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By L Klemettinen, A Jokilaakso, D Attah-Kyei, P Taskinen, M Tiljander, D Sukhomlinov, D Lindberg

In this study, the use of carbon neutral biochars as reducing agents in the pyrometallurgical treatment of nickel slag was investigated at 1400°C in order to recover valuable elements such as copper and nickel from the slag. A large amount of slag is generated during the nickel matte smelting. Nickel slag contains valuable elements such as copper, nickel and cobalt, which can be recovered. Disposal of this slag results in loss of resources and may cause pollution of the environment. It is important to retrieve these metals for environmental and economic reasons. In this study, the slag was reacted with non-fossil reducing agents (biochar) which were produced from hydrolysis lignin and black pellet biomass pyrolyzed at 600 and 1200°C and with metallurgical coke for comparison. The reduction experiments were done at 1400°C for 15, 30 and 60 mins under inert gas atmosphere. The samples were quickly quenched and analysed with Electron Probe X-ray Microanalysis (EPMA). The results showed that the use of biochar resulted in faster reaction kinetics in the reduction process compared to coke. The fast reaction kinetics is attributed to the relatively high content of volatiles in this biochar, leading to gas formation and thus mixing of the sample material. Moreover, thermodynamic modelling was also performed using FactSage™ to simulate equilibria with different amounts of biochar. The metal to slag distribution coefficient calculated from the results of thermodynamic modelling were consistent with experimental results. In addition, thermodynamic calculations confirmed that nickel is reduced rapidly and it deports to the metal alloy phase. As the reduction progresses or extra reductant is available for reactions, more iron is deported to the metal phase. The calculations also revealed that Zn vaporises into the gas phase.

Jun 19, 2024

Since 1969, a substantial number of geophysical methods have been applied in the search for porphyry copper and mesothermal type -sulpha-de deposits. These have assisted with geological mapping as well as the definition of various sulphide depos-its. The application of these methods at the Frieda-Nena deposits, Papua New Guinea, can be used as a case study for exploration in other parts of New Guinea.In 1993, Highlands Gold Limited carried out an intensive geophysical program over the Nena deposit. The methods employed included, CSAMT (controlled-source audio magneto-tellurics), airborne and ground elect-romagnetics, IP/resistivity and ground magnetics. The magnetic method was used as a regional mapping tool as well as a way of mapping alteration zones over both the Nena and Frieda River copper deposits. Electromagnetics, in part-icular FLAIRTEM, is a rapid reconn-aissance tool as well as a detailed mapping tool for the location of Nena-style massive sulphide deposits. IP/ resistivity is an expensive but most useful tool for mapping out Frieda porphyry copper style disseminated sulphides as well as Nena style deposits. It can be used to define drill targets in areas of difficult Access.a

Jan 1, 1994

By A Purvee, M F. Lee, L J. Mollison

Oyu Tolgoi is a large Cu-Au porphyry deposit in the south Gobi desert, Mongolia. The first of several deep, large-diameter, concrete-lined shafts, Shaft 1, is nearing completion. It will have a finished depth of 1380 m at a diameter of 6.7 m. These shafts will provide access to and hoisting capacity for block caving of deep underground ore. Geotechnical site investigations, and associated predictions of stability and ground support requirements, are compared against actual construction performance. Routine mapping is essential, along with checks against predictions and informing the contractor of ground conditions and variances.Advance rates are compared against predicted rock mass quality. A reasonable correlation exists between Qwall and advance rate. Overbreak and concrete liner thickness is related to the blockiness quotient, RQD/Jn.A ætool-bagÆ of just a few support elements (chain-link mesh, fibrecrete and 2.4 m long friction anchors and resin grouted re-bar bolts) was able to cope with the ground conditions encountered. QA/QC procedures are essential from the factory, through site storage to installation.

Jan 1, 2008

By Jones M

The concept of precise, accurate timing with Electronic Delay Detonators (EDDs) was first seriously addressed in the mid-1980s and much was made of the cheapness and profusion of digital watches in terms of the likelihood of EDDs also being cheap and easy to produce. Ten years later, with every major explosives company and many electronics groups having instituted projects to capitalise on the promise of these devices, production devices are still to come into general use. In South Africa, Expert Explosives units have been used in most applications during proving trials and more recently for production blasting in underground ring stoping and open cast coal. The outcome has been valuable learning both as to the benefits and technical requirements for electronic delay blasting, and especially, safety aspects. Examples are shown of production blasts which utilised the power of EDDs. It is evident that it is not delay accuracy alone which determines the value of these systems, but the whole robustness, flexibility and ease of delay allocation when harnessing blast engineering knowledge. Muckpile movement and shape, fragmentation and vibration frequencies have shown to be greatly influenced by designs which can be implemented no other way. The flexibility of a system and the power of the software controlling it are crucial in capitalising on blasting potential, which lies in integrating control of blast timing with other developing electronic Technologies.

Jan 1, 1995

The ores described in this paper are from the two principal orebodies at Wiseman's Creek, a small village about 22 miles south-east of Bathurst in central-western New South Wales.The first official reference to mining at Wiseman's Creek is in "Mineral Statistics of New South Wales" of 1875, which reported that the Wiseman's Creek Copper Mining Company had proved a lode-later known as "North Wiseman's"-to a depth of 120 ft., where it was found to be 20 ft. wide. By 1876 the erection of a mill and smelting works had commenced, and the sulphide ore found to contain copper lead, zinc, silver and gold. Some oxidised ore was also being worked. Operations were, however, generally unsuccessful, and sporadic work up until 1907 produced only about 5,000 tons of ore. The other more important orebody of the locality-the Phoenix-was not opened until about 1895. By 1908, as reported by J. E. Carne, the shaft had been sunk 340 ft., with the extraction of both oxidised and primary ore. At the time of the slump in copper, pric'es in 1907 approximately 3,000 tons of, ore had been produced.Several smaller orebodies were discovered and worked during the same period as the North Wiseman's and Phoenix, but their output was more or less insignficant. THE OREBODIES AND THEIR GEOLOGICAL SETTINGIt is now impossible to examine the orebodies underground, but they appear to have formed a series of flat lenses, whose major axes were parallel to ,the foliation of the enclosing quartz-chlorite-muscovite schists. The largest ,of these lenses was worked as the North Wiseman's orebody, which was reported by Carne to vary in width from 1 ft. to 20 ft., and which probably extended discontinuously over a strike length of about 1,000 ft. The Phoenix orebody is stated to have varied from 1 ft. 6 in. to 3 ft. in width...

Jan 1, 1955

Coal washery wastes comprise tailings, finer than 0.5 to 0.1 mm depending on the sophistication of the washery, and coarse reject, typically finer than 50 mm. Subaerial disposal of coal tailings slurry at about 30 per cent solids by mass results in the formation of a delta with an average slope of about 1 in 100, representing one extreme. The ravelling of coarse reject on loose-dumping, results in an angle of repose slope with an angle of about 37o (1 in 1.3), representing the other extreme. The pumped co-disposal of coal tailings and coarse reject results in the formation of an upper delta with an average slope of about to one in ten, between the two extremes. The depositional behaviour of these three waste streams is discussed and compared in this paper. The important depositional and material parameters, and a theoretical description of the processes involved, are also presented. Comparisons are made between the depositional behaviour of the various coal washery waste streams, and natural depositional systems, such as rivers, alluvial fans, and scree slopes.

Jan 1, 1998

By Griffiths L, Marshall P

fhis paper describes investigations into drainage of gas from the solid to control outbursts. Initial studies conducted on drainage of shear zones showed that, given enough time, these can be successfully drained. Once drained, they can be intersected and driven through without any activity of outbursts. The results of programme of investigations to determine parameters for drainage from the solid show that gas flow rates from the Bulli Seam on the average are about 2 litres/min/metre length of borehole. But when shear zones are intersected, the flow rates could be as high as 8 litres/min/ metre length of hole. Shear zones can be picked up from pressure measurements 50 - 60 m away and this could give sufficient time to drill through these zones and drain them in advance. Systematic drainage of Bulli Seam at West Cliff Colliery could eliminate or reduce frequency of outbursts considerably. At present drainage holes are being drilled systematically in the seam, with drainage installations on the surface. Gas purity of 80% methane is being delivered at the surface plant.

Jan 1, 1980

By J Zhang, R Dimitrakopoulos

A two-stage stochastic mixed integer non-linear program is formulated for a mining complex to optimise strategic and tactical plans. The objective is to find the near optimal decisions for a mineral supply chain in the context with uncertainties in both ore supply and the commodity market (price and demand). The endogenous spot price in the commodity market and long-term sales contracts are considered in the formulation of the mining complex’s optimisation model and an ad hoc heuristic is developed to deal with the throughput – and head-grade-dependent recovery rate in processing plants. Numerical results indicate that the proposed heuristic is effective and efficient in numerical tests. Based on the proposed model and heuristic, a long-term contract design strategy is proposed for making decisions on the contract price and strategic investments. A shadow price based method is also proposed to evaluate the existing mining schedule.CITATION:Zhang, J and Dimitrakopoulos, R, 2014. Optimising a mineral supply chain under uncertainty with long-term sales contracts, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 25–32 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By Chitombo G. P, Thompson A. G

Excavation engineering involves three key design processes; excavation design, blast design and reinforcement design. An excavation engineering methodology is proposed in an attempt to promote integration and simultaneous consideration of these three design processes. This methodology requires research and development of, inter alia, a universal rock mass classification system and a universal data display system. Simple examples are used to explain and illustrate the concepts central to these components in the three design processes.

Jan 1, 1995

By T Peglas, A de Aboitiz

The Queensland Government, via the special purpose company vehicle û City North Infrastructure Pty Ltd û is currently developing BrisbaneÆs Airport Link underground toll road and Northern Busway (Windsor to Kedron).Airport Link is a predominantly underground toll road planned between BrisbaneÆs northern suburbs, the airport and the Brisbane Central Business District (CBD) frame. The Northern Busway forms part of BrisbaneÆs expanding busway network, sections of which will be jointly delivered with Airport Link. Airport Link will connect the North-South Bypass Tunnel, Inner City Bypass and local road network at Bowen Hills to the northern arterials of Gympie Road and Stafford Road at Kedron and Sandgate Road and the East-West Arterial in the cityÆs north-east. The Northern Busway is a two-lane, two-way bus-only roadway proposed to connect the existing Inner Northern Busway at Herston with Windsor, Lutwyche, Kedron, Chermside, Aspley and Bracken Ridge. Airport Link and Northern Busway (Windsor to Kedron) is one of the largest infrastructure projects planned in the first phase of the State GovernmentÆs South East Queensland Infrastructure Plan and Program. The paper will provide an overview of the projects, including a discussion on the technical and environmental aspects as well as the procurement of the Airport Link as a public private partnership.

Jan 1, 2008

By Hewitt D

A study of two laterite profiles developed on a serpentinite near Rockhampton, shows that loss of Si02 and MgO results in the relative concentration of Fe203, A1203 and a number of minor elements. Serpentine is broken down to form montmorillonite, goethite, quartz and kaolinite. Enrichment of nickel occurs, and it is shown that the element is mainly associated with montmorillonite and serpentine. Highest nickel values are associated with a zone in the profile which occurs at a depth of 10.5-22 metres, and the bulk of the nickel in this zone (42-80%) is associated with the

Jan 1, 1974

By C J. R Hart, J K. Mortensen

The distribution of mineral deposits within northwestern North America (Alaska, Yukon, and northern British Columbia) allows for an in-depth examination of the metallogenic patterns of a growing continental margin. A more complete understanding of the tectonic evolution of this part of the Pacific Rim, achieved over the last 15 to 20 years, now allows for the placement of ore systems into a well-defined plate tectonic framework. Ore deposits older than about 185 Ma represent hydrothermal systems that were active in the platform/shelf environment of ancestral North AmericaÆs miogeocline or hydrothermal systems developed in oceanic arcs and continental fragments more distal to the craton. These include important SEDEX, VMS, and pre-accretionary porphyry deposits. In contrast, most mineral deposits younger than about 185 Ma were formed within the growing Cordilleran orogen, as terranes were accreted to the continental margin during interactions between the North America and Pacific/Farallon/Kula plates. Such syn- to post-accretionary mineralised systems include many large lode gold and porphyry/skarn systems.

Jan 1, 1999

The mostly submerged New Zealand sub-continent has a complex geological history and an active oceanographic regime that provides opportunities and challenges for offshore mineral exploration. Known deposits include polymetallic Fe-Mn nodules and crusts, polymetallic massive sulfides, phosphatic nodules, titanomagnetitie ironsands and placer gold deposits. Currently exploration interest is high with some 3.5 per cent of the EEZ under prospecting permit or application.   Article 76 of the UNCLOS convention allows coastal states to have sovereign rights over areas of the seafloor that are natural prolongations of the landmass that constitute submerged parts of the continental margin as extended continental shelf. New Zealand has substantial areas of elevated ridges and plateaux beyond the 200 M EEZ that form extended continental shelf. New Zealand has nearly completed a ten year, $44.4 M programme to define its outer extended continental shelf. New Zealand will lodge its outer limits of the extended continental shelf with the UN-appointed Commission on the Limits of the Continental Shelf in 2006, which if accepted, will enclose ~1.8 million km2 beyond the existing EEZ. Ocean Survey 20/20 is a follow-on marine mapping programme to underpin resource exploration and environmental management of the EEZ and extended continental shelf.

Jan 1, 2005

By A D. Bugarski, G H. Schnakenberg Jr

An investigation was carried out at a US underground mine to characterise diesel aerosols and to asses the effects of various control technologies on the concentrations and properties of particulate matter and gases emitted by heavy-duty diesel-powered equipment. This study was dedicated to evaluating the impact on mine air quality of contemporary diesel particulate filter (DPF) systems installed on mining equipment. Additional efforts were made to assess the effect of blended biodiesel fuels, yellow grease and soy, ultra-low sulfur fuel, a fuel emulsion and of selected diesel oxidation catalysts on air quality and emissions. The carbon analysis performed on the collected samples showed that the tested DPF systems reduced the mass concentrations of elemental carbon in mine air by between 70 per cent and 92 per cent. In addition, TEOM measurements, collected during these tests, showed that the total diesel particulate matter concentration in the mine air was reduced by greater than 65 per cent when DPF systems were used. The tested biodiesel blends were found to reduce elemental carbon concentrations in the mine air by between 49 per cent and 33 per cent, for the B20 (20 per cent biodiesel/80 per cent #2 diesel) of soy and yellow grease respectively and between 66 per cent and 56 per cent for the B50 (50 per cent biodiesel/50 per cent #2 diesel) of soy and yellow grease, respectively. The water-in-diesel fuel emulsion was shown to reduce elemental carbon concentrations by as much as 85 per cent. NO2 measurements showed an increase in the maximum concentrations of NO2 when catalysed DPF systems were used instead of mufflers.

Jan 1, 2005

By M D. Urbani

HiTec Energy Ltd has been conducting research since 1996 into novel process routes for the treatment of low-grade and waste manganese sources for the production of high value and high quality electrolytic manganese dioxide (EMD) for the alkaline battery market. HiTecÆs approach is to treat previously unsaleable manganese deposits and mine site tailings using a novel sulfur dioxide leach route, followed by purification and electrowinning to generate the sought-after EMD product by an environmentally superior processing route to those presently practiced throughout the world today.HiTec Energy Ltd expects to be in commercial production with its Stage 1 facility in Kalgoorlie in the last quarter of 2004 for the production of 12 500 tpa EMD. With this production facility being adjacent to a laterite nickel producer with available waste manganese units, the opportunity arose for HiTec to combine its existing technologies with processes (that will be discussed in this paper) to turn two waste by-products into products that are used for high-tech purposes.HiTec Energy Ltd and the Parker Centre have had a collaborative research relationship for a number of years in areas involving EMD and battery related technologies. Meanwhile the solvent extraction (SX) group of the Parker Centre (CSIRO Minerals) has developed SX processes to separate manganese from nickel and cobalt. A project was initiated by HiTec Energy to recover manganese from waste laterite leach solutions using SX technology. Batch tests were conducted to select a suitable organic system for the extraction of manganese in terms of selectivity and extraction and stripping kinetics.A total of eight organic systems were tested by determining pH isotherms of metals using a laterite nickel process waste stream. Two organic systems, the Versatic 10 and Versatic 10/synergist systems, were chosen for further test work with Shellsol D70 chosen as the diluent for both systems.The Versatic 10/synergist system would be advantageous over the pure Versatic 10 system because fewer SX stages are required, resulting in a smaller organic inventory and lower capital costs. The risk of gypsum formation is also significantly lower with the synergistic system.

Jan 1, 2004

By A Bonani, R Molina, H Constanzo

With conventional undercutting sequence the infrastructure on the production level often has a short serviceable life before major rehabilitation is necessary and is characterised by high maintenance costs. The abutment stress zone is the main cause of this situation. The application of the pre-undercut caving method variant can increase the availability and utilisation of the production level When a pre-undercut is used development and construction are carried out underneath a previously undercut area, far away from the abutment stress zone, under more favourable stress conditions. This paper describes the design principles and the relevant results from the application of the pre-undercut variant over three years to the Esmeralda sector of El Teniente mine. The aspects described are the undercut-extraction, the undercut-development and construction distances, the geometry and drawbells opening, cave extraction rates, and the rate and height of undercutting.

Jan 1, 2000

By I Canbulat, G Si, Y Duan, X Luo

The presence of unfavourable geological structures such as faults and dykes often can contribute to coal burst risk. Seismic events associated with rock fractures tend to cluster around these structures and it is important to understand the characteristics of seismicity for coal burst risk management. In an Australian underground longwall coalmine, two clusters of seismic activities close to the longwall face and within a section of the maingate roadway which was intersected by a major dyke were respectively identified. The induced seismicity in the dyke-roadway area was closely related to the longwall mining. These seismic events were located and the distribution of seismic events shows that more fractures were distributed on the inbye side of the dyke. The spatial-temporal changes of the seismic event locations delineate the fracture propagation as the longwall mined through the dyke. The frequency-magnitude relationship of seismicity was analysed and it was found that it changed significantly when the longwall was mining towards, through and past the dyke. The monitoring results demonstrate that because of the stiff dyke, the seismicity was intensified in the roadway section. It proves that the dyke promoted stress re-distribution and seismicity in its vicinity. More fractures were induced in the hanging wall of the dyke, whereas less strain energy was accumulated and released in the footwall of the dyke.

Nov 29, 2022

Radioisotope X-ray and neutron techniques of analysis can be used for the determination of a wide range of elements in minerals. The most important applications of these techniques to the mineral industry are for on-stream analysis of slurries and solids, and for geological assay. The radioisotope X-ray techniques are the more developed ones and two installations for on-stream analysis are in routine use in mineral processing plants in Australia. Neutron techniques are being developed, and should prove valuable for geological assay of large numbers of mineral samples, for borehole logging, and for specific on-stream analysis when the cost of the equipment is warranted.

Jan 1, 1969

By S E. Wallah, D Hardjito, B V. Ran

The manufacture of Ordinary Portland Cement (OPC) is not only energy-intensive but also releases a significant volume of carbon dioxide (CO2) to the atmosphere. In addition, OPC in concrete often causes premature deterioration that affects the durability of concrete structures. This paper explores an alternative to OPC concrete called geopolymer concrete.The present research utilises low calcium (class F) fly ash as the source material to produce geopolymer concrete. Several factors that affect the mix design process such as mix proportion, curing time, and curing temperature have been studied. In addition, the long-term properties such as drying shrinkage, creep, and exposure to sulfate attack are also being investigated.The test data presented in this paper reveal that geopolymer concrete possesses high compressive strength, undergoes very little drying shrinkage and moderately low creep, and shows excellent resistance to sulfate attack. The result is extremely promising and demonstrates the sustainability of geopolymer concrete as a construction material for a sustainable future.

Jan 1, 2004

Flue gases from electrical power station boilers, roasting, metallurgical and chemical plants could be treated by flotation using conventional flotation machines. The flue gases are introduced into the pulp instead of the air. The flotation media is a suspension of Ca(OH)2 or CaCO3 or a solution of NH4OH etc containing Na oleate as collector and frother. The SO2 and dust content of the initial flue gases were experimentally reduced by 100 to 1000 times in one flotation operation. The velocity of the flue gases through flotation machines could reach approximatively 0.4 to 0.5 m/s and more against 1.5 m/s reached in scrubber absorbers used for this purpose, but the quality of purification is expected to be better for flotation, which is essential for the cases of heavy polluted metallurgical and chemical flue gases. For some chemical plants the flue gases flotation media may be different and more suitable as compared to the above mentioned media. The proposed flotation method could be used for separation of dry grinded ores in the form of aerosols, with a realisation of flotation from a closed space (gas bubble in the pulp) onto the interface liquid-air where the particles are attached inside the bubbles.

Jan 1, 1993