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By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By D. R. Pyke

Many of the gold deposits in the Timmins• area show a close spatial association to ultramafic metavolcanics. Available analytical data suggest that ultramafic rocks contain significantly higher gold contents than other major rock types. In addition, recent analyses by Keays (1975) suggest that talc-carbonate alteration of ultramafic rocks releases significant quantities of gold. It is proposed that the ultramafic volcanics formed the principal source of gold for the deposits in Timmins, and that the gold was derived from the ultramafic flows when they were extensively carbonatized. Carbonatization of the ultramafic rocks and emplacement of the auriferous quartz-carbonate veins was probably coincident with the last major period of deformation in the gold camp. Delineation of hitherto unrecognized ultramafic volcanics could be an important guide to the discovery of further gold deposits.

Jan 1, 1976

By D. Duff, R. A. Cameron, R. E. S. Whitehead

"Although CO2 content indicates the quantity of carbonate in altered basaltic rocks, it does not measure the intensity of carbonate alteration. CO/CaO molar ratios, which correlate with the relative proportions of individual carbonate species, measure the intensity of carbonatization. The Timmins gold area is characterized by pervasive carbonatization, with large parts of the area having CO2/Ca0 ratios greater than 1, representing C02 supersaturation relative to CaO. The mean CO/CaO in the Timmins area is0.67, compared to 0.13 in two unmineralized control areas. Regional arsenic abundance in the gold-bearing area averages 4 ppm, compared to about 0.35 ppm for the non-mineralized areas. The average K20 and Rb abundances are similar in both mineralized and non-mineralized areas (about 0.30% K20 and 7 ppm Rb). Although there appears to have been no wholesale addition of K20 or Rb to the mineralized area from external sources, these alkalies have been redistributed internally, resulting in patterns of local enrichments and depletions which are characteristic of the mineralized region.Local target anomalies associated with known mineralization consist of CO2/Ca0 > 1.5, As > 10 ppm and K2O > 0. 75%. Not all three values are required to be above these thresholds in order to identify local targets. Combinations such as C02/ Ca0 > 1.5 and As < 10 ppm, CO/CaO 1-1.5 and K20 > 0. 75 or K20 > 0. 75 and As > 10 ppm are equally indicative of proximity to gold occurrences. Gold-bearing veins and associated anomalies occur throughout the entire volcanic succession and are not restricted to any particular stratigraphic horizons. The levels and patterns of alteration and occurrences of gold appear to be structurally controlled."

Jan 1, 1982

By S. B. V. Stewart, W. W. Forsyth

"Since the Mathew&apos;s method for open stope design was first proposed by Golder Associates in 1980 it has been applied at a number of mine sites in Canada. The initial hypothesis was based on a relatively small amount of data and the intervening period has allowed the collection of a significant amount of new data to test the validity of the method.This paper examines a brief history of the evolution of rock mass classification systems to provide background and emphasize their empirical and non-rigorous approach. It also presents the new data which appear to indicate that the initial hypothesis was reasonably good. The modification to the original graph proposed by Potvin is discussed as well as the applicability of the method to predicting the onset of caving. The original graph has been updated and has been subdivided into four zones described as ""stable""; ""potentially unstable""; ""potential major failure""; and ""potential caving"". The method is recommended as a useful open stoping design tool provided it is recognized that it is not a rigorous design method.Finally the paper proposes a recommended approach for application of the method by would-be users and addresses some typical pitfalls that may be encountered."

Jan 1, 1995

By Dr. G. R. Hoey

"Abrasive wear and corrosive wear of carbon-steel grinding balls occurred simultaneously during the wet-grinding of hematite iron ore, and Ni-Cu sulphide ore, in laboratory ball mills. Two corrosion control methods, the use of corrosion inhibitors and pH control, were investigated and found to be effective means of reducing or preventing corrosive wear. Up to 50 % reduction of total ball wear resulted from the use of these methods.Corrosive wear is caused principally by the reaction of oxygen in air with the carbon-steel grinding balls, probably by the following reaction: 2Fe + O2 + 2H20 - 2Fe2 + 40H-.IntroductionA survey of corrosion problems in Canadian sulphide ore mines was completed and the findings were published in 197l(l). The corrosion survey was used to develop the present research program with the objective to find more economical and effective ways and means to reduce the corrosion that occurs in the mining and metallurgical industry. The purpose of this presentation is to review the projects being done by staff members of the Corrosion Section, Extraction Metallurgy Division, on corrosive wear and its control in wet-grind ball mills.Both abrasion and corrosion contribute to metal consumption during wet grinding of ores. The total wear of grinding media in this study is assumed to be equal to the sum of corrosive wear and abrasive wear. A great deal of research and development has been reported in the literature on ways to improve the abrasion resistance of grinding media but only a small number of studies has been reported on the corrosion resistance of conventional grinding media."

Jan 1, 1974

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By M. Samuels

"Block and panel cave mining methods are being increasingly proposed as they allow massive, deeply situated ore-bodies to be mined economically at a time when discovery rates of significant near surface deposits are declining. Cave-to-Mill, a mine-to-mill approach for block cave mines, defines ore block models with respect to both mine and mill performance. A cave-to-mill study for the New Afton block caving operation focused on identifying value opportunities related to fragmentation and sorting for a future lift as development progresses deeper. The lack of selectivity and potential for dilution associated with the block cave mining method results in many caving operations having to mine and either dispose of or process material that is below cut-off grade at certain stages of production. As an outcome of the study, the variation in cave fragmentation size and the sensitivity of mill throughput to feed size was examined. To evaluate the amenability of bulk and particle sorting, Prompt Gamma Neutron Activation Analysis and X-Ray Fluorescence sensors were tested. A conceptual bulk and particle sorting flowsheet is presented. Grade data from regular underground sampling was used to predict the performance of a bulk sorter. A heterogeneity analysis of material reporting to drawpoints helped to identify areas of the extraction level that experience high variations in grade and thereby stand to benefit from dedicated ore and waste material handling systems should underground bulk sorting be implemented.INTRODUCTION Block and panel caving are low-cost underground mass mining methods that are suitable for excavating weak, massive and steeply-dipping orebodies. Accordingly, cave mining methods have predominantly been used to mine copper porphyry and diamond bearing deposits. Due to the increasing depletion of near-surface orebodies, it is expected that block and panel caving methods will be increasingly used in the copper-gold industry. Their implementation holds significant potential to extend the life of existing open-pit operations by providing an economic means to access ore located at depths that are beyond the practical limits of open-pit mining. Examples of cave mines proposed for British Columbia include the Kwanika Mine, Red Chris underground, Kemess Underground project, and the Iron Cap and Mitchell cave mines of the Kerr-Sulphurets and Mitchell (KSM) project (Moose Mountain Technical Services, 2017; Imperial Metals, 2017; Golder Associates, 2017; Tetra Tech, 2016)."

Jan 1, 2018

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

It was determined by the authors that the water that remains in the filter cake after filtration in iron ore concentrators can contain several hundred times greater concentrations of calcium ions and other cations, due to surface chemical effects carrying the ions along with the water. Filter cake from two plants was analyzed. The water retained in samples of magnetite concentrate filter cake in Plant 1 contained 5088 ppm calcium and 5995 ppm magnesium, while the Plant 2 filter cake contained 231 ppm calcium and 119 ppm magnesium. These levels were dramatically elevated compared to the water that was removed from the concentrate by filtration for recycle to the plants (9 ppm calcium/15 ppm magnesium for Plant 1, and 11.9 ppm calcium/9.3 ppm magnesium in Plant 2). In addition to possible effects on agglomeration performance, the presence of these cations also affected the efficiency of filtration. In order to reduce the effects of these cations on filtration in Plant 2, carbon dioxide was injected into the slurry before it entered the filter press. This was found to increase filtration rates by up to 23.7%. Comparison of the results from the two plants shows that the concentrations of cations present in the filter cake will vary greatly from plant to plant, with correspondingly large variations in their effects on plant operations.

Jan 1, 2004

By Brian Lewis

"IntroductionThe ion exchange process is classed as a purification and concentration stage. In the uranium industry it is used to separate, and recover uranium, from a solution produced in the leach and subsequent solid washing circuit, that contains uranium as well as some impurities. The final product from this circuit is a solution, containing uranium at a 15 to 25 fold increase in concentration, with a chemical composition suitable for the ""Precipitation"" circuit.The process is a reversible chemical ""ION"" exchange, between a solution, and solid phase, with the ""resin"" being the solid phase. Various chemical changes in the solution phase will permit the resin to remove uranium from a solution or have the uranium removed from the resin back into a solution phase. The former loads uranium onto the resin, and is called the ""adsorption cycle"", and the removal or stripping is known as the ""elution cycle"".Ion Exchange resin is a semi-rigid polystyrene spherical bead, approximately 10 to 30 mesh. It is used by placing the resin in a vessel, so that a porous bed of resin is formed, through which the solution may flow.There are many different types of vessels, and systems used to hold the resin, but it is not the intention of this chapter to describe them all, but to describe two methods used in Elliot Lake. These are the ""fixed bed"", and ""moving bed"" systems, the condition of the bed during normal operation signifies the name of the system.Chemical and Physical Characteristicslon Exchange ResinThe resin used is a strange base Anionic resin, semi-rigid, and spherical in shape. The size of the wet resin is approximately 9007o between 20 and 40 mesh. Physically the beads of resin are broken early, but some have lasted over 15 years and are still in use."

Jan 1, 1989

By P. Toscano, T. A. Utigard

"The objective of this investigation was to determine how the losses of nickel, copper and cobalt in fayalite slags could be controlled for nickel mattes with iron contents below 5 wt%. Laboratory-converting and slag-cleaning experiments were carried out at 1250°C.Several variables were investigated during and after converting to help minimize the amount of nickel and cobalt that reports to the slag. The variables used were oxygen concentration in the blast, coke breeze addition and nitrogen injection stirring. In all the experiments, slag and matte co-existed.Coke additions during converting have little effect on the losses of nickel, copper and cobalt. In fact, coke additions retard the converting process by consuming some of the oxygen injected. On the other hand, coke additions and nitrogen injection applied after converting was completed resulted in decreased slag losses."

Jan 1, 2004

By P. Toscano

The objective of this investigation was to determine how the losses of nickel, copper and cobalt in fayalite slags could be controlled for nickel mattes with iron contents below 5 wt%. Laboratory-converting and slag-cleaning experiments were carried out at 1250°C. Several variables were investigated during and after converting to help minimize the amount of nickel and cobalt that reports to the slag. The variables used were oxygen concentration in the blast, coke breeze addition and nitrogen injection stirring. In all the experiments, slag and matte co-existed. Coke additions during converting have little effect on the losses of nickel, copper and cobalt. In fact, coke additions retard the converting process by consuming some of the oxygen injected. On the other hand, coke additions and nitrogen injection applied after converting was completed resulted in decreased slag losses.

Jan 1, 2004

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By David Evans, David Barnes, Robert Raponi

"The Williams Mine processes, on average, 6,450 t/d of gold bearing ore using two parallel grinding circuits, leaching and C.1.P., carbon stripping, electrowinning and refining. At present, each grinding circuit consists of a SAG mill in closed circuit with a spiral classifier and a ball mill in closed circuit with two stages of cyclones.Since grinding has always constituted the largest portion of milling costs, the Williams Mine has been proactive in trying to reduce such costs through innovative changes. One project under consideration is the replacement of one spiral classifier by a vibrating screen.This paper discusses the testwork performed to evaluate the replacement of one spiral classifier by a vibrating screen, and the preliminary engineering performed to date.IntroductionThe Williams Mine, located in northwestern Ontario, approximately 40 kilometres east of Marathon, is part of the Hernia gold camp. The mine is operated by the Williams Operating Corporation and is owned by the Teck Corporation and Homestake Canada Incorporated. Operation of the mine started in October 1985 at a rate of 3,000 t/d. After a mill expansion in August 1988, throughput increased to 6,000 t/d. Production has increased steadily since the mill expansion and in 1995, an average of 6,450 t/d of ore was processed at a recovery of 95.1 %."

Jan 1, 1997

By Sazol Das, Hany Ahmed, Ganesh Bhaskaran, Zhuoru Wu

"Friction stir welding (FSW) process in lap configuration for dissimilar materials has been developed and tested for steel to aluminum joining. A novel cylindrical tool was designed for improved material flow. The joining of steel to high strength 5xxx and 6xxx aluminum was carried out by FSW technique using optimized process parameters. The microstructure, micro-hardness, joint strength and corrosion properties at the weld interface have been investigated. Optical and scanning electron microscopy reveled a well layered structure at the interface and lap shear tests of the welds showed excellent fracture resistance. Neutral salt spray tests for up to 500 hours (ASTM B117) were carried out on the bare steel to aluminum FSW joints, which did not show neither evidence of corrosion at the weld interface, nor any degradation of the weld strength. The FSW lap configuration was applied to prototype commercial vehicle structural component whereby a steel stiffener insert was friction stir welded to high strength 6xxx aluminum alloy. The interface microstructure showed layered root without any steel shattering in aluminum side. A finite element study was carried out to quantify the benefits where it was found that the stiffness increases by 76% under bending loads and 36% in torsion loads.INTRODUCTION Energy preservation and environmental issues, namely carbon footprint and legislation around emission in transportation industries has led to a growing need to use of lightweight materials such as aluminum and magnesium alloys along with various grades of steel in structural application, while still maintaining their strength and crashworthiness. Assembling dissimilar materials within integrated structure is thus a stringent requirement related to optimum performance. In order to achieve an efficient technology of joining dissimilar materials such as aluminum to steel, it remains difficult to select an effective welding process for a given joint configuration. The use of aluminum in transportation industries for structural component is not exclusive in a design and is almost always used along with various steel grades for a mixed materials solution, thus dissimilar aluminum/steel lap joining is of great interest since this is widely used in the assembly of parts (e.g. pillar, frame rails, chassis, body in white (BIW), CAB, etc.)."

Jan 1, 2018

By Ruy L. Rodrigues

Vale is in the early stages of commissioning its Onça Puma nickel operations. The project is meant for the production of 58,000 tpa of nickel contained in ferro-nickel, substantially contributing to the company?s vision to achieve world leadership in the nickel business. Mineral resources will be exploited from the homonymous deposits in the Midwest of state of Para, Brazil ? some 100 km southwestwards from the company?s Carajás iron ore properties. Resources as of 83 Mt at 1.73 % Ni will sustain a mine life of approximately 40 years. The property was acquired in late 2005 and Vale has since extended the engineering studies and proceeded with the implementation. Nickel will be mined from saprolitic ore at a rate of approximately 10 Mtpa (ore plus waste) in early years ? ramping up to some 15 Mtpa 7 years later ?, to feed the plant at a rate of 2.5 Mtpa. The process uses conventional RKEF (Rotary Kiln Electric Furnace) pyrometalurgical route whereby the ore is homogenized, calcined in rotary kilns, melted in electric furnaces and further refined to ferro-nickel. The plant has been designed and constructed applying the latest available technology, aligned with Vale?s vison to exceed the highest existing standards for environmental control, health and safety and productivity in the industry. Total investments in these operations are anticipated to correspond to USD 2.3 Bi and will materially contribute to the regional development and well being of the nearby communities and other stakeholders.

May 1, 2010

By J. Ga?parík

The optimal selection of machine or machine group for building processes is very important role of building planner during the process of building planning. During this process building planner have to analyze several factors influencing the final effective decision concerning this problem. There are several factors and criteria for effective selection of building machines. In our contribution there are analyzed: ability of machines to realize designed building process (quality aspect), duration of mechanized process (time aspect) and minimizing of energy consumption (cost and environmental aspect). Selected scientific methods and theories of problem solution can be divided into these groups: theory of system (creation of building machine selection method), multi-criteria optimizing method (analysis of mechanized building process from the point of more optimal criteria), queuing theory (application during the mathematical modeling of mechanized soil processes), method of scientific analysis (analysis of factors influencing final decisions), method of scientific synthesis (creation of optimizing method implemented into building processes and possible application in construction sector). Multi-criteria optimizing method were during our research work implemented into soil processes and selected building group machines (excavators and trucks), which are very often used in construction and mining processes. This method can be considered as a multi-level decision making process based on multiple parameters. In our contribution is presented key mathematical models for model example solution and software built in Java, which has been created as a support for method described in this contribution. Application of this method and software will increase the effectiveness of building machine selection from the point of key criteria of optimizing: quality, time and energy consumption.

Aug 1, 2013

By Charles G. Kemsley

MR. C. R. WHITTEMORE: It is interesting to note that the mining industry is making increased use of alloy steels for drilling. They will undoubtedly lead to greater footage at lesser cost. Mr. Kemsley states that, for use in hard ground, the shanks are brought to a hardness of 435 to 440 Brinell by heating them to approximately l,800°F. It seems to me that this temperature is excessively high-it is considerably above the critical point of the steel. The only effect of such a high temperature is to lessen considerably the impact resistance of the steel. The possibilities of an oil quench, followed by a tempering draw which does not lessen the hardness of the steel too much but increases its toughness, might well repay further study; also the temperature control, a factor which depends on the composition of the steel. However, service results are undoubtedly the best criterion of practice. MR. KEMSLEY: I would like to point out that the steel is not quenched at 1,800°F. After heating to this temperature, it is laid aside to cool gradually; this high temperature is necessary to produce the required hardness by simple normalizing-cooling in still air. We all know that ideal conditions for hardening steel demand salt baths and furnaces with automatic temperature control, but for most companies the cost of such equipment having sufficient output capacity is prohibitive. The end we are trying to attain is to make good drills at a cost that will be within the means of any mine.

Jan 1, 1942

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

"Geoscan is used for multi-elemental analysis of conveyed bulk materials in the minerals industry with proven performance and demonstrated paybacks of weeks or months in iron ore, manganese, copper, zinc-lead and phosphate industries. Geoscan-M measures continuously through the full bed depth and is unaffected by belt speed, particle size, layering, mineralogy and dust levels. Increments of typically two minutes are accurately measured and provide the plant operators with tonnage weighted results of contained elements. Measurement of the composition in real time enables prompt feedback to the mining operators and also feed forward to the process operators. Crushed ore increments can be diverted based on composition, such as diverting waste for disposal or marginal material to a stockpile for separate processing. Bulk sorting allows material to be placed into relevant stockpiles for subsequent blending to achieve consistency for process feed. Parameters used for decisions may be primary metal content, deleterious component content, other process parameter, or a combination of these. Process parameter may be the elemental ratio between critical components, e.g. Cu:S ratio, basicity, or the content of an “indicator” element (such as Si indicating material hardness). Benefits will be discussed based on case studies in copper and iron ore.IntroductionAs operators of process plants strive to remain competitive as capital and operating costs increase and commodity prices fluctuate, more focus has been directed at incremental performance improvements at incremental cost rather than major expansions to increase output. The philosophy of working smarter allows plants to adopt technologies proven in other industry sectors to minimise risk. This paper discusses one such technology that the minerals sector is adopting and has found to be safe, reliable and accurate with paybacks of weeks in most applications. New applications continue to be found and major benefits realised at various stages in the processing and handling of ores and products."

Jan 1, 2016

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

In this study, the dissolution behavior of copper and arsenic from five different copper concentrates containing 21-34.7 %wt. of Cu, 1.3-7.3 %wt. of As and 15.6-27.5 %wt. of Fe were investigated under high pressure oxidative leaching conditions. Leaching experiments were conducted using different leaching reagents such as ferric sulfate, sodium chloride, deionized water, sulfuric acid and ferric sulfate-sodium chloride mixture in order to compare the effectiveness of each on the dissolution of copper and arsenic from copper concentrates. The effects of ferric sulfate (0.1-1 mol/L), sodium chloride (0.1-0.5 mol/L) and leaching temperature (100-180C) were investigated under 1 MPa autoclave pressure , particle size >45 m, pulp density of 100 g/L, stirring speed of 750 rpm and leaching time of 60 min. Results showed that the most effective leaching reagents for the dissolution of copper are 0.34 M NaCl and a mixture of 0.1 M Fe2(SO4)3 - 0.34 M NaCl, in which As extraction did not exceed 7%. The copper concentration in the pregnant leach solution obtained after leaching using 0.1 M Fe2(SO4)3 - 0.34 M NaCl was 13-30 g/L, while the concentration of As and Fe were in a range between 0.3-1 g/L and 0.2-10 g/L at 160C. INTRODUCTION Copper sulfide minerals, such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and covellite (CuS) are used for the production of copper in mining and metallurgical industries worldwide. The conventional pyrometallurgical processing followed by electrorefining is a common process for the production of high purity copper (Moskalyk, & Alfantazi, 2003; Padilla, Aracena, & Ruiz, 2012). However, the degradation of copper content and an increase in the amount of metal impurities, especially arsenic (As), antimony (Sb) and bismuth (Bi) in copper concentrates cause serious problems to the production of copper and environmental pollution (Basha, Selvi, Ramasamy, & Chellammal, 2008; Long, Peng, & Bradshaw, 2012). Hydrometallurgical processes are used to recover metals from refractory ores, concentrates and tailings by leaching (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018). During the last decades, hydrometallurgical processing for the recovery of copper from enargite-bearing copper ores and concentrates has been extensively investigated due to its relatively more environmentally benign and less capital costs than the conventional pyrometallurgical processes (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018; Choubey, Lee, Kim, & Kim 2018). However, several issues facing the hydrometallurgical processing are incomplete extraction of copper associated with the coprecipitation of iron compounds, difficult stabilization of toxic impurities and production of a contaminated copper product (Dreisinger, 2003; Safarzadeh, Moats, & Miller, 2014). Hence, a number of studies have been conducted on the selective dissolution of copper from copper ores and concentrates or selective removal of arsenic leaving a clean copper residue using various leaching reagents or lixiviants (Safarzadeh, Moats, & Miller, 2014; Mihajlovic, Strbac, Zivkovic, Kovacevic, & Stehernic, 2007; Tongamp, Takasaki, & Shibayama, 2009). More extensive studies on the selective extraction of copper from enargite- bearing copper ores and concentrates are much needed to improve copper recovery.

Jan 1, 2019