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By D. Collins, J. Winfield, V. Gangrade, B. Slaker, S. Braganza

"Researchers at the National Institute for Occupational Safety and Health (NIOSH) are investigating the unique pillar stability issues associated with room-and-pillar mining in dipping underground stone mines. The objective of this paper is to study the post-blast impact in and around a pillar, using microseismic monitoring. To accomplish this, a microseismic monitoring system has been installed at a dipping underground stone mine in central Pennsylvania. The microseismic system is comprised of 18 uniaxial accelerometers; 12 sensors are installed in a single pillar and 6 sensors are installed in the surrounding area. More than 4,400 microseismic events have been located near the study pillar following the blasts. The number of triggers increased significantly following the blast, and the trigger rate in the first five minutes was 60 triggers per minute and three triggers per minute over the next three hours. The processing of high-quality triggers indicated a large number of low magnitude microseismic events near the blasting face. The event locations were identified more accurately by using a 3D-velocity model, with an average 9 m expected location accuracy for this array calculated using the system data. Seismicity was absent from the core of the pillar, but significant numbers of events were found following cutter roof along a crosscut as it was developed as well as in the location of a rib failure event. Additionally, the events were located in the roof, showing high number of microseismic events within 0–10 m of the roof line compared to 10–30 m above the roof line.INTRODUCTIONGround control stability is essential to any mining operation for ensuring mineworker safety and health and preventing catastrophic failures of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted research in stone pillar design and has established fundamental pillar design guidelines for the underground stone industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2018). However, the data that makes up the S-Pillar database consists of shallow depth, flat-lying, single-level mining operations. Therefore, to expand this dataset and to develop guidelines for challenging conditions such as dipping and multi-level mines, NIOSH is currently conducting detailed pillar response investigations at mines with these characteristics. The study is being conducted using multiple research approaches, including seismic modeling and tomography, numerical modeling (Sears et al., 2019), stress monitoring, and LiDAR-based laser scanning (Slaker, Murphy, and Winfield, 2019). This paper discusses the findings from the microseismic monitoring system installed at the Pleasant Gap Mine, a steeply dipping underground limestone mine in central Pennsylvania."

Jan 1, 2019

By Tim Robinson, Michael S. Moats, William G. Davenport, Andreas Filzwieser, Andreas Siegmund, Shijie Wang

This survey continues the long tradition of providing a snapshot of operating data from industrial electrorefineries. It is a supplement to previous surveys that were performed in 1987, 1991, 1995, 1999, 2001, 2003, 2007, 2010, 2013 and 2016. Analyses of current data and historical trends are presented. Examples of innovations to reduce costs, improve productivity, and improve quality are provided. In general, refineries continue to increase productivity while treating anodes with more impurities. INTRODUCTION This manuscript analyzes global survey data provided by operating copper electrorefineries. This paper continues a series of surveys of copper refining tankhouses that started in 1987 (Schloen, 1987, 1991; Schloen & Davemport, 1995; Davenport et al., 1999; Robinson et al., 2003; Moats et al., 2007, 2013, 2016). In this installment, data collected from 2015 and 2018 will be presented and analyzed. The 2015 survey data were presented at Copper 2016 in Kobe, Japan. This survey will continue the analysis of previous data to illustrate long term trends in copper electrorefining, which were originally presented at the Davenport Symposium in October, 2014 (Moats, Robinson, & Wang, 2014). Refineries who supplied surveys are listed in Table 1. Cathode production data from 2015 and 2017/18 (from surveys presented in 2016 and 2019) are provided to indicate which plants provided surveys and when. This manuscript presents operating data for ~6.5 million tonnes of copper production, which represents 30–35% of the world’s copper electrorefining production. The detailed survey results are available upon request from the corresponding author.

Jan 1, 2019

By L. Vollert

In August 2018, the first full-scale HydroFloatTM cells for the recovery of coarse composited copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales, Australia. The primary objective of the installation is to recover coarse value-bearing composites that are lost to conventional flotation tailings, without the need for additional power input for particle size reduction to improve mineral liberation. This paper examines the application of Eriez HydroFloatTM technology for the recovery of coarse, poorly liberated copper sulphide particles drawing on recent experience from lab scale testwork through circuit design and commissioning of the full-scale installation at Cadia Valley. INTRODUCTION In the face of declining copper head grades and a tightening regulatory environment around the use of wet tailings dams, the processing of copper ores at coarser particle sizes has become a focal point for the industry. Sulphide flotation using the Eriez HydroFloatTM is one of the emergent technologies that sits under this umbrella of coarse pre-concentration. It has been demonstrated through numerous lab and pilot scale testwork programs carried out by Newcrest and others (Awatey, Kohmuench, Thanasekaran, Skinner & Zanin, 2013), to improve the flotation recovery of sulphide-rock composite particles with low surface liberation, relative to conventional flotation technology. The HydroFloatTM technology has been used widely for the recovery of coarse potash, phosphate, coal, vermiculite, spodumene and diamonds but has never been applied at full scale in either gold or sulphide flotation. In August 2018, the first full-scale 3.4 m diameter HydroFloatTM cells for the recovery of coarse composite copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales. The primary objective of the installation is to recover coarse value-bearing composite particles that are lost to conventional flotation tailings, without the need for additional upfront power input for particle size reduction to improve mineral liberation.

Jan 1, 2019

By V. Vekris

A diverse patent portfolio and an effective intellectual property strategy are vital in today’s small business world. Not only does a diverse patent portfolio enable a company to secure a monopoly within the market, it greatly increases the value of a company’s intangible assets and keeps competitors at bay. An overview of the patenting process as it pertains specifically to the materials science-related start-ups will be given, together with a summary of some general patenting strategies and a review of some patenting errors to be avoided, such as premature disclosure of the invention to the public. Additionally, a review of new “green technology” initiatives recently adopted by Patent Offices around the world is also provided. These initiatives are expected to greatly benefit patent applicants in the fields of metallurgy and mining, where research efforts are often directed to environmentally-friendly products and processes. INTRODUCTION Patents are playing an increasingly significant role in the business world. A diverse patent portfolio can enable a company to secure a monopoly within the market, which can provide a competitive advantage over competitors. At the same time, patent portfolio of any size can greatly contribute to the total value of a company’s intangible assets. As an example, Nortel entertained bids in 2011 for its portfolio of about 4000 patents, a large portion of which were directed to 3G- and 4G-mobile communication technologies. The portfolio was eventually sold for $4.5 billion to a consortium including Apple, EMC, Ericsson, Microsoft, Research in Motion, and Sony. Copper mining, and indeed the global mining industry as a whole, is facing challenges. Ore deposits are increasingly low grade, complex, and deeper in the ground, rendering copper mining operations more difficult and costly. Production costs are increasing. According to one study, the cost of producing copper has increased by an average of 10% per year since 2005 (Cantallopts, 2017). To illustrate, the cost of producing a pound of copper in 2005 was 90 cents, but had increased to 217 cents by 2014.

Jan 1, 2019

By N. Molaei, E. R. Bobicki

The continued demand for mineral products, coupled with the depletion of high-grade ore resources, has led to the mining of lower grade ores, which often require fine grinding to achieve mineral liberation. Regrinding of low-grade ores results in the production of fine gangue mineral solids and produces vast quantities of fluid fine tailings which are difficult to separate from water, particularly if they are composed of clay minerals. Organic synthetic polymers and inorganic salts have been widely applied in flocculation of colloidal suspensions in the treatment of mining tailings. However, there are growing concerns regarding their impact on the environment and human health. Recently, extracellular biopolymer flocculants or bioflocculants have attracted much attention as alternative reagents. In this study, much effort has been devoted to considering the effectiveness of protein and polysaccharide-based biopolymers for the dewatering of clay slurries. The interaction between kaolinite and illite clays and biopolymers was investigated via settling tests at pH 7 and 10. Zeta potential measurements were also conducted as a complementary technique. Results showed that protamine and lysozyme protein- based biopolymers were generally the more effective bioflocculants. Pectin, a polysaccharide-based biopolymer, showed a dispersing effect and has the potential to be used as a dispersant and/or depressant for clay minerals in froth flotation. INTRODUCTION With the depletion of high-grade ore resources, the need for mining of low-grade ores has increased over the past few decades (Bourgès-Gastaud, Stoltz, Dolez, Blond, & Touze-Foltz, 2014; Chen, Walshe, Fru, Ciborowski, & Weisener, 2013; C. Wang, Harbottle, Liu, & Xu, 2014). Low-grade ores often require fine grinding and contain clay minerals, leading to the generation of fluid fine tailings (FFT). It is a challenging process to separate suspended clay particles from water (Craciun, Manaila, & Stelescu, 2013; Dompierre, Lindsay, Cruz-Hernández, & Halferdahl, 2016; Kasperski & Mikula, 2011; Mercier et al., 2012). Clay minerals form stable dispersions in water due to their anisotropic nature, non-spherical morphology and colloidal size (Lagaly & Ziesmer, 2003; Olphen, 1977). The difficulty in separating clay minerals from water has led to the accumulation of vast quantities of FFT in oil sands, phosphate, copper and nickel operations, representing a huge liability for mining companies (Chen et al., 2013; Mercier et al., 2012)

Jan 1, 2019

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019

By D. Sancho, M. Weber

"At the start of a new shaft project, a specific number of ground investigations are performed. However, it is not uncommon that the ground conditions during shaft sinking may differ from the designed ones. Therefore, it is extremely important to use tools which minimize discrepancies and to include a monitoring system in the shaft design to collect sufficient data. The paper presents an overview of existing monitoring techniques and discusses future works required to improve, not only the construction during shaft sinking, but also the lining design methodology. INTRODUCTION In most cases, the investigations performed at the start of a new shaft are based on the analysis of rock and soil probes obtained from boreholes. In practice, such analysis performed on a single core often leads to different results when conducted by various experts. The discrepancy in core analysis influences further rock mass assessment and design assumptions. It is not uncommon that the ground conditions during shaft sinking may differ from the designed ones, which affects the estimated stress and strain state of the shaft lining. Therefore, it is extremely important to use tools which minimize such discrepancy and to include into the shaft design a monitoring system to collect sufficient data, which enables control of important phenomena, not only during shaft sinking but also during the life of the shaft. Furthermore, the information collected during shaft sinking, while it is important for proper shaft lining design and updates to the shaft lining due to the local mining and geological conditions, it is also important after shaft sinking. In the whole shaft lifetime, it is not uncommon that the shaft lining is damaged and the liner needs to be renewed (Figure 1) due to various reasons. For this purpose, detailed information collected during construction can be extremely important."

Jan 1, 2019

By N. A. Beier, R. Amos, Smith. L., C. Atherton, D. R. Barsi, D. Blowes, D. C. Sego

"Waste rock is one of the most abundant materials at mine sites and must be properly characterized and managed to limit acid rock drainage and other harmful byproducts. An experimental waste rock pile—part of the test piles research program—located at the Diavik diamond mine (Northwest Territories, Canada) was deconstructed and sampled to study the spatial variability of material properties. Bulk samples were classified based on the amount of material finer than 4.75 mm. Hydraulic properties of each sample were estimated and particle size distribution analysis was completed. These datasets and classification methods might be used to improve the understanding of hydraulic and geochemical behaviour of the material and to study waste rock at other sites. ¦ KEYWORDS Acid rock drainage (ARD), Material classification, Particle size distribution (PSD), Waste rock RÉSUMÉ Les stériles font partie des matériaux les plus abondants sur les sites miniers et, en tant que tels, doivent être correctement caractérisés et gérés afin de limiter le drainage rocheux acide (DRA) et la pré¬sence d’autres sous-produits nocifs. Dans le cadre du programme Test Piles Research Program, un amas de roches stériles expérimental situé à la mine de diamant Diavik (Territoires du Nord-Ouest, Canada) a été décomposé et mis à l’essai afin d’étudier la variabilité spatiale des propriétés des matériaux. Les échan¬tillons en vrac ont été classés en fonction de la quantité de matériaux plus fins que 4,75 mm. Les propriétés hydrauliques de chaque échantillon ont été estimées et l’analyse de la composition granulométrique effectuée. Ces ensembles de données et méthodes de classement serviront à mieux comprendre le com¬portement hydraulique et géochimique du matériau et à étudier les stériles sur d’autres sites. ¦ MOTS CLÉS classement des matériaux, composition granulométrique, drainage rocheux acide (DRA), stérilesINTRODUCTION Statement of problem The characterization of mine waste rock remains a challenge in active mining sites. The large volume of material and the large size of particles make it difficult to collect representative samples. Sampling techniques are often dis-ruptive to mining operations because they alter the structure of the waste rock pile or interfere with mine traffic. The convention at most mine sites to collect little to no information on waste rock material means that models and predictions of how waste material will behave and interact with the surrounding environment are based on general information that might not be site specific. This could lead to environmental damage or higher costs if environmental effects are underestimated during the construction of waste rock structures."

Jan 1, 2019

By N. Bartie

Realising the circular economy (CE) is faced with some significant challenges. Process metallurgy and its infrastructure play key roles at the heart of making the CE work. Therefore, the enabling role of process metallurgy within the CE will be central to the discussion in this paper, touching among others on product and system design as well as the key metallurgical and other process fundamentals that need to be investigated and understood to make the CE a reality. The central role of materials and its processing will be discussed in an integrated circular cities perspective. A key focus will be a discussion on designing a resilient “Smart Materials Grid” using and innovating metallurgical process engineering tools, which will manage the flows through Sustainable Circular Cities. The discussion will be using copper as leitmotiv of the discussion i.e. from copper ore, to metal, to complex products, recycling, product design and simulation and its impact. INTRODUCTION The transformation of our economies from linear to circular models in which waste materials become resources is the focus of the Circular Economy (CE) paradigm. Its important intentions: to take control of the damage we have been doing to the planet to ensure its livability and the welfare of future generations. This can only be achieved through careful utilisation of human, natural and economic resources. The concept is derived from several others (Beaulieu et al., 2015), of which Cradle-to-Cradle, Extended Producer Responsibility (EPR), Industrial Ecology, and Life Cycle Thinking are just a few. Other relevant concepts include resource efficiency (RE), design-for-recycling (DfR), and various others discussed by Blomsma and Brennan (2017) and Homrich et al. (2018), as well as various R-hierarchies e.g. Reduce, Reuse, Recycle (3R). However, does society comprehend these concepts, the actors and actions that influence them and how they interact? Do we know the limits of CE? Does society understand the key role of Copper and other metals to rendering the CE operable? True life cycle and systems thinking, focussed on simulation-based, process and metallurgical design are required to answer these questions. Lieder and Rashid (2016) identify nine widely-varying fields that study the concept ranging from sustainability sciences and engineering to economics, business, law, and social sciences. Overlap between questions addressed highlights the need for interdisciplinary collaboration (Nanz et al., 2017) in the assessment of the current status, and further steps needed to transform to CE. This doesn’t apply just in academia, but also in industry where concrete implementation of CE needs to occur at multiple levels, thus necessitating cooperation between government, civil society and other stakeholders (Beaulieu et al., 2015).

Jan 1, 2019

By K. Mohamed, G. Rashed

A conventional mechanical anchor bolt consists of a smooth bar threaded at the anchor end, with a conical wedge, and a mechanical shell anchor. When the smooth bar is torqued, the conical wedge pushes the shell anchor against the borehole wall. Coal mines use mechanical bolts in addition to other types of bolts to control the deformation and stabilize the yielded coal ribs. Limited research has been conducted to understand how a mechanical anchor performs in a coal rib. Researchers from the National Institute for Occupational Safety and Health (NIOSH) conducted the study described in this paper to define the loading characteristics of mechanical bolts (stiffness and capacity) installed in coal ribs at five underground coal mines. Standard pull-out tests were performed in this study to define the loading characteristics of a mechanical rib bolt. Based on the strength of the coal seam and the conditions of the coal mines, the bolts were installed at different amounts of torque. A typical tri-linear load-deformation response was obtained from these tests. It was found that the anchorage capacity depends on the coal strength, and the anchorage stiffness depends on the installation torque. The outcome of this research provides essential data for rib support design. INTRODUCTION Rib falls are a serious hazard in underground coal mines. In the last 10 years, rib failures have resulted in 17 fatalities, representing 52% of the ground-fall fatalities in underground coal mines in the United States (MSHA, 2018). Although resin bolts has been used increasingly in the last few years to control coal ribs, mechanical bolting (mainly expansion-shell bolts) is still used in many underground coal mines. Recently, NIOSH researchers surveyed 90 sites in 14 underground coal mines in the Eastern United States and found that 79% of the mines determine their rib support requirement based on the depth, mining height, and the loading conditions, of which 35% use the conventional mechanical bolts. Conventional mechanical bolts are preferable for rib support because they do not require the miners to be too close to the rib during rib bolting. Hence, using the conventional mechanical rib bolts can reduce the risk of injuries and fatalities during the installation process. The mechanical bolt or the point-anchored bolt is the oldest type of rock bolt that is still in use today. The point-anchored bolt is a tensioned bolt anchored down the hole with a mechanical expansion shell or a grouted medium (Peng and Tang, 1984). Figure 1 shows the components of the mechanical anchor bolt. The mechanical anchor bolt consists of a plug, a shell anchor, a headed smooth bar with the top end threaded, a bearing plate, a hardened washer, and sometimes a friction-reducing washer. The shell anchor can be either standard or bail type. The shell of the standard type is held in place by a nut, while the bail anchor uses a strap to hold the shell in place (Peng, 2008). The diameter of the smooth bar is generally 5/8 in for the #5 bolt or 6/8 in for the #6 bolt. The diameter of the hole that the bolt is inserted into must be carefully controlled since an oversized hole can result in poor anchorage (Moss, 1971). The anchorage is obtained by applying torque to the bolt head, which in turn pulls the wedge down in the shell and expands the serrated leaves against the sides of the hole-wall. In the resin-grouted anchor, the resin replaces the mechanical expansion shell at the end of the hole. The anchorage is achieved by bonding between the resin, bolt, and the hole-wall.

Jan 1, 2019

By Jacob Wood, Robert Matusewicz

The Outotec® Ausmelt Top Submerged Lance (TSL) Process has achieved widespread commercial acceptance over the past 40 years for the processing of copper, nickel, lead, tin, zinc and precious metal bearing feeds. The continual development and evolution of the technology during this period has resulted in a more intense smelting process with higher energy efficiency and lower operating costs. More recently, considerable effort has been invested in decarbonisation of the process through improvements such as increased oxygen usage, dry feed injection and use of low-carbon auxiliary fuels. This paper covers a number of these recent advances to the technology and highlights their impacts on energy consumption and CO2 emissions for a range of non-ferrous smelting flowsheets. INTRODUCTION Relentless demand for improvements in the profitability, safety and environmental performance of non-ferrous smelting plants has driven a continual development and evolution of processing technologies in this industry. In response to these demands, a number of bath smelting technologies have emerged over the past 40 years and have been implemented for the treatment of primary and secondary feedstocks. The Outotec® Ausmelt Top Submerged Lance (TSL) Process (henceforth Ausmelt Process) is one such bath smelting technology which has been widely adopted in a large number of greenfield projects and brownfield plant modernisations (Wood & Hughes, 2016). Emissions of CO2 from the production of non-ferrous metals represent approximately 4-5% of global totals (Rankin, 2012), comparable with the almost 10% attributed to iron and steel production. Despite significant improvements in the energy efficiency of modern smelting technologies (Coursol, Mackey, Kapusta & Cardona Valencia, 2015), primarily through increased oxygen usage, further innovation and development is still required to address their reliance on fossil fuels such as coke and coal. Transformation of the non-ferrous smelting industry to low-carbon technologies and process flowsheets is lagging behind the power and transport sectors, which have witnessed significant growth in clean/renewable energy technologies to reduce CO2 emissions and address the issue of anthropogenic climate change (IRENA, 2018; IEA, 2018).

Jan 1, 2019

By Zhiyang Long, Ruiling Xiao

"A mine shaft is one main development method of establishing access in an underground mine. The construction technology of the mine shaft sinking is complicated and large equipment setup on surface and in the mine shaft. The paper briefly reviews a single-line operation method, parallel operation method and mixed operation method as well as the features of the one operation method with the excavation, lining and installation. The special construction technology mainly would include ground freezing methods, full diameter shaft drilling methods, caisson methods, grouting technology and concrete curtain methods as well as other methods. The paper summarizes the shaft sinking numbers and effects by the special construction methods during different periods. The paper states the shaft sinking conditions and the each created record conditions in the coal, metallurgy, non-ferrous metal, hydropower, highway, railway, nonmetallic and other industries. The paper has a prediction on the shaft sinking requirements and development tendency in the future for China.INTRODUCTIONA mine shaft is one main development method of access in an underground mine. In recent years in China the new shaft mines represent 45% of the total number of new mines. With the development of new mining area under construction and the development of deeper mines, the ratio of the mine shaft as access for underground mines will increase. The construction technology of the mine shaft engineering will be complicated, the operation site footprint will be small and the working environment will be more difficult. The mine shaft sinking operation will often be varied by the geological conditions and affected by underground water inflows, seam gas outbursts, geothermal and other natural conditions. The safe construction of the mine shaft sinking will be challenged by all these conditions. Although the mine shaft engineering will only be about 5% of the total mine roadway engineering, the mine shaft construction period often will take over 40% of the total mine construction period. With the progress of modernized mine production technology and the construction of a high production and high efficient mine, the mine transportation roadways mostly would be set in the seam and the engineered amount of the mine rock roadways reduced year by year could cause more prominent long extensions of the mine shaft construction period. Therefore, in order to speed up the construction, to shorten the mine construction period and to realize the investment benefits as early as possible, the technical level of the mine shaft sinking should firstly be improved and the construction speed of the mine shaft engineering and sinking should be speeded up, which would have important significant benefits."

Jan 1, 2019

By M. Narita, S. Nakayama, M. Fujihara

Hibi Kyodo Smelting Co., Ltd. was founded in 1968 and celebrated its 50th anniversary in 2018. In 1972, we started producing copper cathode with a production capacity of 84 KTPY. Since the company founding, we have undertaken seven expansion projects, and our current copper-cathode production capacity is 290 KTPY. To increase our production efficiency, two tank houses were converted from Conventional process to ISA process in 2006 and 2014. In another investment, we equipped a continuous glue dosing system, which allowed for strict additive-concentration control, yielded quality improvements and reduced the power-consumption rate. Along with an increase in the production of copper cathode, the amount of impurities eluted from the anode increases. To solve this problem, the chelate-resin purification process that was introduced in 1983 was renovated, and impurities could be recovered more efficiently. In this paper, we report various improvements that have been implemented at the refinery since 2000. INTRODUCTION Tamano Smelter and Refinery of Hibi Kyodo Smelting Co., Ltd., founded in 1968, celebrated the 50th anniversary of its founding in 2018. The Tamano Smelter opened its No. 1 tankhouse in 1972, and began operating No. 2 tankhouse in 1984. Thereafter, with continuous production increases and technical improvements, electrolytic copper production was increased from 84 KTPY to 290 KTPY as shown in Figure 1. Table 1 shows the major operating facilities and operation data in 2017.In this paper, details of equipment introduced to continuously dissolve and add glue, various improvements made to the chelate resin process, enhancements made to the crude Ni sulfate process, and another vibrating screen introduced to the copper slime processing flow in accordance with the expansion of copper production capacity since 2000 are reported.

Jan 1, 2019

By H. A. Khorami, T. Wong, B. Velapatino, E. Asselin, T. Donnelly, E. Bryce, R. Dixon

A copper–nickel concentration gradient alloy was designed and fabricated through a powder metallurgy (PM) process. Copper and nickel powders were mixed with different weight ratios from 0 to 100% copper in 10% increments. Each powder mixture was poured inside a cylindrical die and compacted between two punches using a hydraulic press machine at pressures up to 70 MPa, resulting in approximately 1 mm thick layers (discs) of pressed Cu–Ni powder. These 11 Cu–Ni compacted powder layers, i.e. 0–100% Cu with 10% increments, were then compressed together with pressures up to 420 MPa to form a green part. The green part was sintered in a vacuum furnace at 1000°C for 10 hours to form a solid mass (PM part) of Cu–Ni concentration gradient alloy. In the sintering process, Cu and Ni particles fused together and formed a single piece due to diffusion of the atoms across the boundaries of the particles. The diffusion of atoms also converted the stepwise concentration change into a uniform concentration gradient. INTRODUCTION Copper has numerous applications in different industrial sectors due to its superior physical, electrical, mechanical and chemical properties such as its excellent thermal and electrical conductivity, resistance to fatigue, high ductility, and resistance to corrosion. Moreover, copper and its alloys have natural antimicrobial properties. This has opened up new applications for copper–based self–disinfecting surfaces in healthcare in an effort to mitigate healthcare–associated infections (HAIs). HAIs affect millions of patients each year, leading to significant morbidity and mortality as well as financial losses to healthcare systems (World Health Organization, 2016). HAIs spread through three main routes: (a) iatrogenic in which HAIs are a direct consequence of medical encounters and/or treatment; (b) person to person where organisms are transferred between healthcare workers, patients, and visitors; and (c) environmental where transmission occurs via contaminated surfaces and equipment (e.g. doorknobs, railings, toilets/commodes, medical carts). The use of antimicrobial copper–based materials on high touch surfaces could diminish pathogen transmission via this latter rout. This has subsequently led to the development of a variety of copper–based materials for use in healthcare settings and promoted the investigation of the antimicrobial efficacy of copper–based materials.

Jan 1, 2019

By Jeffrey D. Eisenman

FRP is a proven material for the solvent extraction processes of copper production. There is a history of successful applications of FRP piping and equipment in hydrometallurgical processing. The performance of FRP equipment has not always been consistent, but at no fault of the material. Its non-metal attributes and behavior vary from those of more typical materials of construction, such as steel and alloys. FRP is a mainstay material in many areas of solvent extraction and electrowinning and yet not well understood by all. We will discuss the critical concerns, which are key to reliable performance of FRP systems. This paper will include discussion of key elements, which are fundamental to reliable FRP piping design and considered best practices. Essential design and construction considerations to maximize reliable service life of FRP equipment, such as thickeners and process vessels, used in copper extraction and processing, will be discussed. Additionally, we will expose potential pitfalls and share lessons learned from previous copper processing plant projects, which can aid and impact other copper processing projects to ensure best system performance and reliability. INTRODUCTION The corrosion resistant attributes of fiberglass reinforced plastics (FRP) make it an attractive and cost effective material of construction in corrosive service applications that are found in copper processing. FRP is used all over the processing plant in seawater, brine and sulfuric acid services where the corrosive nature of these services would challenge most ferrous materials and coatings. FRP is a fully customizable material to meet the specific needs of each service and process. FRP piping and equipment can be found throughout the hydrometallurgical process, in the acid plant, desalination, leaching processes, solvent extraction and electrowinning to name a few. Beyond its superior corrosion resistant characteristics, FRP can be made abrasion resistant by introducing particulate additives into the resin, such as silicon carbide and alumina oxide. Because many of these services have combustible organic elements in the flow streams with accompanying safety concerns, the linings can be made conductive with carbon fibers to dissipate static charges that might collect on the surface of the equipment otherwise. Further, FRP can be made flame retardant as well, where flammability may be of concern.

Jan 1, 2019

By Euler De Souza

"The uninterrupted operation of a ventilation system is critical to ensure the mine meets its scheduled production and, as important, is vital to the health and safety of all personnel working underground. Those operating the mine ventilation system must have fundamental engineering training in the art of fluid dynamics and have a good comprehension and control of the mine ventilation network. Ventilation management by untrained and inexperienced personnel may result in serious consequences when the system becomes ineffective. This paper shares observations and experiences pertinent to the occurrence of upset conditions as a result of the improper design and operation of mine ventilation systems. A series of real life case studies are presented to describe disruptions to mine ventilation systems and the gradual deterioration of system operational efficiencies leading to eventual failure. Special focus is given to mistakes made and on the resulting serious consequences. The case studies also demonstrate how each upset condition was resolved, permitting the mines to safely resume production activities.INTRODUCTIONThe ventilation of operating mines is a continuously changing and evolving system; upset conditions will occasionally occur, but should be promptly resolved in order for the system to function properly, according to design, and in compliance.Those designing, managing or operating the mine ventilation system must have pertinent training and have a good understanding of fundamental ventilation concepts to be able to devise and implement engineering solutions to day-to-day challenges. Realistically, the operator must also have extensive practical experience and be able to effectively apply operating procedures, design criteria and ‘best practices’. They must be able to, on a daily basis, evaluate the mine ventilation system, determine and locate any problems, understand the causes of each problem, find a solution, and promptly and efficiently correct those problems.Ten case studies are presented to demonstrate how fundamental design or operational mistakes can lead to adverse conditions or to catastrophic consequences, how detailed on-site engineering assessments can be employed and how simple, low cost, engineering solutions can be implemented to successfully resolve the issues and return the ventilation system to compliance, permitting the mines to safely resume production activities."

Jan 1, 2019

By Caitlyn J. McKinley, Ahmad Ghahreman, Maziar E. Sauber

Ever-growing global needs for critical metals, such as rare earth elements (REE), and base metals, such as copper and nickel, and their environmental impact motivated the pursuit of sustainable flowsheets. Regeneration of hydrochloric acid in chloride-based leaching flowsheets as a critical unit operation is an example of such endeavours. This study presents an efficient hydrochloric acid regeneration method from a magnesium chloride solution waste by addition of sulphuric acid in relatively low temperatures. The effects of temperature, initial magnesium chloride concentration, amount of sulphuric acid added, and airflow are examined. Experimental work are focused on temperatures between 80 and 95°C, initial magnesium chloride concentrations of 2 to 5 M, 100% to 220% stoichiometric sulphuric acid additions, and airflows between 200 to 600 mL/min. The developed technology recovers hydrochloric acid at a high rate and concentration with a relatively small environmental footprint. INTRODUCTION The mining and metals sector is under increasing environmental and economic pressure to make more efficient use of chemical reagents and energy in the production process. This affects several areas of process and flowsheet design such as the selection of the most appropriate unit operations and the overall design of the process steps paying heed to sustainability. Owing to the inherent inefficiencies of physical and chemical processes used in the mining industry, there will be materials and streams generated that are not a desirable part of the envisaged flowsheet. Thus, methods are implemented to recover and recycle such effluents. If the recovery and recycling are not economical, then procedures are followed to neutralize and dispose these effluents. In many cases, these effluents are potential contaminants or hazardous materials, and their disposal should be looked at in a much larger context. The safe management of the contaminants and hazardous effluents is a daunting problem in the mining industry and is fraught with technological, economic, social, and political challenges.

Jan 1, 2019

By L. Frost

"Since the late 1990s, increased prevalence of severe lung disease among US coal miners has been observed, particularly in central Appalachia where thin-seam mining is prevalent. While respirable silica exposures have been implicated in many cases, the available dust monitoring data from mines shows no explanatory trends. One possible factor could be differences in the relative toxicity of silica particles based on their surface condition. Previous research has indicated that particles with occluded surfaces (e.g., by a thin layer of clay) may be less toxic than those with non-occluded surfaces. However, this dust characteristic has not been investigated before now in central Appalachian mines. In the present study, 18 respirable dust samples from seven central Appalachian mines and two northern Appalachian mines were analyzed to assess the relative occurrence of surface-occluded silica. Results showed that the dust from central Appalachian mines actually had higher fractions of occluded silica, which may be due to extraction of large amounts of rock strata along with the coal. However, the central Appalachian mines also more silica particles overall (i.e., occluded + non-occluded) in terms of total number percentage of respirable particles.INTRODUCTIONResurgence of occupational lung disease among US coal miners, especially in the central Appalachian region, has been observed since the late 1990’s (Gibson, 2016; Zosky et al., 2016; Suarthana et al., 2011; Gamble et al., 2011; Antao et al., 2005; Attfield & Sexias, 1995). In addition to increased prevalence of simple Coal Workers’ Pneumoconiosis (CWP, or “black lung”), the prevalence of severe and rapidly progressive disease has risen dramatically (Almberg et al., 2018; Blackley et al., 2018a, 2018b, 2016, 2014; Graber et al., 2017; Cohen et al., 2016). While exposures to respirable silica have long been known to cause or play a role in diseases such as silicosis or progressive massive fibrosis (PMF), which is conventionally considered as the most advanced form of CWP, it is unclear whether silica is the only culprit in the recent outbreak of severe disease. Indeed, as disease rates have risen, both total respirable dust and silica concentrations generally appear to have declined since the late 1980s, based on regulatory monitoring data in the most affected mining districts (i.e., MSHA coal Districts 4, 5 and 12, which cover central WV, eastern KY and southwestern VA, and southern WV, respectively) (Figure 1). Of course, the latency of disease can vary and may be or more 10 years, but many of the most recent cases are likely to have resulted from exposures that occurred since the late 1980s."

Jan 1, 2019

By R. Dawes, B. R. Davis, T. LeBel, C. Pelow

Settling of copper, lead, and other metals in slags is an important part of overall recovery of metals, both in primary and secondary operations. The impact of slag reduction on settling is not well known. This is important since the cycle time for slag cleaning can be significantly changed with reduction of slag, through a decrease in slag viscosity and growth of metal/sulphide particles. KPM has worked with a number of primary and secondary recyclers to better understand how reduction of slag can improve overall operation. In this presentation, we describe the type of test work and analysis done and how this information can be used to guide improvements in metal recovery from slags. INTRODUCTION Typically, copper smelter slags contain about 1-2% copper, both in the form of copper and copper sulphide beads and dissolved copper oxide in the slag (converter slags are recycled to the smelter). With the average grade of world copper deposits close to 0.7%, it is practical to recovery copper from these slags. This is done routinely by one of two methods. The first method uses slow cooling in large ladles or beds to grow particles of copper sulphide. The slag is then crushed, milled, and floated for copper recovery. The slow cooling promotes precipitation and growing of the sulphide particles from the solution and then, the slag can then be milled to recover the copper through froth flotation. A consideration of this process includes the energy cost related to grinding, the use of water, capital cost for ladles, and the availability of tailing dumps. At the same time, the retreatment of the Cu concentrate produced in the mill will displace fresh concentrate, which ultimately results in a reduction of the throughput. The second method is the so-called “slag cleaning” and is based on the settling of copper and copper sulphides particles dispersed in the slag. This is achieved by decreasing its viscosity by increasing the slag temperature and reducing the iron spinel solid phases (magnetite) that increase the apparent viscosity of the slag. Typically, the reduction does not extend to the reduction of copper, and soluble copper (mainly as oxide) and fine matte particles remain at concentrations typically at or above 0.5% (Cardona et al., 2011; Cardona, 2011). This is an improvement on 20 years ago when slag was sent to dumps at 1% or less (Demetrio et al., 2000).

Jan 1, 2019

By M. Kuchta, S. Iverson

INTRODUCTION Underground blasting with perimeter damage control can reduce the requirement for loose rock scaling and reduce the risk of ground-fall injury. In previous work Johnson and associates (2010) from the National Institute for Occupational Safety and Health (NIOSH) developed a rock blasting perimeter damage and control design method included in the DRIFT software tool (NIOSH, 2018). This blast design software tool utilizes current methods of perimeter blasting with the added design element of a buffer row coordinated with the perimeter row to reduce perimeter damage. The coordination is in applying one of several blast damage models to calculate the damage extent for each production, buffer, and perimeter blast hole in the design. The calculated damage is then applied to the spacing between the blast holes. The basis of the buffer row design is the practical damage limit and is supported in this paper with computer models of signature blasts and full blast rounds using PFC2D (Itasca Consulting Group, Inc., 2018). Practical damage limit The practical damage radius (Rd) is not to be confused with burden. The practical damage extends toward the burden side and inward into the rock mass. For all practical purposes, the practical damage radius equals one half the burden (Hustrulid, 1999). The maximum extent of radial crack damage around a blast hole (Rcrack) and the maximum extent of radial crushing damage (Rcrush) are illustrated in Figure 1. A “practical” radius of damage (Rd) lies between the crushing limit and the cracking limit. The “practical” damage means that if the rock mass lying outside of the practical damage circle were removed, the rock remaining within the circle would easily break apart. Blast pressure and strain Work by Johnson (2010) and associates included signature blast tests in large concrete blocks. A signature blast test in concrete as exampled by strain data in Figure 2 was designed to monitor the dynamic strain at incremental distances from a single fully coupled blast hole, measure crushing and radial cracking extent by wire-sawing to expose the damage, and relate the damage to overbreak that is common in underground blasting. The initial slope or rising strain as the stress wave passes by the strain gages shows very high strain and strain rates close to the single blast hole. Since the derivative of strain versus time is strain rate, a line tangent to each of the strain curves at the maximum strain rate is drawn and the strain rates identified. The high strain rates were then plotted on a semi-log in Figure 3 to show a linear trend. The strain rate is greater than 100 s-1 within 20 cm from the blast hole for the signature blast experiment. The strain rate at the blast hole wall is projected to be 300 s-1. Figure 4 illustrates the damage in the NIOSH block exposed by a wire saw cut.

Jan 1, 2019