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Domestic production of pyrite cinder reached 15.95 million tons in 2006. The pyrite cinder used in cement industry accounts for about 30% production. The remaining 70%, 11.17 million tons, was thrown away as waste, which brought serious environmental and resource problems. A new technology of composite pellet reduction-roasting and magnetic-separation (CPRM) has been developed to utilize pyrite cinder. Pyrite cinder sample, containing 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700~800 ? for 20min with 300kg/t pulverized coal injection in rotary kiln. After two stages of ball-grinding and four stages of magnetic separation, high grade magnetite concentrate with 66.23% Fe was produced, meanwhile impurities Cu and S was decreased to 0.048% and 0.053%, respectively. And iron recovery of 73.32%, desulphurization of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which can be removed during wet magnetic concentration. This new technology can be used to fully utilize pyrite cinder and produce high quality magnetite concentrates as feed for steel industry, which will help tackle the pollution problem of pyrite cinder and extend iron-bearing raw material sourcing for Chinese steel industry.

Jan 1, 2014

By Guanghua Ai, Xiong Huang, Huashan Yan, Ting Li, Tingsheng Qiu

"Cyanide tailings of gold and silver concentrates contain considerable quantities of copper-lead-zinc sulfide minerals that can be recovered. However, the strong inhibition effect of cyanide often makes it difficult to recover these sulfide minerals effectively. In this research, a sample of cyanide tailings was investigated based on the principles of process mineralogy; activating flotation tests were carried out for the target minerals in the tailings, and the activation mechanism of the activator and its influence on the target minerals were investigated by Fourier transform infrared spectroscopy (FTIR). Mixed flotation of copper and zinc was carried out using QJ-01, a combined agent containing sulfite, as the activator of copper and zinc minerals, and ammonium dibutyl dithiophosphate (ADD) and butyl xanthate (BX) as the combined collector. Copper concentrate was obtained from the mixed concentrate by using a combined inhibitor of sodium sulfide and zinc sulfate to inhibit the zinc mineral. Zinc concentrate was extracted from the copper tailings by using copper sulfate as the activator and BX as the collector. The flotation test yielded copper concentrate with a grade of 22.56% and recovery of 76.96%, and zinc concentrate with a grade of 42.56% and recovery of 82.29%, which shows that comprehensive recovery of the sulfide minerals – copper and zinc –from the cyanide tailings was realized. The FTIR analysis showed that CN- was chemisorbed on the surface of chalcopyrite and sphalerite following cyanide treatment, while the combined activator QJ-01 containing sulfite reduced CN- into SCN- and weakened the complexing ability of CN- with metal ions on the mineral surface, thus achieving a good activation effect on chalcopyrite and sphalerite. The results of this study can provide practical guidance in increasing the resource utilization ratio of cyanide tailings in gold mines, and thus contribute to alleviating environmental problems caused by stockpiling cyanide tailings. INTRODUCTION Cyanidation, the most widely used technology for extraction of gold, has several advantages such as high recovery, process maturity, low cost, etc. According to available data, the annual discharge of cyanide tailings from China's gold mines exceeds 20 million tons (Li et al., 2011). Lower grades of exploitable gold ore entail increased discharge of cyanide tailings. Huge quantities of cyanide tailings are regarded as waste and stored, resulting in significant wastage of land resources. Moreover, residual beneficiation reagents, cyanide ions, and heavy metal ions in cyanide tailings cause severe pollution of water and land (Laitos et al., 2013; Donato et al., 2007; Mudder and Botz, 2004). In addition, cyanide tailings often contain valuable elements such as gold, silver, copper, lead, zinc, sulfur, and iron, which, if not recycled, would result in considerable wastage of resources. Hence, it is imperative to study the reduction and safety of cyanide tailings, and the mineral resources present in them."

Jan 1, 2018

By F. Q. Dong

According to the principle that should be originated from nature, compatible with nature, used in nature and back to nature and based on conception of designing of eco-material, the author combined the ideas of material, environment, zoology and healthy. Properties of natural mineral materials were used to produce micro-aggregate elements by bionic method, so its components and function could accord with living environment. Eco-mineral functional materials which can adjust, purify and optimize the microclimate were reviewed. The authors pointed out the multifunction, com-pounding, the compound characteristics and integration regularities of micro-aggregates. It was the first time in the world to put forward the ?gene? technique or ?material chip? technique of manufacturing function micro-aggregates and eco-function elementary materials. The results of this re-search supported by the national ?863? Hi-tech Project, mainly including the high-efficient air purifying mineral compound material indoor, the clay elementary antibacterial materials, the masonry cement/coating/putty/compound with preventing radon radiation, environmental friendly composite functional coatings, mosquito repellent and healthcare material and zeolite-based energy-saving composite materials, were introduced. Finally, the foreground of mineral materials in the field of future advanced eco-friendly materials was also discussed.

Jan 1, 2014

By T. Badrujaman

In September 2005, after 30 years experiencing in operating an ESF using a falling water film shell cooling system, Antam entered the new era in operating an ESF, after completely modernized its ESF No. 2 from a falling water film shell cooling system to a copper cooling system. Further, in the beginning of 2007, Ferronickel plant No. 3, where its ESF also uses copper coolers, was successfully commissioned. By operating an ESF using a copper cooling technology, Antam has to face some challenges to establish the operation stability. Besides that, the chances to maximize the furnace efficiency are greatly opened. The shielded-arc mode of electrode tip is selected to operate an ESF under relatively high furnace power to produce metal having tap temperature below 1500? and slag having tap temperature below 1600?. It leads to electric current unbalance. Further, operating an ESF using a copper cooler system under high voltage as consequence of the furnace power raise increases metal and slag tap temperature. This condition damages furnace integrity fast. Besides that, relatively high metal temperature increases its pressure during metal tapping. It leads to failure in closing the metal tap hole. The main different ways in operating an ESF using a falling water film shell cooling system and a copper cooling system lie in the electrode tip mode, the water specification used for cooler, metal tap block maintenance and allowed metal & slag level in furnace. Since a copper cooler system allows an ESF to be operated by consuming nickel ore having ratio Fe / Ni up to eight and producing slag having relatively high Fe content in slag, an undesirable silicon reversion phenomenon becomes an obstacle in reaching the operation stability. A copper cooler technology lets Antam to take a chance to increase its capacity. Modernizing the ESF No.2 had increased its furnace power from 17 MWh to 25 MWh. Meanwhile the ESF No. 3 can be operated up to 42 MWh. This technology allows an ESF to be operated under relatively high furnace power above 25 MWh safely as well as prolong the campaign life of ESF brick. Further, lowering ESF power consumption, extending the limitation of ratio S/M in nickel ore consumed and adjusting Ni grade in ferronickel product can be gained by applying this technology.

Jan 1, 2014

By Hristo Stanchev, Veselin Mehandzhiyski, Sashka Kozhuharova, Stefan Stamenov, Alexandar Penchev, Nikolay Nestorov, Velika Stamatova, Ekaterina Todorova

"This article presents the results of comprehensive research on the quantitative distribution of gold content in the raw ore and tailings from the flotation enrichment process at the Ellatzite Med plant. The study is a quantitative and qualitative determination of the presence of gold in the ore processed by Ellatzite Med AD, as well as its behavior and distribution in the various metallurgical products of the flotation process. The representativeness of the samples taken is ensured by the frequency of sampling: four work shifts of sampling on different days within a period of four consecutive weeks. The form of gold present is determined both in the analyzed samples and in separate fractions - granulometric, magnetic, electromagnetic, heavy and light. A summarized diagram presents the phase distribution of gold in the final products of the dressing process. The results obtained are used for further analysis and evaluation of the actual technological parameters of the gold. It was established that an increase in the initial gold content, respectively in the content of native gold in the raw ore, with the current process, leads to an increase in gold losses, mostly in the native gold phase. The conducted analysis of the results from the comprehensive tests on determining the form of gold present in the various enrichment products gave rise to further research with the use of a Knelson centrifugal concentrator."

Jan 1, 2014

By I. Nishkov, I. Grigorova, N. Valkanov, M. Ranchev

The processing of sulphide ores with variable and complex mineral composition and physical properties, such as those processed by two-stage selective flotation scheme in “Erma reka” concentrator, Minstroy Holding JSC, requires excellent selectivity in order to achieve acceptable concentrate grades. The lead-zinc ores from the hydrothermal lead-zinc deposits mainly contain galena (PbS), sphalerite (ZnS), pyrite (FeS) and chalcopyrite (CuFeS2), as well as non-metal minerals such as quartz, carbonates and clinopyroxenes skarns. One of the main impurities present in sphalerite is iron, which is known to be detrimental to the rate of sphalerite flotation and its recovery. The results from the conducted laboratory and industrial tests, presented in the previous study, showed that it is possible to depress the iron rich sphalerite by adding MINFIT® (modified sulfur-oxy depressant) at the pH of approximately 9.5 in rougher lead flotation circuit, leading to reduction of zinc sulphate consumption and complete elimination of cyanides from the flotation process. Furthermore, the consumption of copper sulphate, which reactivates the surface of the zinc minerals, was significantly reduced. Consequently, the optimisation of the reagent regime in the Erma reka concentrator, led to notably improved qualitative (grade, recovery) properties of the final lead and zinc concentrates. Moreover, when comparing the reagents consumption for 2014 and 2016 – when the processing plant have been applying the new optimized reagents regime, comprises the use of MINFIT as the primary depressant, the following results have been achieved: ZnSO4 decreased by 30%; CuSO4 consumption decreased four times and full rejection of cyanides from the process. Finally, this paper provides a state-of-the-art review of the obtained results during the period of application of the new flotation reagents regime in the Erma reka concentrator, Minstroy Holding JSC.

Jan 1, 2018

By W. Y. Liu

A sulfate reducing bacteria strain (named SRB-A) is isolated from sanitary wastewater by using anaerobic technology of Hungate. The studies of physiological, biochemical and phylogenic of the isolated strain are carried out. The colonies of the strain are circle. Cells that are slightly curve, rod-shaped with the size of 1.0~3.0µm in length and 0.8~1.0µm in width. The optimum temperature for growth of the organism is 30~35°C. The optimum pH for growth is 7.0~7.2. Strain SRB-A can use sodium lactate, sodium citrate, sodium acetate, ethanol and acetone as electronic acceptor but can not use glycerol, glucose, sucrose and sodium oxatate. The isolated strain reduces sulfate, sulfide, sulfur, DSMO and FeCl3, then nitrate and nitrite can not be used. The strain has higher tolerance of NaCl, and the optimum growth occurs in the presence of 5%~8% (w/v) NaCl. The result of 16S rDNA sequence analysis indicates that the isolated strain SRB-A is the most similar to Desulfo-vibrio halophilus, and the level of the similarity was 98.4%. The isolated strain has a stronger ability to reduce sulfate, and the level of sulfate reduction reaches about 90% at pH 7 in the liquid medium. 0.6 to 0.8 is the optimum COD/SO42- in the medium for the isolated strain to show better ability to reduce sulfate. At pH 2.5 the level of removal of Cu2+ reaches 96.3%. Under the condition of pH 3.5, the level of removal of Zn2+ reaches 92.6%. When the value of pH reaches about 7, the Fe3+ is precipitated by the formation of Fe(OH)3, and Fe3+ is removed up to 89.4% at last.

Jan 1, 2014

By B. Courtaud

Uranium plants are generally located quite far from conversion plants, resulting in high transport costs. One way of reducing such costs involves putting more uranium in each drum by increasing the final product?s bulk density, which can be achieved via mechanical compaction of the powder and/or improved precipitation. For most of its plants, AREVA has adopted the latter approach, involving a new precipitation process applicable to all kinds of yellowcake produced (via uranates, uranium peroxide, etc.) that achieves bulk density of 3 for soda uranate, for example, instead of the 1.5-2 density available via conventional processes. At present, this process is being undertaken on an industrial scale and will become the norm for precipitation processes at all AREVA U plants. In addition to producing dense yellowcake, the process also delivers a product with no fines, a spherical particle shape (which allows for high-quality powder flow) and superior post-precipitation filterability

Sep 1, 2012

By M. Unesi, S. Haj Mohammadi, M. R. Abdoli, M. R. Garmsiri

"Hydrocyclone-thickener circuit is a promising solution to enhance the dewatering efficiency in mineral industries. The challenges in the circuit is reducing particle size in the thickener feed and the good feature is a rise in the retention time of sediments in the thickener. In this work, the effect of particle size, bed depth and residence time on the thickener performance were investigated. In this order, pilot scale columns were employed at Sarcheshmeh and Shahrebabak copper complexes. Furthermore, the influence of residence time was differentiated due to the variations in the bed depth and settling flux. Moreover, a new approach was introduced to estimate solids residence time in the thickener. results indicated that with smaller particles that are introduced to the column, the bed density as well as thickener discharge solids concentration dropped significantly. It was found that thickener discharge solids concentration fell from 59.6 to 33.8 % with reducing particle size from 130 to 22 µm in the settling flux of 20 t/m2/day. Additionally, it was found that longer residence time and deeper bed resulted in an increase in the thickener performance while the bed depth has a stronger effect. It was proved that employing a hydrocyclone prior to the thickener resuted in an increase in the dewatering efficiency.INTRODUCTION Thickeners are widely employed in mineral industries to recycle tailings and concentrate water content. A limited fraction of suspension water content is recycled using a thickener. For instance, about 50 percent of tailings water content could be recycled using a shallow bed thickener during copper processing. Since the scarcity of global water resources became more serious, the demand for improving dewatering efficiency in mineral industries became more significant [1]. A number of solutions were recommended to enhance dewatering efficiency of thickeners including optimization of current thickeners, employing deep bed thickeners and utilizing thickener-filter or hydrocyclone-thickener circuits. Optimization of existing thickeners is essential, however, it does not meet the significant demand for recycled water. The application of deep bed thickeners (known as paste thickeners) has been rising in the mineral industries [2] due to a higher dewatering efficiency while its costs is remarkable."

Jan 1, 2018

By Z. G. Guan

The tungsten ore in Xingluokeng belongs to a symbiotic deposit containing granite and fine vein-type wolframite and scheelite. The tungsten (WO3wolframite) accounts for only 0.233% of the raw ore, 49.60% of the , 49.60% of the scheelite and 0.8% of the tungstite. The dissemination size of the tungsten ore is extremely uneven, with 0.02~1.28 mm for scheelite and 0.01~1.28 mm for wolframite. The dissemination size of scheelite is coarser than that of wolframite. The size of 83% of scheelite and 60% of wolframite is greater than 0.04 mm. The composition of minerals in the ore is quite complex. The major metallic minerals include wolframite, scheelite and pyrite, which are followed by molybdenite, chalcopyrite, arsenopyrite, limonite, magnetite, hematite and siderite. The major gangue minerals include quartz, feldspar, muscovite, biotite and sericite, which are followed by chlorite, fluorite, apatite, dolomite, etc. According to the dissemination features and liberation degree of the tungsten minerals, the technology flowsheet of gravity concentration for coarse particles and flotation for fine particles to re-cover the low-grade and fine vein-type tungsten minerals is adopted, and -0.7 mm is selected as the processing size. The closed-circuit grinding procedure, with the combination of the rod mill and high-frequency vibration screen, is adopted. The grinding product is classified into three products of -0.7 +0.2 mm, -0.2 +0.04 mm and -0.04 mm. The gravity separation is adopted for the former two to recover tungsten minerals and the flotation is adopted for the last one. Under the condition that the raw ore contains 0.23% WO3, some technology indexes of beneficiation have been achieved. The gravity tungsten concentrate contains 63.54% WO3 with the recovery 70.11%. The slime flotation tungsten concentrate contains 35.22% WO3 with the recovery 10.48%. The composite tungsten concentrate contains 57.53% WO3 with the recovery 80.59%. Thus, the tungsten minerals are re-covered effectively.

Jan 1, 2014

By L. S. Bbosa

Single particle impact breakage experiments provide essential data to aid in understanding of rock fracture in comminution. Such experiments, conducted using devices such as the drop weight tester, split Hopkinson bars and more recently the rotary breakage tester, have been successfully used to characterize ore breakage properties in relation to measured fracture energies. The work presented in this paper highlights the techniques behind the calculation of impact breakage properties from each of these three devices. The breakage parameters that can be calculated from experimental data from each of these are to be described. Drop weight tests are used to calculate A and b hardness parameters using the standard JK breakage model. Split Hopkinson pressure bars are used to establish the ultimate compressive stress of particles through single impact breakage tests and the fraction of impact energy utilized to cause particle fracture. Low energy breakage tests using the rotary breakage tester are shown to be used in calculating particle breakage probability. Methods to calculate parameters related to particle breakage probabilities such as E0 and Ecrit are also discussed.

Jan 1, 2014

By N. Jovanovic, A. Vazirizadeh

"The main objective of this study is to find a solution to design a mass flow observer system with the minimum required sensors and maximum observability for a mineral processing plant. The second objective is designing a mass flow observer configuration with high reliability to manage sensor failures. This configuration will provide a robust monitoring system that increases plant availability and process measurement fault detection. Furthermore, the monitoring system is expected to improve process efficiency. In this investigation, the procedure of designing an observer system is presented along with three models to design the sensor network. The advantages and disadvantages of each models are discussed and finally the models result for an industrial case are presented and analyzed. INTRODUCTION The concepts of observability and redundancy of mass flow are directly linked with the ability to solve and estimate the mass flow. There are hundreds of streams in a process plant flowsheet, and for technical and economic reasons it is not possible to measure all mass flows. It is thus important to know for a set of measured streams, which of the unmeasured streams can be estimated. The concept of observability deals with this issue. It is also valuable to know whether a measured mass flow of streams can be estimated even if a sensor fails for some reason. Redundancy deals with this failure question. A stream is said to be observable if it can be estimated by using the measurements and/ or mass conservation equations. Also, a stream is redundant if it is observable even when its measurement is removed. Observability and redundancy analysis can be exploited for adding new measuring instruments. It can also play a useful role in efficient decomposition and data reconciliation problem (Narasimhan and Jordache 1999). The value of an observer system cannot be justified without considering its benefits. This justification is done through evaluation of data reconciliation, gross error detection and improving process performance such as outlined below:"

Jan 1, 2018

By J. J. Cai

The status of fossil fuel and secondary resource in metallurgy industry in China were reviewed, and conversion efficiency of fossil fuel, utilization technologies of secondary energy were studied. Fossil fuel, accounting for over 90% of energy structure in metallurgy industry, took in the highest flight in China, and a great deal of which was converted to secondary energy through the equipment of blast furnace and coke oven. These secondary energy which were mostly made of blast furnace gas(BFG), coke oven gas(COG) and Lindz Donawitz gas(LDG) occupied about 30% of total secondary energy. The way enhancing fossil fuel conversion efficiency, secondary resource recovery and the secondary energy such as BFG, COG, LDG utilization promoted to save fossil fuel was discussed in this paper. And efficient use of lower caloric value fuel was studied, such as preheating combustion air and fuel, generating electricity power etc. and regeneration purposes of high-caloric fuel was also researched, for producing hydrogen, methanol or direct reduction iron etc. The using model of secondary energy at iron and steel works was presented as fuel and chemical materials. The results suggest that utilization of these energy efficiently and reasonably could help to energy saving and environment protecting.

Jan 1, 2014

By B. Orberger

The fine fraction (< 2 mm) of the high grade Mn-ore from the world class Moanda deposit, Francevillan basin, in Gabon, contains up to 30 wt. % of manganese and about 0.4 wt. % phosphorous. A pilot study at laboratory scale integrating mineralogy and geochemistry before and after ultrasonic treatment was conducted on the fine fraction (< 2 mm) of oxidized Mn ore in order to reduce the phosphorous content and enrich this fraction in manganese. The fine fraction was dried, crushed at 2 cm and sieved at 2 mm. The two fractions (< 2 mm and 2 mm ? 2 cm) were investigated by X-ray diffraction and scanning electron microprobe ? electron dispersive spectroscopy analyses. Both fractions contain lithiophorite, cryptomelane and pyrolusite as Mn carrier, and goethite, muscovite, illite and quartz as contaminants. The Mn hydroxide nsutite was only found in the fraction 2mm ? 2 cm.The < 2 mm fraction is significantly richer in goethite, muscovite/illite, and quartz. Phosphorous carriers are mainly goethite (up to 2.8 wt. % P2O5), while the Mn minerals contain up to 0.8 wt. % P2O5. The Mn minerals are partly included in an agglomerate of goethite, muscovite/illite, and quartz. The < 2 mm fraction was treated by ultrasound for 30 s in normal water. Mineralogical and chemical analyses after ultrasound treatment showed that the Mn-minerals were largely liberated from the goethite-muscovite-illite agglomerate. Mass balance calculations show that after ultrasonic treatment the < 2 mm fraction was ? 50 % enriched in Mn and ?50 % impoverished in P.

Sep 1, 2012

By A. Chattopadhyay

Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex, ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.

Sep 1, 2012

By ?. S. Potokin

"In general the electric pulse treatment is composed from two processes – electric pulse grinding and electric explosive (electric discharging) activation. The electric pulse grinding with the effect of selective destruction refers to a major slag fraction, more that 2-5 mm, when a one can see a physical prerequisites for electrical breakdown of the slag particles. The electric pulse treatment of slag is considered as an additional operation in the technological scheme extraction of non-ferrous metals from copper smelting slags in addition with mechanical grinding, flotation enrichment and acid leaching. Studies of the reprocessability of pelletized slag have shown the possibility of higher extracting non-ferrous metals via flotation after electric pulse disintegration (EPD) treatment. By using EPD of slag pellets, it is possible to increase the non-ferrous metal yield to concentrate by 18-24%.INTRODUCTION The use of the explosive effect of the plasma discharge channel at electrical breakdown of a solid at a pulsed high voltage is the physical basis of the electric pulse method of destruction of geomaterials (Vorobiev et al., 1971; Andres, 1995; Semkin et al., 1995). The flowing of a pulsed current in the discharge channel is accompanied by a sharp increasing of plasma’s temperature and pressure, leading to a supersonic expanding of the discharge channel, the formation in the solid of intensive mechanical tension field, spreading of cracks, and eventually, to the destruction of the solid. Fragmentation and grinding of ore and mineral aggregates by electric pulse method due to a number of specific physical mechanisms of power load and crack formation, belonging only to this method, is different by high selectivity of destruction. This ensures better liberation of grains of individual minerals and their better preservation from destruction and less formation of a slurry output. These features creates the prerequisites for a more complete extraction of a useful mineral in the concentrate during ore dressing, to improve the quality of concentrate. In contradistinction to mechanical methods, electric pulse technology does not contaminate the product with instrumental metal, material of lining and grinding bodies. The possibility simply and in a wide range to change the dynamic load character allows to regulate the granulometric composition of the product of grinding, to obtain a narrower class of product size than is possible with mechanical grinding. The product of electric pulse grinding is characterized by less roundness and large specific surface area of grains due to the trait, that a new surface is formed in the process of splitting during the expanding of cracks. The degradation product has increased sorption and reactivity in chemical reactions. Liberation of the mineral inclusions particle better corresponds to their initial natural state in the rock and this is the great importance for the study of mineral raw materials."

Jan 1, 2018

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By Azin Zangooi, Cesar Gomez, James Finch

Frother concentration is a variable which significantly affects the flotation performance by decreasing bubble size and helping froth stabilization. Variations in frother concentration, which mostly go unnoticed in industrial operations, may affect these functions. Some factors that can cause variations include the fact that frothers are normally dosed based on feed tonnage and not solution concentration, unstable frother delivery, incomplete dissolution for low solubility frothers, addition of frother-free wash water, remnant frother in recycle waters and frother partitioning to the froth. A colorimetric technique developed for determining frother concentration on site makes it possible to detect the occurrence of these problems and to establish their magnitude, allowing conditions to be adjusted to reduce frother concentration variations. By sampling and analysis, frother distribution throughout a circuit can be established, referred to as ‘frother distribution mapping’. Experiences at several concentrators processing sulphide ores are used to illustrate time restrictions for sample analysis, and to demonstrate temporal and spatial frother concentration changes as a consequence of variations in the grinding stage, recycled waters containing frother, and frother partitioning.

Jan 1, 2014

By K. B. Venkatesh

In view of the importance of size reduction operations from the energy consumption point of view, during the past one hundred and fifty years a number of attempts have been made to develop a general energy-size relationship. However, to date it has not been possible to clearly define the scope of application of various laws proposed, though Bond law has been widely used with a moderate degree of success. It was, therefore, decided to carry out a thorough analysis of the batch ball mill grinding data available in the literature on several minerals that were ground under normal range of operating conditions. In particular, relationships proposed by Bond, Kapur, Voller and Morrell were examined in detail. It was found that the relationship proposed by Kapur in terms of the mean particle size provided a more accurate basis for estimation of energy. The value of the exponent of mean particle size in this relationship, a, is same as the exponent of the particle size in the expression for the grinding rate parameter: ki = Axia, provided the particle size distribution range corresponds to the self-similar or self-preserving regime. In this regime, mean particle size is proportional to the 80 percent passing size and size modulus. From the practical application point of view, it was possible to describe the variation of µ1 over limited, but significantly broad size range, using a constant value of a. Thus, by carrying out a few batches, grinding experiments over the size distribution range corresponding to the contents of the production mill, the applicable value of a can be determined. Keywords: energy-size relationship, ball mill, mean particle size, self-similar size distribution regime

Sep 1, 2012

By N. V. Ramana Murthy

Utilisation of Low-Grade Iron Ore Fines after concentration not only helps in conservation of the mineral wealth, but also substantialsly improves the economics of iron ore mining. There has been need to develop suitable beneficiation process for upgradation of low-grade iron ores towards their rational utilisation. Presently the circuit adopted for processing iron ores has limitations in reduction of alumina. The depletion of high-grade reserves, utilisation of low-grade reserves coupled with in-creasing market pressure for improved product quality necessitates re-examination of the process flow sheets and evaluate alternative or supplemental processing routes. The main objective of the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm) is to get Pellet grade concentrate with +65% Fe (min), SiO2 1.8% (max), Al2O3 1.8% (max) and other proportionate constituents by adopting suitable beneficiation techniques and to collect the relevant data (Quality and Quantity of the Products) for the process development. In an effort to formulate a conceptual process flow sheet, the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm), which is lying at a mine site in India, samples were collected and taken up for the study. The efforts of R & D of NMDC are discussed in this paper. Low-Grade Iron Ore Fines (-10mm) sample assayed 60.10% Fe with 3.48% SiO2 Aland 4.48% 2O3from 40 microns to 300 microns. The sample consists of hematite as the chief ore mineral followed by minor amounts of maghemite. The gangue minerals include quartz and ferruginous clay in which quartz occurs as medium grained where as ferruginous clay occurs as fine to sub microscopic size mineral. The economical processing route evolved out of the studies finally could yield a final concentrate constituting 58.63% by weight along with Iron unit?s recovery of 63.51% assaying 65.10% Fe with 1.48% SiO2 and 1.85% Al2O3route that adopted comprises the following operations. Making slurry in a sump pump followed by grinding in close circuit with 48mesh size Screen. The -48 mesh size product was subjected o the Cycloning to remove slimes. The Cyclone Underflow product was subjected to Floatex Density Separation (FDS) to separate fine heavy minerals from the gangue minerals. The FDS Underflow was collected as concentrate. The FDS Overflow product was further subjected with Wet High Intensity Magnetic Separation (WHIMS) to recover more Iron units as magnetics. A conceptual process flow sheet was evolved, which may become the prelude to the subsequent finalisation of the process flow sheet for commercialisation.

Jan 1, 2014