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By Antti Porvali, Vivek Agarwal, Mari Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2·H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can then be further converted with NaOH solution to form REE hydroxides. However, present literature has paid little attention to how to minimize the consumption of reagents in this recovery process. In the current study, a process model was built using HSC Sim software, and metamodeling of the simulated flowsheet was conducted with the design of experiments (DOE), after which the basic functionality of the flowsheet was verified by experimental work, starting from sulfuric acid leaching of spent batteries. As the process is based on chemical circulation internally in the process, the objective was to investigate the accumulation of the elements in solution, specifically Na+ , K+ , SO4 2− ions and impurities liberated in the NaOH conversion step. It was found out that metamodeling could be utilized in obtaining first estimate of the process behavior, prior to any experiments. Flowsheet functionality with circulated solution was confirmed, obtaining at best 96.9% La recovery.

By Antti Porvali, Vivek Agarwal, Mari Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2·H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can then be further converted with NaOH solution to form REE hydroxides. However, present literature has paid little attention to how to minimize the consumption of reagents in this recovery process. In the current study, a process model was built using HSC Sim software, and metamodeling of the simulated flowsheet was conducted with the design of experiments (DOE), after which the basic functionality of the flowsheet was verified by experimental work, starting from sulfuric acid leaching of spent batteries. As the process is based on chemical circulation internally in the process, the objective was to investigate the accumulation of the elements in solution, specifically Na+ , K+ , SO4 2− ions and impurities liberated in the NaOH conversion step. It was found out that metamodeling could be utilized in obtaining first estimate of the process behavior, prior to any experiments. Flowsheet functionality with circulated solution was confirmed, obtaining at best 96.9% La recovery.

By S. M. Dar

The U.S. Bureau of Mines constructed a full-scale model of a 15-ft-wide coal mine entry to use in combination with finite-element analyses to investigate roof support systems and various types of roof bolts. The objective was to enhance understanding of the fundamental mechanics of the interaction between rock and supports and the relative integrity of bolted mine roof as a function of roof bolt type, length, spacing, and tension, and the basic characteristics of the roof strata. The laboratory test results, when correlated with computer simulations using fmite-element analysis and underground verification tests, should provide a basis for desigillng safer, more cost-effective roof control systems and help to establish guidelines for employing fully grouted resin and mechanically anchored bolting systems. The background for this research, the research approach, the methods and equipment employed, and the results are described in this report.

Jan 1, 1989

The Torington Lodes.This paper describes investigations into mineralogical, petrological and structural associations of cassiterite in occurrences of economic value. The work was carried out in three mines, during a number of years, in the hope that the, data collected might be helpfulin the search for occurrences of cassiterite in stanniferous zones and reduce unproductive exploratory work. Tin-bearing lodes at Torington, in the New England district, New South Wales, have been worked since 1880, and the locality is the most important centre of lode tin occurrence in the, State. The township of Torington is 18 miles westerly from Deepwater, a station on the Great Northern Railway, 446 miles from Sydney.The tinfield forms part of the Mole Tableland, which has an altitude between 3,000 ft. and 4,000 ft. above sea level. The country rock, in which the stanniferous lodes occur, is granite of Permian age, which has been intruded into Carboniferous claystone. An inlierof claystone is exposed to the west of the stanniferous area, 'and in it, close to' its contact with the enclosing granite, are occurrences of wolfram and bismuth. These minerals, together with chalcopyrite, pyrite, arsenopyrite, zinc blende, galena and molybdenite, in very small quantity, are associated with cassiterite in lodes traversing the granite, particularly near the claystone, but decrease in amount with distance from the contact. Their occurrence is sporadic and usually causes no trouble in dressing the cassiterite concentrate, the final product containing less than 1% of total penalisable impurity. In Curnow's mine, pyrite, galena and molybdenite have been observed at 700 ft. from surface.The granite is of the biotite type and its structure may be divided into four groups, or classifications, arising from segregation processes during cooling and consolidation. The four classes, in order of extent of distribution, are:1. Granite of normal type, in which the constituent quartz felspar and mica, have a particle size approximately 14, in.2. Porphyritic granite, in which the felspar particles are from % in. to lin. in size, that of the quartz and mica approximately % in.3. A fine-grained granite, in which the particles of all constituent minerals are % in. or less in size;4. A rock of highly siliceous ground mass containing very small particles of felspar and almost negligible biotite.Type 1 is the general type of granite in all mines of the field; types 2 and 3 may occur as large masses, or all three classes may merge rapidly one into the other, and all be disclosed in 20 ft. of driving. Usually, however, the segregations are massive, but are not associated with any special horizon. For instance, a mass of porphyiiticgranite extends from surface to a depth of 440 ft., for a distance of 350 ft. south from the New England main shaft. The upper levels of Curnow's mine, 14" mile south-east, are in normal granite, but a restricted mass 'of porphyritic granite occurred between Nos. 5 and 6 levels, or 400-500 ft. below the collar of the shaft...

Jan 1, 1950

In 2004, a total of 741 nonmetal mining operations reported employment to the Mine Safety and Health Administration (MSHA). These mines (e.g., potash, gypsum, salt) comprised 5.1% of all operations.

Sep 1, 2007

By K. Hanna

This U.S. Bureau of Mines report describes a rock mechanics instrumentation program conducted in a shallow underground coal mine in central Illinois. This research program was designed to provide a basic understanding of the structural behavior of entry intersections. A wide variety of instruments and measurement techniques including hydraulic borehole pressure cells, multiple-point borehole extensometers, roof bolt compression pads, and overcoring were employed to monitor roof stresses, pillar loading, strata movement, floor heave, and bolt loading before, during, and after intersection development. A summary of intersection design theories, failure modes, and support techniques is included and instrumentation installation procedures and analysis methods are presented. The study identified two critical parameters that affect intersection stability: in situ horizontal stresses and geological discontinuities. Important design parameters for improving intersection stability are roof span and intersection geometry.

Jan 1, 1991

By T. Schmidt, J. Merza

"This study considers two lead/zinc/silver orebodies which have historically had a problem with pyrite, pyrrhotite and sphalerite contamination in the lead circuit. The problem was previously addressed with high dosages of sodium cyanide as the primary depressant. However, large amounts of cyanide led to environmental problems in the effluent, especially during winter months. The objective was to reduce cyanide consumption while maintaining or improving overall lead grade and recovery via the reduction of the undesirable sulphides.Extensive laboratory and mill testing was necessary to determine the optimal operating parameters for continuous plant application. Evaluation of data received from this testing has shown that selective addition and optimization of the dosage of Unimax SD100 to specific areas of the flotation and grinding circuits has resulted in improved Pb grade and recovery. Parameters such as pH control, regrind operation, the cyanide/Unimax ratio and sulphide mineral content may also affect the performance of the depressant. Each factor is discussed and optimal operating conditions were determined based on the testing.Results are presented for two case studies. Both indicate that Unimax SD100 improves the lead grade/recovery curve by increasing iron and zinc rejection while reducing cyanide consumption and the resulting environmental concerns. 1. Hart"

Jan 1, 1992

By Dale Preece, Stephen Chung

Blasting induced rock fragmentation is an art that has been developed and refined for hundred’s of years through blasting and recording the results. Good blasting fragmentation practices were thus developed through experience. However, this method requires a history that is typically developed in a mine over a number of years and sometimes at considerable expense. Quantification of fragmentation as a function of rock-mass characteristics and blast design is attractive. Developments towards this end have included semi-empirical methods as well as computer codes that explicitly treat shock wave transmission and the subsequent rock breakage. This paper will present predictions of fragmentation resulting from rock blasting using the computer code AUTODYN and a new state-of-the-art material model for brittle rock and concrete.

Jan 1, 2003

By Goldney L. H

The authors review the literature and discuss the application of methods to the design of thickeners for ilocculated metallurgical pulps. The use and evaluation of flocculents is described. Experimental data show that design based upon laboratory settlingdata is acceptable. The economic aspect of design is also discussed.INTRODUCTIONFor many years there has been little change in the methods for the design of thickener installations. While modifications have been made in the method of applying the data all methods have been based on the observee settling rate of the solids. The development of a theoretical approach based on physical data would involve so many variables which affect the settling rate that the more practical approach of direct observation seems unlikely to be replaced as the basis of design.The advent of synthetic fiocculents has introduced a modification in operation which affects design and should be considered. The authors review the subject and attempt to bring it up to date with present day procedure. Until recently the original work of Coe and Clevenger (1916) remained the basis of thickener design. They described their observation of the different zones encountered in settling, namely clarification, feed, transition, and compression or thickening- zones. The solids pass through the transition zone in settling from feed density to some higher density where settling ceases and ·some compression or compaction effect controls. the density obtained. The point at which the settling zone ceases to exist is known as the critical point.

Jan 1, 1959

By A Bax, G Wardell-Johnson, W P. Staunton, J McGrath, J J. Eksteen

Since 2001, the AMIRA P420 gold processing technology project series has been studying the recovery of gold using gravity devices, with particular emphasis on the centrifugal units, Knelson and Falcon concentrators. The work has entailed the surveying of operating gravity circuits in Australia, Africa and North and South America.This paper reviews some of the results and lessons of these studies, including common circuit operating and design factors, which limit gravity recovery; pointers towards effective modelling of gravity circuits; and the contribution of gravity to overall gold recovery.CITATION:Wardell-Johnson, G, Bax, A, Staunton, W P, McGrath, J and Eksteen, J J, 2013. A decade of gravity gold recovery, in Proceedings World Gold 2013 , pp 225-232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

General recognition of the potential benefits of utilizing advanced technology has focussed public attention on the organisation of tertiary education. This has produced a situation where opportunities exist for significant changes to be implemented. The challenges to Mining education in this environment of change are analysed with respect to the setting of education objectives, the role of centres of education, course structures and student access to courses. The scope of the analysis includes formal courses for professional education and technical training, and programmes for continuing education and postgraduate research. Previous significant advances in mining technology illustrate the importance of encouraging the establishment of an extensive involvement with mining education. Education cannot be the sole responsibility of professional academic organizations; significant industry participation is essential. Methods of achieving this interaction are discussed. Major changes in techniques available for disseminating information provide a significant incentive to assess the relevance of existing course structures and restrictions on student access to courses. Establishment of a less rigidly progressive system of education is discussed with respect to the development of the full potential of computer based learning. This will expand the availability of mining education to include remote locations. The practical feasibility of such changes and recognition of the value of education as a commercial resource could also increase overseas involvement in Australian mining education. Benefits of such changes and problems that may develop if accreditation systems are not also changed to take account of new technology are outlined.

Jan 1, 1989

The first metal-mine accident-prevention course was prepared and published 1942-45 as a series of seven miners' circulars (Nos. 51-57). The course has been broadened, revised, and brought up to date and is being published as a similar series of seven miners' circulars on accident prevention at metal and nonmetallic mines. These circulars are: 1. Accident Statistics (Miners' Circular 51), dealing with general statistics on accidents and injuries at metal and nonmetallic mines, including causes, costs, and the uses of investigations and reports of all accidents.

Jan 1, 1957

By J. Chai

In order to find the behavior of dewatered unconsolidated strata during the process of injecting water through a borehole, a new type of fiber Bragg grating (FBG) sensing system was successfully used for the real-time strain monitoring of unconsolidated strata during a water injection process for a dewatered unconsolidated strata of a coal mine. The unconsolidated strata water injection test was implemented through a borehole at a depth of +115.83 to +135.15m. The employed FBG strain monitoring system and ground water level observation system were installed at the depth in the unconsolidated strata where the water injection was conducted through two different boreholes. The water injection pressures in the test were 0.1, 0.2, 0.3MPa respectively, and the total water injection volume was 4226.84m3. The relationships between the water injection pressures, water injection volume and the strain change of the unconsolidated strata, the stress and strain conditions of the unconsolidated strata before and after water injection, were analyzed. This paper presents the results of these tests, and shows that the dewatering compression of the unconsolidated strata is reduced with increasing water injection pressures and water injection volumes. Comparing the stress-strain conditions before and after water injection, it is found that the stress of the water injection strata is in tension, which confirms the theory that the settlement of the thick unconsolidated strata is directly caused by the reduction of ground water levels. The high sensitivity and stability of the FBG monitoring system used was able to realize the real-time strain monitoring of the water injection process within a deep unconsolidated strata. This FBG monitoring system and the test results presented are very important for understanding further treatment of settlement in unconsolidated strata.

Jan 1, 2012

This paper is a collection of thoughts and frameworks. It addresses a simple question: æIf we are to believe the large number of people and institutions indicating that humans are destroying the Earth and that the end is nigh, why do we bother trying to be sustainable?Æ The paper lays out evidence for the existence of multiple hazards to global society. The existence of a hazard alone is insufficient to make an assessment of risk. Risk estimates are required to support decision-making. An approach to assessing risk is provided and some limited data are presented. A new ædefinitionÆ or statement of what sustainability (in a broad sense) might have become is then given. A decision framework for guiding decision- making about the risks is developed. This framework includes a definition of leadership with inherent implications for what determines whether a leadership position by title is actually leading. The paper concludes by offering a view of minerals industry sustainability and considerations around maturity in the current economic situation. It is hoped that by placing this collection of frameworks around sustainability, a supporting structure emerges that will facilitate action. It is proposed that action taken in this way will be more effective than reaction to regulation or even social license to operate imperatives because it is driven by a more holistic view of the challenges and the potential roles of individuals û all of whom are potential leaders at some scale of action.

Jan 1, 2009

By Manuel Arnáiz, Pedro R. Sola, Rogelio Baudot, Manuel Herrera, Carlos S. Oteo

The aim of this paper is to describe and analyze the ground treatment performed between January and May 2002 in order to increase safety during excavation and reduce instability problems along 180 m of tunnel, during the construction works associated with line 10 extension to the Madrid Metro. The tunnel was excavated using the traditional Madrid Method and in the section considered in this paper layers of sand were detected around the tunnel crown area with a significant presence of water, the in?ow of which needed to be controlled with a minimum impact on the surrounding environment.

Jan 1, 2003

By Claude Bazin, Jalna Lamontagne

"The operators of mineral processing plants collect daily samples from strategic process streams with a view to prepare production balances to assess plant performances. The rules to minimize the risk of systematic sampling errors are known and applied in many mineral processing plants. The mass of the sample to be collected is calculated to yield a target measurement reproducibility considering the fundamental error associated to the sampling of heterogeneous material. This paper demonstrates that this practice is partly valid if one does not account for the time variation of the ore composition during the day. The concept is demonstrated using samples collected on a 30 minute basis from different streams of a gold ore concentrator. Results show that depending of the natural variability of the stream characteristics the mass of the daily samples may not be the critical variable to obtain reproducible measurements. On the other hand the number of cuts taken during the day could impact on the variance of the measurements obtained from daily samples.IntroductionMineral processing plants may treat several thousand tons of ore every day to produce concentrate or impure gold ingots. The operation and performances of these plants are monitored on a daily basis through the collection of ore samples from various streams of the processing circuit. The samples are prepared and assayed to obtain the concentrations of target elements that are subsequently used to calculate the mass flowrates in the streams of the circuit and ultimately the distribution of the target metals for the estimation of the plant performances (Morrison, 2009; Lachance and Leroux, 2016).The acquisition of representative and reproducible samples is therefore the first step in the characterization of plant performances. The term representative sample is used here to indicate an unbiased sample, i.e. a sampling procedure that does not introduce a systematic error. Rules for the collection of unbiased samples are reviewed in the literature by different authors (e.g. Morrison, 2009) and are not discussed in this paper. The term reproducible indicates the dispersion of the measurements around the average value of a characteristic of a stream meets an acceptable level of variance. The reproducibility of a measurement process (sampling and analysis) is assessed by the relative standard deviation or coefficient of variation of the measurement that is a function of the sampling and assaying errors (Morrison. 2009; Gy, 1979). Usually the focus is put on the fundamental error of sampling whose variance can be controlled by the choice of the primary sample mass or adequate particle size reduction during the preparation of secondary or tertiary samples extracted for the chemical analysis. When a sample is taken from a stream that exhibits a time varying characteristic, the obtained measurement exhibits a variability that is not only a function of the sample mass but also of the natural variability of the ore in the sampled stream. This paper examines this aspect of the sampling of a time varying process on the reproducibility of composite samples for a day of production."

Jan 1, 2017

By Rafael C. Castro, Geoffrey Hughes, Fredrick (Rick) Vincent, Philip H. Albert

Seven pairs of drop and ventilation shafts, between two and nine feet in diameter, will convey combined sewer flow to a 230-foot-deep, 26-foot diameter storage tunnel. This paper will present case histories for each site. Discussion will include functional requirements, program and site access constraints, structural design, geology, the variety of excavation and lining construction methods used, and lessons learned. Noteworthy observations include the importance of assuring competent ground sup-port at the soil-bedrock interface and of achieving tight verticality tolerance using both top-down and raise bore excavation methods.

Jan 1, 2007

By James A. Schneider

The evolution of the American Petroleum Institute (API) design method for axial capacity of driven piles in siliceous sands is explored, and complemented with an overview of how changes in offshore site investigation practice have increased the level of knowledge with respect to vertical variability of soil characteristics. Increased use of the cone penetration test (CPT) provides near continuous profiles of soil type and strength which can be used in calculation methods that address variation in local shaft friction rather than the API method which seems to have initially been based on observations of average shaft friction in relatively uniform sand deposits. Development of a formulation for CPT correlations to axial pile capacity in sand is discussed, along with implications to existing factors of safety used in routine design.

Jan 1, 2006

By C J. Hogan

Increasing demand for fine grinding to improve mineral liberation and metal recovery and the need for stricter control of the environmental impact of tailings deposition poses problems for tailings disposal. This has led to an increasing number of investigations of properties of tailings and their disposal. This paper describes laboratory model testing undertaken on Macraes mine flotation tailings to provide information on tailings behaviour under conditions of subaerial deposition. The in-place density or 'dry density' of the impounded tailings and the impoundment depth relationship are important for utilisation of the available impoundment storage facility and results of dry density to depth relationships are given for the Macraes mine tailings impoundment.

Jan 1, 1993