major requirements to achieve sustainable future underground mining practices. A field trial of Epiroc’s 2nd generation of Battery Electric Vehicles (BEVs) at Agnico Eagle Finland’s Kittilä mine was conducted during 2019–2020. Vehicles tested were MT42 mine truck, ST14 Load-Haul-Dump (LHD), and Boomer E2 jumbo drill rig. This paper outlines the improvement of the working conditions observed in the field trial, and the opinions of the mine personnel at Kittilä mine on using BEVs instead of diesel machines. Measurements of atmospheric contaminants and air temperatures taken during the field trial clearly demonstrated a significant improvement of working conditions when BEVs were operating as opposed to diesel machines. This field observation was supported by the opinion of the majority of the Kittilä mine workers. However, some remaining concerns must be addressed before BEVs can replace diesel machines.

Oct 25, 2021

By Dejan Petrović, Pavle Stojković, Jelena Ivaz, Saša Stojadinović

In spite of the fact that flyrock phenomenon represents the real threat for personnel and machinery, it still remains insufficiently investigated. There are efforts, in the mining community, to explain the causes of flyrock, but the models capable to accurately predict flyrock occurrence and define the flyrock distance still do not exist. This article is an attempt to establish such a predictive model. The model utilized the adaptive nature of artificial neural networks and combined it with the accuracy of numerical modeling of physical phenomena. Necessary data were collected by high-speed camera recordings of actual blasts at three different surface mines and processed for further use for artificial network training. The result was a neuro-numerical couple which was capable to predict flyrock occurrence, estimate the launch velocity of flyrock fragments, and calculate the maximum distance of flyrock fragments. The safe distance was then calculated by multiplying the flyrock distance with a factor of safety. The article explains the procedure for data acquisition and processing, artificial network construction, training, and validation. It also explains the principles of flyrock distance calculation and, finally, provides a definition of factor of safety and safe distance. The results showed that the prediction was satisfactorily accurate and reliable.

Oct 22, 2021

By Molood Saeedi, Nima Sadeghi, Eskandar Keshavarz Alamdari

This study showed the kinetics of gold chlorination leaching from an anode slime complex containing copper, silver, barium, selenium, and tellurium. AgCl and BaSO4 control the rate of gold leaching, and the interface transfer and diffusion across the product was selected as the desirable kinetic model. The concentration of hydrochloric acid, chlorine gas flow rate, pulp density, and temperature have been precisely studied. The results showed that temperature and hydrochloric acid have a favorable influence on the leaching rate. However, the chlorine gas flow rate is inactive in the reaction rate. Furthermore, the leaching rate decreased with an increasing pulp density. The leaching process was controlled by the interface transfer and diffusion across the product, and the activation energy was determined to be 13.66 kJ mol–1.

Oct 19, 2021

By Qingwen Shi, Gang Xu, Shuwen Wang, Brijes Mishra

Pressure relief borehole is one of the most effective methods to treat coal burst in deep-buried coal seams. However, due to the large amount of randomly distributed fractures in the coal body and the varying stress environments in underground coal mines, there is no practical method to assess relief boreholes by far, which brings problems for borehole design and construction. This study focuses on the assessment of relief boreholes in a single driving entry wherein the impact of mining panels on relief boreholes is eliminated. A practical method, focusing on field monitoring of borehole deformation with a new device, is developed to evaluate the single driving entry’s relief boreholes. This method is applied to a Chinese coal mine. The application results showed that the convergence process of the boreholes showed a three-phase characteristic. Phase one involves the fastest deformation, reaching up to 8% in the first 3 to 4 days. Phase two lasts longer and converges more, reaching up to 30% in 4 months. Phase three stays balanced until the excavating face moves. The three-phase characteristic indicates that a large diameter of the borehole ensures relief efficiency because the borehole provides adequate space for deformation throughout its life span. In addition, it is verified that long boreholes and slow footage improve relief efficiency by providing adequate time for the boreholes to work. The application proposes that boreholes in the test coal mine need to be drilled larger and longer for optimization.

Oct 19, 2021

By Shannon Seitz, Qingwen Shi, Junfeng Pan, Shuwen Wang, Brijes Mishra, Shaohong Liu

Delayed coal bursts in deep coal mines have caused significant fatalities and economic losses in recent years. Instead of occurring right around the advancing face, this particular type of coal burst is characterized by its occurrence at a certain distance behind the advancing face. To better understand the mechanism of a delayed coal burst, we used borehole camera, electromagnetic CT, and borehole deformation monitoring device to observe the fracturing and deformation process of an advancing entry’s surrounding coal in the field. Borehole camera detection showed a zonal disintegration phenomenon in the advancing entry’s surrounding coal. Electromagnetic CT detection showed that zonal disintegration developed within 14 days of excavation. Borehole deformation monitoring indicated a deformation rate difference between the intact zone and fractured zones. The deformation rate difference was observed to increase with time and cause increasing elastic energy accumulation in the intact zone. The cumulative elastic energy in the intact zone finally caused a delayed coal burst in the entry. Sensitivity analysis of the cumulative elastic energy was conducted based on a thick-walled model deduced from field detection. The model shows that the smaller thickness of the intact zone brings higher elastic energy in the intact zone. This investigation provides an improved understanding of delayed coal bursts in deep coal mines.

Oct 19, 2021

By M. SIDDARAJU, Rameshwar Sah, T. Umadevi, K. S. SRIDHARA, B. D. Ganesh Shetty, M. RAJU

The production of high strength iron ore sinter for blast furnace iron making unit was developed by optimizing the granulometry of less than − 0.150 mm fines in sinter base mix which consists of iron ore fines (− 10 mm size with 0.150 mm: 41%), beneficiation plant jig concentrate, i.e., washed ore (− 3 + 0.150 mm size with − 0.150 mm 3 to 9%), beneficiation plant concentrate (− 0.150 mm size 97%), limestone, dolomite, coke breeze, lime, sinter return fines, direct reduced iron (DRI plant) fines, and micropellets produced from steel plant waste. The sintering process consists of preparation of base mix, mixing, and production of nodules using mixing and nodulizing drum by maintaining the optimum moisture, transferring of nodules to the sintering machine, and firing of sinter by applying optimum suction pressure. To optimize the < 0.150 mm fines in sinter base mix, the − 10-mm size iron ore fines was replaced with washed ore. The size analysis, granulation index (G index), and optimization of moisture w.r.t. sinter bed permeability were carried out by varying the washed ore addition from 0 to 55% in sinter base mix to vary the − 0.150 mm fine size. With decrease in washed ore addition from 55 to 0% in sinter base mix the finer fraction, i.e., − 0.150 mm in sinter base mix increased from 9.4 to 26.7%. Granulation (G) index increased from 1.46 to 3.10, sinter bed permeability increased from 33 to 53 Japanese Permeability Unit (JPU), and balling index increased from 1.4 to 3.0. With increase in − 0.150 mm fines in the sinter base mix from 9.4 to 26.7%, the sinter tumbler index (T.I) increased and sinter reduction degradation index (RDI) decreased. Increase in sinter strength and decrease in sinter RDI was due to increase in formation of Silico ferrite of calcium and aluminium (SFCA) phase and decrease in pore phase. The SFCA is the main bonding phase in iron ore sinter, and it provides strength to sinter. Sinter base mix with − 0.150 mm fines 18.9% (washed ore addition 25%) achieved desired sinter properties with moisture 8.0%, G index 2.44, balling index 2.3, and sinter bed permeability > 45JPU. Decreased the sinter properties with washed ore addition in sinter base mix beyond 25% due to decrease in − 0.150 mm fines in sinter base mix. Further, to improve the sinter properties with washed ore 30 to 45%, 3 to 10% beneficiation plant concentrate, i.e., − 0.150 mm fines was added to maintain the 18.9% of − 0.150 mm fines in sinter base mix. From the laboratory sintering studies, it was found that minimum 18.9% (range from 18.9 to 26.7%) − 0.150 mm fines should be maintained in the sinter base mix to achieve desired sinter properties.

Oct 16, 2021

By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By Xuezhong Wang, Hao Guo, Tao Tu, Qingsheng Liu

The scheelite concentrate was leached with a mixture of sulfuric and oxalic acids. Chemical compositions, mineral phases, and morphology were characterized by XRF, XRD, and SEM–EDS. Based on the results of the single-factor experiments, the response surface methodology (RSM) was chosen to optimize the leaching parameters: temperature, time, and concentrations of sulfuric and oxalic acids. The RSM results indicate that the optimum values for those parameters are as follows: temperature 72 ℃, sulfuric acid concentration 1.48 mol/L, oxalic acid concentration 0.96 mol/L, and reaction time 2 h. Under the optimal leaching conditions, the model predicts a maximum leaching yield of 99.5%, compared to the value of 99.1% obtained experimentally, that is, a discrepancy of only 0.04%. This good correlation shows that the quadratic polynomial equation obtained by the RSM optimization is reliable. The importance on leaching parameters of scheelite is, in decreasing order, temperature, time, sulfuric acid concentration, and oxalic acid concentration.

Oct 11, 2021

By Huiqin Yao, Dongmei Liu

The study investigated the potential use of low activity circulating fluidized bed combustion (CFBC) ash and phosphate tailings for the production of a filling material based on the cement. The phosphate tailings were used as aggregate and consolidated by cement and CFBC ash. The results showed that the bleeding rate and fluidity of all mixtures decreased with the increasing the amount of CFBC ash. The fluidity of filling slurry is highly related to the experimental factors such as the content of sulfur solid ash, B/A ratio, and mass concentration. The replacement of CFBC ash ranging from 20 to 40% led to a significant decrease in setting time and an obvious increase in compressive strength, but the above effect was obviously weakened when reducing the mass concentration and B/A ratio. The hydrated calcium silicate gel and ettringite generated from the hydration of cement and CFBC ash were the main sources of strength for the filling materials. When the recommended proportion was 1/6 binder/phosphorus tailings ratio, 76% solid content, and 40% CFBC ash replacement, the filling material still met demands on working and mechanical properties; at the same time, the utilization of CFBC ash and phosphorus tailings was maximized.

Oct 11, 2021

By Atta Ur Rehman, Kwame Awuah‑Offei

This paper evaluates the effectiveness of similitude theory in predicting the draft of a rubber tire loader’s bucket during initial penetration. The work uses 1:16 and 1:8 scale models of an 18-t capacity load haul dump, scaled with the Buckingham Pi Theorem, to evaluate the prediction of draft and penetration under different operating and different dynamic conditions. The authors hypothesize that the observed relationships between draft and longitudinal penetration and the operating and dynamic conditions will hold true for an upscaled model. Similarly, the authors hypothesized that the results of experiments conducted with the smaller scaled model should predict the draft on an upscaled model. The results show that the relationships between draft and longitudinal penetration and operating and dynamic parameters are similar for both scaled models. Similarly, the draft on the upscaled model, predicted by using the experimental results of the small model, is similar to the measured draft on the upscaled model. The mean difference between the two is 1.71 N with 95% confidence interval of [-3.51, 6.93], which is very good given the average draft is approximately 330 N. Thus, the work indicates that both hypotheses are true for draft. However, the work shows that scaling muck pile particle sizes using the Buckingham Pi Theorem is not adequate to ensure good predictions of penetration. This work provides insights that will help design engineers to acquire useful data on scaled models and use it for various analyses on heavy machinery.

Oct 6, 2021

By R. C. Nkhoma, K. A. Annan, S. Ngomane

The effects of welding current, electrode force, and welding time in a resistance spot weld were studied to investigate the effectiveness of welded joints between a thin EN10130: DC04 material and a thicker 817M40 part, through analysis of the microstructural and mechanical properties. All welded specimens were subjected to tensile testing at room temperature (25°C) and sub-zero temperature (–46°C) to test the strength of the welded joints. No full button failure was observed at either room temperature or sub-zero temperature after optimization of the weldng parameters. The fusion zone was observed to consist mainly of martensitic phase, due to rapid quenching, while the HAZ was composed of clusters of martensite in a ferrite and bainite matrix. The base 817M40 metal remained fully ferritic after welding. The hardness was found to increase with increasing welding current. An increase in nugget size, indicating good fusion of the weld, was observed with an increase in the welding current.

Oct 1, 2021

By A. C. Johnstone

The aim of the study is to determine if pit lakes are a sustainable coal mine closure option in South African. The water balance, chemistry, limnology, and bacterial population of three selected pit lakes were investigated. The lakes are in the three major coal basins of South Africa and are associated with different lithologies and mining methods. The major factors driving the water balance of the pit lakes are direct rainfall, runoff, inflow from old mine workings, and groundwater infiltration, with the major losses being evaporation or discharge onto surface. The study indicated that pit lakes can be designed as ’terminal sinks’ to provide a sustainable mine closure option. The pit lakes sampled have an alkaline pH, and mostly a sodium/calcium sulphate water with total dissolved solids content of less than 3000 mg/l. The phytoplankton and microbiological data indicates that the pit lakes support aquatic life. The study shows that correctly designed pit lakes can be an environmentally sustainable closure option for South Africa’s coal mines. A suggested design manual has been developed to assist mine owners and regulators in developing sustainable coal mine pit lakes as a closure option.

Oct 1, 2021

By D. Sethuram, P. G. Koppad, S. Iyengar, R. Shobha

TiB2 and CeO2 particle-reinforced Al6061 hybrid composites were manufactured using stir casting and hot rolling techniques. The base alloy and composites were hot-rolled at 500ºC and a 50% reduction was achieved through 12 passes. The effect of varying TiB2 and CeO2 particle additions on the microstructure and mechanical properties of the Al6061 matrix was studied. Scanning electron microscopy showed uniform dispersion of both the reinforcements, with good interfacial bonding. Microhardness and tensile properties like yield and tensile strength were found to be higher for hybrid composite with 2.5% TiB2 and 2.5% CeO2 compared to Al6061 alloy and other hybrid composites. The increased tensile strength is attributed to good dispersion and interfacial bonding between the particles and Al6061 matrix. Fracture analysis using a scanning electron microscope revealed ductile fracture for the Al6061 alloy and mixed characteristics of ductile-brittle fracture for hybrid composites

Oct 1, 2021

By K. A. du Preez, P. J. van Staden, M. van Rooyen

Mine-impacted water, including acid mine drainage (AMD), is a global problem. While precipitation of dissolved metals and neutralization of acidity from mine-impacted water is accomplished relatively easily with lime addition, removal of sulphate to permissible discharge limits is challenging. This paper presents a high-level comparison of four sulphate removal technologies, namely reverse osmosis, ettringite precipitation, barium carbonate addition, and biological sulphate reduction. Primarily operating costs, based on reagent and utility consumptions, are compared. Each process is shown to be subject to a unique set of constraints which might favour one over another for a specific combination of location and AMD composition. Access to and cost of reagents would be a key cost component to any of the processes studied. The total cost calculated for each process also depends on the type of effluents that are allowed to be discharged.

Oct 1, 2021