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By L. A. André Santos

Atmospheric processing of nickel lateritic ores with low costs has been encouraged. In this work the kinetic of atmospheric acid leaching of a northern- Brazilian ore with 1.63% Ni and large amount of fine particles (d50 ≈ 0.075 mm and 40% below 0.038 mm) is presented. Chemical analysis showed a trend of Ni and Fe concentration in finer fraction (−0.075 mm) and Si and Mg in the coarsest one (−0.500 + 0.150 mm) associated to distinct mineral phases. Nickel is widespread in the mineral matrix. Distinct behaviors were observed as a function of particle size associated to the distribution of silicates and iron oxides in the ore. The kinetic modeling indicated that leaching is controlled by porous layer diffusion at 65 °C, but at 95 °C exhibits a mixed control by porous layer diffusion in initial minutes (60 min) and by chemical reaction or diffusion through the pore layer in final minutes (60–240 min) depends on metal evaluated.

By James R. Craig

The General Image Processing System (GIPSY) is being employed for the quantitative textural analysis of complex sulfide ores from the Southern and Central Appalachians and for the determination of liberation characteristics of the mineral constituents during grinding. Optical images from a microscope-mounted TV camera or from 35mm film are converted into digital images which are subsequently analyzed by GIPSY, a transportable image processing software package. Properties measured by GIPSY include spatial distribution of mineral constituents, grain sizes, grain shapes, grain orientation and mineral co-occurrences.

Jan 1, 1982

By John R. FitzPatrick

The separation and purification of uranium from either nitric acid or hydrochloric acid media tan be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-exchange as a method for extraction/purification of uranium from acidic media. In addition, waste stream polishing is associated with this effort in order to achieve more complete removal of the uranium prior to recycle of the acid. Extraction chromatography has been demonstrated' to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps. We will discuss contact experiments for evaluation of eleven different resins for uranium removal from nitric acid, the evaluation (again by contact experiments) of uranium elution from the ion-exchange media by various chemicals, and small-scale experiments for the removal of 235U from nitric acid. Larger-scale (100-gram) flow experiments using depleted uranium, were done after the small-scale evaluation Of the selected resin. A discussion is also included concerning the shortcomings of the contact experiments and how the flow experiments were modified in order to overcome these problems. We will also discuss the application of ion-exchange for some specific process needs at Los Alamos Contact experiments were used to evaluate some commercially available solvent-impregnated resins in addition to evaluation of several resins of this type synthesized in our laboratory. These experiments' involved both nitric and hydrochloric acid media. The data from these experiments will be used to determine the column size and' amount of resin required to polish the waste stream produced by the ion-exchange process described above. Small-scale flow experiments will be described and data given on the mass balances achieved using this two step process. Future work for evaluation of new ion-exchange and solvent-impregnated resins as well as the search for new eluants will be discussed. Other future experiments for both processes, including large-scale experiments, will be discussed in detail.

Jan 1, 1996

By Batric Pesic

Silver dissolution with thiourea was studied by using the rotating disk technique. The major parameters studied were: thiourea concentration (0-0.5M), ferric sulfate concentration (0-0.5M), sulfuric acid concentration (0-0.5M), and the effect of many foreign ions (Mn, o.i, Co, Ca, Na, etc.). Temperature effect was studied in the range 5-35 .C. The activation energy was 5.4 Kcal/mole. The dissolution of silver was first order with respect to ferric sulfate, and the secord order with respect to thiourea. Among the additives, copper had a dramatically negative effect. The strong oxidants such as hydrogen peroxide and manganese dioxide were also detrimental for silver dissolution. Silver does not dissolve with thiourea in the absence of ferric ions. Sulfuric acid does not participate in the dissolution reaction either. Chemically, the most important parameter for silver dissolution is the ferric sulfate/thiourea ratio. Thus, in the solutions with excess of ferric sulfate, a solid silver-thiourea complex is formed, which precludes transfer of silver into solution. In the solutions with the excess of thiourea, the free thiourea reacts with formed solid silver-thiourea complex and silver goes into the solution. The solid silver-thiourea complex was characterized according to its chemical composition. The complex contains 6.54%C, 2.49\H, 14.77%N, 16.09%0, 21.62%8, and 37.13% Ag. This composition corresponds to a Ag2so4.3'1U.2ff:i0 compound The soluble silver species are present in the solution as the dimers of AgTU+3 complexes.

Jan 1, 1989

By D. Donald Downey

Pilot Testing Ion Exchange Resin (IEX) can go from very simple beaker testing to complicated column testing. Space velocities, regenerant quantities, loading capacities, ion leakage, are all terms that get accumulated together to prove or disprove a resin’s (or resins’) ability to load a single ion (or specific set of ions). Not getting all the resin’s operating parameters correct will disqualify (or at least skew) the results. Laboratory tests for capacity, moisture content, bead size, metals fouling, etc.—what does it all mean? At last count, there were over twenty-five separate ion exchange resin tests (analyses) that were available to end users. Standard testing procedures identify the resin properties but more specific procedures can be used to identify problems with equipment operation. Then, there are the costs to consider; simple cation resin testing (moisture content, total capacity and bead integrity) is in the $200/sample range. However, add to this Chatillon, Russian Ball Mill Test, HIAC particle size, metals and % regeneration test procedures and the lab work can increase to over $1000/sample. In this paper, the author will explain the “must-do” pilot and test procedures and why they are important and the key to understanding how resin performs ion exchange.

By Tsembel Darjaa, Toru H. Okabe, Yoshiaki Umetsu

"With the purpose of extracting molybdenum and rhenium from molybdenum sulfide concentrate; .electrolysis of slurry, solvent extraction and ·precipitation operations were carried out. The slurry of the concentrate in 10 mass% NaCl aqueous solution was continuously circulated into a vertical type 10 stack bipolar electrolytic cell consisted of carbon electrode disks, and, the concentrate was dissolved by electrochemically generated oxidizers at 313 K. The current efficiency for molybdenum dissolution was 73 % after 10 hours electrolysis, and the leach solution was found to contain 0.2 mol/l of molybdenum and 4x10-5 mol/l rhenium. This result shows the dissolution is more than 8 times faster than that obtained using a single cell. The leach solution from electro-oxidation was then subjected to a solvent extraction for rhenium which is then recovered as sulfides. After rhenium separation, molybdenum was precipitated by pH adjustment, and solid MoO3 (H2O)x crystals, free of sulfate, were obtained from the leach solution containing large amount of so42-.IntroductionIn the past, electro-oxidation using a bipolar cell was applied for leaching molybdenite concentrate and ores at U. S. Bureau of Mines [1-3] and also at Bhabha Atomic Research Center [4]. In· these previous studies, Moebious type bipolar cells, in which electrode plates were vertically inserted into the free surface of the electrolyte, were employed and its effectiveness was demonstrated.Recently, the present authors studied on leaching of Mongolian molybdenite concentrate, and the effectiveness of leaching of the concentrate by electro-oxidation in alkaline and acidic NaCl solutions was demonstrated [5]. The leaching reaction during the process can be explained by the 18 electron transfer reaction of molybdenite (MoS2) with the oxidizers produced in-situ by electrolysis of NaCl aqueous solution. Further investigation was made with respect to various process parameters for electrooxidation such as pH, pulp density and temperature of the slurry, and the dissolution behavior of minor elements such as iron, copper, and rhenium [6]. Solubilities of molybdenum in the leach solution at, various temperatures and pH .was · studied, and feasibility of molybdenum recovery by hydrolysis of molybdenum species was demonstrated. By adjusting the pH of the leach solution, molybdenum oxides or hydroxides free from sulfate were successfully obtained from the solution containing large amount of sulfate ion. Rhenium present in the concentrate at a level of several tens of mass ppm was found to dissolve into the leach solution, and co-precipitate with the molybdenum compounds. Rhenium in the leach solutions, therefore, has to be recovered before precipitation of molybdenum, otherwise it is lost in the precipitate."

Jan 1, 2000

By Zhi-yong Liu

A novel process, which includes hydrochloric acid leaching, iron powder cementation, sulphide precipitation and spray pyrolysis, was proposed to treat iron concentrate recovered from zinc kiln slag for comprehensive utilization. Treated by two-stage hydrochloric acid leaching, the leaching extents of Ag, Pb, Cu, Fe and Zn are 96.78%, 95.14%, 97.72%, 94.51% and 87.74%, respectively. More than 99% Cu and Ag are recovered from the leach liquor when iron powder is 25% higher than the stoichiometric requirement. More than 96% Pb and Zn is removed with three times of theoretical consumption of FeS, and the concentration of impurities of the final solution is less than 500 mg/L. Fe2O3 powder, which is spherical with a mean size of 12 μm and purity of 99%, is prepared with final solution at 700 °C. In this process, not only the metal values can be recovered effectively, but also the iron resources of zinc kiln slag can be converted into high purity Fe2O3, thus, the comprehensive utilization of iron concentrate recovered from zinc kiln slag can be realized.

By L. Xia

Sodium silicate(s), also known as “water glass”, are one of the oldest and most widely used industrial chemicals. Its first use in Canadian operations can be traced back to around 1925, which coincided with early use of xanthates in mineral flotation. Silicate functions as a sulphide and non-sulphide gangue mineral dispersant, depressant and modifying reagent in grinding and flotation operations. It is believed that soluble sodium silicate promotes selectivity of value added sulphides against gangue minerals, resulting in both grade and recovery improvement. This paper seeks to link improved grade/recovery to the interaction characteristics of minerals and the sodium silicate. A systematic study was performed with individual mineral species, an artificially designed model ore and the feed ore from a copper flotation operation. The function of sodium silicate was evaluated in the context of colloidal chemistry and linked to mineral surface chemistry. Measurement of pulp rheology and mineral zeta potential identified that sodium silicate works as a dispersant. The dispersion is accomplished by increasing a mineral’s net surface charge, resulting in a change in slurry viscosity. Bench scale laboratory flotation tests suggest that better dispersion leads to a diminished interaction of chalcopyrite with gangue. The improved Cu grade and recovery then are likely in response to an increased accessibility to collector along with a linked increase in particle bubble attachment resulting in better separation efficiency. ToF-SIMS surface chemical analysis of the flotation samples found a higher proportion of sodium silicate on minerals from the flotation tailings relative to the concentrates. Moreover, attachment of sodium silicate appears to be mineral specific; the data indicates that sodium silicate favours the surface of gangue phases over the value sulphides.

By Guohua Bai, Yuanbo Zhang, Guihong Han, Zijian Su, Daoyuan Zhang

"Specularite ores have poor hydrophilicity and ballability as well as inferior high-temperature reactivity, which restrict the large-scale application of them in the pelletizing and sintering production. Modified humic acid (MHA) organic binders are firstly used for pellet preparation from specularite in this paper. The results show that the drop strength of green pellets is 3.7 times/0.5m and compression strength is 12.5 N/P by using 1.0 wt% MHA as binder. Under the optimal experimental conditions of preheating temperature 980 °C, preheating time 12 min, roasting temperature 1280 °C and roasting time 10 min, the preheated pellets have the compression strength more than 400 N/P, and that of roasted pellets is 2747 N/P. The strength of finished pellets meets the requirements of blast furnace iron-making. MHA is a kind of more effective organic binder for specularite pellets compared with the inorganic bentonite.IntroductionAcid Pellets have advantages of good strength, uniformity particle size, high iron grade and good reducibility, which can be used as high-quality burdens for blast furnaces [1]. With fast development of Chinese iron and steel industry domestic magnetite concentrates with high grade of iron and good firing performances become shortage.Imported specularite ores have advantages of low price and high grade of iron (generally above 67 wt%), so the application of them in pellets is an effective way for sustainable development of pellet industry in China. However, the specularites have not been utilized in pelletizing and sintering at present because of the poor ballability and high-temperature reactivity [2, 3]. Most of the pellet plants use bentonite as binders, the amount of which is about 2~3 wt%. The pellet production practice shows that 90 wt% bentonite is still residual in finished pellets and reduces the iron grade [3]. Developing a new organic binder instead of bentonite is very important to the high-quality pellet production. On one hand, the consumption of bentonite is obviously reduced, resulting in decreasing the ironmaking coke ratio and slag discharge; On the other hand, the iron grade of finished pellets are improved, which brings the benefit for the ironmaking production."

Jan 1, 2011

By Jim Sundal

Primary steel manufacturers using electric arc furnaces generate one of the largest hazardous waste streams nationwide. The waste stream, known as electric arc furnace dust, is a listed hazardous waste with the designation K061. Oregon Steel Mills, Inc., (OSM) of Portland, Oregon, has implemented a process known as Glassificationn, which uses KO61 as an ingredient in an onsite recycling process. Because OSM was able to demonstrate that the Glassificationm recycling process beneficially uses all toxic constituents in the electric arc furnace dust and that the recycling process produces marketable products, the process is not subject to Resource Conservation and Recovery Act (RCRA) permit requirements. The marketable products manufactured using Glassificationn include roofing granules, ceramic glazes and colorants, abrasive blasting media and, more recently, synthetic slag fluidizers. The purpose of this paper is to identify the regulatory issues for recycling hazardous waste and demonstrate that OSM glass frit is effective as a slag fluidizer in primary steel manufacturing.

Jan 1, 1994

By Harrison Cooper, Stephen Pack

"Data from samples taken during rotary air blast and reverse circulation drilling are crucial to properly assessing economics of mineral deposits in the case of exploratory work, and are equally critical in accurately delineating ore and waste in execution of mine operation plans. Past studies of sampling procedures, comparing results of conventional splitting to more precise extraction of representative samples, illustrate the significant degree of error frequently encountered. Economic impact of error in mine blast hole sampling work can be shown to result in theoretical losses valued at millions of dollars annually in operating large scale mining projects. Results of past drill sampling studies are reviewed.Drill sampling technique can be improved by collecting coarse and fine particles together and extracting samples for assay from the complete flow of rock and dust simultaneously. This can be accomplished with a collection unit attached to the drill stem through which all except a small proportion of extreme fines are retained. The bulk mass can be static sampled as flow takes place through the collector when size reduction is not required. Alternately, collected mass with fines and coarse intermingled can be processed for increased accuracy through size reduction to obtain proportional samples."

Jan 1, 1999

By Kuniaki Murase, Tetsuji Hirato, Yasuhiro Awakura

"Electrodeposition of CdTe was studied using aqueous ammonia-alkaline electrolytic baths in which Cd11-and Te1V-ions are dissolving as Cd11(NH3)/+ and Te1vol-ions, respectively. Ca-thodic polarization curves of the baths suggest the presence of strong interaction between the Cd11-and Te1V-ions; electrodeposition of tellurium is inhibited by the presence of Cd(NH3)/+ ions. The interaction makes it possible to electrodeposit CdTe films with stoichiometric composition. Polycrystalline CdTe thin film of about 1 µm thickness was electrodeposited at 343 K from ammonia-alkaline solutions (pH= 10.7) containing TeO32-(<20 mmol dm-3) and Cd(NH3)/+ ( < 60 mmol dm-3) ions. Increasing Cd(NH3)/42+/TeO32- mole ratio or decreasing total concentration of ammonia/ammonium-ion gave flat and smooth crystalline CdTe deposits at constant cathode potential-0.70 to -0.30 V vs SHE at 343 K.IntroductionCadmium telluride (CdTe) is well-known as a compound semiconductor whose band gap, i.e. 1.44 eV, is suitable for solar energy conversion with a photovoltaic cell. Various methods, such as CVD (chemical vapor deposition) and electrodeposition, of preparing CdTe thin films for solar cells have been investigated.Acidic sulfate solutions with a pH of 1-2 are usually employed for CdTe processing by electrodeposition.1-3) The electrodeposition of compound semiconductors is usually achieved (i) at a higher cathode potential than the redox potential of less-noble species, can in this case, and (ii) under the condition of diffusion-limiting current of a more noble species, Te1Y.4) There-fore, a suitable CdII/TeIV concentration ratio in the acidic electrolytic baths, resulting in the deposition of stoichiometric CdTe, is determined by the diffusion-limiting current density of TeIV- reduction, i.e. the concentration of HTeIVO2+ · Since the solubility ofTe1v species HTeIVO2+ in the acidic solutions is quite low, the rate at which CdTe is deposited from the acidic solutions is extremely slow."

Jan 1, 1998

By K. R. Robilliard

The Peru based tin mining company, Minsur S.A., commissioned Ausmelt Limited to design, supervise construction and commission a tin smelter and refinery for production of refined tin metal. The plant is located 240km south of Lima, near Pisco, Peru and is operated by Funsur S.A., the wholly owned subsidiary of Minsur S.A.. Selection of the Ausmelt Technology followed a series of crucible scale test work and pilot plant trials conducted at Ausmelt&apos;s facility in Dandenong, Australia and two feasibility studies undertaken by Ausmelt in 1991 and 1993. Ausrnelt began the plant design in 1994 with the construction phase following in 1995. Commissioning of the plant commenced early in 1996 with a target throughput of 30,000 tonnes per annum of concentrates. In mid 1998 oxygen enrichment of the Ausmelt lance air was introduced to expand the capacity to the throughput of 40,000 tonnes per annum of concentrates. The process route involves the use of an Ausmelt furnace for primary concentrate smelting, followed by a conventional tin pyro-refining circuit to produce high grade tin suitable for sale. Further work continues between Ausmelt and Funsur to investigate the use of an alternative, more economical, fuel source and the installation of a second Ausmelt furnace. The paper reviews the project to date with details of ongoing operations and developments at the Minsur Tin Smelter.

Jan 1, 2000

By N. Mizutani, S. Harada, Z. Asaki, T. Tanabe

"The development of lead-free solders is urgent in view of environmental standpoints. In this -work the wettability of tin-bismuth- silver solders on copper was studied. Three kinds of fluxes were used. The wettability of conventional eutectic tin-lead .solder exhibited an excellent level over the other solders of tin-bismuth systems. Poor wettability of the tin-bismuth solders may be caused by the growth or dendritic copper-tin compounds at copper/solder interface, in contrast to the case of tin-lead'· solder. The wettability was improved by the addition· of silver in the solder. In this tin bismuth- silver system, silver was abnormally concentrated at the copper I solder interface even in the initial stage of contact. The wettability of the solder and the thickness of compound formed on the copper have a good correlation; the solder containing 2% silver exhibited the best wettability and the formation rate of copper-tin· compound on the copper was slowest.IntroductionSocial demand to avoid lead use in the industrial fields has been recently promoted· (1) because of the environmental protection of water resources. Especially the lead-bearing solders have been widely used in electronics and automobile products, and it is urgent to replace them with nontoxic materials (2)-(4). Thus the development of lead-free solders becomes an indispensable subject to the new generations and many works (5)(6) have already been carried out on the research and development of new solders. New lead-free solders are expected to have some requirements, for example, moderate melting temperature, proper strength and integrity, and lower prices, as compared with conventional solders. There have been already several alloy systems developed. Among ·these alloy systems, tin-bismuth binary or tin-bismuth-silver ternary alloys have great advantages such as having a wide range of soldering .temperature by controlling con:ipositions, though they have such disadvantages as ""lift-off"" (7)-(9): It is said, on the other hand, that a frequently overlooked property of solders, or one that is typically ignored by the research scientist as an ""issue"" for the manufacturing or product engineer, is wettability (10), although a ·work on the wettability has recently been published (11). In this Work, therefore, the authors selected Sn-Bi-Ag solders and focused mi the effect of Ag-addition to wettability of the solder."

Jan 1, 2000

By T. R. A. Davey

Previous publications on the application of EIETSIM include the modelling of an electrolytic zinc plant and a copper flash smelter. In the present case METSIM has been used to model the desilverising of lead by the reagent zinc, whereby a silver-zinc intermetallic compound is formed, and floats out of the lead. This compound has a variable composition, depending upon the ratio of dissolved zinc/silver in the lead bath. Its solubility in lead decreases with falling temperature. A number of variations and modifications of the Davey Desilverising Procedure are modelled, and applied to a wide range of silver contents in lead bullions at several plants. METSIM uses both feed- back and feed-forward controls to simulate plant conditions, and a logic control to distinguish between different phases in the Zn-Ag system. Use is made of extensive (previously unpublished) fundamental data on the ternary Pb-Ag-Zn system, and of plant data, to establish certain operating parameters.

Jan 1, 1993

By J. H. Huang

In this investigation, the selective precipitation of cobalt and molybdenum from Co-Mo aqueous solutions was studied in order to recover efficiently valuable elements from industrial effluents generated from a novel electrodeposition of nanocrystalline Co-based alloys process and reduce the effluent impact on environment. It was found that the behavior of cobalt in aqueous solutions was substantially affected by the presence of molybdenum. When adding 11.6 to 46.6g/L molybdenum to a 50g/L cobalt solution, the co-precipitation of molybdenum and cobalt started to occur at pH value of 3-4. However, without the presence of molybdenum, cobalt could only be precipitated out of the solution at about pH 6. Most of the molybdenum was found in the solid phase when the solution pH reached 5. After further increasing pH to greater than 7, the molybdenum dissolved back into the solution. Cobalt kept precipitating as the pH increased. When the pH was greater than 7, most of the cobalt was present in the solid phase. The chemical and physical characteristics of the precipitated materials were investigated by SEM, XRD, AAS and EDX. It was revealed that the precipitate was initially present as cobalt molybdate oxide hydrate and subsequently transformed as sodium cobalt molybdenum oxide. With further increasing the solution pH, the precipitate was transformed into cobalt hydroxide. Further investigation implied that most of molybdenum was chemically tied to the precipitate produced at the low pH, yet at the same time, physically entrapped at the high pH. The paper also presents the influence of reaction temperature and time on the precipitation process and kinetics.

Jan 1, 2003

By T. T. Lin, N. H. Madsen, K. Groom, B. A. Chin

"The objective of this research is to investigate the feasibility of using infrared sensors to monitor the welding process. Data were gathered using an infrared camera which was trained on the molten metal pool during the welding operation. Several types of process perturbations which result in weld defects were then intentionally induced and the resulting thermal images monitored. Gas tungsten arc using AC and DC currents and gas metal arc welding processes were investigated using steel, aluminum and stainless steel plate materials. The thermal images obtained in the three materials and different welding processes revealed nearly identical patterns for the same induced process perturbation. Based upon these results, infrared thermography is a method which may be very applicable to automation of the welding process.IntroductionAutomatic welding is commonplace in industry today. However, most, if not all, involves preprogramming for performance of a repetitive task. These systems are incapable of correcting for perturbations which arise during the welding process. Control of the welding process requires the identification and monitoring of perturbations in a wide variety of parameters. The varied nature of these parameters and the large number of variables involved have thwarted previous attempts at closed loop control of the welding process. The sensor(s) employed by a control system need to meet rather strenuous requirements. First and foremost of these is that such a sensor must be able to identify and discriminate between perturbations that might affect the quality of the weld, including such geometrical perturbations as a change of direction in the seam between the parts being welded, gaps in the seam or a misalignment of the parts being welded. The sensor should also be able to locate and identify contaminants and impurities in the weld puddle and ahead of it while monitoring the extent of the heat-affected zone and the cooling rate of the metal. The sensor(s) should, additionally, be able to perform these tasks in a time frame that is consistent with automatic control of the welding process. This paper presents results that could aid in the assembly of such a controlled welding system."

Jan 1, 1986

By T. Iriyama, Y. Fujita, R. Omatsuzawa, T. Nishio, N. Okochi

Sm-Fe-N hard magnetic materials are good candidates for high performance bonded magnets. Rapid-quenching method should be highly favorable for the fabrication of isotropic magnet powder with high coercivity. We report here the magnetic properties of Sm-Fe-N powders produced by a few kinds of rapid-quenching processes. Sm2Fe17 powders were prepared by gas-atomization (GA), rotating-disk atomization (RDA), or melt-spinning (MS) method. The Sm2Fe17 GA powder had dendritic solidification structure, while the RDA powder had micro crystalline structure with size of 3-5 µm. Coercivities (HcI) of their nitrides were 56 (for GA) and 217 ka/m (for RDA). The H cI of nitrided Sm2Fe17 MS powder with wheel velocity (V5) of 5-20 m/s, which had also microcrystalline structure, was 53 to 509 Wm. These coercivity values are not sufficient for bonded magnet applications. From the study of additive effects, it was found that C, C-Si, C-Ga, or C-Al addition decreased the crystal size of quenched Sm2Fe17 powder. Consequently, high coercivity was obtained; the HcI of nitrided Sm2Fe1C1Si1 MS powder with V5 of 10 m/s was 898 kA/m, and 708 kA/m for the nitrided Sm2Fe15C1Si1 RDA powder. The compression-molded bonded magnet made from Sm2Fe18Si0.1Nx MS powder showed a high (BH)max of 82.7 kJ/m3.

Jan 1, 2000

By B. K. Chakrabarti

Modeling and a screening design of experiment (DOE) was performed with the process variables to identify the greatest effect of variables on the response quality in the dead burning of magnesite refractory in a rotary kiln. Among various interdependent variable factors, the design variables chosen were raw magnesite (RM) feed rate, kiln rotation time i,e, seconds per rotation(SPM) and burning zone temperature (BZT). The response variables chosen were exit gas temperature and density of dead burnt magnesite(DBM). ANOVA and normal plots were used to evaluate the effects.This work had enabled to correlate the BZT, RPM, RM feed with the exit gas temp and density of magnesite produced. The result opens up an avenue to look into the optimum region of operations within the ranges of variables considered in order to conserve energy and to minimize the exhaust gas temperature and to maximize the density of the DBM produced

Jan 1, 2015

By S. P. Song

A computational methodology based on the coupled finite element and boundary methods is developed to predict the free surface shapes of electrically conducting liquids supported by the electromagnetic field. The work is an extension of our previous FEIBE model for induction calculations. The free surface algorithm is developed using the Weighted Residual Method, the very same used for nonlinear finite element formulation. This allows the treatment of field computation and free surface prediction in the same manner, thus making easier the formulation of the magnetically-supported free surface problems. Like other nonlinear algorithms, the boundary/finite element free surface scheme is also iterative owing to the fact that free surface shapes are unknown a priori. But the numerical scheme is robust and efficient and is capable of handling rather complex free surface deformations. Computational algorithms will be given and are tested by comparing with other solutions whenever available. Computed results of magnetically-supported free surface shapes are presented for magnetic levitation under microgravity and floating zone refining processes under normal gravity.

Jan 1, 1996