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By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By N. Tounsi

The use of analytical modeling of continuous chip formation in conjunction with orthogonal cutting experiments was presented in the open literature to identify the coefficients of material constitutive equation within the practical range of stress, strain, strain rate, and temperature encountered in metal cutting. Identification of reliable constitutive data was hampered by a lack of a reliable model for the prediction of the primary shear zone thickness that affects directly the effective strain rate field. An original analytical model to determine the primary shear zone thickness is proposed in this paper. It is based on the mechanics governing the material flow in the primary shear zone. Based on the distribution of the hydrostatic pressure and the forces measured from orthogonal cutting tests, the model that describes the thickness of the primary shear zone is derived. To validate the model, FE simulations of chip formation using DEFORM3D were carried out for different materials and cutting conditions. The results of the analytical model are in reasonable agreement with FEM results.

Jan 1, 2006

By B. S. W. Buffam

"The property of Aunor Gold Mines, Limited, is in Deloro township, Ontario, about 3 miles southeast of Timmins. It consists of a group of eleven claims between the Buffalo Ankerite and Delnite mines.In the autumn of 1909, two brothers, John A. and W. S. Mitchell, joined the 'gold rush' to Porcupine. By the time they arrived the township of Tisdale, in which the Hollinger and Dome discoveries had been made, was staked solid but they managed to locate four claims in the northern part of Deloro township. Sufficient surface work was performed to bring the claims to patent in 1915. Following the Porcupine fire the Mitchells left the north to follow the oil developments in southwestern United States. In 1935 because of the rise in the price of gold and the successful development of the l3uffalo Ankerite and Delnite mines, they returned to Timmins and organized Augite Porcupine Mines, Limited, which combined the original four claims in Deloro and two adjoining claims controlled by Montreal River International Silver Mines, Limited. There were few rock exposures on the property, and as the overburden was generally deep surface exploration was impracticable. A programme of diamond drilling was, there; fore, undertaken in an endeavour to locate the western extension of the orebearing formation of the Buffalo Ankerite mine. This drilling was started in August 1936, and 5 months later ore was intersected at a depth of 500 feet on the south boundary of the property."

Jan 1, 1954

By D. G. Eskin

"It is well known that it takes some time for the solid phase to completely dissolve upon melting, especially inside the defects of insoluble particles, e.g. oxides. Until then the oxides remain active solidification substrates in the case of subsequent solidification. It is also known that ultrasonic melt treatment causes grain refinement through activation and dispersion of solidification substrates (one of the mechanisms) and also accelerates the dissolution of solid metal in the melt. In this study we combine these effects and demonstrate that the introduction of an alloy rod into the matrix melt of the same composition results in significant grain refinement, this effect being increased by the ultrasonic vibration of the rod. The achieved grain size is comparable to that obtained by a standard Al–Ti–B grain refiner. All samples were cast using a standard TP-1 mould to enable correct comparison. The effect of the temperature range of the rod introduction, as well as the effect of ultrasonic vibrations are discussed.INTRODUCTION The fact that by introducing solid metal into the melt one can achieve structure refinement is rather well known. As early as in the 1930s–1950s a series of papers and patents have been published, showing the benefits for grain refinement when dissolving solid metal in the melt before solidification (Danilov and Neimark, 1938; Scheil, 1956). Later on this way of structure refinement was developed further and dubbed “suspension casting” or introduction of “internal chills” (Madyanov, 1969; Zatulovsky, 1981). The solid metal was added in a form of cut wire, cut sheet, or powder, with the resulting grain refining, elimination of columnar grain structure in ingots and castings of steel, copper and aluminium alloys. The underlying mechanisms have been suggested as (1) rapid cooling of the melt due to the latent heat consumption upon melting of the solid metal with the resultant melt undercooling and (2) introduction of many solidification substrates in the form of crystal fragments and active non-metallic inclusions (Danilov & Neimark, 1938; Balandin, 1973). A number of patents have been filed where either the same solid alloy or a master alloy with additions (e.g. Ti for Al alloy) is introduced in the amounts up to 50% (typically less than 10%) into the melt close to the liquidus temperature (Schmidt, 1966; Talbot & Soller, 1973, Krupp, 1974; Bondarev, 1979). The main reason that this technique is not widely used in industry is the possible incomplete dissolution of the solid parts introduced into the melt with ensuing inhomogeneous as-cast structure and potential defects. Also the selection of the temperature range where the technology works the best is not clear."

Jan 1, 2018

By R. P. van Hille, N. Mooruth

Remediation of acid rock drainage (ARD) was performed within a linear flow channel reactor (LFCR) via a floating sulphur biofilm (FSB). A full sulphur species material balance was conducted in order to characterize the sulphide oxidation. The reactor was able to achieve an 82% and 93% conversion of sulphide with a hydraulic residence time of 2 and 5 days respectively. 92% and 55.5% of the converted sulphide reported to the biofilm as sulphur for the 2 and 5 day residence times respectively. The mass transport limitations within the biofilm were identified via a dissolved oxygen gradient profiling system.

Jan 1, 2011

By R. M. Oliver

THE Falconbridge property is almost completely covered with over-burden to a depth varying from 60 to over 200 feet. This overburden consists of grave], sand, and boulder, with bands of very fine silt, and there is usually a layer of water-bearing quicksand adjoining the r:ock surface. In previous shafts sunk at Falconbridge, this water-bearing quicksand had given considerable trouble, and further difficulties were expected in sinking No. 5 shaft, due to its greater size. The method described in this paper is the one adopted in sinking this shaft, after the matter had been carefully considered. No. 5 shaft is located 2,400 feet east of the old main No. l shaft, and is sunk in norite in the hanging-wall of the ore-body, which is, however, ? practically vertical to the deepest known intersection. The greatest depths of overburden prevail on the south side, or footwall, of the ore-body, and this, together.. with the fact that the footwall is wet and more badly fractured, swayed the final decision to sink in the hanging-wall. After the shaft site had been chosen and cleared, a diamond drill was set up a few feet away and a hole bored to a depth of 405 feet to test the over-burden and character of the norite bedrock. The depth of overbudren indicated by the hole was Ill feet, with the last 10 feet water-bearing. The norite was rusted and broken up for only a few feet below bedrock. A steel sinking shield (Figure l) was assembled at the shaft location, and consisted of 5/8-inch plate, 5 feet deep, built around a frame of 6 inch by 6 inch angle-iron, and braced at the corners with the same material. Twelve-inch I-beams held the shield as rigid as possible. In order to reduce binding against pebbles to a minimum, the shield was constructed with a 1-inch batter on all sides.

Jan 1, 1938

By L. Vinnett, T. Ledezma, F. Contreras, F. Díaz

"Mass balances in secondary grinding are subject to critical constraints mainly because of the unknown load distribution from the SAG mills, the uncertainties in the hydrocyclone split estimations and the lack of flowmeters in the key streams. In this paper, a methodology to support mass balances based on the use of radioactive tracer is presented. This approach was successfully implemented in two secondary grinding circuits of Minera Los Pelambres, which operate with ball mills of 21’ x 33.5’. The method allowed the load distribution of the SAG product (secondary grinding feed) to be determined. This load distribution was used as an input in the mass balance data reconciliation.The effective residence times of solid tracers were obtained in the secondary grinding equipment, where irradiated solid was used as a tracer. The residence times were obtained from the parametric deconvolution between the input and output tracer signals. The model fitting was performed to reconstruct the normalized output tracer concentration. Effective residence times of solid tracers in the ball mills ranged from 1.9 min to 9.5 min. The use of radioactive tracer measurement in grinding circuits is a powerful tool to consolidate mass balance results as well as to characterize grinding mills.INTRODUCTIONGrinding is the last stage of the comminution circuits. At this stage, the ore particles are reduced in size by a combination of impact and abrasion, either dry or wet (Austin & Concha, 1994). The grinding equipment mostly used in industrial operations correspond to horizontal tumbling mills (Wills & Napier- Munn, 2006). Tumbling mills employ steel balls or rods as grinding media. Ball mills, which are a type of tumbling mills, use steel grinding media with greater surface area per mass unit than SAG (semiautogenous grinding) mills or rod mills (primary grinding). Hence, the ball mills are suitable to obtain the particle size required in the next separation stages (Napier-Munn et al., 1996; Wills & Napier-Munn, 2006)."

Jan 1, 2016

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By W. Hunka

PACIFIC PETROLEUMS, Ltd. first discovered commercial quantities of gas in the Peace River area in 1952. Development of gas wells in this area is quite ex-pensive due to low penetration rates. To improve the economics, the potential of the wells in many cases had to be increased. At that time, well stimulation was still in its infancy in Canada and in this area, in particular, no treatment of any consequence had been attempted. Therefore, trial-and-error was the only means available to determine the stimulating technique that would give optimum results. Various fluid treatments were available and these were used wherever the application was warrant-ed. This paper covers acid fracture and explosive treatments as carried out on various gas-bearing horizons.

Jan 1, 1958

By Naoki Takada, Dae-Sung Cheon, Minoru Sato, Masaji Kato, Manabu Takahashi, Weiren Lin

"The permeability and specific storage of rocks and sedimentary layers deep underground are critical parameters for issues related to the buried evaluation of natural gas and oil, CO2 aquifer storage, various kind of waste storage and so on.The Shirahama sandstone of the Wakayama prefecture, Kii peninsular in central Japan, consists mainly of quartz grains with no cracks and rock fragments that are aggregations of various kind of minerals. The quartz grains have an average size of about 150 micron. The pre-existing pore sizes were distributed dominantly at approximately 1 micron, and the total porosity was about 13%.During the hydrostatic compression test, we measured permeability of Shirahama sandstone by Transient Pulse test for three mutually perpendicular directions. Permeability of Shirahama sandstone remained fairly constant while increasing the effective confining pressure. Permeability anisotropy was observed slightly in the normal and two parallel directions to the bedding planes.We used micro focus X-ray CT with high resolution of 10 micron to visualize and measure the voids space information in Shirahama sandstone. Three-dimensional data were obtained in the intact and stressed sandstone simultaneously. Pore structures and grain boundaries were clearly distinguished. Pore closure and grain movement were clearly observed with increasing confining pressure. Micro focus X-ray CT is an effective tool to visualize and measure the geometrical information in rocks.Three-dimensional medial axis (3DMA) method was introduced to quantify the flow-relevant geometric properties of the voids structure in Shirahama sandstone using µfocus X-Ray CT data. The number of connecting path between two faces, tortuosity and the shortest path distribution within an arbitrary region of Shirahama sandstone specimen were analyzed. Geometrical information on the number of connecting path shows reasonable correlation between permeability anisotropy and mutually perpendicular directions normal and parallel to bedding planes. In addition, we introduced numerical simulation of fluid flow of pressurized Shirahama sandstone by LBM, to discuss the permeability change caused by pressurization on effective confining pressure. We obtained the detailed distributions of fluid pressure and fluid velocity in relatively narrow voids space more than 10 µm. It was confirmed that pressurization effect on permeability caused by the decrease of the connecting path and the shortest path between arbitrary faces, and then caused a complex condition on fluid pressure and fluid velocity."

Jan 1, 2015

By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By D. J. MacDonald

UNDERGROUND development at the Lynn Lake property of Sherritt Gordon Mines, Limited, was begun in 1948 with the sinking of the A shaft in the area of the A orebody. By June, 1949, the shaft was completed to a depth of 1,024 feet. Twelve stations were cut, with the bottom level at 992 feet below the collar. Since completion of the shaft, lateral work has been carried out on the 12th level in order to expose the known orebodies and to provide openings from which deeper exploration could be conducted. Dur¬ing the change-over from sinking to lateral work, preliminary diamond drilling was done from the 12th level station to locate the A? ore-body. Later, drilling was carried out from the 5th and 9th level sta-tions, where, also, the outline of the A orebody was established. As the work progressed on the 12th level, and with the commence-ment of drilling below that level, the geological picture was found to be complicated by numerous faults. Instead of operating two drills it became necessary to use at least four. The original plans had provided air sufficient to drive two headings and to operate two diamond drills. The addition of two more air-driven drills resulted in a serious shortage of power.

Jan 1, 1951

By G. W. Poling

"Construction, equipping and planned operation of a new laboratory for engineering-teaching and research in coal and mineral processing is described. This facility will provide approximately 1860 m2 (20,000 ft. 2 ) of laboratory space with nearly half devoted to a new venture in coal preparation. Two high-bay, overhead crane-accessed areas will accommodate major unit operations for each of the ""coal"" and ""mineral"" laboratories. COAL PREPARATION FACILITIES:The coal facility provides three main functional areas:(1) Sample preparation (drying, blending, crushing, screening) and sink-float washability testing.(2) Unit operations U1igh-bay, serviced by crane).(3) Analytical laboratories.(l) Sample Preparation and Sink-Float TestingBreaking or comminution of coal will be accomplished using a rolls crusher, a hammer mill, a jaw crusher, or a pulverizer. Capacity to prepare coal at rates of up to approximately 4 tph will be provided by some of these units. Large diameter (~0.5m) baths of heavy organic liquids will be available for sink-float washability tests on coal samples of several kg. Particle sizes of up to 25 mm can be tested in these baths. Smaller scale washability tests on finer samples will be accelerated by centrifuges."

Jan 1, 1980

By J. M. Cummings

The importance of controlled sand properties to the production of quality castings has been recognized by foundry men for many years, but the maintenance of requisite standards results in a relatively high sand consumption, which in steel foundries, for instance, may range from half a ton to over one ton of sand per ton of finished casting. During the war, obtaining and maintaining adequate sand supplies became a serious problem in many foundries, owing to increased wartime production and serious 'bottlenecks' in transportation. As a result, considerable interest was aroused in the possibilities of various sand reclamation systems by which up to 85 or 90 percent of discarded sand may be returned to a usable condition. During the past five years or so, a number of sand recovery installations have been made by both ferrous and non-ferrous foundries in Canada and the United States, and have resulted in substantial reductions in sand costs in every case. The possible benefits of sand reclamation are particularly apparent in British Columbia where no suitable sands for steel and heavy iron foundries occur naturally, and where freight costs on imported sands are considerably higher than initial selling prices. This is well illustrated by the fact that silica sand, which sells for about $2.00 per ton at pits in Illinois, is laid clown in British Columbia for around $11.00 or $12.00 per ton. The operating costs quoted for certain of the reclamation schemes, i.e. $0.25 to $1.50 per ton, may actually be no higher than the cost of waste sand disposal in city-located foundries. In view of the foregoing considerations, the British Columbia Research Council has undertaken a study of the possibilities for sand reclamation, with particular attention directed to its application in local steel foundries. No commercial occurrences of silica sand are known in the Province, and, with this in view, the Council previously investigated the possibility of recovering silica sand from local impure sands. Results were definitely encouraging, but it was felt that the present market is too small to permit economical production by the method developed.

Jan 1, 1947

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By Z. Trojanová

Mg micropowders generated by gas atomisation of a magnesium melt with argon were mixed and ball milled with ceramic nanoparticles prepared by laser-induced gas phase reaction. The materials were then hot extruded. Specimens were deformed in tensile as well as compression tests at temperatures between 20 and 300 °C at a constant initial strain rate. The flow stress is significantly influenced by the test temperature. The yield stress decreases with temperature. This decrease and the flat character of the stressstrain curves at elevated temperatures indicate possible contributions of softening processes. The materials studied exhibit high-damping characteristics. The results are analysed and possible mechanisms are discussed.

Jan 1, 2006

By Xiqing Wu, Liang Dai, Tao Yue, Longsheng Yi, Ruifang Wang

Magnetic seeding flotation (MSF), i.e. adding magnetic seeds and pre-magnetization-flotation, is a new flotation technology especially for fine particles, which improves the flotation performance by enlarging the apparent size of the particles in a way of magnetic agglomeration. Both the fine coal slimes with a size of 66.68% –38µm and the pyrite slimes with a size of 73.95% –23 µm were investigated by the MSF, respectively. Flotation tests with variable of dosages of magnetic seeds and polyacrylamide were conducted, and some measurements, such as laser diffraction size analysis, magnetic susceptibility by vibrating sample magnetometer (VSM) and infrared spectroscopy (IRS), were also applied in order to probe the mechanism of the MSF. Based on the tests, measurements and calculations it was found that both the recovery of coal and the flotation kinetics of pyrite slimes increased with the additions of the magnetic seeds, and in the presence of polyacrylamide the coal flotation was further strengthened due to a synergetic effect of magnetic seeds and polyacrylamide on the flotation and a relatively larger apparent size of slimes after additions of magnetic seeds and polyacrylamide. The reason for the MSF lies in fact that the presence of the polyacrylamide intensified the adsorption of magnetic seeds on the coal particles and increased the coverage of the magnetic seeds on the coal surface from 0.2 to 1.3 wt%, resulting in increased magnetic susceptibility of coal particles from 9.13×10-9 to 22.17×10-9 m3/kg and thus a low magnetic field strength of pre-magnetization needed for the magnetic agglomeration among the coal particles from 602 to 24 mT prior to proper flotation. IRS shows that polyacrylamide chemisorbed on the surfaces of both coal particles and magnetic seeds, thus acting as the bridging media between particles and seeds.

Jan 1, 2016

By H. Huang, R. N. Gow

Acidic treatment of enargite (Cu3AsS4) dissolves both arsenic and copper from the mineral and then attempts to separate them in the leach solution. The reactivity of enargite was examined in acidic to neutral solutions, over the pH range 1-7, to determine a potential range for co-dissolution. Enargite mineral samples from Butte, MT and Quirivilca, Peru were used as working electrodes in a cyclic voltammetry corrosion cell setup, which were then cycled multiple times over -1000 to 1000 mV. Surface reactions and transitions were characterized using in-situ Raman spectroscopy, which were then compared to updated EH-pH diagrams for the copper-arsenic-sulfur-water system from a previous study done under alkaline conditions. The region of co-dissolution is limited to > 600 mV vs. SHE and pH < 1 under the proposed diagram.

Jan 1, 2014

By F. E. Lathe

The method of feeding blast-furnaces to be described below is simply the application of well-known principles, and an attempt to carry that application to its logical conclusion. It does not involve radical changes in equipment, nor does it require unusual skill on the part of the furnaceman. In fact, much of its value lies in its very simplicity. Before giving details of the method it will be well to consider briefly the conditions under which it was used at the Nickelton plant of the British America Nickel Corporation, in the Sudbury district, before that plant closed down. The Sudbury nickel ore consists chiefly of pentlandite, chalcopyrite and pyrrhotite in a gangue of norite or greenstone. The proportions of sulphide and gangue vary widely in different mines, the former constituting about 45 per cent of the total in the British America sorted ore. The gangue is fairly uniform in analysis, carrying about 55 per cent Si02, 18 per cent A120 3, 13 per cent FeO and smaller quantities of CaO, MgO, Na20 and K20. The ore has been frequently described as refractory, a word which seems suitable when one considers the many unsuccessful attempts to smelt it pyritically, as well as the high percentage of coke normally used at all the plants in the district.

Jan 1, 1925