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By PAITIP THIRAVETYAN, KANJANA KUDPENG

The aim of this study was to investigate the influence of amino acids (glycine, aspartic acid, glutamic acid, lysine and tryptophan) and organic acids (citric, malic, tartaric, fumaric, oxalic, succinic and ascorbic acid) on gold extraction from silicate ore. Use of amino acids to extract gold was preferred compared with organic acids due to the presence of carboxylic group and amine groups in amino acids. Among the assessed amino acids, aspartic acid and glutamic acid had higher capacities to extract gold due to their structures, which lacked aromatic rings and long side chains. Organic acids could also extract gold. In particular, oxalic and succinic acids had the greatest capacity to extract gold versus the other tested organic acids. Moreover, aspartic acid had a greater capacity to extract gold from ores than the same concentration of succinic acid. We confirmed the aspartic acid and succinic acid functional groups by Fourier transform infrared spectroscopy. The findings revealed that aspartic acid had a greater capacity to extract gold than succinic acid due to the presence of both amine and carboxylic groups (succinic acid contained only a carboxylic group). The optimal gold:aspartic acid molar ratio was 1:6 and low concentrations of aspartic acid extracted 35–42%of gold from silicate ore within 15 days. This can be used as an alternative to traditional methods for extracting gold from ore; it is non-toxic to human health and environmentally friendly.

Aug 10, 2021

By F. C. Bond

Nature of Empirical Calculations The size reduction of large tonnages of ore and rock is an operation of great magnitude. It is a necessary and important part of industry. Its development has been motivated by practical need and has followed the path of an industrial art without much help from theoretical science. Knowledge has been accumulated from experience. Trial and error established the methods; then collected data were tabulated and served as the basis for empirical equations that have been continually modi¬fied and amplified as new data became available. These equations now constitute the bulk of our present knowledge of comminution. There is no accepted scientific theory that is basic to comminution. In electrical, mechanical, and civil engineering, as well as in many other industrial activities, such theories exist and are extremely help¬ful, but rock is essentially heterogeneous, and the zones of weakness that control its breakage are thoroughly diversified. No theory has yet been discovered which can account for the variability of rock, although many attempts have been made. Empirical equations tell nothing of the why of a phenomenon, but if they are properly derived they can tell much about the how. They always represent only an approximation of behavior but never a law. In a proper empirical equation a symbol is assigned for each of the variable quantities that obviously affect the relationship. In a grinding mill these include mill diameter, mill speed, and feed rate among them. In setting up and revising an empirical equation the cardinal princi¬ple in establishing and modifying it is this: any change must be strictly ascribed to the variable which caused it. A useful empirical equation is rendered useless when a change in any convenient coefficient or exponent is made to make it fit a particular set of data, without certainty that the altered coefficient or exponent is the responsible variable in the new data. Such indiscriminate revisions have brought the use of empirical equations into some disrepute. When existing equations are changed to accommodate new data it is a good rule to make a change which gives results intermediate between the new and the old. A halfway point is usually a good choice.

Jan 1, 1985

By T. Tamagawa

A gaseous chlorination process for hydrometallurgical treatment of a chalcopyrite concentrate was investigated. The overall process is visualized to consist of low temperature chlorination-selective oxidation, followed by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide. In this article, the chlorination phase of the processes is described. Initially, the chlorination behavior of chalcopyrite-concentrate micro-pellets was investigated using a small batch-type fluidized bed reactor. The optimum conditions thereby established was used in continuous chlorination tests. The chlorinated products thus prepared were used in the selective oxidation phase of the investigation.

Jan 1, 1999

By A. Sinha, C. Sawmliana, P. Pal Roy

Using the newly developed and permitted explosive Pentadyne-HP (Gulf Oil Corporation Ltd., Hyderabad), the Blasting Department of the Central Institute of Mining and Fuel Research, Dhanbad experimented at the GDK-5 Incline, RG-1 Area of the Singareni Collieries Company Ltd. (SCCL) to establish one modified angular cut blasting pattern as an alternative to conventional solid blasting in India to obtain longer pull, as well as to achieve at least 40 t of coal in a single blast round for the deployment of diesel load-haul-dump units at the face. This permitted explosive satisfied the statutory requirements of incendivity characteristics applicable to P5 explosives of the regulatory agency Directorate General of Mines Safety (DGMS) of India. The present paper summarizes the development of this new blasting pattern and its possible use in Indian coal mines.

Jan 1, 2010

By D J. Bradshaw

It is well known that the chemical environment determines the success of the flotation process, however its characterization and control is difficult to achieve. This work evaluates the use of various measurements, including mineral potential measurements, in gaining an understanding of the influence of varying parameters such as the milling media and the reagent suite composition on the flotation performance of a platinum group metal (PGM) bearing ore. The results showed differences in the response of the various mineral electrodes to the different conditions, however the changes in flotation performance of the different minerals in the ore could not be wholly described by the electrochemical changes, demonstrating the limitations of these measurements.

Jan 1, 1999

By T. Krumins, L. Zunti, R. Frischmuth

"Titanium and titanium alloys are commonly selected for pressure oxidation autoclave vent piping and pressure control valve components, as well as autoclave internals and other process piping. In the autoclave vent application, titanium ignition risk is controlled by limiting oxygen concentration, and preventing high gas velocity gas impingement on surfaces. Oxygen concentration is dependent on the autoclave pressure and temperature operating conditions and therefore oxygen concentration and the associated titanium ignition risk is dependent on standard operating procedures, process control interlocks and permissive conditions. It is not uncommon for these standard controls to be deficient during atypical operating conditions, or for operations to deviate from the operating procedures, increasing the potential for a titanium ignition incident. Titanium ignition risk caused by elevated oxygen concentration in autoclave vent systems can be reduced with the introduction of an online autoclave overpressure calculation and the configuration of associated interlocks and permissive conditions. INTRODUCTION High temperature pressure oxidation (>190°C) is a well recognized and versatile metallurgical oxidative pre-treatment process commonly used to liberate gold from refractory sulphide ores and concentrates before conventional leaching with cyanide. Titanium and titanium alloys are highly corrosion resistant in pressure oxidation process conditions and are therefore commonly selected as materials of construction for many components including: autoclave internals, agitators, process piping, and components in autoclave vent systems. Operations that anticipate or have experienced aggressive corrosion in the vent system often have little choice in material selection other than the use of titanium (Krag & Henson, 1992). Titanium is not suitable for use with elevated oxygen concentrations and is considered a restricted material because of its high pyrophoricity and combustion propagation properties (Beeson, Smith, Stewart, 2007). Several serious incidents have occurred in which titanium materials have ignited in autoclave applications (Zawierucha, McIllroy, Million, 1995). In autoclave vent applications, titanium ignition risk is reduced by preventing elevated oxygen concentrations, maintaining low gas velocities, and minimizing the potential for gas impingement on surfaces. Oxygen concentration in the autoclave vapour phase and vent system is dependent on the autoclave operating pressure and temperature conditions and therefore titanium ignition prevention controls typically include process interlocks and operating procedures based on the selected nominal design operating conditions. However, it is not uncommon for these controls to be deficient or for operations to deviate from the nominal operating conditions over time, increasing the risk of titanium ignition. The introduction of an online calculation of autoclave overpressure and a maximum target autoclave pressure as well as associated process control interlocks and permissive conditions can alert the autoclave control room operator and prevent an elevated oxygen concentration from developing, and therefore reduce titanium ignition risk in autoclave vent systems."

Jan 1, 2016

By G. Hoffmeyer, I. Ream

"Several copper projects exclusively utilizing in-situ recovery methods are currently under development in Arizona. Favorable conditions for In-Situ Copper Recovery (ISCR) include a saturated orebody, fracture hosted mineralization, hydraulic conductivity sufficient to effectively inject and recover solutions using wells, and a relatively flat background hydraulic gradient. Safe operation of an ISCR project requires that the operator have the ability to induce and maintain localized hydraulic gradients, thereby controlling the movement of injected and recovered solutions. Benefits of ISCR include reduced initial capital, and a greatly reduced environmental footprint. THE ISCR METHOD EXPLAINED The method chosen to extract a mineral from a deposit is driven by characteristics such as its size, grade and depth of burial. Large lower grade deposits that require significant excavation to access using surface methods are potential candidates for in-situ recovery. ISCR may also be ideal for smaller deposits due to the lower initial capital. However, regardless of the size of the deposit, certain hydrogeologic conditions must be present for ISCR to be successful. In-situ recovery methods do not require excavations of rock from the surface or underground, resulting in a dramatic reduction in surface disturbance when compared to conventional mining. With the ISCR method, what is visible above ground is the processing plant, well heads, piping, process solution impoundments and evaporation ponds. There are no waste rock piles, tailings impoundments, leach pads, or impacts associated with blasting and hauling. Other benefits include reduced initial capital, reduced dust and noise, and lower water use. Early testing of the in-situ copper recovery method by Occidental on the Van Dyke deposit east of Phoenix and by Kennecott at Safford Arizona in the 1970s produced encouraging results, but the permitting regime for a large-scale operation was not yet in place. Additional testing and commercial application of in-situ copper recovery techniques have expanded since the 1980s, most commonly in conjunction with open pit or underground mining operations. For example, several operations in Arizona (San Manuel, Miami East and Tohono) have used in-situ techniques to extract additional copper following conventional mining from parts of the deposits adjacent to open pits or underground workings. Where the rock has been broken up by conventional methods, the method is called “in-place” leaching. The US government has also been involved in assessing in-situ techniques. For example, joint research was conducted by the US Bureau of Mines and industry on the Santa Cruz deposit in Arizona; and both federal and state agencies have been involved to establish the comprehensive permitting regime that exists today. Currently there are several projects in Arizona being evaluated as stand-alone ISCR operations."

Jan 1, 2016

By E. M. Frizzell

An ongoing research program at the Spokane Research Center of the U.S. Bureau of Mines is directed toward investigating drilling parameters (thrust, torque, penetration rate, and drill revolutions) during the drilling of roof bolt holes. A system that measures these drilling parameters calculates the specific energy of drilling, and determines drill bit position has been developed by the Bureau and mounted on a roof bolting/drilling machine, through the use of a microcomputer, critical drilling parameters can be immediately interpreted and analyzed. This makes it possible to inform the operator of hazardous roof conditions. Initial results of this program are presented here.

Jan 1, 1990

By D. Boreck

The Bureau of Mines is conducting research on the feasibility of incorporating in situ stope leaching into active underground metal mines. Stope leaching, a modified in situ leaching technique, proposes to recover metals by leaching fragmented ore in existing underground openings and collecting and processing the metal-bearing solution to recover the valuable metals. If leaching solutions escape from the stope, either through geologic discontinuities or highly permeable zones in the rock, valuable metals dissolved in the solution may be lost. Escaping solutions may also contaminate ground waters. Consequently, in fractured rock, the characteristics of the fractures in the vicinity of the leaching stope must be understood before introducing actual leach solutions into the stope. Effectively characterizing a rock mass requires the integration of several disciplines including structural geology, borehole geophysics, hydrology, geochemistry, and mining engineering. This paper will focus on the general geologic and geophysical techniques that can be used to characterize the rock mass at an underground simulated stope leaching site. The results of several geophysical logging methods, tested at the site, are compared to the geologic core descriptions. Then, the? effectiveness of the different geophysical techniques in delineating fracture zones will be assessed. Knowledge gained through the geologic and geophysical analyses can be used to supplement results from hydrologic testing. This information can also be utilized in designing blast patterns and developing strategies for controlling or blocking movement of escaping leach solutions.

Jan 1, 1991

By J. Herhold, S. Plaum

"Increasing worldwide energy demands, coupled with desires for cleaner energy, have led to greater research of renewable energies. Strongly weather-dependent energy sources, e.g. solar and wind energy, are unable to provide a constant control energy to withstand the fluctuation of the extensive power systems during peak hours. The pump storage plant Nant de Drance in Switzerland will not only have the capacity of a nuclear power plant, producing 900 MW, but will also combine the environmental aspect and the demand for controlled energy. Nant de Drance is one of the pioneer projects for upcoming energy challenges and serves as a model for future pump storage plants. This paper focuses on the planning process and the project execution of interdisciplinary large-scale projects such as Nant de Drance, including project related data handling, communication systems and project handling skills. Furthermore, the paper discusses mining excavation in the context of large scale projects and their regional environmental challenges, e.g. high alpine rock mass on the site of Nant de Drance. PROJECT BACKGROUND Project Overview Nant de Drance is a 900 MW pump storage plant located in the Swiss Alps. To provide such a high energy storage, six turbines (reversible Francis type), each with a capacity of 150 MW, were installed. Due to the efficiency factor of 80% the pump storage plant is able to provide an energy production of 2500 GWh per annum. Construction of the pump storage plant, which has been selected as “Major Tunneling Project of the Year” in 2014 by NCE and ITA-AITES, will be completed over 10 years. Therefore, the project has been divided in six major phases outlined below: - Launch: 2008 - Access Gallery: 2010 – 2012 - Excavation KMA, KTR: 2011 – 2014 - Concreting KMA, KTR: 2014 – 2016 - Installation of HEM equipment: 2014 – 2018 - Tests & entry into service: 2017 – 2018 Figure 1 outlines the single process phases of the project. For the construction of the shafts, galleries and caverns, 1.7 million m³ of metamorphic rock with sedimentary origin (mica schist & paragneiss of the massif „Aiguilles Rouges“) were excavated. A tunnel network with a total length of 15 km was created. The machine cavern measures 194 m long, 32 m wide and 52 m tall."

Jan 1, 2016

By M. E. Smith

Chile is the world's largest copper producer and as such sets the standard of practice in copper SX/EW design. The authors summarize the liner systems used at many of Chile's major copper producers both operating and planned. The evolution in the state of the art is also discussed, considering both economic factors and Chile's burgeoning environmentalism.

Jan 1, 1994

By D. Malhotra

The effect of some of the reagents, namely hydrocarbon oil, Syntex (sulfated coconut oil surfactant), pine oil, sodium silicate, and lime, used at the Climax mill on the recovery and grade of molybdenite and gangue minerals has been investigated experimentally using factorially designed test approach in the laboratory. The results of the investigation are presented in two dimensional plots. The lower additions of lime (equivalent to a pH of 8 to 8.5) were desirable for maximizing recovery subject to constraints on grade. Higher additions of pine oil improved recovery, but only at the expense of grade. A mathematical model of the objectives of an operating plant was formulated and optimum reagent conditions obtained.

Jan 1, 1977

By F. Dehghani, M. Kebe, H. Askari-Sabzkoohi, T. Ghosh

The depletion of bauxite reserves around the world has necessitated the search for viable alternative sources of aluminum. The major non-bauxite source of aluminum is alunite [KAl3 (SO4)2(OH)6]. Lixiviation is the common industrial process to recover aluminum from alunite. Due to the presence of quartz (40%) as the main gangue mineral, this process causes the formation of Sodium aluminosilicate and Potassium aluminosilicate complexes that leads to loss of alunite, and chemical reagents. Thus, pre-concentration of alunite is required to remove the gangue minerals. Because of the low degrees of freedom (DOF) of alunite, froth flotation, as a preconcentration method, is a viable alternative to increase selectivity in downstream processes. In this work, the possibility of Alunite preconcentration with micro flotation and mechanical flotation cells was studied. The influence of type and dosage of collector, pH, solid percent, particles sizes were considered on the flotation. Flotation tests were designed based on Taguchi method, followed by performing based on surface charge differential between alunite and quartz on direct and revers flotation. In the reverse flotation, Ca+ 2 and Ba+ 2 were used to activate the quartz surface. Under optimum conditions of reverse flotation, alunite grade and recovery were 40% and 62.1% respectively. In the direct flotation, the surface of alunite was activated by F- . The grade and recovery were 50 and 89%, respectively.

Mar 2, 2022

By Bo-Hyun Kim, Mark K. Larson

"Bumps remain a critical safety concern in underground coal mining, despite significant advancements in engineering controls. These events occur when relatively high stresses in a coal pillar in conjunction with low confinement exceed the pillar’s critical capacity, causing the pillar to rupture without warning. Floor failure often occurs and can be an indicator of bump risk, as it is strongly associated with brittle failure known as spalling under a lower confinement. Significant floor heave at a western U.S. coal mine has been observed where the pillar width in a three-entry gate road system was 53 m, while no significant floor heave was observed where the pillar width in another gate road system was 22 m. This phenomenon was widely reported in the region and at another mine in another western coal field it has been reported that larger pillars are always associated with floor heave. In this study, a spalling model based on the S-Shaped brittle failure criterion and associated with the anisotropic characteristics of the materials was used in FLAC3D. The observed floor heave phenomenon associated with the larger pillars was demonstrated using this modeling approach.INTRODUCTIONFloor failure in a coal mines often inhibits longwall mining operation, as large displacement of floor strata, known as floor heave, interferes with travel, access, ventilation, and equipment operation. Aggson (USBM 1978) investigated floor heave in West Virginia where underclay is relatively strong and high horizontal stress is present. It was reported that the failure mode is mainly by buckling rather than by plastic flow.This study was developed as part of an effort by the National Institute for Occupational Safety and Health (NIOSH) to better understand rock mass behavior in longwall coal mines in highly stressed, bump-prone ground. More specifically, this study attempts to explain through numerical models small energy releases in the form of floor heave. The authors believe that brittle rock failure is associated with both floor heave and some bump mechanisms, if not directly involved in their cause."

Jan 1, 2019

By H. Colijn

Introduction Bulk commodity prices are ever increasing. This forces buyers and sellers in world markets to look more carefully at methods for obtaining an accurate accounting of commodity transactions in commerce and materials utilization in processes. Weighing and sampling inaccuracies can result in loss of income, product quality, and cost controls. So weighing and sampling accuracies are extremely important. They are the key components of managing the quantity and quality control aspects of bulk materials handling. This article will confine itself to the weighing systems and will deal with various aspects of system design, calibration, and operations. Emphasis will be placed on new developments and requirements in this field. Weighing methods To measure the gravimetric pull on a body being weighed (the load), the gravimetric force must be countered by an opposing force. Measuring this counter-balancing force thus becomes the measurement of weight. The conventional even-arm balance shows the concept of balancing an unknown mass with an equal known counterbalancing mass. But the loads encountered in industry generally range up to many thousands of pounds. So it is obvious that the even-arm approach is not practical. Thus, with the exception of direct load-bearing load cells, most of the weighing equipment uses some form of lever system. This is usually a combination of first- and second-class levers, to gain a mechanical advantage. These levers permit the load force to be counter-balanced and hence measured within a practical range. Lever systems not only perform this force-reducing action, they also serve to focus the load force at a single point, for convenient measurement. They align the force vertically in one direction so that measurement accuracy will not be affected by unrelated side forces. There are five basic methods of gravimetric weight measurements. That is, there are five basic types of opposing forces. • The first is the standard weight counterbalance. It uses a known weight to counterbalance the load directly or through a lever system.

Jan 9, 1988

By B. M. Kunar, C. S. N. Murthy, B. Rao K

Rock particle size has a very important significance in the mining industry, starting from blasting till the mineral processing. The present study was carried out to understand the particle size distribution in various sieves after conducting the ball milling process. The time of the grinding process was varied at different intervals. It was observed that 80% of the particles of both granite and marble rock samples passed through the 4800 μm sieve when subjected to grinding time of 40 minutes. Also, it was observed the number of particles that were retained in the smallest sieve of <75 μm was higher in the case of granite sample when compared to a marble sample. INTRODUCTION India is a major exporter of granite and marble stones. The major use of marbles and granites are constructing walls and floors. There are several machining processes that are applied before it is used as floors and walls. During this process, wastes are produced these wastes are used in various ways. These include use of powders for clay products (Segadães, Carvalho, & Acchar, 2005), as an additive in cement production (Aruntaş, Gürü, Dayi, & Tekin, 2010), to enhance the properties of brick ceramics (Saboya, Xavier, & Alexandre, 2007), in constructing bricks (Bilgin et al., 2012) and as an additive in concretes (Aliabdo, Abd Elmoaty, & Auda, 2014). Usually, the powder form of marble and granites are used as an additive in the above-mentioned applications. Powders of marble and granite are obtained through the grinding process. One such process of grinding is the ball milling process. In the ball milling process, a quantity of samples along with the charge quantity consisting of steel ball is subjected to a grinding process within a closed chamber as shown in Fig. 1. An even particle size can be obtained through sieving the material after subjecting it to grinding. The present study is planned to understand the particle size distribution in various sieves due to varying time and charge quantity in the experiment. Only time was varied to understand the amount of particle distribution in the case of granite and marble rock samples and a comparison is drawn. A statistical model was developed for marble rock specimen considering the data obtained by varying time and charge quantity in the ball mill experiment.

Jan 1, 2019

By P. A. Roberts

A proposal for a modified in situ leaching method for extracting gold from oxidized gold ores using a non-cyanide lixiviant is described. A non-cyanide lixiviant is suggested because of the obvious concerns posed by injecting cyanide-bearing solutions into the subsurface. Oxidized gold ores were chosen as a focus because earlier research on the use of sodium thiosulfate as a lixiviant under anaerobic conditions indicated that the presence of pyrite led to rapid thiosulfate breakdown. A reconnaissance research program involving ore characterization and hydrometallurgical test work on samples from four Australian ore deposits and preliminary reactive transport modeling studies was carried out. This work showed that lixiviant-oxidant combinations of sodium thiosulfate and ferric EDTA and iodide and iodine are both capable of extracting high percentages of accessible gold from the selected samples in bottle roll tests under anaerobic conditions. The ore characterization and reactive transport studies suggested that both physical and chemical methods of permeability enhancement may be required to lift bulk permeability and the availability of gold for dissolution to sufficiently high levels to obtain adequate gold recoveries. Assuming that such methods prove to be both necessary and economically viable, the mining method would no longer be regarded as simple in situ leaching. Therefore, the term ?in-place leaching? has been adopted for the proposed gold extraction system.

Jan 1, 2010

By Peter Zhang, Daniel Su, Berk Tulu, Bo Hyun Kim, Zoheir Khademian

Over 2,000 shale gas wells have been drilled in the Pittsburgh Seam longwall reserves. As longwall panels are laid out, some of these shale gas wells must be located in longwall chain pillars. With longwall mining on both sides and the constraint of chain pillar size, gas well in chain pillars are subjected to longwall-induced ground movements and stresses, which could induce deformations in gas well casings Casing deformations are associated with several factors such as overburden geology, surface topography, setback distance, and casing construction. Overburden geology is one important factor that largely determines the locations and levels of deformations in gas well casings Previous NIOSH gas well research has found that casing deformations above the coal seam horizon are smaller under deep cover than unde shallow cover and that casing deformations could occur at the coal seam horizon under deep cover. Recent mine-by cases have provided more insights into the locations and amount of longwall-induced casing deformations as well as the potential occurrence of a large casing deformation at the coal seam horizon. This paper presents three recent mine-by cases with shale gas wells in the chain pillars between two adjacent longwall panels under different overburden depths. Casing deformations were measured by multi-finger caliper surveys and predicted with numerical modeling. With the established numerical model, the effect of overburden depth was further analyzed to investigate the potential occurrence of a large casing deformation at the coal seam horizon under deep cover. These mine-by cases not only provide a general demonstration of how overburden depths can affect longwall-induced stresses and deformations but also give a good indication about the level of casing deformations that could occur under different overburden depths. The study concludes that (1) casing deformations reduce with increase of overburden depths at the gas well; (2) a cementing alternative with production casing uncemented is an effective means to eliminate production casing deformations; and (3) large plastic casing deformation could occur in the production casing at the coat seam horizon under deep cover. The experience and knowledge gained from these mine-by cases would help longwall operators and gaza companies to take appropriate measures to minimize the influence of longwall mining in shale gas wells in chain pillars.

Jun 25, 2024

By Daniel de la Rosa, Juan Manuel Mayoral, Damián Vital

"This paper presents a numerical study regarding the loads, and the corresponding damage, taken by the primary and secondary lining of a tunnel built in cemented fine-grained stiff soils. This study aims at establishing more rational design criteria that take into account explicity the lining performance. A 3.5 km long tunnel to be built in a densely populated northwest area of Mexico City, was considered as case study. Series of three-dimensional finite difference models, developed with FLAC3D, were used to simulate the tunnel construction, and to compute the ground settlements, internal forces, bending moments, and displacements acting both on the primary and secondary tunnel linings. Interaction diagrams were used to study the lining performance. Several advancement lengths, and tunnel covers were considered to establish their impact on the loads transferred to the tunnel lining. A practice-oriented damage criterion for tunnels was proposed based on the interaction diagram analysis. INTRODUCTION Lining performance during conventional tunnelling, CT, as defined by the International Tunnel Association, ITA (ITA 2009) is strongly affected by the construction procedure. Special attention must be taken in cemented fine-grained materials, such as those found in the northeast portion of Mexico City, due to the potential of fragile failure (i.e. the soil fails suddenly without important deformation) that these soils may exhibit. During CT, it is assumed that the ground strength contributes to the stability of the excavation, as long as the lining is built correctly. It is common practice to consider two structures, which together form the tunnel support: 1) A primary lining, which is a flexible support, which allows excavation walls to deform to mobilize part of its shear strength, and thus contributes to the tunnel self-stability, and 2) A secondary lining. Commonly, the primary lining consists of several layers of shotcrete. In this case the installation method guarantees perfect contact between the lining and the excavation perimeter. The secondary lining, if required, is used to withstand the load conditions in the long term and also has an esthetic function. This paper presents a numerical study aimed at establishing a performance damage criterion for the primary and secondary lining design in cemented fine-grained stiff soils. Due to the lack of data, the strength and deformation parameters were established through empirically-derived relationships. Three-dimensional finite difference models were developed to simulate the tunnel construction, and compute ground settlements, internal forces, bending moments and displacements acting both on the primary and secondary tunnel linings. Interaction diagrams, along with a damage criterion were used to study the lining performance. From the results gathered insight was gained regarding tunnel lining performance during CT."

Jan 1, 2016

By H. S. Castro

The by-product molybdenite technology in Chile is reviewed. Flowsheets, reagents and some operation features for the actual six Chilean moly plants(Chuquicamata, El Teniente, El Salvador, Andina, Las Tortolas and Pelambres), are presented. The chemical and physicochemical factors involved in the depression of copper and iron sulfides during the selective flotation of molybdenite, with sodium sulfide, sodium sulfhydrate, anamol-D and LR-744, are discussed. Advances in technology to solve problems of excess of lime (precipitation with sulfuric acid); excess of residual flotation reagents (activated carbon and kerosene); and optimization of depressant consumption (Eh control, nitrogen and low-oxygen air), are discussed.

Jan 1, 1998