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By J. Châteauneuf, R. Dupéré, D. Mrabet

"In gold processing plants, it is common to start gold cyanidation in the grinding circuit by simple cyanide addition or as a result of recycling residual cyanide. In such cases, advantages such as a decrease in gold lockup and reduced leach time have been noticed. The prevailing conditions in grinding circuits such as intense mixing, particle breakage and friction or high temperature are quite different from those found in tanks and so is the resulting cyanidation behaviour. To gain a better understanding of the cyanidation behaviour in mills and of the pertinence of cyanide addition in grinding circuits, lab tests were conducted using an industrial ore from Canadian Malartic mine. In this study, the effects of different parameters on cyanidation in grinding circuits were examined; parameters such as such as temperature, dissolved oxygen, cyanide concentration and pH. The results showed that the kinetic benefits of high temperature in the mill can overcome the low dissolved oxygen concentration thus leading to an overall gold dissolution kinetics improvement for temperatures up to 50°C. However, gold leach in the studied grinding circuit at lab scale caused an increase in cyanide consumption with a higher generation of iron cyanide and SCN-. These results were confirmed by tests in the Canadian Malartic plant where the cyanide addition was moved from the SAG mill to the leaching tanks resulting in a 20% savings in cyanide consumption.IntroductionCyanidation in grinding circuits can benefit gold processing by decreasing gold lockup and by reducing leach time. However, other aspects regarding gold and cyanicide dissolution come into play in the conditions prevailing in grinding circuits. Indeed, high turbulence, high temperature, recycling load, friction and particle breakage make cyanidation behaviour in grinding circuits different from in-tank cyanidation (Marsden and House, 2006). In several cases, cyanide in grinding is limited to a very low level or completely avoided such as in circuits with gravimetric separation, for ores requiring oxidative pretreatment or for preg-robbing ores. In other cases, water management imposes a certain recycling of residual cyanide. This problem is generally addressed by a case-by-case approach. However, the chemistry of cyanidation in mill circuits is worth investigating in order to assess the advantages and disadvantages."

Jan 1, 2016

By Marcel Vallée

Frequently, costs overruns and defaults in mining project performance result in serious problems and headaches for all project participants and impact on corporate objectives, profits and image and, occasionally, lead to project failure. As mining professional s, we should be very concerned that, in a recent World Bank paper (Weber-Fahr, 2001), geological and technical risks were considered the most important ones facing mining projects. Whenever we manage to reduce or minimize these risks, we are in better position to overcome the environment-, market-, finance- and community-related ones. The causes of this situation seem rather systemic, as a fairly long list of industry problems with new pro jects has been described in industry papers in pas t and recent years. A brief review of industry problems with mining projects will be given first, followed by a review of the basics of the current Quality Management and Continuous Improvement perspectives that have evolved from earlier quality control and quality assurance systems and policies. Particular particular attention will be given to the work of W. E. Deming. As the system approach is an essential part of such policies, it will be described succinctly. Given that poor communications and interactions among geologists, mineral processors and mining engineers/operators ca n seriously affect project efficiency and profitability, these interrelated processes with in the mining systems will be analyzed and modelled and the impacts of such situations will be described through a number of anonymous case histories and examples. A synthesis of Dr Deming's management system, includ ing his Four teen P oints and System of Profound Knowledge, will be prese nted .

May 1, 2002

By Glenn Norris, Tyler Buckingham

"Gold recovery gains in the order of one to two percent have been realized in 2009 due to changes in the operation of the grinding circuits at Barrick Gold Corporation’s Hemlo - Williams Mill. The initiative known as “split milling” involves milling low grade open pit ore in one grinding circuit and higher grade underground ore in the other grinding circuit under different conditions.The philosophy of split milling involves processing higher grade underground ore at a lower throughput rate and a finer grind while milling lower grade open pit ore at a higher throughput rate and a coarser grind. Bench scale tests showed that the recovery relationship for underground ore sources was much more grind sensitive than that of open pit ore. This relationship proved to hold in the plant. The gold recovery gain due to finer grinding of the higher grade ore is much greater than the recovery loss due to coarser grinding on the lower grade ore. Since the majority of gold is being recovered at a higher rate, this results in higher overall plant gold recovery when compared to the traditional operation philosophy of blending the ore sources.The challenges for achieving the maximum benefits of split milling were two fold; the need to increase throughput on the open pit ore milling circuit and a means of grinding finer on the underground circuit. The former was met with an increase in SAG (Semi-Autogenous Grinding) mill ball charge, a basic “drill to mill” blasting campaign and changes to the primary gyratory crusher. The latter was met with a reduced SAG mill ball charge and a higher milling density. The resulting benefits in additional gold recovered are in the order of $3-5 million per annum.INTRODUCTIONThe Williams Mill processes ore from three different ore sources, the David Bell Mine (DB), the Williams Underground Mine (WUG) and the Williams Open Pit (OP). All three ore sources are located within the Hemlo camp in Northwestern Ontario adjacent to the Trans-Canada Highway. The Williams Mill was built in the mid 1980’s at which time it was designed to process 3,000 dry metric tonnes per day through a 22’ SAG mill in series with a 16’ ball mill. In 1988 a Mill expansion doubled the mill capacity by adding a second identical grinding circuit. A photo of the current grinding circuit can be seen in Figure 1. Today the Williams Mill processes an average of 8,000 tonnes per day of which approximately 60% is from the Williams Open Pit."

Jan 1, 2010

By Göran Bäckblom

The Swedish mining companies LKAB and Boliden, the equipment supplier Atlas Copco, the general contractor NCC and the specialist company Reflex joined forces in 2005 to advance the field of rock technology for the purpose of mining and underground construction. The creation of the company Rock Tech Centre is part of the strategy developed by the Swedish mining industry to strengthen co-operation with industry, academia and society. This paper outlines the current R&D strategies developed for the industry in general, discusses what focus areas are selected and provides some details on the current RTC project portfolio, especially faster and better drifting.

May 1, 2006

By Keith R. Vining

Solid fuel, usually coke or anthracite, is commonly added to ground iron ore fines in the pelletising process to reduce the amount of burner fuel required and the maximum firing temperature, while maintaining pellet strength and the productivity of the pelletising plant. However, the use of coke and coal contribute to the production of greenhouse gases (eg carbon dioxide) and are a source of NOx and SOx emissions. Utilising wood biomass / wood char is one methodology CSIRO Minerals is investigating as an alternative to coke and coal, as it is a renewable energy source that is very reactive, has a low ash content and the potential to reduce emissions of greenhouse gases from the iron and steel-making process. Previous work has established that charcoal can effectively replace coke in the sintering process (Lovel et al, 2005), and the following experimental work aims to demonstrate that it can also provide an adequate replacement for coke and coal in the pelletising process. The paper presents the results of an experimental testwork program comparing the behaviour of fired pellets containing traditional solid fuels and charcoal. The physical properties of the pellets are compared in terms of their compressive strength, tumble and abrasion indices and the reduction properties. A qualitative assessment of the pellet microstructures is also presented.

May 1, 2007

By Seppo Haapamaki

"Since it started production in 1970, Anderson Lake Mine has experienced several radical changes in mining methods as a result of the physical characteristics of the ore zone along with the need for improved productivity. This paper examines the transition from longhole open stoping to mechanized cut-and fill then to vertical crater retreat at Anderson Lake Mine. The reasons for the need to change mining methods is analyzed taking into consideration the impact of such criteria as improved productivity and ground conditions and how these criteria affected the over-all economic viability of the mine. IntroductionAnderson Lake Mine is one of five producing copper mines in the Snow Lake area and is situated approximately 3 km southeast of the townsite of Snow Lake (Fig. I).The mine production rate at Anderson Lake is 700 tpd and all ore is trucked from the mine to the mill located approximately 2.5 km from the mine site . The mine is serviced by a three-compartment shaft sunk to a depth of 3300 ft with level spacings at 175 ft and 150 ft intervals from the 600 ft level to the 3000 ft level. .The shaft was collared in 1965 and, a year later, the hoist and compressors were installed. By 1969, a crusher system had been built and actual production began in 1970. During 1978, production was suspended for the year to allow for 430 ft of shaft deepening."

Jan 1, 1988

By J. Allaire, P. N. Muteb

The Meadowbank mine is operated by Agnico-Eagle Mines Ltd. and is located in the Kivalliq District of Nunavut in northern Canada. The process plant operates presently at a throughput of 11,500 tpd with gold grade varying between 2.9 and 3.6 g/t. The ore supplied to the process plant come from two different open pits and it expected to come from a new open pit early 2014. The ore is mid-hard materials so the feed size ore have a bigger impact on the throughput. The average gold recovery is 94.0% with about 15-30% of gold recover from the gravity circuit. The Meadowbank mine commissioning started in February 2010 utilizing a flowsheet consisting of one stage of crushing followed by primary and secondary grinding. The commercial production began in March 2010. During the commissioning several difficulties were observed to reach the designed throughput of 8,500 tpd. It was evaluated to insert a second stage of crushing. The insertion of the secondary crushing have two objectives, first to reach easily the process plant design throughput as well as to evaluated the mill capacity increasing. The process plant team evaluated various expansion alternatives eventually deciding to install a secondary crusher, increased the SAG and Ball mills motors capacities and maintain the rest of the process unchanged. Early 2011, with the improvement in the gold markets, decision was made to install the secondary crusher between the primary crusher and the primary grinding. The process plant continued to operate on the initial design until early June 2011. This paper presents the SAG mill throughput increasing from the designed tonnage of 8,500 tpd to 2012 targeted tonnage of 11,500 tpd, secondary crusher commissioning and the difficulties to operate in Canada Artic (Nunavut).

Jan 1, 2013

By T. A. Kirk

"The Linatex Dewatering System is a compact, low capital and maintenance cost matched set of processing equipment suitable for solids recovery, dewatering and desliming sand-like materials in the range 3/8"" to 325 mesh ( 1). Since its introduction to North America in the early 1970s, various elements of the system have been successfully installed in a variety of applic11tions both in Canada and the U.S.A. Examples are chosen from the coal, fine aggregates, iron ore and industrial minerals industries.II. Elements of the Linatex Solids Recovery System(A) The Linatex Separator (See Fig.I)The Linatex Separator, which is the heart of the system, is a specialized type of hydrocyclone designed to give a self regulating rope discharge product. It has the familiar cyclone geometry of cylindrical and conical section, tangential inlet, apex and vortex finder. The apex is enclosed in a unique patented automatic underflow regulator consisting of a collapsible rubber sleeve, and the overflow line is a siphon-leg, with a controlled air bleed valve. The siphon leg is adjusted so as to balance the internal negative pressure acting as a closing force on the underflow regulator against the mass of slurry pressing down on it from the cone section of the Separator. With correct adjustment the underflow regulator will close drip-tight on a water only feed. As solids accumulate in the apex of the cone the weight of solids counterbalances the vacuum and cat1ses the underflow regulator to open and discharge classified material at a controlled density."

Jan 1, 1978

By R. W. Watson, H. D. Peer

"This paper outlines the history of steel linings in the Autogenous Mills, the factors influencing the decision to convert to rubber lining, and the operating and cost experience with the rubber liners to date. INTRODUCTIONSherman Mine is an open pit iron ore mining, concentrating and pelletizing operation located at Temagami, Ontario. The operation employs 392 hourly employees and 81 salaried employees and has an annual capacity of over one million L.T. of high quality iron ore pellets produced from low-grade magnetite ore.The Sherman Mine is a joint venture; 90% owned by Dominion Foundries and Steel Limited (Dofasco) of Hamilton, Ontario, and 10% owned by the Tetapaga Mining Company, a wholly-owned subsidiary of the Cleveland Cliffs Iron Company of Cleveland, Ohio. The operation and management of the mine is by Cliffs of Canada, Limited. Development of the property was started in 1965, with pellet plant production beginning on March 17, 1968. At the present time, the orebodies contain sufficient reserves to sustain operations at current production levels for 30 years. Mining was originally carried out in three orebodies, the North, South, and West pits. The North Pit has been exhausted and mining operations ceased in the spring of 1980. A fourth pit, the East Pit, will be developed during the early 1980's."

Jan 1, 1981

By Claude Bazin, François Robichaud

"The control of the operation of semi autogeneous grinding (SAG) mills is mainly achieved through adjustments of feed rate, water addition and speed of rotation. With the introduction of image based sensors it is possible to have on-line measurements of the size distribution of the ore feeding a SAG mill. This information could be used for the development of a control strategy to regulate a SAG mill feed size distribution to a set-point. The control of the size distribution is carried out by adjustment of the speed of the ore extractors underneath the ore stockpile. The potential and difficulty associated with the implementation of such control are assessed using a multivariable statistical analysis of data collected from the operation of the grinding circuit of the Agnico-Eagle Goldex mine in Val d’Or, QC. A control strategy for the ore feed size distribution is assessed using a simulator of the ore stockpile operation.INTRODUCTIONThe popularity of autogeneous (FAG) and semi autogeneous (SAG) grinding mills has been increasing over the last 20 years (Napier Munn et al., 1996). These mills use the ore or a combination of ore and steel balls as the grinding media. Since the ore is used as a media for the size reduction the mill ore feed size distribution impacts the performance of the mill. Several papers were recently published on this subject (Dance et al.,2011; Wennen & Murr, 2011; Dance & Valery, 2011; Allaire et al., 2011) showing the advantages of preparing the feed size distribution to maximize the circuit throughput or mill efficiency (Wennen & Murr, 2011; Dance & Valery, 2011; Allaire et al., 2011). With the availability of particle size sensor based on image analysis of the ore on a conveyor (Partanen et al., 2001; Bobo et al. 2004; Edwards et al., 2002; Wei & Craig, 2009) it is possible to control the size distribution of the ore feeding autogeneous or semi autogeneous mills (Partanen et al., 2001).This paper describes a method to control a size distribution index to a set point via the manipulation of the speed of the extractors that withdraw the ore from the stockpile feeding the grinding circuit. The paper consists of 4 sections. The first section describes the considered grinding circuit. A statistical analysis of the collected data on the grinding circuit is presented in the second section. This analysis demonstrates the necessity of using real-time adaptation mechanisms to develop a control strategy for the size distribution of a grinding circuit. The third section describes the method used to simulate the ore stockpile operation and the last section describes the preliminary development and assessment of a control strategy of size distribution of the ore feeding a SAG mill."

Jan 1, 2013

By Panagiota Tsolis-Katagas, Basilios Tsikouras, Tassos A. Grammatikopoulos, C. Katagas

"Mineralogical techniques including microscopic methods, reflected and transmitted light microscopy, Cathodoluminescence (CL) and Scanning Electron Microscopy equipped with an Energy Dispersive Spectrometer (SEM-EDS), are useful in determining the quality of industrial minerals. They are essential for studying ores and metallurgical products including the evaluation of physical characteristics of the mineral, paragenetic relationships, associations with possible deleterious contaminants (e.g., sulphides), spatial distribution within the ore zones and liberation characteristics. The methods are inexpensive, and provide quick identification and distinction among the industrial minerals and the gangue minerals in a section. Additionally, SEM is necessary to reveal complex textural sequences and 3-D measurements of minerals and quick semi-quantitative analysis.Common analytical methods include Electron Microprobe Analyses (EMPA) and Whole Rock Analysis (WRA) (commonly with XRF and ICP) for major and trace elements. The EMPA analyses of industrial minerals provide information on the purity of the analyzed grains as opposed to the bulk chemical analyses that may be misleading due to contamination by other associated common “gangue” minerals. These techniques have been implemented for the case studies of wollastonite, V-magnetite and muscovite. Therefore, these methods can provide extremely useful information and lead to the implementation of a successful pilot-testing programme.MINERALOGICAL EVALUATION OF DEPOSITSDespite their considerable and increasing economic importance, industrial mineral deposits have traditionally been neglected by economic geologists, and are only rarely the subject of the detailed analysis widely lavished on metallic mineralization. Moreover, in that they generally represent concentrations of “normal” rock-forming minerals, albeit commonly with particular textural and/or geochemical features, they have tended to fall between the mainstream of petrogenetic studies and mineral deposit research (Grammatikopoulos 1999). For many industrial minerals, little attention has been paid to the factors responsible for their local concentration as large and high-grade bodies. This comparative neglect has particularly been the case for minerals such as talc and wollastonite, widespread in metamorphic rocks, in which they are reasonably interpreted as components of assemblages derived, respectively, from pelitic sediments, ultramafic igneous rocks and siliceous limestones."

Jan 1, 2003

By Stuart Elliot

Brownfield project portfolios are notoriously hard to manage. Day to day there is a constant stream of changes and challenges within projects and across the whole program. When the budget year is over, we?re often left wondering: did the facilities get what they really needed? Did we get value for the capital that was spent? Did we get all the project control and process improvement that we paid for? Great work has been done over the years by the Project Management Institute, Construction Industry Institute and Independent Project Analysis to identify what leads to project success, develop project delivery systems and equip project leaders to perform better. But is attention to individual projects all we need when the job is to deliver a portfolio of many projects? Let?s work with an analogy for a moment, and say a project is like a car, and a project manager the driver. Why can?t all the projects in the portfolio get home in time for dinner? The answer, of course, is that the commute home is about traffic, not just about cars. The road, the signals and the actions of other drivers affect us in our individual cars. Optimizing traffic flow is not about managing individual cars, it is about creating the conditions that allow all traffic to move as smoothly as possible. When we?re stuck in traffic, it doesn?t really matter that we are skilled drivers who know our exact location and our engine?s vital signs. Success with a brownfield portfolio requires more than the equivalent of driver training and a good GPS in every vehicle. Managing the annual budget requires more than tight management of each project. This is not a suggestion to abandon project management in the brownfield multi-projects world; the idea is to find and apply the right tools for delivering a portfolio. Remember, we want confidence in 3 areas: 1. that the facility is getting what it really needs, when it needs it 2. that we are getting value for money invested in facility modifications and improvements, and 3. that our controls are adding value by guiding our improvement What are those portfolio tools? The job they have to do is distinct from project-level thinking: ? Create a clear and balanced business pull for project ideas ? Maintain a respectable plan for fiscal, resource and business control ? Organize the work into a steady flow ? Manage the nature and timing of value-driven project substitutions and priority changes ? Focus on overall business value added and best use of resources ? Repurpose the projects organization into being the way the facility gets improved

Nov 1, 2011

Les Mines Inmet ? La Division Troilus exploite une mine d?or à ciel ouvert depuis 1996 et produit un concentré de cuivre. La Division Troilus est localisée à 175 KM au nord de la ville de Chibougamau? au 51 parallèle.

Feb 1, 2008

"The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media. Due to the lack of higher precision influence of temperature on thermal conductivity, we took 6 groups of experiments on rock samples (including igneous rock, sedimentary rock and metamorphic rock) under different operating temperatures from 20? to 50? by 7 acquisition points. The general equation of thermal conductivity drives the value of it increasing along with the decreases of the temperature. While in our experiments, it is easy to find a singularity among them for each sample. The experimental investigations we attempted to observe and interpret the alteration mechanism. According to the Heat Capacity Theory in solid state physics, this research gives the explanation about the “singularity” from 3 understanding of specific heat, average free path, and thermal conductivity. Our research divided the condition of the rock thermal conductivity into 3 different types. INTRODUCTION The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media(Huang & Han ,1988; Peierles ,1955). This parameter is necessary for analysis of heat transfer(Vaferi et al, 2014;Hans-Dieter & Rudiger,2003). It’s well known that a general equation for ?(T) was set by Sass et al. (1992) which based on the coupled effect of composition and temperature on the thermal conductivity(Jesse et al, 2013; Mongelli et al,1982).The equation was further successfully verified for other rock (Zumrud et al,2010;Abdulagatova et al,2009;Seipold& Huenges,1998).Thermal conductivity is also related to other physical proper ties of porous rock, such as thermal diffusivity, heat capacity(Brettmann et al,2011;Abuel-Naga et al,2008). It is well known that ETC and other thermo physical properties of rock materials are affected by various factors, such as temperature, pressure, mineralogical composition, porosity, stratification, size and shape of the components, and nature of pore fluid, etc. (Tiedje & Guo, 2014; Touloukian et al,1970).The understanding of heat transport processes still requires the knowledge of thermal properties of rocks."

Jan 1, 2015

By N. I. Basuki, E. T. C. Spooner

"The Bongara area, northern Peru, contains Zn-Pb mineralization with characteristics typical of Mississippi Valley-type (MVT) systems. The northwest-southeast-trending late Triassic-Jurassic car¬bonate host rocks of the Pucará Group were locally replaced by early (D1) and late (D2) dolomite. Fluid inclusion microthermometric data from dolomite and sphalerite are typical of MVT ore fluids (78° to 187°C; ~15-23 wt.% CaCl2 equivalent), and do not show apparent covariation between temperature and salinity.Homogenization temperature data from D1 and D2 dolomite show a decrease from northern (mean Th = 138°C) to central (mean Th = 126°C) to southern areas (mean Th = 102°C), suggesting fluid flow from north to south. Assuming a geothermal gradient of ~30°C/km and an average surface temperature of ~20°C, the lower temperature limits might approximate the ambient host-rock temperatures, whereas the upper temperature limits may represent minimum temperatures of a deeper aquifer, probably at a maximum depth of ~6000 m. The lower temperature limits are also similar to the estimated temperatures if dolomitization and mineralization took place in the Late Cretaceous at ~2000-3000 m depth, probably during the formation of the Peruvian fold and thrust belt near the present day Peru-Ecuador border.Fluid inclusion data show that the fluids in each studied location had relatively uniform temperatures and salinities during dolomitization and mineralization. A significant salinity drop and a slight temperature decrease are observed during late calcite precipitation, suggesting mixing of brines with dilute, cooler fluids."

Jan 1, 2009

By R. H. Seraphim

"Western Mines Limited produces gold, silver, copper, lead and zinc from a number of Paleozoic volcanogenic deposits near Buttle Lake on Vancouver Island. The deposits were emplaced along a series of submarine linear volcanic ridges that extended for at least 6,000 metres in a northwesterly direction.Rock types mapped include: andesitic, dacitic and rhyolitic flow s and volcanic breccias; detrital breccias, tuffs and hematitic silts; black and green cherts; and a variety of dykes and sills, including quartz porphyry and diorite. Orebodies are associated invariably, and in places intimately, with quartzsericite schist and rhyolitic rocks. The ore is complex, varying in mineralogy and tenor both within each deposit and from one deposit to another.Recent studies have increased our knowledge of the structure and left no doubt that the orebodies were deposited both within the throats of the linear vents and on paleoslopes adjacent to these vents.IntroductionWestern Mines Limited operates an 850-tonne-per-day mine, located 85 km south of Campbell River, B.C. The mine is at approximately 400 metres elevation, near the south end of Buttle Lake on Vancouver Island (Fig . I). It has operated since early 1967 and produced 3,650,000 tonnes with an average grade of 1.9 g (0.06 oz) gold, 93 g (3.0 oz) silver, 1.6 per cent copper, 1.0 per cent lead and 7.5 per cent zinc per tonne by the end of 1978. Current reserves are 1,157,000 tonnes of 2.7 g (0.09 oz) gold, 117 g (3 .8 oz) silver , 1.2 per cent copper, 1.2 per cent lead and 8.0 percent zinc per tonne (December 31, 1978).Ore from one zone, known as Myra High-Grade, is mined and milled separately because of its grade. Ore milled prior to December 31,1978, plus reserves, 180,715 tonnes of6.6 g (0.21 oz) gold, 554.5 g (17 .7 oz) silver, 0 .8 per cent copper, 3.2 per cent lead and 10.6 per cent zinc are included in the figures listed in the preceding paragraphs."

Jan 1, 1980

By J. O. Marsden

Over the past decade, the copper industry has been through an extended downturn followed by several years of sustained high copper price. A number of new technologies have been developed over the past 10 years aimed at reducing costs by decreasing energy, labor, and materials requirements, or by increasing metal recovery. The energy intensity of different copper extraction routes and different technologies varies considerably and this has a significant impact on the economics of extraction. Based on average ore grade materials, the total energy for the extraction of copper typically varies from about 24-26 MJ/lb (6.7-7.2 kWh/lb) for the mining, crushing, milling, flotation, smelting and refining route to about 14¬16 MJ/lb (3.9-4.5 kWh/lb) for the mining, crushing, heap leaching, solution extraction and electrowinning route. New technology developments are providing opportunities for significant reductions in energy consumption for copper extraction, representing energy savings up to 20-25% in some cases. In addition, in many cases, these new technologies have introduced environmental, safety and health benefits over the incumbent technology. Some of these technology developments have been more successful than others, and many hold great promise for application in the coming decade. This paper provides an overview of the technology developments that have occurred, and explores the underlying reasons behind successful implementation.

Jan 1, 2007

By G. I. Mathieu, R. W. Bruce

Flotation schemes for the separation of molybdenite from other minerals are based on utilizing the Inherent hydrophobicity of molygdenite (Fuerstenau1). This natural floatability was attributed to the crystalline structure of molybdenite by Gaudin et al.2 who suggested that any surface formed by the rupture of van der Wall's bonds should be hydrophobic and, therefore, naturally floatable. Other authors argued that "natural floatability" is dependent of adsorption of hydrocarbon ions and/or molecu1es on the surface of the minerals. This theory, albeit-c questioned 1,2 has long been recognized in actual practice of molybdenite flotation as the latter in carried out with hydrocarbons, such as fuel oil, kerosene and stove oil. Although conferring ready floatability to molybdenite, these presents generally have little effect on other sulphides and silicates. However, talc is a noteworthy exception because of its innate floatability4. Not withstanding the reason for this behavior which has also been attributed to crystal structure2 its end results as in the case of molybdenite is an immediate flotation response to frothing oils arid kerosene, as was observed by Baranovski5, Sutherland and Wark6.

Jan 1, 1974

By B. Tanda

A process has been developed at Curtin University whereby glycine is used in an alkaline environment to leach gold, silver and copper from their ores, concentrates, process intermediates and wastes. Copper mineralisation investigated includes various oxides, sulfides and native copper. The leach process utilises an oxidising environment such as oxygen. Glycine is a non-toxic, non-volatile, edible, low cost reagent which is produced in large industrial quantities for use in several industries. Glycine and its copper and precious metals complexes are stable over wide pH, Eh and temperature ranges. Other than losses in leach residues, the glycine is recovered and recycled for leaching. Iron dissolution is insignificant in the pregnant leach solution. Iron in pyrite remains unaffected, whereas iron associated with base metal sulfides (e.g. chalcopyrite and bornite) is converted to a readily filterable iron hydroxide. Efficient separation of copper by solvent extraction and conventional electrowinning has been shown to be feasible for a number of organic extractants, whereas gold and silver glycinates adsorb very well onto carbon allowing CIP/CIL/CIC (carbon-in-column) based processes. The process is ideal for ores containing acid-consuming gangue, concentrates with high arsenic or halide contents and for copper-gold ores with significant sulfide mineralisation. The process eliminates many of the problems associated with the processing of copper-gold-silver ores, such as elemental sulfur formation, silica gels, unwanted metal co-dissolution, and jarosite precipitation. The reagents used and process residues are much safer and environmentally benign than conventional process options. The processing technology can be applied to in-situ, heap and vat, or agitated tank leaching at temperatures ranging from ambient to below 100?C at atmospheric pressure and is currently being commercialised. This paper will focus on copper leaching and recovery and iron rejection from a chalcopyrite flotation concentrate.

Jan 1, 2016

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009