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By Ahmad Ghahreman, James McNeice

"Cerium is the most abundant rare earth metal and is often found in deposits along with small amounts of more valuable metals such as neodymium and gadolinium1. As a result, the production of cerium oxide often exceeds market demands, thus in some cases it would make more sense to remove the cerium from the process solutions before further purification. A common method of cerium removal is to precipitate CeO2 from the acidic leach liquors by raising the pH to oxidize cerium(III) to cerium(IV). This study investigates the oxidation kinetics using three oxidants; hydrogen peroxide, sodium hypochlorite, and potassium permanganate. The effect of oxidant, pH, cerium concentration and temperature on the oxidation kinetics will be discussed. Cerium oxidation in solutions with pH ranging from 1.0 to 4.0 was investigated at cerium concentrations ranging from 2.0 g/L to 16.0 g/L. A cerium recovery of 40% can be achieved at different conditions with each oxidant at room temperature, with higher recovery at 60°C.INTRODUCTION Over the last 70 years, the rare earth elements (REE) have become crucial components of modern technology. These metals are categorized as light rare earths (LREE) or heavy rare earths (HREE) by governments and miners based on weight, abundance, and therefore value. The minerals bastnaesite, monazite, and xenotime compose the majority of the world?s exploitable sources of these metals (Binnemans, 2013; Parker and Baroch, 1971). Geologists classify the LREE ores as „cerium group? minerals, approximately 50% cerium oxide by weight. The cerium group minerals monazite and bastnaesite compose the majority of world production, leading to an overproduction of cerium relative to world demand. This ratio of light to heavy REE in deposits has led to a phenomenon referred to as the balance problem (Binnemans et al., 2013). As an example, to produce 1 tonne of europium oxide from a bastnaesite deposit 450 tonnes of cerium oxide must be processed. This means that any push to increase production and access the value of the HREE metals will drive down the value of the LREE metals leading to diminishing returns (Zepf, 2016). These ores also contain measurable levels of thorium, subjecting them to complex radioactive waste regulations. During the 20th century, the USA was the largest producer of rare earth metals (REMs), primarily sourced from the Mountain Pass mine in California. However, due to a combination of market dynamics and regulations, China has dominated the market for the last two decades. The largest Chinese REE mine, Bayan Obo, produces rare earth (RE) concentrate as a byproduct of iron mining, decreasing their relative production costs (Gupta and Krishnamurthy, 2005). This mine alone represents about half of world bastnaesite production (Zhi and Yang, 2014). Rising demand for high-tech products has forced Chinese producers to commission other large mines, climbing to 90% of world production in the early years of the new millennium (Mancheri, 2016). This presents the west with a looming supply risk of these critical metals in the future."

Jan 1, 2017

"IntroductionNOTE.-All figures on the supply and consumption of coal in Canada cited in this paper were collected and reported by the Dominion Bureau of Statistics. The friendly and efficient co-operation of the officials of the Bureau. is the foundation upon which it has been my privilege to rely in the preparation of this and two earlier papers ( 1). My thanks are due also to our own staff on the Dominion Coal Board, who spared neither time nor effort in helping to prepare this paper.STATISTICS are comparatively dull and, to many people, coal statistics are duller than most. Coal is, however, the one basic mineral upon which our whole way of life depends and it may be well if attention is drawn to this fact by an occasional statistical review of the coal position in Canada. The recent furore over the oil and gas discoveries has so obscured the basic position of coal in many minds that a little basic coal information may be useful. It is for this reason that, for the third successive year, a factual survey of the coal position is being presented.In the previous papers (1) explanations have been given of the basic considerations in the preparation of these reports and some special phases of the overall picture have been examined. For these explanations, the earlier papers may be consulted."

Jan 1, 1952

By Lars A. Bergstrom

High-voltage direct -current transmission is a relatively new technology. The successful development and operation of AC/DC converters, capable of handling large power blocks, have made HVDC transmission generally accepted by utility engineer s and planners around the world. HVDC technology still has significant development potential and, as a result, it is expected that equipment costs will escalate at a substantially slower rate than those of conventional AC equipment. This development will also result in still more compact terminal stations. This paper reviews two modern HVDC installations. In Zaire in Africa. a 1700-km overhead DC line rated at 500 kv, will supply power to the copper mining district in the Shaba region. Another HVDC link connects Norway and Denmark through a submarine cable rated at 250 kv. This is the longest HVDC cable in the world, 127 km, and the water depth , maximum 530 m, is also much greater than for any previous similar cable. The reasons for selecting HVDC are discussed, and the design and layouts are presented.

Jan 1, 1978

By Mary A. Wells, Amir Hadadzadeh, Mark A. Whitney, Stephen F. Corbin

In an effort to produce less expensive titanium sheet via roll compaction, the room temperature compaction behavior of titanium sponge granules (99.9% pure, Alfa Aesar) was studied under uniaxial die compaction. The titanium sponge granules were irregularly shaped, with a high degree of porosity, having a maximum particle size of 3mm. Manual die compaction was conducted using a Carver hand press, in a hardened tool steel die with 12.61 mm inner diameter. Uniaxial die compaction in a hardened tool steel die with 9.50 mm inner diameter was also performed using a Gleeble® 3500 thermal-mechanical simulation testing system which allowed for controlled deformation rates. Compaction behavior of the titanium sponge was studied using well-established compaction equations (Heckel, Panelli-Filho and Ge), and it was observed that compaction rate influences the room temperature compaction behavior of this material. The Heckel analysis of the titanium sponge showed that the behavior of the material could be analyzed in two compaction pressure regimes. In the low pressure regime (<100 MPa) the granules exhibited high compressibility, while; in the high pressure regime (>100 MPa) lower compressibility of the titanium sponge was observed.

Jan 1, 2015

By K. Bowes, M. D. Maley, R. J. Ring

The Honeymoon Uranium Project is an acid In-Situ Recovery (ISR) mine in South Australia. It was previously operated for approximately 18 months before being placed on care and maintenance in 2014, it was then acquired by Boss Resources in 2015. Boss has been performing a number of studies to plan for reopening of the mine, including a successful field leach trial (FLT) in 2017. The current configuration for uranium precipitation at Honeymoon is a batch process. Whilst this achieves effective uranium recovery, the precipitates produced are often very fine, with poor settling and solid/liquid separation characteristics. Continuous precipitation, involving recycling of solids, has reportedly been successfully utilised in other operations to increase the particle size and density of the product, leading to solids that can be more readily dewatered, dried and drummed, with less fines and dust generation. However, no operational data are available from such operations.

Jan 1, 2020

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By A. A. de Gast, R. B. James

"The metal content of ore blocks can be calculated by the use of many different methods. These methods range in sophistication from manual calculation to computer. oriented techniques. In this case a cubic polynomial regression model is developed to depict the grade distribution of an orebody. Mine production, in stope dimensions, is then simulated on a computer to predict the output of metal content. The volume, grade and variance of the grade are estimated by triple integration and matrix algebra. A case study shows reasonable agreement between the results from the mathematical model and the mine geologists' estimate of production and ore reserve grade and tonnage."

Jan 1, 1972

By A. H. C. A. Zimmerman

WE have just heard what must be regarded as a thoughtful, constructive and somewhat painful analysis of the financial function of our industry. While thinking about this, it is interesting to reflect on the conditions which have stunted the growth of the financial side of our affairs. Mining must be regarded as a wealthy business. •while immeasurable grub takes and development budgets have been lost, there can be little argument that a productive ore-body nearly always produces the type of wealth that breeds some extravagance. I recognize that this statement can be attacked from many sides, but an historical comparison with a commercial enterprise involving similar investment will demonstrate what I mean. However, these old times are be-ginning to disappear for a variety of reasons. High amongst these are: ( l) Increased costs of exploration. (2) Remoteness of many new finds. (3) Fixed or declining metal prices (particularly when expressed in constant dollars). ( 4) Constant demands for higher wages.

Jan 1, 1962

By H. G. Warrington

Abstract As part of the active development programme pursued by Dominion Magnesium Limited since 1945, a modern extrusion plant was erected and has been in operation for about twelve months. The only source of nigh purity magnesium in the world, Canadian metal is produced by metallurgical processes within the frame-work of the mining industry, which gives a different viewpoint to every phase of production from other world suppliers of commercial grade metal whose operations are based on chemical industries and techniques. The superior properties of corrosion resistance and grain refinement have aided a programme of standardization, reducing the number of alloys supplied in extruded form from seven to four as an aid to economic production. The first big step was the development of a general purpose alloy known as AZ?21x covering all decorative and medium stressed applications, which will supersede two older alloys. Sales approaching a million feet in this alloy show that it bids fair to become the &apos;mild steel&apos; of the magnesium industry, its applications ranging from terrazzo floor strip to textile machinery and television mast components. In the high stressed field, metallurgical features preclude low-cost extrusion of the older high-strength alloys, but recent development of a magnesium alloy containing zirconium promises an easily workable metal. Hitherto produced by expensive chemical additions, research now shows that the alloy can be produced by metallurgical means, which may make this alloy available for a wide range of commercial applications. Thus the future development programme for extruded products in the form of tube, bars, shapes, and structural angles and channels may evolve two alloys to cover all applications for strengths up to 52,000 lb. per sq. in. Such standardization is the result of taking advantage of the physical and metallurgical properties of high-purity magnesium instead of accepting techniques based on metal produced by older processes.

Jan 1, 1951

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and¬error techniques. This paper introduces a two dimensional finite element model of compacting/briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, velocity field, stress distribution, roll force, roll torque and other important process variables. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquet after its exit from the pressing zone. This enables to perform realistic computer experiments which are helpful for establishing the pressing system design, forming cavity geometry and process conditions necessary to produce compacted or briquetted product with the desired properties.

Jan 1, 2004

By T. Imgrund, A. Bischoff, S. Spürk

"Specific conditions of underground coal mines at great depth, such as high temperatures, high rates of methane inflow and natural ventilation pressure provide considerable challenges for the reliable design of appropriate mine ventilation systems. For decades coal mining in Germany has coped with these extreme circumstances. Based on these experiences appropriate software tools for simulating mine ventilation networks have been developed and continuously enhanced. This paper examines differences in the simulation results and underlying calculation methods of two software solutions. The analysis is based on the comparison of FlowNetTM and VentSim DesignTM (Version 5.1) regarding the accurate prediction of fluid mechanical quantities and their validation with real measurements. A special focus lies on exceptional ventilation scenarios typical for deep coal mines, like gas inflows, fire events and buoyancy effects. The purpose of the comparison is the future utilization of the experiences gained during mining at up to 1,500 m depth for state of the art ventilation design. INTRODUCTION Ventilation is an essential component of mine operations—as providing fresh air to workplaces, diluting and removing explosive, toxic or asphyxiating pollutants and assuring sufficient climate conditions. On the other hand, the costs of ventilation contribute to a large extend to the overall operating costs of a mine, as the share in the energy consumption of a mine may be in the range of 25–50% (Belle, 2008). Accordingly, proper design of ventilation systems has been a task since early times. Consequently software for modelling of ventilation networks has been developed in order to improve efficiency and accuracy of calculations (Maleki, 2018). Compressible flow has not been considered by initial ventilation modelling software tools. In Germany, the consideration of changes in airflow density—depending on pressure and temperature—in the algorithms of ventilation simulation software has been started in 1974 by Duepre & Hofbauer. This development had been continued by the Pruefstelle fuer Grubenbewetterung (Test Centre for Mine Ventilation) and resulted in the release of a computer ventilation software named “Wetter”. The mine inspectorate of the German state of North Rhine-Westphalia, which supervises the major coal mining district in Germany, declared ventilation simulation based on compressible flow being “state of the art” in 1985 (Pollak, 1985). This pronouncement made allowance for assessing the consequences of underground fires and downtimes of main fans based on advanced software solutions."

Jan 1, 2019

By M. O. Pekguleryuz, D. S. Aydin

The high temperature oxidation and ignition resistance of Mg-(0-6) wt% Nd alloys have been investigated via isothermal and continuous heating experiments conducted in air atmosphere. Alloy composition is observed to be effective in low levels (~ 0.5 %) in the ignition temperature (Ti) of the alloys; the Ti of pure Mg increased from 630 °C to 770 °C with 0.5 wt% Nd addition. However, no noteworthy improvement was achieved with further additions up to 6 wt% Nd. The initial microstructure was observed to determine the oxide structure on the surface due to the differing oxidation behavior of the phases (a-Mg + Mg12Nd intermetallics). It has been found that the formation of a Nd-depleted region at the subsurface due to extensive Nd oxidation at the oxide/intermetallic interface lowers the protective ability of the oxide scale.

Jan 1, 2015

By G. M. Card, K. D. Card, B. V. Sanford

Abstract-The Canadian Shield and its extensions are traversed by an orthogonal system of northwest and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches influenced patterns of sedimentation and tectonism in the intervening epicratonic basins and marginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structures also triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By G. M. Card, K. D. Card, B. V. Sanford

The Canadian Shield and its extensions are traversed by an orthogonal system of north-west and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches in?uenced patterns of sedimentation and tectonism in the intervening epicratonic basins andmarginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structuresalso triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By Kathy S. Kalenchuk

Damages have been observed in shafts, backfill infrastructure and the slick line at the Leeville Mine. Shaft damage (shearing and spalling of the concrete liner) is attributed to mine-induced rock mass deformations concentrated where regional faults intersect the shafts. Aggregate bin, mixer station and conveyor drive damage (shotcrete shearing, heave of concrete floor slabs and bending of a vertical steel beams) is attributed to rock mass squeezing induced by elevated magnitudes of the vertically orientated major principal stresses. Separation of the slick line has occurred do to extension of the stressshadowed rock mass immediately above the mined out areas. Three-dimensional numerical models have been developed and calibrated to simulated rock mass deformations with magnitudes similar to those believed to have produced the observed damages. By stepping through the mine sequence, models reproduce deformations at the same mining stage as when damage has occurred. Calibrated models have been used to forward project further damage over the remaining mine life.

Jun 1, 2012

By Kamran Esmaieli

This paper investigates the behavior of ore pass walls under impact loads caused by material transiting through an ore pass. In particular it considers the influence of foliation in the rock mass surrounding an ore pass as both a triggering and accentuating cause of degradation. Based on empirical observations in several underground mines a numerical experiment was designed to understand the influence of rock mass foliation on impact-induced damage on ore pass walls. The distinct element method, and in particular the Particle Flow Code (PFC2D) was used to simulate three different rock masses surrounding an ore pass. Each simulated rock mass has similar properties but was defined by distinct dominant foliation (70o, 80o, 90o) along the foot wall. The numerical experiments investigated different scenarios whereby the walls were loaded by a projected rock fragment striking the foliated walls at a constant impact angle and velocity. The damage inflicted by the projectile rock fragment, on the foliated rock mass, was quantified using the number of impact-induced micro-cracks initiated on the ore pass wall. The results of the numerical analysis indicated that the presence of foliation resulted in greater damage zones in the surrounding rock mass. In addition, the extent of impact-induced damage to the ore pass wall increased as the angle of interception between the ore pass wall and the rock mass foliations decreases. This is in agreement with qualitative field observations.

Jun 1, 2012

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936

By Masahiro Eguchi, Giuseppe Granata, Chiharu Tokoro, Hiroki Fukuda, Yuichiro Toba, Shungo Hobo

"Currently, large amounts of wastewater containing boron are discharged from industries like coal-fired power plants. Although coagulation-sedimentation is widely employed for their treatment, only a little consideration has been given to its mechanism. An additional problem is that the produced sludge has poor solid-liquid separation. This study is focusing on coagulation-sedimentation using magnesium, examining the mechanism and improving the solid-liquid separation. First, the co-precipitation with magnesium hydroxide was conducted against high-concentration boron wastewater with 500 mg/dm3as B. Second, in order to improve the solid-liquid separation by maintaining high reactivity, low-crystalline magnesium oxide was synthesized from magnesium carbonate by calcination at 400–700°C. It was tested as an adsorbent of boron and compared to co-precipitation with magnesium hydroxide. Co-precipitation showed high removal capacity. X-ray diffraction (XRD) of the sludge revealed the presence of other compounds besides magnesium hydroxide. This result suggests that other processes play a role other than simple adsorption on to magnesium hydroxide, and provides a plausible explanation for the observed high separability. As for the adsorption, the synthesized magnesium oxide immobilized as much or more amount of boron than co-precipitation. Furthermore, the results of fourier transform infrared spectroscopy (FT-IR) suggested the residual magnesium carbonate improved solid-liquid separability due to its poor solubility.INTRODUCTIONBoron is used in various industrial applications. In glass industry, the addition of a little amount of boron into glass products can enhance heat-resistance and chemical-resistance. Semi-conductor industry also employs boron as dopant for silicon. From these industries, large amounts of wastewater containing boron have been discharged. Additionally, coal-fired power plants have been recently discharging highly concentrated boron wastewater because the amount of boron contained in coal has been increasing due to a gradual decrease of the quality of coal. Since boron is partially proved to be toxic for animals, plants, and human beings (WHO, 1998),the guideline of the World Health Organization limit the boron concentration in drinking water to 2.4 mg/dm3(WHO, 2009).Because boron does not precipitate from solutions by simply changing the pH, the removal could be carried by operations such as adsorption or ion exchange. However, since ion exchange is an expensive operation with relatively low capacity, it is not suitable to treat the large amounts of wastewater produced by heavy industries like the coal-fired power plants. Therefore, coagulation-sedimentation method is still widely used as a suitable alternative way."

Jan 1, 2017

By J. -F. Blais, M. -O. Simonnot, J. Mocellin, G. Mercier, J. -L. Morel

Large quantities of ferromanganese sludge are generated as waste material by blast furnace during the manufacturing of ferromanganese. These slags are very rich in manganese, zinc and lead (5 to 40 %). These residues have been deposited in a pond in periphery of the steel industry. Considering the market value of the metals, these brownfield sites can now be considered as secondary resources. We have developed a hydrometallurgical process for selectively leaching Zn, Mn and Pb in order to produce compounds of Mn and Zn pure enough to be economically recoverable and a residue rich in Pb. Batch laboratory experiments were carried out to determine appropriate leaching conditions to maximize zinc extraction (100 %) and manganese extraction (90.0 %) with sulfuric acid and to generate a residue containing 15 to 30% of lead. This Pb residue is recyclable by another process.

Jan 1, 2015

By J. W. Rogers, S. K. Schwartz

"The Cape Breton Development Corporation (CBDC) is a federal Crown corporation which operates two coal mines (Phalen and Prince Collieries), a coal preparation plant, a railway, a central workshop and a deep water shipping facility.The Sydney coal field consists of 11 major seams, which range from 0.8 m to over 3.7 m in thickness. Of the 2.4 billion tonnes of known coal resources in the field, approximately 550 million tonnes can be mined with present mining technology. These parameters define reserves which extend more than 8 km beneath the ocean to a depth of 1200 m. With today’s design and present high production faces, the colliery life is projected at approximately 20 years."

Jan 1, 1996