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By M. Vallée, J. -P. Charette, D. P. Gold

"The Oka Carbonatite and Alkaline Complex is a Lower Cretaceous intrusive body of the Monteregian petrographic province. Carbonate rocks of various types, and associated alkaline rocks of the ijolite and okaite suites, are distributed in a double ring-dyke structure 4 Yi miles long by 1 1/2 miles across. Alnoite and alrioite breccia pipes intrude all rocks of the Complex and indicate, from inclusions, that a cover of Palaeozoic rocks existed at the time of emplacement.The results of radiometric, magnetic and gravity surveys of the Complex are compiled and discussed both with respect to the regional pattern and, locally, the bed-rock geology. The Complex is characterized by high-intensity anomalies.Exploration activities started during 1953, and mining operations began in 1961 on the property of St. Lawrence Columbium and Metals Corporation, at one time the world's largest producer of niobium concentrates. Because of the boudinaged and fractured nature of many of the rocks and the variability in grade of the ore minerals, the role of the mining geologist is both demanding and exacting. Rock types are varied and their mutual relation-ships ambiguous, the minerals are rare and complex, and close geological control of the ore is needed in the mine and in the mill. Closely spaced diamond drill holes are needed for mining control, and the ore-waste contact is defined mainly by assay results.In the exploration for 'carbonatites' in Eastern Canada, aeromagnetic surveys are judged to be the best exploration tool, followed in decreasing order by the search for circular structures on aerial photographs, regional gravity surveys and radiometric surveys."

Jan 1, 1967

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By Karl J. C. Harries

"14.1. INTRODUCTION1The boilerplate of an agreement is not a single provision, but a series of provisions that are expected in “every agreement”. They are sometimes also referred to as the “lawyer’s provisions”. Many businessmen consider the boilerplate to be superfluous and, to some extent, window-dressing by the lawyers – even legalese. They will often offer advice to the effect that it can “pretty well be ignored”. Such advice could not be more wrong.Most boilerplate provisions are essential parts of every agreement. Some may be part of a “standard package” and may have little relevance to the agreement at hand, but these are the exception rather than the rule. The exceptions should not be treated as justification for giving all these provisions short shrift. The boilerplate should receive the same review, consideration, and negotiation as the provisions that set forth the business deal. It is often these provisions that make the deal work or that are turned to at the time of disputes. If they are inadequate, as they sometimes are (unfortunately, some draftsmen are also loath to review or update their standard boilerplate provisions or to tailor them to the deal at hand), they can create problems, rather than offer solutions. Such problems can be costly and time-consuming for the parties to address. Inadequate or incomplete provisions may ultimately be one of the reasons for the parties to turn to the courts to settle their differences. On the other hand, good boilerplate provisions can help keep them out of the courts.One of the principal objectives of an agreement should be to provide procedures, or mechanics, for implementing agreed principles and for the parties to follow to settle their differences, real or perceived, without going to the expense and disruption of a lawsuit. An agreement should aim to keep the parties away from the courts, not serve as a springboard to the courts. It must nevertheless be acknowledged that, if there is a major falling-out among the parties to an agreement, the chances are that, however carefully the provisions of that agreement have been negotiated and drafted, the parties will end up before the courts or some other adjudicating body."

Jan 1, 2003

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By J. Asfahani

"The inverse slope method (ISM) was applied to reinterpret vertical electrical soundings (VES) data from pits at the Al-Sharquieh phosphate mine, in order to demonstrate applicability and suitability of the ISM for interpreting VES data from sedimentary phosphatic environments. The ISM overcomes limitations of the curve matching method and the complexity of lithological sections. The ISM geo-electrical interpretation results correlated well with lithologies of the pits. This method characterized resistivity and thickness of the phosphatic layer, and identified favourable phosphate-prospecting areas using the newly developed thickness/depth parameter. The ISM is recommended for interpreting VES measurements in similar sedimentary phosphatic regions.RÉSUMÉ La méthode d’inversion de la pente (ISM) a été utilisée pour réinterpréter les données de sondages électriques verticaux (VES) effectués dans des puits de la mine de phosphate Al-Sharquieh, afin de démontrer l’applicabilité et la pertinence de cette méthode pour interpréter les données VES dans des environnements de sédimentation de phosphates. Cette méthode (ISM) surmonte les limitations de la méthode de comparaison de courbes et la complexité des sections lithologiques. Les résultats de l’interprétation géoélectrique ISM correspondaient bien aux lithologies des puits. Elle a permis de caractériser la résistivité et l’épaisseur de la couche phosphatique et d’identifier les secteurs favorables à la prospection pour le phosphate en utilisant le paramètre nouvellement développé épaisseur/profondeur. ISM est recommandée pour l’interprétation des mesures VES dans des régions semblables où se trouve du phosphate sédimentaire."

Jan 1, 2016

By K. Huang, L. Pan

"Darcy’s law has been used extensively to model cake filtration. It is a macroscopic model, in which particle size dominates the kinetics and cake moisture. In the present work, a capillary flow model has been developed from first principles to study the effects of microscopic parameters such as capillary radius, boundary layer slip, disjoining pressure, and surface tension that may be important for dewatering ultrafine particles. Laboratory-scale pressure filtration tests show that dewatering kinetics is strongly dependent on capillary radius, which in turn is influenced by surface hydrophobicity, surface charge, and length scales of particles. The model parameters determined from laboratory-scale filtration tests show that use of a hydrophobizing reagent can greatly improve fine particle filtration due to increased slip and decreased capillary pressure. The kinetics of dewatering kaolin clay is fastest at a pH where the layer-structured particles coagulate with a face-to-edge orientation. The capillary flow model developed in the present work may be useful for designing filters and optimizing operating conditions.INTRODUCTIONIn 2014, Canada produced 2.2 million barrels per day of crude oil from the oil sands resources in Alberta, which is expected to grow to 3.2–4.0 million barrels per day by 2030 (CAPP, 2013). One of the challenges to meeting these projections is the tailings management. At present, the industry uses ?77 km2 of the lands to construct tailings ponds. Significant amounts of the tailings disposed to the ponds are silts and clays that are slow to settle and consolidate, creating problems for reclamation. It is, therefore, the objective of the present work to develop a filtration model that may be useful for developing advanced dewatering technologies that can address the tailings management issues.Darcy’s equation is the governing law for filtration. It was derived as an empirical model by H. Darcy in 1856 while he was studying fluid flow in sand filters (Hall, 1956). Since then, many investigators derived it from first principles. It relates superficial fluid velocity to the pressure drop across a porous medium of known permeability. In filtration, the latter can be related empirically to particle size using the Kozney equation (Yoon, 2005)."

Jan 1, 2016

By Walter Greaves

THIS paper describes a series of tests performed at the Hollinger mill during the past four years, in which both metal and rubber-lined pumps were used for pumping sand and slime. While conditions will not be the same at other mills, it is felt that the information gained from the tests should be of value to other operators and of assistance to them in selecting the most efficient size of pump and kind of lining for economical operation. For the successful operation of pumps with rubber linings there are certain conditions, which, if recognized at the outset, will save the operator a good deal of work and trouble. First is the necessity of keeping sharp pieces of steel, or anything that might cut the lining, out of the pumps. This can be effected by placing screens in the proper locations. Second is to recognize the fact that the rubber lining of the shell, and the rubber cover of the impeller, are subjected to very different conditions. The shell lining, :being at rest and well supported by the metal case, has a relatively easy job compared ? with the impeller covering, which is subjected to centrifugal force and has a tendency to tear itself away from the metal core. Also, the pulp travels through and past the impeller at a high velocity. These two factors, centrifugal force and velocity of the pulp, would appear to set a limit to the speed at which, for a given set of conditions, it is economical to run a rubber-covered impeller. Therefore, a pump should be large enough for the work to be done. To get the best mechanical efficiency, it must be operated somewhere near the limit of its capacity, but this may not give the best overall cost, because the saving in power, due to the high efficiency, may easily be lost through excessive wear on the lining. It would appear that this condition is more critical in a rubber-lined pump than in one lined with metal.

Jan 1, 1939

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By André Chagnon, Yvon Héroux

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du faciès ""F"" de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Formation de Horn River. La matière organique se compose principalement de bitume solide et de quelques fragments de fossiles (organo­ clastes). La majorité des échantillons ne renferment que de l'illite et des interstratifiées illite/smectite.Si on compare les températures d'homogénéïsation (Th = l00°C) des inclusions fluides de la sphalérite et des dolomites associées à la minéralisation aux températures estimées à partir de la réflec­ tance de la collinite (84°C à ll7°C), l'on ne peut pas conclure à la présence d'une anomalie ther­ mique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gîtes. L'analyse des minéraux argileux conduit à la même conclusion : aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract- The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the biturninous unit at the base of the Horn River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th(l00°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectanœ (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994

By C. Dupuis, P. Waite, S. Leboeuf

Casthouses throughout the aluminium industry commonly use chlorine gas as a fluxing agent for furnace and in-line treatment of molten aluminium alloys. Its positive impact on the removal of alkali elements and non-metallic inclusions is well known. Nevertheless, the elimination of its use is highly desirable due to the safety and environmental risks associated with storage and handling. Over the past decade, the aluminium industry has significantly reduced its chlorine consumption. This has been achieved by maximizing the chlorine gas utilization efficiency during metal processing, and by the chlorine replacement for crucible and furnace metal treatment applications. Operation of sealed in-line treatment units without chlorine is now possible, but with lower or inconsistent removal efficiency penalties for alkali and inclusions respectively. This paper reviews the progress made at Arvida Research and Development Centre regarding the reduction of chlorine and the development of an alternative to chlorine for in-line metal treatment without penalizing the metallurgical performance.

Jan 1, 2006

By D. A. Beattie

Three novel dextrin polymers of varying functional group chemistry but similar molecular weight have been used to depress talc in single and mixed mineral studies. The mixed mineral system was a model sulphide ore consisting of talc, pentlandite, and chalcopyrite. Adsorption isotherms for the three polymers on both valuable and gangue mineral phases were determined to give initial clues as to the ability of the polymers to depress talc. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc in the single mineral system (MP Dextrin > CM Dextrin > Dextrin TYM), reflecting the observed adsorption affinity and adsorbed amount of the polymers on talc. However, a different order of effectiveness was observed for talc depression in the mixed mineral system (CM Dextrin > MP Dextrin > Dextrin TYM). Competition between the valuable and gangue mineral phases for uptake of MP Dextrin is responsible for its observed decrease in efficiency in mixed mineral flotation. All three polymers were found to be reasonably selective in their action, although at high dosages the polymers began to affect the flotation of the valuable minerals.

Jan 1, 2006

By Zhan Zhang, Hiromi Nagaumi, Zhen Li

"Recently, the remarkable strengthening effect of ??-Al(Mn, Fe) Si dispersoids at both ambient temperature and elevated temperature were found by several researches. A large amount of dispersoids can be formed by applying special heat treatments and within a suitable range of chemical composition of AA3xxx alloys. In the present work, the influences of Cr addition on the mechanical properties and microstructures of the Al-Mn-Mg-Si alloys were investigated. The mechanical properties at ambient and elevated temperatures were evaluated by micro-hardness and yield strength. Moreover, the microstructures in as-cast and heat-treated conditions were quantitatively analyzed by optical and electron microscopes. Results revealed that Cr also had effect on the number density and volume fraction of dispersoids. Micro-hardness and yield strength at ambient temperature increased with the increasing content of Cr, and the Cr addition increased the yield strength at elevated temperature as well. Moreover, the creep resistance at 300°C improved dramatically with the increasing content of Cr.INTRODUCTION Traditionally, AA3xxx aluminum alloys were widely used in packaging, automobile and architecture industries, because of its good formability, excellent corrosion resistance and weldability. And AA3xxx alloys were considered as non-heat-treatable alloys. However, the strengthening effect of dispersoids in AA3xxx alloys was discovered recently (Li & Arnberg, 2003;Li, Muggerud, Olsen, & Furu, 2012; Li, Zhang, & Chen, 2016; Liu & Chen, 2015).Alarge amount of dispersoids could precipitate by a proper heat treatment.In order to further improve AA3xxxalloys, the composition of the alloys should be optimized. A few previous studies were reported to investigate the influence of compositions on AA3xxx alloys. Adding Mn element could enhance the precipitation of ??-Al(Mn, Fe)Si dispersoids and improve the yield strength(Muggerud, Mørtsell, Li, & Holmestad, 2013), as long as the concentration of Mn was under the solid solution limit. Fe decreased the solubility of Mn and accelerated the precipitation rate of ??-Al(Mn, Fe)Sidispersoids(Li & Arnberg, 2003), the yield strength and creep resistance at elevated temperature could increase with an optimized content of Fe(Liu & Chen, 2016). Mg element would affect the nucleation process of ??-Al(Mn, Fe)Sidispersoids by forming metastable Mg2Si(Hirasawa, 1975; Li, Zhang, & Chen, 2017a; Lodgaard & Ryum, 2000), metastable Mg2Si precipitated during heating process and promoted the precipitation of ??-Al(Mn, Fe)Sidispersoids, moreover, Mg provided solid solution strength for AA3004 alloys(Li et al., 2016). Si increased the volume fractionof ??-Al(Mn, Fe)Sidispersoids(Muggerud et al., 2013)and decreased the size of ??-Al(Mn, Fe)Sidispersoids(Li, Zhang, & Chen, 2017b). With the addition of Mo, the size of dispersoids became finer with a higher volume fraction, the volume percentage of dispersoid free zones was reduced. Elevated temperature yield strength and creep resistance improved due to Mo addition (Liu, Ma, & Chen, 2017).However, the effect of Crelements on microstructure and mechanical properties of AA3xxx alloys were rarely reported."

Jan 1, 2018

By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By F Kelly

"A central composite experimental design was used to determine empirical relationships between the operating variables of a ball mill and the characteristics of the ground products. The independent variables selected for the study were the work index and size distribution of the feed material, the feed rate and the pulp density. The measured responses included product size distribution, product surface area, viscosity of pulp discharge, weight of dry solids in mill, mill time constant and emitted sonic vibrations. The ball mill was operated continuously in open circuit during each experimental run.Multivariable regression techniques were used to derive linear empirical models from the experimental results. Of the four factors studied, the grindability of the feed material significantly affected every measured response. The size distribution of the ground product was affected significantly by the feed rate and the size distribution of the feed, but not by the pulp• density. Feed throughput capacity and pulp density were significant to the viscosity of the pulp discharge, the weight of solids in the mill and the mill time constant. Significant first-and second-order models are given for the above relationships. The relation-ships between the characteristics of the sonic vibrations of the operating mill and the various dependent variables have not as yet been established."

Jan 1, 1970

Operating CIP/CIL gold recovery plants in the arid regions of Western Australia face unique challenges due to water and ore quality issues. The presence of cations of Mg, Fe and Cu metals in water supplies and leached sulphide ores can have considerable effect on plant consumption of lime and cyanide, due to pH buffering and complexation effects. Reagent costs are critical to many of these operations. In this paper, computational modelling is used to analyse a number of process options to mitigate such issues. This requires careful consideration of the chemistry of the process system, and the ability to predict accurately the response of speciation and precipitation reactions to changing process conditions. The Mg-Fe-Cu-CN-H20 system is specifically modelled in this application. The Gibbs Free Energy Minimisation thermodynamic framework has been selected to model equilibrium phenomena. Furthermore, this approach has been extended to the process flowsheet level, incorporating multiple unit operations and recycle streams in a steady-state mass balance model. The Gibbs equilibrium composition module of HSC Chemistry software has been successfully integrated into the commercial flowsheeting package SysCAD. Consideration of the Gibbs Energy Minimisation capabilities of other flowsheeting packages has also been given. This approach has been successful in simulating the aqueous process chemistry typical of such plants. It has resulted in a predictive capability where equilibrium states respond appropriately to process changes. Potential cost savings may be identified by examining alternative process conditions to minimise overall reagent consumption.This methodology may be extended to other hydrometallurgical plants where issues of solution ideality, temperature and other equilibrium processes are sufficiently understood.

Jan 1, 2005

By Greg Barnes

Agenda ? The Mining Stock Life Cycle ? Current Environment ? Valuation ? Golds ? Valuation ? Base Metals ? Case Study ? Quebrada Blanca Hypogene Commodity Investment Cycle ? Macro-Economic Indicators ? LME Inventories ? watch the trend; rising inventories ? bad for prices, declining inventories good for prices ? OECD Leading Indicators ? PMIs ? Purchasing Manager Indices ? Industrial Production ? more important for metals consumption than GDP ? Housing Starts ? US, Europe ? Auto Sales ? All things China ? metal imports/exports; SHFE inventories; SRB stockpiling ? Seasonality ? it does play a role ? What is Chris Dutton (TDSI Quantitative Analyst) saying?

May 1, 2010

By U. Caliskan, S. Miskovic

Gravity separation is a technique that depends on the difference in density of minerals for their separation. Although this method is one of the oldest separation techniques, it is still preferred in the industry because of its low capital and operating cost while it is environmental-friendly. In this paper, we present a new numerical methodology that can be used to investigate dynamics of dense slurry flows in gravity separation systems. A simple channel with a set of riffles is selected as a test platform in order to observe the effect of the riffle shape on segregation profile of particles with different densities. It is believed that the riffle shape would affect the slurry flow and possibly cause one class of particles to segregate within the riffle zone. The turbulence, as a disturbance effect within the riffle zone, causes heavy particles to displace the light, that is, the heavy particles will be trapped in riffles, while the lighter particles are carried by water to the end of the channel, which is an example to uninterrupted suspension. MP-PIC model in OpenFOAM is used to study the effect of riffle shape and slurry percentage of solids in this simple gravity separator on particle segregation profile of four discrete mineral density classes, which are Quartz/Clay (SG 2.6), Pyrite (SG 4.2), Chalcopyrite (SG 5.1), and Gold (SG 19.32). Gold particles are found to be readily captured and retained in the riffles because of their high density, while particles with the intermediate densities are more influenced by the flow. The developed model framework has been proven robust and capable of providing physical results even for the flows with a very high percentage of solids, characteristic for mineral processing operations. INTRODUCTION Gravity-based ore concentration techniques make use of differences in density of minerals within an ore to enable separation of valuables from the gangue. As some of the oldest techniques used for ore beneficiation, they are known to offer a range of benefits such as low specific energy consumption and low capital and operating costs (Burt, 1999; Falconer, 2003; Holland-Batt, 1998), however, they suffer from low selectivity, poor separation efficiency, and low capacity. Gravity separation techniques are common practices in the mining industry and are employed widely for the precious mineral concentration, iron ore recovery and coal preparation (Kroll-Rabotin, Bourgeois, & Climent, 2013; Laplante & Spiller, 2002; Williams, 1997). For example, gravity separation systems are highly applicable for precious metal enrichment operations by being included in primary grinding circuits, shaking table tailing separation, pre-concentration of leach feed and flotation concentrate enrichment for both flash and conventional flotation purposes (Burt, 1999; Falconer, 2003; Holland-Batt, 1998; Laplante & Spiller, 2002; McAlister, 1992). Gravity separation can be employed in the copper processing circuits by being integrated into the pre-flotation circuit to capture the gravity recoverable gold (GRG) and any free copper aiming to enhance the gold and copper recovery of the plant. When native copper and GRGs are present in the deposit, this integration not only facilitates plant overall performance via removal of the valuables early in the circuit, but it also reduces downstream operational expenditures due to less retention time of coarser copper particles in the system.

Jan 1, 2019

By Marcel Vallee, Fernand Dubuc

"The St-Honoré carbonatite complex, located 8 miles north of Chicoutimi, Quebec, was discovered in September 1967 as abnormal radioactivity was detected in the course of SOQUEM's aerial surveys. The complex, covered by a shallow layer of Trenton limestone, has been explored by aeromagnetic, ground gravimetric and magnetic surveys, and 12,013 feet of diamond drilling. Its age, from potassium-argon dating, is 650 million years. The carbonatite is approximately kidney-shaped and has a surface area of 6 square miles, 20 per cent of which is explored. It shows a central core of coarse-grained massive dolomitic carbonatite and an outer ring of foliated dolomitic carbonatite.The exploration work to date has resulted in the discovery, in the foliated carbonatite, of an incompletely drilled niobium (columbium) zone of pyrochlore-bearing carbonatite, at least 1,000 by 800 feet in size. This zone contains 5,000 tons per vertical foot grading 0.86 per cent Nb205 or at least 15,000 tons per vertical foot grading 0.66 per cent Nb205 or 45,000 tons grading 0.48 per cent Nb20s. The pyrochlore contains an average of 64 per cent Nb,Os. The central core contains a zone of rare-earth-bearing carbonatite (as monazite), grading up to 4.5 per cent rare-earth oxide, 3,500 ppm zinc and 290 ppm molybdenum. Stocks of nepheline syenite and magnetite diorite accompany the carbonatite. The total analysis and trace-element contents of typical rocks are presented."

Jan 1, 1970

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966