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By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By L. Li

ABSTRACT Stope backfilling is a common operation in many underground mines, which requires a barricade at the base of the stope near the drift entrance to retain the backfill in place. In this paper, the distribution of pore-water pressure in barricades made of waste rock is analyzed. An analytical solution is introduced and applied to estimate the pore-water pressure along the base and full height of the barricade. Results show that the analytical solution generally accurately predicts the distribution of pore-water pressure obtained from the numerical calculations, especially in the upstream part of the barricade, where it is most critical.

Jan 1, 2013

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge's Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge's Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

By John D. Smith, Robert J. Mitchell

"There is a world-wide trend toward underground bulk mining methods employing hydraulically placed backfill. This trend is recent and therefore there is little in the literature to assist an operator in the design of backfill properties, the design of drainage facilities, the calculation of the operating forces on a bulkhead, and the control procedures considered necessary before, during and after pouring. This paper presents recommended procedures that are based on over to years of experience in the various aspects of backfilling large openings. Free-draining timber or concrete block bulkheads are shown to be a viable alternative to massive reinforced concrete bulkheads for the containment of backfill pours. Hydrostatic pressures cannot develop in backfills provided adquate drainage facilities are installed.IntroductionThe increasingly adverse relationship between mining costs and mineral values has led mining companies to develop more productive, lower-cost, bulk mining methods. This has led to the increasing use of large, more or less continuous, hydraulically placed backfill pours to enable the recovery of a higher proportion of pillar ore. The success of any bulk mining method depends on the degree of stability maintained during the stoping operations with reference to the mining rate, the performance of the backfill with respect to the per cent extraction of pillar ore, and the control of the mine structure with respect to safety and productivity. One such method has been previously described(I) where a steeply dipping orebody is being mined with a sub-level method that employs large, hydraulically placed tailings pours for delayed pillar recovery. The paper describes the rock mechanics analysis undertaken to establish the stope and pillar geometry and the approach taken to establish backfill strength requirements to prevent dilution during pillar recovery. Production with this method started in 1970 and because few, if any, large bulk pours had previously been used in- this way (judging by the lack of information in the literature), design data and criteria were needed for several aspects of the work. Methods to establish backfill quantities and pertinent ""in-place"" fill properties are described in 2, 3 and 4 in the list of references. Results of field measurements taken to establish fill pressures for bulkhead design purposes are described in 5 and 6. Laboratory large-scale model tests undertaken to confirm a fill strength design equation, which takes into account fill arching, have recently been completed. A paper describing these tests and the results will be forthcoming in the near future."

Jan 1, 1982

By M. C. Bétournay

? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough ? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough Disadvantages ? High cost and long time for equipment development ? Hard rock mining condition limitations ? Size of equipment ? Equipment set-up time, down time ? Performance does not meet financial return targets ? Ground control issues ? Drill and blast retains overall advantage

Feb 1, 2008

By P. C. Thurston, T. Setterfield, D. H. Watkinson

"The Maybrun copper deposit IS In a succession of pillowed basaltic flows in the Wabigoon sub-province, northwestern Ontario. The rocks have primary flow morphologies and remarkably well-preserved crystallization textures, including quench-textured plagioclase, in spite of metamorphism to the amphibolite facies. The sulphide assemblage chalcopyrite-pyrrhotite-cubanite with minor sphalerite and pyrite is primarily in interpillow spaces and is stratabound. Basaltic rocks immediately enclosing the copper sulphide minerals have an enrichment in Fe, Mg and K and depletion in Ca and Na relative to surrounding flows. The Maybrun deposit is interpreted to have formed contemporaneously with volcanism and alteration, and was subsequently metamorphosed with the enclosing basalts.IntroductionThe association o f significant base metal accumulations with mafic submarine flows in the Archean is as yet poorly documented. Such deposits, where noted, have typically been small, and are therefore commonly over looked. The Maybrun Mine, a 2.6 x 106-tonne copper deposit in pillowed basalt, has many similarities with large, well-documented volcanogenic deposits. Given the interpretation of the Maybrun Mine to be volcanogenic in origin, there is n o reason why similar processes could not produce large deposit s. This is an important realization in an area where Archean submarine mafic rock s are very common, but frequently are examined only superficially. As gold commonly occurs in deposits such as Maybrun, even modest-sized deposits may be economic. The basalts at Maybrun are remarkable for amphibolite-facies rocks because of their extremely well-preserved delicate volcanic textures, including quench textures.The Maybrun Mine is one kilometre south of Atikwa Lake, in the Wabigoon sub-province of the Superior structural province, 75 km southeast of Kenora, northwestern Ontario, at longitude 93°35'W, latitude 49°25'N (Davies, 1973). Archean metavolcanic and metasedimentary rocks and intrusions underlie the area. Goodwin (1970) concluded that the mafic and minor felsic metavolcanic rocks, as well as the overlying metasedimentary rock s, were an eastward extension of the lower cycle of the Keewatin type section for the Lake of the Woods area. He estimated that the stratigraphic thickness of Keewatin rock s in this area is about 6900 m, of which 87% is basalt. The flows contain numerous interlayered sills, predominantly of basaltic composition; they have been extensively folded, faulted, metamorphosed to amphibolite facies and intruded by numerous felsic bodies, most importantly the Atikwa Batholith."

Jan 1, 1983

By William C. Martin

"Consolidated Sudbury Basin Mines Limited owns two mines, 4 miles apart, near the southwest end of Sudbury Basin. The Errington mine lies close to the north boundary of Creighton Township and about 18 miles by car from Sudbury. The Vermilion Lake mine is in Fairbank Township, on the south side of Vermilion Lake.The first discovery of base-metal mineralization within Sudbury basin was made by James Stobie in 1897 at Stobie Falls on the Vermilion River, half a mile west of the Errington mine. A few years later Alphonse Oilier made a discovery of massive pyrite with base-metal sulphides near the west end of the present Errington workings.No work of consequence was done on these discoveries until 1924, when Joseph Errington acquired options on a large acreage of ground which was later taken over by the Treadwell Yukon Company Limited. After considerable diamond drilling this company sank No. 1 shaft in 1926. In the next three years, a large amount of underground development was done, a pilot mill was constructed and operated for two years. All operations ceased in 1931 with the fall in metal prices. While in operation the pilot mill treated 186,172 tons of ore the average grade of which was 1·07 per cent copper; 1 10 per cent lead; 4·60 per cent zinc; 0·03 ounces gold; and 1 70 ounces silver.Up to the time of closing in 193 l there had been completed at the mine 26, 790 feet of lateral work and 75,500 feet of surface and underground diamond drilling. The company records, however, showed no figures on ore reserves, except broken ore in stopes amounting to about 60,000 tons. A study of the plans, prior to reopening the mine in 1952, showed 1,450 lineal feet of ore (at 1952 prices) opened up by drifting on the 300-foot and 500- foot levels. It is clear that no comprehensive picture of the structure was had at this time. The orebodies were considered to be very irregular pods scattered through masses of quartzite-carbonate in a sheared zone about 800 feet wide. In some way the ore was believed to be related to the tuff-slate contact zone. With this picture it was impossible to make a reasonable ore estimate or even gauge the tonnage potentialities with any feeling of reliability."

Jan 1, 1949

When underground extractions occur beneath or in close proximity to valleys and other forms of irregular surface topographic features, the observed vertical subsidence at the base of the valley is less than that would be expected in flat terrain, while the valley sides are observed to move inwards towards the centre of the valley. The reduction in subsidence at the bottom of the valley is referred to as upsidence and the convergence of two sides of the valley is termed valley closure. Research coupled with mining experience over the past few decades in Australia has identified valley closure subsidence as being very real and quite significant part of non-conventional subsidence effects, which always have adverse effects on natural features, with risks to water flow and aquatic ecosystems. In this paper, we describe a threedimensional numerical modelling approach to investigate the geomechanical mechanisms which cause the valley closure subsidence behaviour, using distinct element computer package 3DEC. The calibrated models can accurately predict subsidence and horizontal displacements, and they are subsequently extended to specifically study the effect of a series of mining geological and topographical factors on valley closure subsidence phenomenon, by developing a range of hypothetical scenarios. Previous analyses carried out using a two-dimensional numerical modelling technique have identified the potential parameters that affect the valley closure subsidence, which mainly include longwall position, horizontal stresses, valley sloping angle, and valley shape. Further three-dimensional analyses regarding the relationships between the major factors and valley closure subsidence are discussed in this paper. The results have significant implications with regard to both the underlying mechanisms that lead to this nonconventional subsidence behaviour, and how these should be incorporated in future valley closure subsidence prediction and mitigation of its impacts on natural features.

Jan 1, 2015

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GrG) test procedure at McGill university is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill university has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GrG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill university. as a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GrG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GrG tests were carried out at McGill universityon ores from all over the world. recently, a modi?ed version of the GrG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GrG in a sample; this simpli?ed test has theadvantage of reduced mass, processing time and cost. to recognize and honour the contributions madeby the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GrG test be named after Laplante.

Jan 1, 2010

By J. W. Merks

"Simulation is the process of designing a computerized model, of a system or procedure, for the purpose of understanding its behaviour and developing strategies to control its operation. Simulation models are rapidly becoming an effective tool for mineral processing plants. Powerful software and fast hardware are more readily available than a basic understanding of the theory of mathematical probability and applied statistics that process simulation models demand.Simple spreadsheet software can be used to develop simulation models that take into account any set of conditions at a mineral processing plant. In addition to an unbiased estimate for each variable in the set on which two-and three-product formulas are based, reliable variance estimates for all variables are required. How to estimate variances, effectively and at the lowest possible cost, and how to compute variances for simple functions such as the metal content of a quantity of ore or concentrate, or more complex functions such as the percentage recovery at a mineral processing plant, are the key to useful simulation models.IntroductionSimulation models for systems and procedures have become one of the most powerful and effective applications for computers( 2.6). Simulations are applied to a wide range of scientific and engineering disciplines. Generally, a model is designed to investigate the effects of changes in and interactions between a set of variables before a system is in operation or a procedure is implemented, by simulating weeks, months, and even years of operation, in a few minutes of computer time. Along with practical and useful applications always comeabuse and misuse. For a simulation process cannot be more reliable than the methodology that was applied to design the model, to estimate variables and variances, to check performance, and to verify validity. A mineral processing plant is a dynamic system that changes continuously as a function of time but within probabilistic constraints that can be estimated by applying statistical tools and techniques to the variables and variances that interact in the system.A model should be designed to simulate not only the set of variables but also the variance for each variable. Models in which constant variances are used to generate normally distributed random numbers, are less realistic than models in which the variances are simulated first, and then used to simulate the variables."

Jan 1, 1991

By J. Kalynchuk, R. Poulin, R. Pakalnis, D. Peterson

"A market survey of all underground mines in Canada (Fig. 1) was completed to determine the ex1ent to which cable bolts are being used as ground support. One hundred and nine questionnaires were distributed with 65% of them being returned completed. As a result, the quantity, types and locations of cable bolt installations have been determined. In addition, the grout pumps used, time required and cost of installations have been addressed. The popularity of other support types used in underground mines is summarized.IntroductionRock reinforcement consists of installing support within the rock mass (internal) or within the excavation (external). Within the past twenty-five years several new types of ground support have been introduced within the mining industry. Cable bolts were first introduced to the Canadian mining industry in the 19605 (Gramoli, 1975).Cable bolts have gained increased acceptance as a method of ground support during the past decade. The cable bolt is comprised of one central wire surrounded by six slightly smaller outside wires and typically having an over-all diameter of 15.2 nun to 15.9 nun (0.6 in. to 0.625 in.). The cable wires are made from high-strength steel with an ultimate strength of 26 tonnes (58 000 Ibs) (Goris, 1990). Current cable bolting practice consists of cement grouting one or more steel cables within a drill hole in order to reinforce the surrounding rock mass. Cable bolts are a form of internal support and are generally used in open stoping and cut-and-fill mining methods (Fig. 2).They can be either tensioned (active support) or untensioned (passive support) and may be of any length, though for underground mining applications, they are generally less than 20 m (65.5 ft) and are untensioned. A major advantage compared to previously used ground support is that the cables are flexible and can be coiled to approximately 1 m (3.3 ft) diameter coils allowing relatively long support to be installed in areas with limited head room (1.8 m).With the advent of bulk mining methods which require comparatively large stopes, it has necessitated the use of relatively long support tendons to stabilize the large spans being created. As a result, the use of cable bolts for ground support in mines has increased significantly within the past decade."

Jan 1, 1995

By Beatrice Pierre, Juan Carrasco

Altonorte began as a concentrate roasting operation in 1988 under the name of Refimet. In 1993, a copper smelter was built with a design capacity of 203,000 tonnes per annum of concentrate. Since 2001, many technological advances have been made in Altonorte, where the biggest Noranda Reactor in the world is installed being the first Noranda Reactor reaching above one million tonnes of copper concentrates processed per annum. In 2013, Altonorte was acquired by Glencore. Recently due to various new environmental regulations in Chile, Altonorte has evolved to new standards of operation in order to reach the vision of becoming a World Class Smelter. This paper describes the path followed to improve safety, environmental performance, process capacity, reliability, and productivity. The foundation for the growth and success in Altonorte is our People. Employee engagement and branding of our cultural journey is what allows Altonorte to face the future with the certainty of becoming a World Class Smelter. INTRODUCTION Altonorte is located in Antofagasta, the mining capital in the north of Chile and is the last smelter built in Chile practically completed with second hand equipment. The biggest technological change in Altonorte occurred during the phase 3 expansion in 2003, where the old Reverberatory furnace was shut down and replaced by the biggest Noranda Reactor installed in the world. The vessel measures 5.3 m × 26m. ºAdditionally, this project contemplated a new rotary dryer, three (3) new Peirce Smith converters, new anode furnaces and a new Acid plant. The nominal capacity was to treat 816.000 tons of new concentrate per year. In 2008, a new expansion phase was implemented where a new double absorption acid plant replaced the oldest acid plant. Bottlenecks such as blowing capacity and oxygen availability were solved installing a new air blower and a new contract was negotiated with our oxygen supplier to increase oxygen availability up to 683 tpd. This improvement defined the current nominal capacity of 1.100.000 ton of new concentrate per year. Current process description All concentrates are received by trucks directly from domestic mines or from the Antofagasta international port in cases of imported concentrates; the concentrate warehouse has a capacity of 25 kt where the blend is prepared to feed the smelter.

Jan 1, 2019

By G. E. Agar

"The distribution of gold in the grinding-classification circuit of an operating gold plant was determined by assaying the size fractions of samples from each of the streams. This analysis identified the streams with the maximum potential for gravity recovery of gold and revealed that there was up 110 seventy-five times as much gold in the primary cyclone underflow as in the concentrator feed.Laboratory jigging and tabling tests were done on samples from two of the streams to determine what the recovery might be with a gravity circuit and to show that a high grade concentrate could be produced. A numerical simulation procedure was used to calculate a material balance for a circuit that included gravity separation on the primary cyclone underflow. The numerical simulation optimistically indicated that as much as 84% of the gold might be recovered in a reasonable grade of concentrate even though the recovery in batch bench scale tests was only 14%.Incorporation of a gravity separation device would reduce the inventory of gold in the grinding-classification circuit.INTRODUCTIONMany gold concentrating plants include a gravity concentration operation while others do not and the reasons that some do and some do not is not clear. Some of the advantages and disadvantages of gravity circuits are discussed by Penman (Penman 1987) without clear cut resolution. Penman's comments elicited an interesting response from Lloyd (1989) who produced a simple way to determine if the addition of a gravity concentration circuit would enhance the recovery of gold. Lloyd's method does not consider the cost of running the circuit so it only partially answers the question. There are reports in the literature (Wells and Patel 1991, Matwijenko 1988) that as much as 60% of the entire production comes from a gravity circuit when it is used, and that the grade of the concentrate produced often exceeds 65% gold, an assay that far exceeds most Merrill-Crowe precipitates that are sent to refining. In at least one instance (Hood 1984) a range of recovery from 40-50% was indicated from laboratory test work and the plant subsequently realized recoveries in the range of 26-40%. Despite these favorable numbers other plants use gravity separation when as little as 20% of the gold is recovered in the gravity concentrate (Carter 1992)."

Jan 1, 1993

By A. Dreimans

Tracing of 'float' against the latest ice-flow directions ha!' led to or assisted in discoveries of several mineral deposits in Canada at lP.ast since 1891, e.g., fluorite and corundum in eastern ?Ontario, Steeprock and Josephine iron ore in western Ontario, Malartic, Fisher-Quebec, and Lamaque gold ore, and Vendome zinc ore, in western Quebec, Sullivan zinc and lead sulphides in British Columbia, Orvan Brook or New Calumet sulphide deposit in New Brunswick, Lynn Lake nickel sulphide de-posit in Manitoba, etc. Pebbles or ore boulders whose source has not yet been found include diamonds in the Great Lakes region and ?sulphides in several localities in Ontario and Quebec. Complexity of transport of ore boulders, including non-glacial transport, may be the explanation. Tracing of ore boulders requires knowledge of the Pleistocene history of each particular area (ice flow directions, their ?changes during glacial oscillations, existence of pre-glacial lakes with ice-rafted boulders, later interference by streams, lakes, mass movements). Important also is distinction of till from similar non-glacial deposits and knowledge of the bed-rock geology. Quantitative methods, e.g., pebble counts, maybe applied while tracing magnetite, hematite, or goethite. Fragments of sulphide ores are less abundant in indicator trains, and quantitative methods are less suit-able for tracing them. Heavy-miner-al investigations may give good results for minerals resistant to weathering. Geochemical methods are of value only in the vicinity of ore deposits.

Jan 1, 1958

By F. W. Tregarthen

"This paper gives a brief description of the methods used to form and implement the present planned maintenance program. The system is designed to assist plant personnel in their task of controlling a large work-force and maintaining the many and varied types of equipment used in a mining and concentrator operation. The types of reports and methods used in scheduling and work-loading are described. General built-in flexibility is derived from computer assistance to the Central Planning Group."

Jan 1, 1971

By Z. D. Hora

The major fluorite producer in British Columbia was the Rock Candy Mine, inactive since 1942. Other deposits of economic interest include the Rexspar deposit, in which fluorite is associated with uranium and rare earth mineralization, and the Eaglet and Liard River occurrences. THE former Rock Candy fluorite mine, located 26 km north of Grand Forks, is the only major past producer of fluorite in British Columbia. The deposit was in production from 1918 to 1929 and again in 1942; total output was about 36,000 tonnes with average grade between 22 and 32 per cent CaF2. The fluorite body occupies a steeply-dipping vein structure, approximately 175 m long and up to 12 m wide, in porphyritic syenite. The chief vein-filling minerals are quartz and fluorite with local small len ses of barite. Fluorite content decreases with depth and the deposit becomes silicified. The Rexspar (or Birch Island) fluorite deposit is located 130 km north of Kamloops. The deposit is complex with rare earth elements and high uranium values, but !1uorite mineralization forms an independent zone adjacent to the uranium orebodies. Fluorite is present as fine-grained impregnations and as breccia cement in strongly schistose or brecciated alkali feld spar porphyry. Reported reserves are 1,088,000 tonnes of 22 per cent CaF2 or 450,000 tonnes of 29 per cent CaF2. 268 Another potential deposit of fluorite is Eaglet, situated on the north side of Quesnel Lake. Fluorite occurs as a stock work with scattered veins and irregular lenses up to 20 centimetres wide and as impregnations in altered Proterozoic Kaza Group feld spathic gneiss over an area of 1,500 metres by 500 metres. To date (1983) approximately $2 million have been spent on the exploration of this property and reserves of 18.8 mimon tonnes grading 11.59 per cent CaF2 have been outlined . A group of significant occurrences is known from north of Liard River Hot Springs Park , where fluorite occurs in small zones up to 17 m thick along the interface between Middle Devonian Dunedin Formation limestone and Middle Devonian to Mississippian Besa River Formation argillite. Fluorite, associated with witherite, barytocalcite and barite, is present as replacement bodies, breccia fillings and minor veins.

Jan 1, 1984

The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By Paul Guliov

Industrial clays, including a variety of bentonites and kaolinbased clays in southern Saskatchewan are hosted by Late Cretaceous and Early Tertiary sediments. Ofparticular significance are the deposits of swelling bentonite in the Cretaceous Bearpaw Formation and the kaolinitic clays of the Cretaceous Whitemud and Paleocene Ravenscrag Formations. Swelling bentonite is currently produced in the Wilcox-Truax area by Canadian Clay Products Inc. and yields at least seven different commercial products for a variety of applications. Kaolinitic plastic clays, including ball clay, stoneware and earthenware clay, as well as kaolin in southern Saskatchewan, have a long history of development and use. Products include common and face brick, refractory bricks and other shapes, chinaware, pottery, sewer pipe, chimney flue linings and tiles. Currently clay production is for out-of-province brick manufacturing and for pottery. Recent research and improved technology combined with expansion in certain areas of the global clay industry generally hold promise for a resurgence of a clay-based industry in Saskatchewan. Products of particular promise include: clay tiles; kaolin fillers and extenders; and aluminum as well as related by-products from kaolinitic clays based on the carbochlorination process.

Jan 1, 2001