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By 000-900-009-492

The flotation has been and is still the most widely used mineral concentration method. Because of its complexity, the flotation process required the development of robust control strategies which was facilitated by the introduction of on-line sensing instruments such as x-ray fluorescence (XRF) on stream analyzer (OSA), gamma density gauges and electromagnetic flowmeters. The interest in developing control strategies has persisted because the benefits to be gained in terms of improved metallurgical performance are substantial. As the flotation control becomes more and more difficult due to the emergence of low grade and complex ore cases, other control strategies have to be introduced. Froth based control is one of the emerging useful control strategy This paper will focus on the state of the art in the on-line froth characterization as obtained by numerical image analysis. The technology of machine vision provides a novel solution to several of the problems encountered in conventional flotation systems for monitoring and control, and constitutes a powerful tool for the investigation and interpretation of the effect of various flotation parameters as driven for the froth phases. Copyright @2001CIM

May 1, 2001

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By David Scott, Denis V. Lachance, Daniel Marcotie

"LocationThe Heath Steele mine is located 50 km northwest of Miramichi, New Brunswick.Brief DescriptionHeath Steele is a 2700 t/d, copper-lead-zinc operation which employs conventional crushing, grinding, and differential flotation.HistoryThe Heath Steele mine is located in northeastern New Brunswick approximately 50 km northwest of the city of Miramichi and 65 km southwest of Bathurst. The massive sulphides containing ore values in zinc, lead, copper and silver were discovered in 1953 as a result of a joint venture between the American Metal Company and the International Nickel Company of Canada. The discovery was named after Mr. Heath Steele, manager of exploration for Amco at the time of the discovery.Mill production began in February 1957; however, the mine was forced to shutdown in 1958 due to depressed metal prices and metallurgical problems. It was re-opened in 1962 and milling operations resumed at 725 t/d until 1968 when the milling capacity was boosted to 1450 t/d and then to 2700 t/d in 1969.OreThe main ore zones are massive sulphides with very fine mineral grain. The chalcopyrite, galena and marmatitesphalerite occurrences are finely disseminated.Liberation is accomplished by grinding to 68% to 72% <400 mesh. Average mill feed assays are 0.8% to 1.2% copper, 1.8% to 2.5% lead, and 5.5% to 6.5% zinc, with 60 to 75 g/t silver."

Jan 1, 2000

By J. W. Kramers, R. A. S. Brown

"Samples from seven test wells distributed throughout the surface-mineable area of the Athabasca Oil Sands have been evaluated to determine the amounts of heavy minerals present and the titanium and zirconium contents. The samples were treated to yield the size distribution of the titanium and zirconium minerals as well as their spatial distribution. The study has shown that heavy minerals are found throughout the surface-mineable area; concentrations range from 0.24 to 2.29 per cent (by weight), with a mean of 1.02 per cent. Titanium and zirconium contents vary throughout the area, and are found preferentially in the finer size fractions. •on the basis of preliminary calculations, the tailings streams from an oil sands plant would provide sufficient feed for a large-scale titanium pigment plant, and the tailings from one plant would provide sufficient zircon feed to satisfy Canadian demand for. metallic zirconium. Variability of the heavy mineral content and composition is such that the heavy mineral potential must be evaluated in detail for each mine site."

Jan 1, 1976

By Norman A. M Macleod

FOR the past seven years, all flotation at the Britannia mill has been done in Forrester Air-Lift cells. Prior to 1931, the roughing and part of the cleaning operation had been performed in four 21-cell and two 14-cell M.S. machines. The resulting economies in reagent, power, maintenance, and general operating costs, and the increased recovery, more than justified the exclusive use of the Forrester machine. About three years ago, the possibility of still further improving the efficiency of the flotation section was the subject of considerable discussion and experiment. Arising from these experiments, tests were made of the practicability of using a cell of greater depth than that of any pneumatic or mechanically-agitated machine in common use. Cells were constructed with depths of 7 .5 feet, 10 feet, and 15 feet, and, in all cases, a very definite improvement in operation was indicated. The cell now being used in the mill treats from 5,500 to 6,200 tons of dry feed per day. It is 100 ft. long by 5 ft. wide by 8 ft. deep, and has replaced a total length of over 500 feet of standard Forrester machine. The choice of a depth of 8 feet was governed by the type of blower which was available-in this case, a Roots-Connersville blower, driven by a synchronous motor and delivering 6,000 c.f.m. of free air at 4.0 pounds per square inch. At the Chelan Division of the Howe Sound Company, where a new mill was recently built, all flotation is carried on in cells 10 feet deep, with good results.

Jan 1, 1938

By Brian W. Mackenzie

The paper addresses five questions concerning the economic of gold exploration in the western Canadian shield. Can historical footprints be used to project future gold prices for exploration planning? Experience suggests that gold price forecast are too clo ely tied to current market events to provide meaningful guidelines. What range of breakeven gold price will typically be required to ju tify gold exploration in Canada? Minimum price requirements. initially asses ed at $540 to $1080 per ounce, probably lie in the range of $480 to $760 per ounce (expressed in 1985 Canadian dollar). Within Canada, what role do regional conditions and taxation policies play in determining the viability of prospective gold exploration targets? Striking interprovincial differences are found to exist, given the same geological circum tance -Nova Scotia, ew Brunswick, and Quebec rank towards the top in term of motivating exploration, Briti h Columbia provides the least investment incentive, while Saskatchewan and Manitoba place around the middle of the Canadian league. How can minimum acceptable tonnage-grade conditions for gold targets in the western shield be established and, then, constructively applied to provide exploration planning guidelines? Minimum target conditions, realis tically defined in terms of a broad band of doubt, can be used judiciously to help balance the direct costs of uneconomic exploration with the opportunity costs associated with rejecting economic deposits. How does the average cost per ounce of gold discovered in the western shield compare with the overall Canadian experience? Average discovery costs for the we tern shield, apprai ed at $100 per ounce, are shown to compare favourably with the Canada-wide record.

Jan 1, 1986

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na&apos;) properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

"6.1. Mineralogical Techniques ApplicableTo the Platinum-Group Elements6.1.1. IntroductionThe named platinum-group minerals (PGM) usually occur as grains smaller than about 200 microns and, even when present as larger grains as in nuggets, these are often complex multimineral intergrowths. Therefore, the PGM must be examined by microscopic techniques and, because all named PGM are opaque, they are suitable for microscopic study by reflected light. Special techniques for concentrating PGM and preparing suitable polished sections are detailed in Chapter 5. Another characteristic of the PGM is that the majority have very high reflectance at 589 nm, i.e., over 450Jo, but they range from about 38 to 74%. In contrast, micro-indentation hardness has a wider range from - 60 to - 3,000 kg I mm, and the PGM range from brittle to malleable.The small grain-size of PGM imposes certain limitations, or complications, on the usual mineralogical determinative methods of reflectance, micro-indentation hardness and X-ray diffraction. In addition, certain combinations of elements in some PGM render electron-probe analyses difficult. The usefulness and shortcoming of these methods, as applied specifically to the PGM, are discussed in the following sections. These are not, however, meant to be exhaustive descriptions of the techniques, which are fully described in other texts.6.1.2. Micro-Indentation HardnessDetermination of the Vickers Hardness Number (VHN) is discussed in detail in recent publications, such as Bowie and Simpson (1977) and Craig and Vaughan (1981). In addition, the recommendations of the Commission on Ore Microscopy (COM) of the International Mineralogical Association (IMA) are given by Criddle (1980). The usual small grain-size of the PGM, however, precludes the widespread use of this technique and very few PGM have, in fact, had their VHN determined at the COM-recommended standard load of 100 gf (cf. Cabri, 1981b, in Chapter 7). Examination of VHN data reported in the literature reveals that the few PGM whose microindentation hardness has been measured have incomplete VHN data, measured with loads other than 100 gf (Chapter 7). The small grain-size may also result in unreliable VHN data because, even though the correct load may have been applied, a thin grain will give erroneous data due to the matrix, or the grain may even shatter or pop out of the section. On the other hand, micro-indentations may give useful qualitative diagnostic clues. Moncheite, for example, shows fractures near the indentation (Chapter 7, Plate 1). In other cases, intergrown PGM produce different-sized indentations: e.g., froodite-michenerite-gold in Cabri (1972); isoferroplatinumtulameenite in Cabri et al. (1973); michenerite-moncheite in Cabri and Laflamme (1976) and Chapter 7, Plate 1; altaitemichenerite- testibiopalladite in Hudson eta/. (1978) and Plate 1, Chapter 7."

Jan 1, 1979

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By Paul W. Billwiller

Introduction In 1937, the Britannia Mining and Smelting Company, Limited, was carrying on an extensive exploratory diamond-drilling programme. Most of this drilling was done on the 4100 level, the lowest working level in the mine. One of the exploratory diamond-drill holes, at approximately 12,500 feet from the portal of the tunnel, encountered heavily mineralized stringers of chalcopyrite and sphalerite in silicified grey schist. The mineralization was encountered just to the hanging-wall of the green mottled schist at a point 350 feet south of the 4100 tunnel. To delimit this new orebody, drifts and cross-cuts were driven on 3500, 3800, and 4100 levels to the hanging-wall in the area of the projected mineralization. On the 3500 level, the top of the mineralized zone was encountered. The zone was thoroughly explored by drifting and diamond drilling. The mineralization, however, was not sufficiently concentrated to be of commercial grade. On the 3800 level, the zone was found to consist of disconnected stringers of chalcopyrite and pyrite. Drifting was continued to the west and a long lens-shaped area of grey schist containing fairly heavy stringers of chalcopyrite was delimited. This lens later proved to be very close to the top of the commercial mineralization of the No. 8 orebody. On the 4100 level, a diagonal cross-cut was driven to the footwall of the downward projection of the mineralized zone. Diamond-drill holes from this cross-cut indicated a zone of heavy mineralization. A drift was driven off the cross-cut parallel to the zone and some distance to the footwall of it. Further diamond drilling disclosed a mineralized zone approximately 300 feet long and 35 feet wide containing sphalerite, chalcopyrite, and pyrite. The foregoing development work indicated a fairly large lens of mineralization of sufficient concentration to be classed as ore between the 4100 and 3800 levels. To explore this mineralization at depth, long diamond drill holes, dipping at minus 57° and minus 80°, were planned from some point to the hanging-wall of the orebody. The 4100 level was not suitable for small development headings, due to wider gauge track and larger cars than on the levels above. Therefore, a raise was driven from the diagonal cross-cut on the 4100 level to a point some 70 feet above and just inside the footwall of the orebody. From the top of the raise, drifts were expanded east and west to delimit the ore zone. In addition, a long cross-cut was driven 350 feet to the hanging-wall, and drifts were opened east and west from the end of the cross-cut to provide diamond-drill stations for the exploration of the orebody at depth.

Jan 1, 1946

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By M. H. Pelley

To increase drill fleet capacity and meet increased ore demands at its Carol Lake Project, the Iron Ore Company of Canada initiated a program in 1975 to convert the Gardner-Denver 120 and Bucyrus-Erie 60-R rotary drill fleet from 12 1/4-inch-diameter multi-pass drilling to 15-inch-diameter single-pass drilling. This paper will examine briefly the conversion program , including some tests and results, and examine how the utilization of the 15-inch-diameter blast-holes, coordinated by a comprehensive drilling and blasting program, has improved the drilling, blasting and drilling-plus-blasting aspects of the mine operations, from both economic and operational viewpoints.

Jan 1, 1978

By Edgar Stanfield

Since April, 1923, the Scientific & Industrial Research Council of Alberta has had an analyst, Mr. W. P. Campbell, steadily employed analyzing coal samples taken by the provincial Mine Inspectors. Mr. Campbell has also analyzed a number of coal samples taken by one of the Council&apos;s Geological Survey parties. We have thus, at the time of writing, over four hundred analyses of Alberta coal, made by the same analyst, and strictly comparable. These samples come from widely distributed points, some 88 townships being represented. The stream of samples is still flowing in, and it is hoped by the end of this year that the number of townships represented will be increased at least fifty percent. The time has arrived to publish some of the data collected; but it must be clearly understood that this is merely a progress report, subject to revision as further information is obtained. Three hundred and fifty-three coal mines in the province were operated during 1923. The production per mine varied from 5 up to 500,000 tons. With this number of mines to examine (and fresh mines are being opened every year) it is a large task to make even a proximate analysis of representative samples from every mine. Any chemist will appreciate the fact that to make ultimate analyses representative of even the larger mines will be a long and tedious task. It has seemed better to make a comprehensive survey by proximate analysis and determination of calorific value before beginning the more thorough survey by ultimate analysis. This paper, therefore, deals only with proximate analyses and calorific values; and, owing to limitations of time and space, does not deal with other chemical and physical characteristics of coal, such as storage quality and fusibility of ash, important though these are.

Jan 1, 1925

By W. Holdsworth

The flotation mill of Dentonia Mines, Limited, at Greenwood, B.C., went into operation on April 20th, 1934, and by October 11th a total of 15,000 tons of ore had been treated. It is intended in this paper to describe briefly the operation and to give some of the operating data which have been gathered. The metallic minerals in the Dentonia ore are pyrite, chalcopyrite, galena, and, occasionally, native gold, and the gangue includes chloritic material, vein quartz, and calcite. Pyrite makes up about 90 per cent of the metallic content of the ore, in which it is disseminated as irregular grains and well-formed cubes. An average analysis of the ore is: gold, 0.27 oz. per ton; silver, 1.73 oz. per ton; copper, 0.12 per cent; lead, 0.31 per cent; and zinc, trace. From the mine ore-bin, situated near the portal of the tunnel at the mine, the ore is hauled by motor truck to the mill, a distance of three-quarters of a mile, and there dumped into the receiving bin, which has a capacity of fifty tons. The hauling is done during one eight-hour shift, commencing at 7 a.m. The maximum size of the ore fed to the mill-bin is ten inches. Lumps larger than this are broken by sledge hammer to pass through grizzly bars, spaced ten inches apart, installed above the bin. The ore is drawn from the bin by a 30-inch, 6-ply conveyor belt, 18 feet 6 inches long. In the near future, when the cross-cut tunnel is completed, the ore will be trammed to the receiving bin. This will effect a considerable saving in cost. At the same time, the bin will be set back several feet, so that the length of the conveyor belt may be doubled. This will make efficient ore-sorting possible, and so ensure a minimum of waste rock in the mill feed.

Jan 1, 1935

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (&apos;) that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By Thomas J. Ferree

"IntroductionThe objective of this chapter is to provide important criteria relating to the operation and maintenance of spiral concentrators and Reichert cones, so that optimum performance can be achieved and maintained in a mill circuit. Little space will be devoted to the theory of the forces of separation or the technical details of the devices, as that in(ormation is available from other sources. The discussions in this chapter will be presented in a manner that should be interesting and useful to anyone who may be exposed to these methods of gravity separation. It is most important for the reader to understand that each application of the equipment should be considered on its own merit, as no two suites of minerals respond exactly alike in mineral processing circuits. The information herein should be useful as a guide toward increasing the metallurgical efficiency of the processes, irrespective of the type of minerals being concentrated.It is highly recommended that certain tools be made available to the personnel responsible for metallurgical performance of the spirals and cones; these include a set of standard type laboratory screens, a medium quality petrographic microscope, and a vanning plaque or gold pan. These devices, when used in conjunction with a basic understanding of the mill circuit, provide immediate knowledge on the characteristics of any sample in the mill circuit. The information gained by visual evaluation of sized fractions of products can solve many of the basic problems of mineral beneficiation, and at the same time increase the interest of the non-technical personnel associated with the plant operation. There are many problems associated with obtaining satisfactory performance from a mill operation. Many of the problems have to be solved using a technical approach. Some of the problems, however, can be solved with practical knowledge and common sense. It is hoped this chapter can provide a guide to both techniques."

Jan 1, 1989

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By P. Karimi, A. Amini, H. Abdollahi, A. Mirzaeian

Due to detrimental effects of cyanidation process on the environment in gold industry, application of cyanide alternatives such as thiourea are being highly considered in recent projects. In this study, the extraction of gold from poly metal ore, using thiourea was precisely investigated. The representative sample contained 2.5 ppm Au and 160 ppm Ag. The sample was categorized as oxide gold ore, because the main part of its pyrite was changed to iron oxide and hydroxide such as goethite and lepidocrosite. According to mineralogy, the main gangue mineral was quartz. It shows that gold grains are free and interlocked with quartz matrix. Also, the presence of a high amount of silver in free and sulfide forms and also the low content of other sulfide minerals such as base metal sulfides is a remarkable point of these studies. In the gold extraction process with thiourea, there are several parameters that affect the rate of gold dissolution such as concentrations of thiourea as a gold lixiviant and ferric sulfate as an oxidant, pH and size fraction of feed and leaching time. The influence of these parameters on the gold dissolution rate were investigated and optimized. The results showed that the concentration of thiourea is the most influential parameter which could increase the gold recovery to 71% (at 10 g/kg sample). The optimal amount of ferric sulfate was determined as 6 g/kg sample. Also, the optimal levels of size fraction of feed and pH of solution were 88% under 75 micron and 2 as acidity; respectively. Leaching time was 6 hrs. In addition, this sample was leached with cyanide and the optimized values of size fraction of d88=75 microns, pH=10.45, 2500 ppm of sodium cyanide with time leaching of 24 hours were concluded for maximum recovery of gold in solution. Finally, the results of cyanidation tests were compared to the thiourea dissolution after optimizing all affected parameters in cyanidation process.

Jan 1, 2016

Accurate hematite solubility data are required to construct predictive solution chemistry models for complex hydrometallurgical solutions. These data are useful in understanding Fe(III) speciation and precipitation in a variety of hydrometallurgical processes. Hematite solubility data were generated in 10 to 70 g/L H2SO4 solutions and at temperatures from 130 to 270°C, using specially modified titanium autoclaves. These measurements represent an improvement over previous experimental data because of better in-situ filtration of the sample aliquots, the approach to equilibrium via hematite dissolution, and the inhibition of Fe(III) reduction on titanium surfaces. Fe(III) reduction was particularly studied to evaluate the inflationary effect of Fe(II) on hematite solubility measurements. Chromate was found to reliably inhibit Fe(III) reduction on titanium. Finally, the generated hematite solubility data were used to construct a solution chemistry model using the OLI software.

Jan 1, 2006