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By A. J. Barry

Two methods of testing anchorages of headed expansion-type mine roof bolts were investigated by the Federal Bureau of Mines to determine whether they are acceptable for general use. In both methods a load was applied to a tightened bolt with a hydraulic jack. A total of 80 tests, 40 using each method, was conducted in 4 test areas in 3 commercial coal mines. Electric resistance strain gages were used in all tests to indicate true bolt load as the bolt was tightened and when an additional load was applied with the hydraulic jack. The results indicate that: 1. The relationship between the true bolt load and the jack load will vary according to the test method until the two loads become equal. The bolt load-jack load relationship below this point can be determined only with strain gages. 2. The point at which the two loads become equal can be estimated by noting the load when the hardened washer becomes loose in one method, and when the bearing plate becomes loose from the roof in the other. It also can be approximated for either method of testing by noting the load when the first abrupt change in the slope of the jack load-bolt displacement curve occurs. 3. The anchorage characteristics of the test bolt can be determined from the data obtained from either method by examining the slope of the jack load-bolt displacement curve above the point at which the true bolt load is equal to the jack load.

Jan 1, 1960

By Carla A. Kertis

Because coalbed discontinuities often pose serious economic and safety problems in underground coal mines, criteria were documented for the recognition and prediction of discontinuities in advance of mining. Pennsylvanian strata in Indiana and Armstrong Counties, PA, were deposited as part of fluvio-deltaic complexes with channel-phase sandstones as the predominant type of coalbed discontinuity. Coalbed isopach maps constructed for this study delineated numerous want areas (areas of no coal) with elongate to linear geometries. A comparison of coalbed isopach and corresponding sandstone isolith maps of the study area revealed many examples of a thick-sandstone, thin-subjacent-coalbed relationship. Nearly 60 pct of the want areas in the study area were found to lie subjacent to thick (> 20 ft [6 m]) sandstone accumulations. In addition to erosion of the coalbed, channels may contribute to coalbed splitting, coalbed thinning over paleotopographic highs, abnormal coalbed thick- nesses, and deterioration of coal quality. If these features are considered, then approximately 80 pct of all interruptions in the economic coalbeds in this area result from channel activity. By using the criteria developed in this study and described in this Bureau of Mines report, the occurrence of coalbed discontinuities may be predicted and anticipated in advance of mining.

Jan 1, 1985

By John J. Mulligan

Lead-silver deposits in the Omilak area, on the western slopes of the Darby Mountains, Seward Peninsula, Alaska, were investigated by the Bureau of Mines, during the 1953 and 1954 field seasons, as a part of the U.S. Department of Interior's continuing program for the development of Alaska's resources. The Omilak area was the scene of early day prospecting and mining activity. The Omilak mine, which operated from 1881 to 1890, was the second producing lode mine in Alaska; the first was a small gold mine near Sitka. Several hundred tons of ore were produced at the Omilak mina; as an indication of grade, 41 tons shipped from Omilak in 1889 contained 75 percent lead and 142 ounces of silver per ton. A prominent, nearby occurrence of lead-silver minerals, found but not explored during this period, has since become known as the Foster prospect. Subsequent exploration of this prospect revealed an abundance of massive galena occurring on an outcrop and as float scattered through limestone talus. Evidence of lead deposition, together with the generally high silver content of lead ores previously shipped from the district, indicated that deposits might be found which would be commercially valuable even in this remote area. To investigate the possibility, the Bureau of Mines made a reconnaissance of the Omilak area and did bulldozer trenching, diamond core drilling, and sampling at the roster prospect. Data resulting from the investigation are presented in detail in this report and are summarized in the following paragraphs.

Jan 1, 1962

By S. Gallagher

If we consider ergonomics to be an exercise in matching job demands to worker capabilities, one of the principal capabilities we must be concerned with is that of human strength. Our ability to evaluate different characteristics of muscular strength has increased dramatically over the past couple of decades with the development of new and increasingly sophisticated instrumentation. One would think that armed with such advanced techniques, we might be able to develop methods to conclusively identify workers at risk of injury in physically demanding jobs. Unfortunately, this has not yet proven to be the case. Instead, what these instruments have continued to point out is how intricate a function muscular strength really is, and how complicated and ambiguous its relationship is to musculoskeletal injury. While we cannot just use isolated tests of strength to specify precisely who may be at risk of injury, studies have indicated that strength testing can be a useful tool for job design and, under certain circumstances, selection of workers for demanding jobs. However, because strength is such a complex phenomenon, there has often been some confusion regarding the proper application and interpretation of strength tests in ergonomics, especially among persons not thoroughly familiar with the limitations and caveats associated with the available procedures. The purpose of this chapter is to discuss some of the fundamental principles of strength assessment in ergonomics, so that these procedures can be better applied to control the risk of musculoskeletal disorders in the workplace 1.1. What is Strength? (And what are we Measuring?) Many of the complications associated with strength assessment arise from the simple fact that even our most sophisticated machinery does not directly measure the force or tension developed by a muscle in a living person. Instead, we can only observe the consequences of force development by a contracting muscle, or more likely, by a combination of muscles There are many ways in which we can measure the effects of muscular contraction, and the techniques we use can have a dramatic impact on the strength readings we will obtain. Consider the situation illustrated in Figure 1. In this example, the muscle exerts a constant force of 1000 Newtons (N). However, the forces we measure can vary quite dramatically depending on where we place the force cuff - from 167 N if we place it near the wrist to 500 N if we place it near the elbow. Which value should we select as properly representing the muscular strength for this elbow flexion exertion? The preceding example illustrates some important points with regard to strength assessment. Perhaps the most important is that "muscular strength is what is measured by an instrument" (Kroemer et al. 1999). It should also be clear from this example [ ] that two researchers could perform an elbow flexion strength experiqent on the same group of subjects, but if each selected different force cuff positions, they might end up with wildly differing estimates of strength. Differences in the strengths of various muscle groups in the published literature may be the results of differences in the procedures and measurement methods used by the experimenters Thus, it is critical that any strength data presented be accompanied by a detailed account of the manner in which the data were obtained. A few additional points need to be made with regard to the testing of human strength. We must be clear that what we are obtaining in such tests are not a person's maximal strength capability, but their maximal voluntary strength. The voluntary nature of the exertion introduces an unknown, but surely substantial, amount of variability in our measurements of strength. One can imagine two subjects with identical muscular strength capabilities, but with varying levels of motivation or discomfort tolerance, for example. We are likely to observe considerable differences in the voluntary force exerted by the two, but it should be understood that such results may be largely the result of psychological factors, and not differences m muscular strength per se. The important point to be made here is that not only are we unable to directly measure muscular force, what we are able to measure is modified by an invisible filter - a filter subject to a wide variety of influences and which will differ considerably for every person we test To make matters worse, this filter would be expected to change even within a given individual on a given day. From the foregoing discussion, one can perhaps better appreciate some of the difficulties with establishing a definitive relationship between an individual's measured strength and that individual's risk of injury.

By J. F. Barkley

"A knowledge of the carbon dioxide (002) content of the products of combustion, particularly from the boiler furnace, is very valuable. An instantaneous indication of the CO2 can be used as a useful guide to efficient burning. A permanent record over a. period of time gives a story to the management which tends to keep the operators more alert. Many instruments that indicate and record CO2 have appeared within the last fifteen years. More are about to appear. Although simple principles involving chemical, physical, or electrical qualities, are being used, there is at present a general feeling of uncertainty about such instruments in the boiler room any instruments are bought, run awhile, then lie idle indefinitely.Inquiries as to CO2 machines continually come to the Bureau of Mines from the general public, as well as from other branches of the Government. Some ten years ago a series of tests was made on certain instruments at that time on the market. The following test was made quite recently on four of the newer types, including one using an electrical principle. The four instruments were installed on one boiler each, according to the instructions of the makers, and the recommended routine attention was given them. The test was of a service nature duplicating the conditions under which the instruments ordinarily serve. The boiler that was available for this purpose was practically banked for some hours of the night. This caused the average CO2 for the entire twenty-four hours to be rather low, although it reached the higher ranges of the instruments during the day.Each day the charts were averaged and the results plotted to form the accompanying curve. The record of each instrument is shown by its particular mark, the dot, circle, cross and square being used in addition there is plotted for each day a rectangular area representing 1 % CO2 in height. The proper positions of this area was determined by means of the Crsat. Where the plotted point for an instrument falls within the rectangel its accuracy is within 1/2% CO2, which is considered satisfactory. Where it falls outside the rectangle, inaccuracy is indicated."

Mar 1, 1925

Detect hazards associated with abandoned mine openings through the use of integrated geophysical technology. Background Many abandoned mines in the U.S. present hazards to the public. The first step in abatement of these hazards usually requires locating the abandoned workings. Recent Colorado legislation resulted in a concerted effort aimed at mitigating the hazards associated with abandoned mine workings. The Colorado Department of Natural Resources-Mine Land Reclamation Division (CDNRMLRD) is responsible for locating and backfilling abandoned mine openings such as shafts, adits and collapsed features. Many shafts and adits can be located by inspection, other openings give little or no surface expression and must be located by drilling, or through the use of geophysical methods. A common method used for locating underground mine workings is to drill throughout the suspected area. However, it is prohibitively expensive to drill holes at the spacing needed to detect backlilled shafts and small voids associated with caving and/or chimneying. It may also be dangerous to move heavy equipment over shallow mined-out workings. Geophysical investigations that employ only a single method have had mixed success in detecting hazardous abandoned mine land cavities.

Jan 1, 1991

By Dennis R. Dolinar

Screen material in the form of welded wire mesh and geogrids are used in underground coal mines to prevent the fall of small pieces of rock from the roof between roof bolts. Further, if the screen is installed during the production cycle, roof fall injuries can be reduced significantly. Therefore, the National Institute for Occupational Safety and Health (NIOSH), because of the safety implications, conducted an evaluation of screen materials commonly used in U.S. coal mines to determine their support characteristics and identify the parameters that could affect their performance with respect to controlling the fall of rock from the roof surface. To evaluate the load and stiffness characteristics of the screen, a test frame was designed and installed in the Mine Roof Simulator (MRS) at the NIOSH Pittsburgh Research Laboratory (PRL). With this test set up, the screen is bolted at four corners of the frame and a center load is applied. The test set up allows for up to 20 in of screen deflection while the load and screen defection are continuously recorded. A series of tests were conducted to evaluate the effects of various parameters such as bolt tension, the type of load bearing surface and the size of bearing plates on welded screen performance. The most common screen material used in U. S. coal mines is an 8-gauge wire welded in a 4-by-4-in spacing or aperture. The peak screen load was normally limited by wire breakage. The conditions at the bearing plate influence the nature of the wire breakage. However, the screen stiffness was controlled by slippage at the bearing plates, and by weld and wire failure. The size of the bearing plate had a significant effect on the performance of the welded screen. Therefore, the design capacity of the 8-gauge screen is evaluated based on plate size. For a 6-by-6-in bearing plate the average peak load is 2,900 lb with a stiffness of 250 lb/in. For an 8-by-8-in bearing plate, the average peak load is 4,500 lb with a stiffness of 430 lb/in. These test results are based on a 4-by-4-ft bolt spacing. A geogrid mesh was also tested.

By R. D. Leitch, W. P. Yant

"In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information- as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report.The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. .Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and to others for information received; and to Dr. R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.The Lower Kittanning is the most important bed in the locality studied. A great many of the abandoned mines examined are in this bed, and nearly all of the present active ones are. The Upper Freeport bed is also mined to some extent, and a number of the abandoned mines formerly worked this bed. As only three active mines are now (1927) working the Upper Freeport, the comparison of acidities is necessarily limited. Of these three, one had been idle since 1922 until shortly before it was sampled.The location of most of the mines was already known from previous work, but some of them had to be located by following up streams known to contain acid waters. A sample of the- outflow was collected in self-sealing bottles known as ""citrate bottles"" for the determination of dissolved oxygen by the Winkler method.5 Another sample was taken for the determination of acidity according to standard methods of water analysis.6 Ferrous iron was determined at the mine or very soon after taking the sample by titrating with a standard solution of potassium permanganate in acid solution. The hydrogen-ion value was determined by a standard double-wedge comparator.7From the total acidity values in each sample, which are the most important values, the total iron was calculated on the assumption that acidity as sulphuric acid was due to dissolved ferrous sulphate. This assumption is commonly made for mine waters, but is inaccurate to the extent that free acid is already present, and some of the iron is present as ferric, rather than ferrous, sulphate. The amount of ferrous sulphate may be a rough measure of the extent to which oxygen is lacking within the mine. The permanganate titrations just mentioned showed what part of this total iron was in combination as ferrous sulphate, and the difference .was assumed to be that in combination as ferric sulphate, after correcting for the amount of free acid already formed as shown by the titration values."

Oct 1, 1928

By W. N. Poundstone, W. M. Merritts, B. A. Light

A joint investigation by the Bureau of Mines and the Christopher Coal Co. at the Humphrey No. 7 mine, operating in the Pittsburgh coalbed in northern West Virginia, was undertaken to gain more insight concerning the hazardous emission of methane gas in mining. This report describes the equipment, procedure, and results. Horizontal bleeder holes drilled in the faces drained large quantities of methane, eliminating downtime of mining equipment. Also, larger quantities of methane were removed by forcing 14 to 25 g,.p.m. water at 25 to 200 p.s.i. 5 pressure into the bleeder holes. In one infusion test a fluorescein dye was added to the infusion water; in later mining operations, the infusion water was traced for a distance of 1,500 feet. With vacuum pump applied to the horizontal hole the gas-flow rate increased, and the methane content decreased. Tests indicated that methane and water infused in bleeder holes traveled along the bedding planes of the Pittsburgh coalbed at a faster rate than across the planes. Methane associated with coalbeds is produced by the slow decomposition of carbonaceous material in the absence of air and the presence of water. It is lighter than air and, depending on its concentration, forms an inflammable or explosive mixture with air. It is believed that methane is entrapped in and around the pores of the coal and adjacent strata--often under great pressure. In many cases where the strata have been disturbed by geologic movements the

Jan 1, 1962

By David C. Byrne

PURPOSE: Evaluate practical technological advances in hearing protective devices for use in different mining environments. RESEARCH SUMMARY: Previous NIOSH research shows that miners develop hearing loss much more quickly than nonoccupationally noise-exposed individuals. Also, miners experience a greater severity of hearing loss than would be expected for nonoccupational noise-exposed persons of the same age and sex. As described in the National Occupational Research Agenda, problems created by occupational hearing loss include (1) the reduced quality of life due to social isolation and unrelenting tinnitus, (2) impaired communication with family members, the public, and coworkers,(3) a diminished ability to monitor the work environment (e.g., warning signals, equipment sounds, etc.), (4) lost productivity and increased accidents resulting from impaired communication and isolation, and (5) expenses for workers’ compensation and hearing aids. Although the elimination of hazardous noise is the ideal long-term solution to the noise problem, miners will likely need to rely on personal hearing protection in certain situations for quite some time. However, it is well known that noise attenuation provided by hearing protectors as they are worn during everyday use in the workplace is usually worse than when tested under laboratory conditions. Additionally, workers may refuse to wear their hearing protection for any number of reasons. Therefore, this project was initiated to evaluate practical technological advances in hearing protectors, with an emphasis toward optimizing the balance between effectiveness, comfort, overprotection, and communication ability. Currently, the necessary in-house laboratory facilities and research techniques are being finalized. Individual experiments are planned that involve analysis of new hearing protector technology under both laboratory and field conditions. The laboratory components are to consist of con-trolled studies using human subjects and/or an anthropometrically correct artificial test fixture to evaluate the adequacy/effectiveness of various hearing protective devices. Field studies are planned to determine the actual usefulness and practicality of the hearing protectors as used in diferent mining environments. Recommendations can then be offered to the mining community regarding correct earplug/earmuff usage that maximizes recognition of hazard/warning sounds while adequately protecting the miners’ hearing.

Jan 12, 2000

Develop an environmentally feasible method of mining shallow oil sands without removing overburden. Approach Oil sands are extracted through a single borehole by cutting into the sands around the borehole with a high pressure water jet, and pumping the resulting slurry to the surface. Although oil can be extracted from shallow fields by open-pit mining methods, this type of mining may create significant environmental impacts, including; (1) disruption of the surface, (2) accumulation of waste rock piles, (3) accumulation of tailings, (4) damage to the ground water quality, and (5) surface water pollution. The borehole mining system developed and successfully field tested by the Bureau of Mines offers a method for extracting oil from oil sand with minimal disturbance to environmental quality. (For examples of other applications of borehole mining, see Technology News Nos. 95, 63 56, and 48.) How It Works Prior to the start of mining operations, baseline conditions for ground subsidence and ground water quality are established at the test site so that the degree of subsidence and changes in ground water quality can later be determined. Oil sands mining is conducted using the Bureau of Mines borehole mining system. The borehole mining tool consists of a 12-inch-diameter pipe string and accessories capped with a three passage swivel terminated with a mining section. The mining section has an auger at the bottom. Four slurry inlet holes and an eductor are located above the auger, and a single cutting nozzle is located near the top of the mining section. The tool generates a high velocity water jet that erodes and slurrifies ores. The slurry is drawn into the inlet of the eductor which lifts the slurry to the surface where it is deposited into a slurry discharge sump. To detect evidence of subsidence, surveys of the land surface are made at regular intervals during, and until 30 days after, the termination of the mining operations. Samples of ground water from the borehole and two adjacent monitor holes are taken on alternate days during the mining operations, and are later analyzed to determine if any ground water contamination has occurred.

Jan 1, 1981

By R. Raines, S. P. Signer

Researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health installed 39instrumented, fully grouted bolts at six test sites in a trona mine retreat panel to study mine roof stability for the improvement of workplace safety. Variables at each test site included bolt spacing, bolt length, roof span, and location in the panel layout. At most test sites, two rows of instrumented bolts were installed, one in or near the intersection created during development and the other in or near the intersection created during second-pass mining. The most significant factor affecting bolt load was roof span. The highest loads were on the bolts installed in the intersections of the 6-m-wide entry. Mining-induced stress resulting from panel layout was the next most significant factor affecting bolt loading. Minor variations in bolt loading could be attributed to changes in bolt spacing and bolt length. Gas pressure release in the immediate roof contributed to some bolts showing compressional loading during gas bleed-off.

It was decided to demonstrate the use of latex as a soil sealant by irrigating three small plots at Lanse coded 03A on the west of Brown's run, 3C on the east of the stream, and SB, an area on the spoil bank. Earlier plans to sprinkle latex on twenty acres of the side were abandoned because of easement difficulties. On the basis of results from laboratory soil columns and small plot experiments at Lanse, Naugatex J-3471 was the latex of choice. The irrigation system consisted of plastic pipe (two inch size) for the main line from the water meter to the irrigation area because of lower price and ease of handling. Because the municipal water supply was limited to 20 gpm, low-volume 14V-LA-TNT Rainbow sprinklers were specified with low angle 20° 3/32 inch nozzles to reduce wind effects. At the expected nozzle pressure of 50 psig, each sprinkler covers a 56 foot diameter area at a delivery rate of 1.64 gpm. Each of the three test areas was covered with twelve sprinklers, six used with water alone as a control area and six used with latex and subsequent water spraying. One-quarterturn inlet valves were positioned on the main lines leading to each area. Flow to the treated and untreated areas was set at 10 gpm by Dole flow control valves in the' main entry lateral to each of the six sprinklers. To avoid the use of dilution tanks, a Moyno pump operated by a 1/2 HP, 1140 rpm 5:1 reducing drive was used to deliver 1/2 gpm 48% latex for mixing with 10 gpm water. A 3500 watt gasoline generator provided power for pump and light. Latex was applied at night to take advantage of the lower evaporation and higher humidity. Neutron gauge access tubes were placed in orthogonal arrangement in the areas that were irrigated, with four tubes in the section that were sprinkled with latex and four tubes in the untreated irrigation section in each of the three locations. Each tube, five and one-half feet long and sealed at one end with a plug welded in place, was inserted five feet into the ground in a cored hole. In each irrigation area, the left section of six sprinklers spread the dilute latex while the right section sprinkled the same amount of water to serve as a control plot. As shown in Figure 7 each sprinkler has a 56-foot sprinkling diameter at 50 psig design water pressure. The sprinklers are 30 feet apart on the laterals and 35 feet apart between the laterals. The access tubes (coded AT on Figure 7) were placed in comparable spots on the two sections of each area, so that four soil moisture measurements on the two sections could be compared. Bouyoucos resistance blocks (BB) were also placed in areas 03A and 3C at one, two and three foot depths, but not on the spoil bank area.

Jan 1, 1972

By T. M. Klemetti, G. M. Molinda, D. M. Pappas

Some of the most difficult coal mine roof in the U.S. can be found in the Illinois Basin. Factors contributing to the high roof fall rate include: weak moisture-sensitive roof rock, high horizontal stress, and limited longwall mining. The depth of cover ranges from 90-1,000 ft and roof damage from horizontal stress can be severe. Moisture sensitive-roof rock is common above the Springfield-Harrisburg Herrin #5 and #6 seams in the Illinois Basin, and contributes to roof skin deterioration. The roof fall rate increases significantly in the humid summer months. The National Institute for Occupational Safety and Health (NIOSH) has shown, using lab and field studies, that highly moisture-sensitive roof rock can be directly correlated to poor roof conditions. Controlling the skin is the key to reducing rock fall injuries, and roof screening is, by far, the best remedy. Illinois Basin coal operators have been successful in reducing the number of rock fall injuries in recent years. NIOSH has documented best practices for screen installation which has resulted in safe, efficient operations. Other solutions to skin failure include: the use of denser five bolts per row patterns to reduce spans between bolts, systematic supplemental support in intersections, straps and large pans protecting operators, and air conditioning to remove moisture from the intake air.

By C. N. Schuette

"The production of silica and magnesia crucibles in the induction furnace was attempted and achieved in the laboratory of the Pacific Experiment Station of the United States Bureau of Mines. This work was undertaken at the request of other stations for laboratory crucibles of a certain specified wall thickness and capacity.The essential new parts of this work are the development of a technique for the high-frequency furnace production of silica crucibles of greater wall thickness than could be readily fabricated from commercial fused silica, and for heavy-walled magnesia. crucibles of great density and mechanical strength. A considerable bode of patent literature on the Production of fused silica ware in resistor-type furnaces was examined, but it furnished no significant help for the present problem. Similarly sintered magnesia refractories are often made for technical purposes, but for use at temperatures of 2000o C. or over, the material must be sintered at higher temperatures than can be attained by combustion firing, and the very great shrinkage encountered at these temperatures requires special methods. Small crucibles. of magnesia fused in the electric arc have been made by Tritton and Hansen,3 but the practical size of such containers is very limited.Many different methods of making crucibles in the induction furnace were tried before satisfactory results were obtained. The following description covers only the most satisfactory method, which produced crucibles of excellent quality in a reasonable time and with a moderate expenditure of power and materials."

Oct 1, 1929

By Douglas A. Donato

This Information Circular presents the MULSIM/PC system of numerical modeling computer programs developed by the U.S. Bureau of Mines. This system consists of four programs: PREMUL, the preprocessor or mesh generator; MULSIM/PC, the actual numerical modeling program (number cruncher); MUL3D, a three-dimensional postprocessor; and MUL2D, a two-dimensional postprocessor. These programs were specifically designed to operate on IBM-compatible (MS-DOS-based) personal computers for easy transfer of this technology to the mining industry and academia. MULSIM/PC uses a subvariation of the boundary-element method, namely, the displacement-discontinuity technique, for linear-elastic geomechanical analysis of mine plans in one or two parallel underground tabular deposits. Results calculated by this technique include stresses and displacements as they relate to changing mine geometries and materials. In addition to describing the MULSIM/PC program and its features, and providing a detailed example model, this report also documents the associated preprocessing and postprocessing programs that are part of the MULSIM/PC system. User's guides for all the programs are contained in the appendixes following the main report.

Jan 1, 1992

By A. Dale Marcy, Pamela L. Drake

Workers who perform routine welding tasks are potentially exposed to fume that may contain manganese. Manganese may cause respiratory problems and is implicated in causing the occurrence of Parkinson-like symptoms. In this study, a field colorimetric method for extracting and measuring manganese in welding fume was developed. The method uses ultrasonic extraction with an acidic hydrogen peroxide solution to extract welding fume collected on polyvinyl chloride filters. Commercially available pre-packaged reagents are used to produce a colored solution, created by a reaction of manganese(II) with 1-(2-pyridylazo)-2-naphthol. Absorbance measurements are then made using a portable spectrophotometer. The method detection limit and limit of quantification (LOQ) were 5.2 mg filter-1 and 17 mg filter-1, respectively, with a dynamic range up to 400 mg filter-1. When the results are above the LOQ for the colorimetric method, the manganese masses are equivalent to those measured by the International Organization for Standardization Method 15202-2, which employs a strong acid digestion and analysis using inductively coupled plasma-optical emission spectrometry.

By P. Yant, A. C. Fieldner

"IntroductionIn its investigations relative to reducing the hazards of carbon monoxide poisoning, the Bureau of Mines recently had its attention drawn to a compound2a sold under a trade name for which claims are reported to have been made regarding its efficacy in reducing that type of poisoning in automobile garages. Accordingly, some of the product was obtained and analyzed for its power to absorb, oxidize, or destroy carbon monoxide; and the results are herein reported.Description of ""Compound"" (quoted from manufacturer's circular)While the circular does not actually state that the ""compound"" protects against carbon monoxide, the inference is therein, because each of the two following quotations is below these respective headings; ""Carbon-Monoxide Poisoning,"" and ""Chronic Gassing Among Garage Workers.""The ""compound"" holds chlorine and oxygen gases in solution with formaldehyde, which unites with the hydrogen to form hydrochloric acid., giving an over-supply of oxygen which burns up carbon just as a piece of wood is burned in the fire. The formaldehyde in the composition of the ""compound"" is a great affinity for ammonia and hydrogen sulphide."

Apr 1, 1924

By J. Bender

The objective of this research was to (1) Further develop cyanobacteria mats' for metal-tolerance and cold-tolerance, (2) test them for durability in the field environment and (3) assess them for metal sequestering potential with actual and simulated field samples. Results show that mats performed well In the field and effectively sequestered metals from actual and simulated field samples. Metal uptake from Iron Mountain Hine samples was for Ins 87%, Cu and Cd 99%, Initial concentrations (mg/L) were Zn = 3,250, Cu , 279, Cd = 28. In solutions simulating the Gulf Tunnel drainage, Zn and Mn were effectively removed by mats immobilized on glass wool. Effluent water, after treatment, generally had a Ph of 7 .5-8.5. Al though the final metal concentrations in the mats 'harvested from the decontaminated water were only 1% or less, the actual mechanism of metal deposit was probably a mat-mediated alteration of the environmental conditions causing the metals to deposit outside the mat as oxides or carbonates. Bioflocculents, released by the mats, were likely involved in the metal-removal process.

Jan 1, 1996

By S. D. Sanders

Goals of the Bureau of Mines include utilizing readily available minerals as substitutes for scarce mineral commodities and minimizing occupational hazards associated with mineral processing occupations. Therefore, the Tuscaloosa Research Center investigated using rapid-set cement as a suitable molding sand binder for small ferrous castings; currently petroleum-based binders are used. Substitution of a rapid-set cement would eliminate organic vapors associated with the petroleum-based binders; these vapors constitute occupational hazards and environmental pollutants. A binder containing 60 percent white portland cement (WPC) and 40 percent calcium aluminate (CA) would be an acceptable and economic substitute for petroleum-based binders where the foundry requirements are compatible with its limitations. It produced a set time and a pattern strip time of less than 1 hour. Cement, sand, and water mixtures developed compressive strengths from about 40 to 75 psi after 2 hours and from 120 to 130 psi after 24 hours. Tensile strengths of 18 to 22 psi were obtained after 2 hours, increasing to 30 to 35 psi after 24 hours. The addition of about 1 percent polyphosphate to the sand-cement-water mixture doubled the compressive strength and increased the tensile strength about 50 percent after 4 hours, but also increased the set time from 30 minutes to 1 to 1-1/2 hours. Po1yvinylacetate (PVA) resin latex additions resulted in rapid strength development. When castings were poured into the cement-bonded molds, the surface finish was fair to good on gray iron castings, but some areas of burn-on were present on steel castings. Using a graphite wash on the cement-bonded molds produced good surfaces on gray iron castings.

Jan 1, 1979