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By Serdar Aktaş, Burcu Nilgün Çetiner

According to critical statistical studies, antimony is one of the rarest elements in the world, and global resources could be exhausted by 2050. In light of these observations, its extraction will be costly due to poor-quality ore, deep mining, remote locations, and high energy consumption. In the present study, an alkaline leaching process was carried out on stibnite concentrate to evaluate the effect of reaction parameters on the percentage of antimony extraction. The leaching efficiencies of different sulfur and hydroxide sources were studied and compared to one another to create a better understanding of the reaction process. Kinetic models were investigated to identify the reaction pathway and calculate the activation energy. The activation energy of the stibnite dissolution was assessed as 19.13 kJ/mol using a two-dimensional diffusion-reaction model. The value of activation energy indicates the quantity of energy necessary for a reaction to proceed. As expected, potassium hydroxide leaching was significantly more successful than was sodium hydroxide; however, in terms of economics, the use of sodium hydroxide was found to be more cost-efficient. Interestingly, this finding indicated that caustic leaching is still the most effective method for stibnite extraction.

Jul 23, 2020

Clean Diesels fuel-borne catalyst, Platinum Plus, helps improve fuel economy for all engines up to 10 percent while reducing particulate emissions by up to 25 percent. When used with a simple diesel oxidation catalyst, particulate emissions can be reduced by 30 to 50 percent. The use of Platinum Plus enhances combustion in the cylinder, burning fuel more completely. This reduces CO2 and other greenhouse gases and lowers total operating costs by improving fuel economy.

Jan 1, 2007

By M. A. Barclay, D. Samson, A. M. Esteves

Several companies have adopted policies and standards aimed explicitly at increasing ‘local procurement’, recognising that local economic participation has benefits for companies and communities alike. From a corporate perspective, local economic participation is seen as one means of maintaining a social license to operate, as well as ensuring reliability of supply by having a supplier located nearby. From a community perspective, the participation of local businesses in the resource project is a means by which the benefits of resource development can flow into their communities. This paper is based on the research undertaken to produce a good practice guide for the mining, oil and gas sector. Our research revealed that the extent to which the local community will actually benefit from local procurement initiatives is dependent on the capacity of the community to supply goods and services to the project and, even more importantly, on its ability to adapt to the inevitable changes that accompany large-scale resource development. We provide guidance on adapting impact assessment tools to guide planning of procurement interventions.

Jan 1, 2011

By T. A. de Almeida, M. de Paiva Bueno, M. Powell

The mining industry is one of the foundations of modern society, providing not only the raw materials needed to maintain a contemporary lifestyle, but also serving as a basis for the development of future technologies. From the most basic components of an appliance to the materials needed to design an electric car or a space rocket, each raw material has gone through a painstaking procedure of extraction and processing, and ways to make this process more efficient will be of great help to meet an ever-increasing demand for minerals. One of the biggest challenges when extracting mineral resources is to measure the variability of the mineral body prior to processing. Comminution is the most power-demanding stage, and the lack of geometallurgical testing, often for financial reasons, may result in an inefficient operation. The Geopyörä Rock Breakage test was developed with the objective of making mineral variability data more accessible by providing both standard comminution parameters and rock mechanical properties at low cost, and with a modest sample size, allowing a larger number of samples to be tested to reduce uncertainties and assure productivity. The objective of this paper is to present the results of an extensive validation of this new rock breakage method against two of the main tests currently in use, namely the SMC® and Bond ball mill work index tests. More than 100 samples have been tested and the results compared, showing that the new method can accurately estimate the parameters of the traditional tests. This confirms that the new test is a reliable tool for comminution and geometallurgical tests.

Feb 1, 2023

By Saghar Farajzadeh, Fatemeh Kazemi, Ataallah Bahrami

Spirals, the most common equipment for the separation of heavy minerals such as chromite, are greatly affected by size distribution and the liberation degree (hence the specific gravity and size) of the feed particles. In this study, the efficiency of spirals in separation of low-grade chromite particles has been investigated by studying the distribution of grade, size distribution and liberation degree of feed, concentrate, and tailings of spiral. For this purpose, mass balance constraints were applied to the spiral-containing chromite processing circuit. Afterwards, the grade variations and size distributions have been investigated. According to the results, when the feed to the spiral has a larger size distribution, the enrichment ratio of the feed is 1.32 and, with the smaller feed size, this value has increased to 1.99. When the spiral feed has a larger size distribution and higher specific gravity, the recovery of chromite increases with increasing particle size up to 250 microns, and then with increasing particle size, recovery decreases with a relatively steep slope. Evaluation of spiral efficiency with respect to particle liberation degree has also shown that despite the high degree of liberation of spiral feed in size fractions smaller than 75 microns (88.9%), the liberation degree of spiral concentrate and tail in this faction is equal to and less than that of feed, which can indicate poor spiral performance in these size fractions.

Oct 27, 2020

By R. D. Lord

This paper deals with the search for the best practical means of storing sulphide bearing tailings, where there is no residual excess of carbonate material. It is the common experience that the sulphide content decomposes, with the aid of bacterial action, and the resulting sulphuric acid escapes, along with any heavy metal solutes, through embankments that are usually porous to some degree. The problem is typified in the tailings of the uranium operations of Elliot Lake, Ontario, where mining started some 20 years ago. The approach to tailings disposal paralleled the practice for other hydrometallurgical plants treating gold and base metal ores. Impoundment areas were designed to retain solids, and a clear and neutral overflow was considered satisfactory practice. Now experience has shown that these areas, some idle for over a dozen years, release acids, in seepage and overflows, to an unacceptable degree. To protect natural water courses neutralizing plants are operated wherever required. Lime slurry is fed continuously into the tailings outflows in a quantity sufficient to raise the pH to 8.5 and precipitate heavy metals that may be in solution. The objection to this procedure is that the plants will require servicing indefinitely, unless a better remedy is found.

Jan 1, 1975

By Morgan M. Sears, Gamal Rashed, Michael M. Murphy, Brent Slaker

A parametric study was conducted using FLAC3D numerical models to examine the impact of oblique loading on the strength and yield pattern of a stone pillar using two simplified geometry types. In type-1 the side walls of the pillars were assumed to be perpendicular to the roof and the floor, while in type-2 the side walls were assumed to be vertical. These two geometries are frequently used to simplify/model the creation of pillars in dipping mines. Results from the numerical modeling indicate that dipping pillars have reduced strength compared to horizontal pillars, and they are at an elevated risk of failure. Also, an asymmetric failure propagation pattern could be obtained depending on the interaction between the pillar width/height (W/H) ratio, seam dip, in situ stresses and pillar geometry.

By H. N. Dougherty

"The National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR) ventilation gallery was used to study methane-air flows around a continuous miner mockup with water sprays and a scrubber fan. Methane gas was released from pipes located at the face to simulate face gas emissions. Methane concentrations and air velocities were measured while varying parameters such as airflow quantity, entry width (sump or slab cut), and face ventilation configuration (blowing or exhausting curtain). Test data showed a similar pattern of methane concentrations at both low and high airflow quantities, but a difference in the distribution of methane concentrations between narrow and wide entry widths. Most tests showed that blowing face ventilation was more efficient in diluting methane than exhausting ventilation, similar to observations made in previous empty gallery studies. The patterns of airflow and methane concentrations observed in this testing can further improve the understanding of airflow in and around the CM and face, promoting effective use of face ventilation to improve the health and safety of miners. INTRODUCTION Attaining an accurate understanding of airflow distribution at the continuous miner face is instrumental in maintaining a safe mining environment. US mining regulations require that sufficient airflow must be directed to the deepest penetration of the face and render harmless contaminant gases, as verified by the Mine Safety and Health Administration (MSHA). Currently, continuous miner face air readings can be taken in the last open crosscut and at the inby end of the curtain mouth. By measuring adequate airflow in a pre-determined area it is accepted that a sufficient quantity of that air exists to sweep the face of harmful dust and gasses. Unfortunately, due to the location inaccessibility, precise face velocity readings cannot be measured in situ. Face velocities may be estimated through computer-simulated programs based on laboratory models. Improving upon previous empty gallery testing and to more effectively determine representative face methane readings, a mockup of a continuous miner with water sprays and a scrubber fan was used in the current study to further refine face airflow conditions that would be closer to actual mining conditions."

Jan 1, 2016

By Jieliang Wang, Shiwen Yi, Zhao Cao, Peng Zu

Bayan Obo ore contains mainly bastnaesite, monazite and associated iron, fluorite, calcite, dolomite, barite, and trace amount of columbite. Due to its complex mineral compositions and similar mineral properties, it is difficult to separate and obtain rare earth and fluorite concentrates with high purity by conventional magnetic separation and flotation. In this paper, a stepwise magnetic separation process comprised of wet permanent magnetic separation (PMS), wet electromagnetic separation (EMS), and superconducting magnetic separation (SCMS) was proposed to pre-concentrate iron, rare earth, and fluorite minerals from Bayan Obo ore. The results showed that iron, rare earth, and fluorite preconcentrates with high purity and low impurity content could be achieved, which might be helpful to shorten the technological process and improve the separation efficiency for the subsequent flotation of iron, rare earth, and fluorite minerals.

Sep 15, 2020

By H. R. Manouchehri

"Pyrrhotite (Po) is one of the most abundant sulfide minerals in processing industry and must be rejected in most cases. Particularly, Po rejection and its selectivity against pentlandite (Pn) have long been a challenge due to similarities in the mineral composition of the two minerals and the collectorless flotation characteristics of Po. Xanthates have been widely used to promote sulfide mineral flotation; however, in the presence of xanthates, the redox potential established at the mineral/solution interface is most important, determining the flotation performance. In this paper, the importance of electrochemistry in Po and Pn flotation has been demonstrated and a comprehensive study was conducted on two different feed streams (i.e., magnetic concentrate and scavenger cleaner streams, containing magnetic and nonmagnetic forms of Po, respectively), from Vale’s Clarabelle Mill in Sudbury, Ontario, with an objective to determine if improvements in Po rejection and Pn recovery could be achieved by controlling pulp electrochemistry. By conducting a series of flotation tests under different Eh conditions and reagent usage schemes, it was revealed that higher Po content in the magnetic stream may protect Pn from being oxidized, improving Pn recovery. The results indicated that at low oxidizing pulp chemistry, the rest potential for the Pn is still high enough to allow the formation of dixanthogen to promote its flotation. Using a Pt electrode, it was found that by controlling pulp potential at -50<Eh< +50 mV, the Pn recovery and Po depression would be satisfactory. The results, using mineral electrodes (Outotec Chena analyzer), indicated that selective separation can be achieved if low-to-moderate oxidation potentials (0 to 100 mV) or reduction (0 to -100 mV) potentials are monitored using Pn and Po electrodes. Mixing two streams at 50:50 wt % would be possibly beneficial in selective separation.IntroductionPyrrhotite (Po), Fe1-xS, is one of the most abundant sulfide minerals in the processing industry. It is an iron-deficient sulfide that occurs either in monoclinic or hexagonal form. The monoclinic one is richer in sulfur and is ferromagnetic, whereas the hexagonal Po is poorer in sulfur and has no magnetic properties. In general, the ferromagnetic properties of natural Po increase with increasing sulfur content. Although Po holds significant iron content, it is not used as a feedstock for the iron and steel industry due to the difficulty in achieving complete removal of sulfur. The common availability of iron oxide ores makes the iron sulfides irrelevant for the steel industry."

Jan 1, 2015

By Frank Agyemang, Zainab Nasrullah, Richard LaDouceur, Mehran Saddat

To sustain the circular economy, defence applications, and other renewable technologies, recycling rare earth elements (REEs) and other critical elements from their secondary resources is important. This cause has resulted in rigorous research and development for viable extraction and separation of REEs. Previously, Sm-Co recycling has been done with technologies, which fall under the categories of pyrometallurgy, physical separation, and hydrometallurgy. All these methods have limitations associated with energy, cost, and environment. Reportedly, the chemical leaching technology has successfully recovered and separated Sm-Co. Still, it has limitations associated with slow mass transfer and leaching kinetics, and there is a need to intensify the process to make it time efficient. This approach has also adversely impacted the environment by an extensive use of toxic, corrosive, non-selective, and expensive reagents. In this research study, chemical leaching of Sm-Co was performed using this new class of solvents, Deep Eutectic Solvents (DESs), which fall under the category of ion metallurgy. Four different DESs were used, proven to be green, non-toxic, biodegradable, cheap, and selective for cobalt over samarium by 82% leaching conversion. To improve the slow mass transfer and leaching time, this new technology of resonant vibratory mixing (RVM) was also tested. RVM intensifies mixing by establishing near instantaneous, low energy mixing conditions through resonance. It has been shown to improve the adsorption kinetics and was tested for the leaching kinetics. Four combinations of DESs were prepared, which are made up of two quaternary salts: Choline Chloride and Tetra Butyl Ammonium Chloride, and three organic compounds: Oxalic Acid, Urea, and Ethylene Glycol. These combinations were used for chemical leaching of Sm-Co with leaching factors of time, temperature, and type of DESs. After leaching, the samples were tested with and without resonant vibratory mixing with conditions of time, intensity (%), and type of DESs. Samples were analysed with Induced Coupled Plasma - Optical Spectroscopy (ICP - OES). Future work will involve a life-cycle assessment to assess the RVM technology with other conventional mixers, and an extensive study of DES properties to improve selective leaching.

Feb 1, 2025

By Gabriele Eccher, Michele Caponero, Paolo Cucino, Roberto D’Angelis

"This paper describes the optic fiber structural monitoring system implemented for Pavoncelli Bis tunnel. The paper highlights the optic fiber sensors customization capabilities, how they smoothly fit precast concrete lining processes and TBM operations, and how a lifelong service monitoring can be achieved. An overview of readings’ evolution during excavation concludes the paper.INTRODUCTIONPavoncelli Bis is a 10 km hydraulic tunnel designed to by-pass the existing Pavoncelli tunnel which experienced severe damages during the 1980 Irpino-Lucano earthquake, in south of Italy (Barla 2009). Pavoncelli Bis excavation work commenced in 1988-90, however, when excavation approached pk. 0+583 in 1992, water percolations became more and more consistent and resulted in work suspension. The tunnel was eventually sealed at pk. 0+383, leaving a flooded section between pk. 0.383 and pk. 0+583. Work resumed in 2012 where EPB-TBM excavation was adopted to cross the flooded section and to overcome complex hydro-geological conditions in various lito-types and, in particular, in the Varicolori Clay-shales area (Figure 1).Consequently, stress evolution monitoring is extremely important during construction and during the service life of tunnel lining in clay-shales and in faults areas. In particular, the paper focuses on the monitoring system proposed for the newly EPB-TBM excavated portion from pk 0+583 onwards where optic fiber sensing technology was chosen for its reading stability and reliability in presence of water and its ability to be connected in series and remotely interrogated at kilometers of distance. FBGS OPTICAL FIBER SENSOR TECHNOLOGYFiber Bragg Grating Sensors (FBGS) are gaining increasing attention in the field of experimental stress analysis. Basically, Fiber Optic Bragg Sensors are strain-measuring devices and therefore provide many of the advantages of the well-known metal foil strain gages (Kreuzer 2007).Bragg gratings are written into so called single-mode fibers. These fibers consist of a very small inner core of 4 to 9 µm diameter and an outer part (cladding) of pure glass (SiO2) of 125 µm diameter. The difference of refraction indexes between inner core and cladding causes the light to propagate only inside the small core."

Jan 1, 2016

By E. W. Davis

This paper deals with the role of the Maintenance Department in a milling operation; specifically, the Mines Development, Inc., processing plant at Edgement, South Dakota. The goal of very maintenance department is the smooth and uninterrupted operation of the plant it serves, To achieve this goal, maintenance men adapt various features and procedures into a program designed to fit the characteristics of their particular plant operation. A few of the basic elements of a sound maintenance program are: 1, A periodic preventive maintenance schedule. 2, A systematic inspection and lubrication procedure. 3. A training program for maintenance personnel. 4 A good equipment-history file system, 5. A carefully planned spare parts inventory.

Jan 1, 1962

By D. H. Stonehouse

There is no such thing as an industrial minerals industry. There are, however, many industries operating in the general field of industrial minerals. And although we use the phrase "industrial minerals industry" out of sheer convenience, the only common denominator among, say, the potash mining and processing industry, the sulphur-sulphuric acid industry and the granite industry is, in fact, that they each are exploiting an industrial mineral resource. May I quote the person whom I consider to be the reigning Mr. Industrial Minerals, Robert L. Bates, who in the 4th edition, 1975, of Industrial Minerals and Rocks states: "An industry is considered to belong to the industrial minerals field if its operations consist of extraction and processing, but not manufacturing. Thus the mining and beneficiation of feldspar is a mineral industry, but the manufacture of ceramic products is not. In the cement and lime industries, processing merges into manufacture, and the line is less distinct. It disappears altogether in a plant that extracts salt as artificial brines, and makes sodium and chlorine chemicals, all under the same roof."

Jan 1, 1981

By W. K. Choi

Using electrochemical techniques it was demonstrated that bioleaching of gold from refractory pyritic ores is a complex phenomenon. Many intermediate electrochemical reactions were found to be involved in the oxidation of pyrite, using cyclic voltammetry and carbon paste-pyrite containing electrode. Furthermore, the oxidation process was controlled by solid-state diffusion as suggested by chronoamperometric and chronopotentiometric measurements. Using the Sand&apos;s approach, the activation energy of solid-state diffusion was found to be = 22.4 kJ. After bioleaching, 96% gold was extracted from the leach resi¬due with a thiourea solution in 1 hour. A generalized model for the mechanism of pyrite oxidation has been presented.

Jan 1, 1990

By X. Tang, N. Ripepi

The Langmuir model has been widely used for the coal-methane sorption process through an isothermal test. However, even though the temperature-dependent Langmuir model was recognized theoretically and experimentally, the quantitative relationships between the Langmuir constants a and b and temperature have not been clarified and confirmed by laboratory test data. This paper collects 158 methane-coal sorption data under different temperatures that apply the Langmuir model to the relationships between the Langmuir constants a and b and temperature. Even though the Langmuir model cannot be used to show the physical state of methane adsorption on coal, it is widely used because of its simplicity and the reasonable explanation of its parameters a and b. The results from these published isothermal tests indicate that (1) there is no consistent relationship between Langmuir constant a and temperature, (2) the Langmuir model is a temperature-dependent model whose temperature-dependent feature is mainly shown by the relationship between the Langmuir constant b and temperature, and (3) the relationship between the Langmuir constant b and temperature can be described by both exponential and linear relationships with dried coal. This paper provides a database for the temperature-dependent Langmuir model that can be used for the reservoir simulation of coalbed methane reservoirs and for the coal seam degasification modeling of underground coal mines, considering the heating effects induced by geothermal and heat injection through factors such as hot water, hot steam and ultrasonics.

Jan 1, 2016

By Reinhard Gertl, Soroush Dabiri, Juan-Carlos de Rueda

The Tunnel of Guillermo Gaviria Echeverri, spanning 6.05 miles, will be Latin America’s longest road tunnel, is currently under construction in Colombia’s Antioquia Department with a single bidirectional tube connected to a parallel rescue tube through multiple cross-passages. The study faces challenges in implementing the prescriptive semitransversal ventilation system due to design restrictions. Different ventilation concepts are eplored to nd the most suitable system for regular operation and re scenarios. A quantitative ris assessment evaluates each alternative system and identies the longitudinal ventilation system, accompanied by ris mitigation measures, as the safest choice, since it surpasses the prescribed semitransversal ventilation concept.

Jun 23, 2024

Due to deposit shape and dimension, narrow vein makes reserve modeling, geological control, stope design, drill and blasting more challenging. It needs high standard quality control as errors can be created easily, which could cause significant amount of ore loss or dilution. From channel sampling, survey control, reserve modeling, drill hole design, blasting, communication with underground drillers to backfill, this paper illustrated every step and its quality control of a long hole stope mining. Compared to other narrow vein mining methods (cut and fill and shrinkage), long hole stoping means higher production, less labor, and significantly lower cost when deposit characteristics allowed.

Jan 1, 2012

By Huiqin Yao, Dongmei Liu

The study investigated the potential use of low activity circulating fluidized bed combustion (CFBC) ash and phosphate tailings for the production of a filling material based on the cement. The phosphate tailings were used as aggregate and consolidated by cement and CFBC ash. The results showed that the bleeding rate and fluidity of all mixtures decreased with the increasing the amount of CFBC ash. The fluidity of filling slurry is highly related to the experimental factors such as the content of sulfur solid ash, B/A ratio, and mass concentration. The replacement of CFBC ash ranging from 20 to 40% led to a significant decrease in setting time and an obvious increase in compressive strength, but the above effect was obviously weakened when reducing the mass concentration and B/A ratio. The hydrated calcium silicate gel and ettringite generated from the hydration of cement and CFBC ash were the main sources of strength for the filling materials. When the recommended proportion was 1/6 binder/phosphorus tailings ratio, 76% solid content, and 40% CFBC ash replacement, the filling material still met demands on working and mechanical properties; at the same time, the utilization of CFBC ash and phosphorus tailings was maximized.

Oct 11, 2021

By Tyler A. Dawson, Ryan P. Butler, Timothy Gualandri, Jason R. Edberg

"In the early 1920’s, the City of Tulsa, Oklahoma constructed an approximately 8,238-foot long tunnel, the Tiawah Tunnel, through bedrock. Voids behind the concrete tunnel liner were detected via probe drilling in early 2000 as part of an interior visual condition assessment. In 2012 and 2015, conditions along the entire tunnel were efficiently assessed through geophysical investigation using ground penetrating radar (GPR) along the inner tunnel crown and at various select locations within the tunnel. Fifty-seven (57) potential voids, extending up to 19 inches in depth and 12 feet in width, were detected with 1,000 MHz GPR and confirmed through probe drilling with approximately 80% accuracy. GPR proved to be an efficient and reliable technology for void detection behind concrete tunnel lining. This paper highlights the geophysical investigation and how geophysical efforts were combined with other investigation efforts to definitively determine the presence of voids outside of the tunnel lining.INTRODUCTION The city of Tulsa, Oklahoma has a population of about 400,000 people. The original source of water for the city was the Arkansas River. The first pumping operation provided untreated water to homes and businesses in 1904. The residents of Tulsa found this water to be unacceptable due to the high levels of salt and gypsum present. As the city grew, land and storage/treatment facilities were acquired in order to obtain and distribute a more suitable raw water. The raw water needs for the city are currently satisfied by transport and treatment of about 100 million gallons per day (MGD) of water from surface water sources. Water is transported many miles from Spavinaw/Eucha and Oologah lakes to Yahola Lake and the Lynn Lane Reservoir (totaling over 3-billion gallon capacity). From here, the raw water is treated and transported to the various customers (City of Tulsa 2015). The Tulsa Metropolitan Utility Authority (TMUA) is responsible for the operation and maintenance of the raw water transport system."

Jan 1, 2016