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By J. Wade Watkins, Joseph W. Horne, Arthur Matzick

"A successful procedure for the recovery of a valuable product from weathered tank-bottom settlings has been developed in the laboratories of the Bureau of lines and used in a field pilot plant. These heavy emulsion settlings, generally regarded by the industry as waste material, have usually been drained into open pits or storage ponds and eventually destroyed.Laboratory examination of the waste material shows it to consist essentially of a ""water-in-oil"" emulsion containing a considerable volume of congealed ""paraffin."" This paraffin is mainly high-melting-point wax; known in the industry as microcrystalline wax, for which there is an increasing demand.Because of the physical properties of this wax, the tank-bottom settlings are not responsive to conventional methods used for demulsifying ordinary crude-oil emulsions.The work upon which this report is based was conducted by the Bureau of Mines in cooperation with -the Kansas State. Board of Health and with special cooperative agreements-with the Cities Service Oil Co, Bartlesville, Okla., and the Bareco Oil Co,. Barnsdall, Okla. The studies were made under the general supervision of R. A. Cattell, chief engineer, Petroleum and Natural-Gas Division, Bureau of Mines, Washington; D. C., and H. C. Fowler, supervising engineer, Petroleum Experiment Station, Bureau of Mines, Bartlesville, Okla., and under the direct supervision of Ludwig Schmidt, senior petroleum engineer, Bureau of Mines, Bartlesville, Okla.Gratefully acknowledged are the assistance and cooperation given by the Cities Service Oil Co. of Oklahoma and especially by M. J. Kirwan, manager of production, and by Q. E. Beecher, general superintendent of production, Bartlesville, Okla., and to members of their staff at Oil Hill, Kans.The assistance and suggestions of V. R. Oakley, general superintendent, E. R. Wiles, director of research, L. G. Willis, field engineer in charge crude-oil supply, and Gerald DeWalt, chief chemist, and his staff of the Bareco Oil Co., Barnsdall, Okla., were of much value in the laboratory and recovery work."

Mar 1, 1946

By H. B. Humphrey

[EXPLOSION of gas and dust in coal mines, have caused death t lid injure to mines, and destruction of workings in all countries where coal is mined underground. In the United Stales the first reported explosion wits in Min; explosions have continued to the present. The danger to film ill it mine When an explosion occurs in not always measured by the violence created or by their nevi lies, to the area through which flame and Violence extend. As many, perhaps more, risen have died from gases and lade of oxygen (known as "after-damp") than have been killed by the blast and hart. Me explosions often are caused by it combination of factors, including concentration of methane in air, formation of clouds of dust, and the presence of a flame or spark. These explosion factors have varied with changes ill milting method and practises over the years, but the basis causes have always been the salve. Understanding of the causes and to acceptance of ways to guard against explosions and their effects have been slow to spread from investigates to officials and Own to bosses and miners. To a considerable extent there hats lawn a belief that explosions were a joining risk but might hr, put oil hut could not be presented. Such belief is based on the human failure to maintain and observe necessary precautions. These failures, caused by inertia to change, carelessness, or reliance on continuance, of past explosion-free years, are being reduced in number and effect by education of miners and supervisors and acceptance of higher prevention standards.]

Jan 1, 1959

By D. F. Smith

The thermodynamic data presented in the literature for zirconium compounds are incomplete. Among the compounds for which adequate data are Zacking are zirconium fluoride and sulfate. This paper reports experimental heat-content values determined by the Bureau of Mines for these two zirconium salts throughout the temperature range of 273° to 1,200° K. No crystalline transformations were found in the two compounds investigated, and neither of the compounds melted over the temperature range studied. MATERIALS TESTED The Oak Ridge National Laboratories, Oak Ridge, Tenn., supplied the two zirconium salts used in this investigation. The zirconium fluoride was high- purity reactor grade material. The zirconium sulfate contained between 0.01 and 0.10 percent hafnium and calcium, and other elements in concentrations below 0.01 percent, A spectrographic analysis of the two compounds is given in table 1. Before use the compounds were dried at 400° C. for several hours to removed adsorbed moisture.

Jan 1, 1962

By K. L. Erickson, Gerald A. Munson

"The need for spodumene as a source of lithia for war purposes led to the exploitation of the Edison pegmatite deposit 1-1/2 miles southeast of Keystone, S. Dak. The operation was conducted during 1943 and 1944 by the Lor Mining Co., Rapid City, S. Dak. Spodumene concentrates in the ratio of 15:1 were recovered by hand picking from a sorting belt. This method was expensive and wasteful of spodumene, owing to the small size of the crystals.Data4/ obtained by the Bureau of Mines indicates that blunging with hydroflouric acid or sodium hydroxide is a prerequisite to selective flotation. Results of tests by Denver Equipment Co., Denver, Colo., indicate that economic recoveries can be obtained in an alkaline circuit after desliming.At the request of the Lor Mining Co., K. L. Erickson, metallurgical engineer, was permitted to work in the pegmatite research laboratory to verify previous investigations and to determine problems that might be involved in commercial milling. The ensuing investigation indicated that electrolytes in the mill water produced a profound inhibiting action on the flotation of Edison spodumone.An investigation of mill water from various sources showed that some waters are suitable for the process and others are not. Subsequent testing showed that all of the available waters are suitable after treatment. The flotation of the Edison spodumene in an alkaline circuit after desliming and using oleic acid as collector is efficient and economical when the water does not contain impurities.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B.Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches arc under the supervision of Dr. R. S. Dean, assistant director.As the work was of a practical nature, samples from possible mill-water sources in the southern Black Hills were obtained, and commercial softening and demineralizing methods were investigated. Data on various waters tested are given in table 1."

Jun 1, 1946

By Eric E. Cather

A mineral survey of the Fisher Gulch RARE II area (A5299), Trinity County, California was conducted by the U.S. Bureau of Mines and U.S. Geological Survey. The Bureau of Mines was responsible for detailed examination of mines, prospects, and mineralized zones; the Geological Survey conducted geological, geochemical, and geophysical studies of the area. The area is underlain by the Salmon Hornblende Schist. Tonalite stocks 1.5 mi (2.8 km) to the east and northeast of the area intrude the schist and are closely associated with the nearby nines (Cox, 1967). The mines have quartz veins containing sulfides and gold in shears trending east to north past in the schist and tonalite (Hotz, 1972). Strewn and terrace gravel s occupy most of the drainages, many have yielded substantial quantities of gold.

Jan 1, 1981

By P. R. Jones

A computer program was written for design and cost of a shell and tube heat exchanger in which the total cost, which includes annual fixed charges and annual operating costs, was minimized. The program was written for the type of heat exchanger in which only the tube side pumping costs were significant and for triangular pitch, single or multiple pass, heating or cooling, and no change in phase. Tube diameter was not optimized since the tube dimensions do not affect the cost very much. However, the tube dimensions do affect the shell diameter, number of tubes, and length of tubes; and price optimum design was obtained for four standard tube diameters. Standard heat exchangers having at least the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By Hillary W. St. Clair

This is an initial progress report on a theoretical study of the iron blast furnace. The purpose is to develop a thermochemical model that will simulate mathematically a real furnace. An analysis is made of the behavior of a hypothetical furnace, operating adiabatically on pure ferric oxide, graphitic carbon, and dry air. Relationships are derived for carbon consumption, gas composition, and reaction temperature for a furnace operating at steady state, and in which the smelting rate is slow enough for the gas and solids to approach thermal and chemical equilibrium. Analyses are made for two contrasting types of gas flow: (1) Nonturbulent flow, having no vertical mixing; and (2) turbulent flow, having perfect mixing during each step of the process. It is shown that some vertical mixing is essential for complete reduction of ferrous oxide and that the extent of vertical mixing is one of the critical factors in the behavior of the furnace, This analysis indicates that the thermochemical relationships in a blast furnace can probably be best simulated by a finite series of gas-solid reactors through which gas and solids flow countercurrently and in which the temperature and composition of gases and solids are assumed to be uniform. Any degree of vertical mixing can be approximated by the proper choice of the number of reactors.

Jan 1, 1963

By A. L. Engel

In recent investigations of chloride Volatilization of gold at the Reno Station, it was found that the addition of small amounts of copper and NaCl to the charge brought about improved volatilization of the gold. The investigations described in this report were concerned with the recovery, in an aqueous medium, of fumes from chloride volatilization of gold. It was attempted to discover a suitable aqueous medium that would permit absorption, solution, or precipitation of all the volatilized gold immediately upon contact with the medium. A simple laboratory apparatus was employed to produce fumes by volatilization. To this furnace was attached an absorption train consisting of a series of chambers containing the aqueous medium, through which the fumes were drawn by suction. A satisfactory synthetic ore that contained metallic, gold in a quartz-matrix was made and utilized, enough. gold being present in a' small amount of material to permit an accurate, metallurgical balance of the volatized values' to be obtained in all the experiments.

Jan 1, 1949

By A. B. Hooker

All State mining laws require that flame safety lamps be used in gassy mines; the laws of some States require that safety lamps be kept for emergencies at every coal mine, whether gassy or nongassy. The use of the flame safety lamp has been widespread because it is the only defice readily available for detecting both the presence of methane and deficiency of oxygen. This paper reports the results of an investigation by the Electrical Section, in cooperation with the Gas Section, of the Pittsburgh Experiment Sta¬tion relative to the behavior of permissible flame safety lamps in mine atmospheres deficient in oxygen and the effects of methane5 on the detection of Oxygen deficiency.

Jan 1, 1937

By A. B. Hooker

All state mining laws require that flame safety lamps be used in gassy mines; the laws of some States require that safety lamps be kept for emergencies at every coal mine, whether gassy or nongassy. The use of the flame safety lamp has been widespread because it is the only defice readily available for detecting both the presence of methane and deficiency of oxygen. This paper reports the results of an investigation by the Electrical Section, in cooperation with the Gas Section, of the Pittsburgh Experiment station relative to the behavior of permissible flame Safety lamps in mine atmospheres deficient in oxygen and the effects of methan5/ on the detection of oxygen deficiency.

Jan 1, 1937

By Forest J. Sur

"INTRODUCTION This report describes an exploratory project conducted by the Bureaus of Mines on a fluorite deposit, near Glenwood, N. Mex. Results of wagon drilling, crosscutting, and test pitting are given, together with results of metallurgical tests made upon samples of the ore. Mining and treatment methods are suggested.C. H. Johnson, Bureau of Mines engineer, examined the deposit in August 1942. H. E. Rothrock, of the Federal Geological Survey, completed a preliminary geologic study and mapped the deposit during the fall of 1942. As a result of these brief investigations, it was concluded that the deposit contained substantial inferred ore reserves, and exploratory work was recommended. G. A. ApelI, also of the Bureau of Mines, made a topographic and underground survey and report on the mine in March and April 1944. A wagon drill, air compressor, and other equipment and supplies were delivered to the property on May 19 to 23, 1944. Drilling began under the direction of the author on May 25, 1944, and was completed in October 1944. The results of drilling and. sampling form the basis of this report."

Apr 1, 1947

By Wing G. Agnew

It is thought that a brief description of the unique mining and milling procedure at the Doyle nine may be interesting to those engaged in small-scale operations at old mines or in working new ore body adjacent to old workings. It also shows what can be done with r. small capital outlay in working a zinc-lead mine on a small scale; as the operation herein described was begun 3 years ago with four men and it now employs 17 men. The original idea was to mine out any ore left around the edges of some old stones above the water level and to rob pillars after an old stope became filled with waste and tailings. This has been done, and the procedure is still being followed; at the same time a paying lead is being mined toward an area in which churn-drill holes have shown ore. Also, preparations are now being made to do some pumping.

Jan 1, 1936

By Ross W. Smith

Microflotation and surface chemical studies were conducted on a chromite from the Stillwater Complex in Montana and on some of the minerals usually found to be associated with such chromites. Considering the chromite it was found that aging the ground mineral in air or heating it markedly affected its flotation behavior. Much of the observed effects could be attributed to oxidation reactions involving surface chromium and iron species. Strongly acid pretreating the mineral appeared to reverse such effects. Thus, it can be concluded that the manner in which the mineral (or the ore) is pretreated is of utmost importance in its flotation. Work carried out on associated gangue minerals determined how they are likely to behave in a flotation environment and how certain foreign ions derived from a chromite ore itself can affect their surface characteristics and, thus, presumably also their behavior in a flotation circuit.

Jan 1, 1981

By D. S. Kingery

Recent Federal coal-mine inspections have revealed some good and some definitely hazardous practices and systems for transporting; handling, and storing lubricants in and about coal mines. Improper storage or handling of. lubricants in coal mines has caused disastrous mine fires or, by supporting combustion, has made fires from other sources more difficult to fight. Careless handling of grease and oil around electrical equipment wastes much oil and permits entrance of grit and foreign substances into the working parts, which causes excessive wear and increases the possibility, of electrical ignition.

Jan 1, 1943

By Thomas P. Dolley

Building stone, cassiterite, kaolin, gold, lime, and peat were the only commodities mined, The country's main economy was in agriculture, primarily in coffee exports. Tribal violence occurred again, between the Hutu and Tutsi tribes, causing an estimated 50,000 deaths, mainly in rural and mining areas. The inflation and a large deficit continued. The country continued to import cement, fertilizers, oil, and petroleum products. Burundi possessed numerous small gold deposits. The northwest and north-east were the country's two most important gold-bearing regions. A large kaolin deposit was found at Ngozi, and its mining was specified in the fifth 5-year development plan for 1988-1992. In the area of Rugombo, limestone was being explored with the intention of opening a cement plant.

Jan 1, 1990

By A. Iannacchione

Major Hazard Risk Assessment (MHRA)1 is used to help prevent major hazards, e.g., fire, explosion, wind-blast, outbursts, spontaneous combustion, roof instability and chemical and hazardous substances, etc., from injuring miners. The structured process associated with MHRA helps to characterize the major hazards and evaluate engineering, management and work process factors that impact how a mine mitigates its highest risk. The National Institute for Occupational Safety and Health (NIOSH) studied the application of this technique to US mining conditions through a field-oriented pilot project. Risk assessment teams used in the pilot project were primarily composed of mining company personnel. Ten case studies were performed over a wide cross-section of mines. These mines were representative of the important mining commodities in the US minerals industry, i.e. coal, metal, non-metal, and aggregate. Also, the sizes of the mines ranged from small to large and were located across the country. The ten case studies demonstrate that most US mines have the capability to successfully implement an MHRA and that the MHRA methodology produced additional prevention controls and recovery measures to lessen the risk associated with a select population of major mining hazards. The basic ingredient for a successful MHRA is the desire to become more proactive in dealing with the risks associated with events that can cause multiple fatalities. A successful outcome is marked by a thorough examination of existing prevention controls and recovery measures. When pressed to consider more controls to further mitigate the risk, a well-staffed risk assessment team was able to identify additional controls. For these mining operations, it was important to add additional controls, even if they were not required by existing mining regulations, to lower the risks associated with the major hazards under consideration. If a mining operation is not willing to commit its best people to an MHRA or will not provide them with sufficient time to see the process through to its conclusion, the MHRA output may prove to be useless. Additionally, if a mining operation is not prepared to discuss its major hazards in an open and honest fashion and to present the findings of the risk assessment in a written report, the MHRA output will be unclear, and attempts to monitor or audit important controls may not be possible. A MHRA is most effective when the mining operation possesses 1) a proper understanding of its hazards, 2) experience with informal and basic-formal risk assessment techniques, 3) proper facilities, machinery and equipment, 4) suitable systems and procedures that represent industry Best Practice, 5) appropriate organizational support with adequate staff, communications and training, 6) a formal and thorough plan for emergency response, and 7) a safety risk management approach that is promoted and supported at all levels of the organization.

Jan 1, 2008

By Oliver Bowles

A conviction is growing that depressions and other adverse conditions are not entirely unavoidable if a knowledge of past achievements and shortcomings is intelligently, applied in shaping the course of industry. Mineral producers have available a source of such knowledge concerning; their industry in the statistical records of the United States Bureau of Mines, and by scanning, this increasingly exact history can obtain information on which to found a more stable future. This paper contains a brief history, covering more than 50 years, of the activities of the nonmetallic mineral industries as a group, followed by short histories of each of the more important commodities in which are noted the circumstances that lave influenced their development.

Jan 1, 1933

By J. G. Groetsch

Municipal solid waste (MSW) contains about 8 pct ferrous metallics which are typically recovered by magnetic separators at municipal resource recovery facilities. At present, only about 182,500 ton/yr of MSW magnetics are being processed for remelting out of the -11 MMton/yr discarded. The Sn in MSW magnetics makes this material difficult to recycle to the steel industry. An electrolytic method using stannous fluoborate-fluoboric acid for removing Sn was evaluated. Optimum concentrations of Sn in the electrolyte and the effects of impurities such as Al, Cu, Fe, and Pb on Sn recovery from the electrolyte were evaluated. Operating parameters were 60 to 65 g/L fluoboric acid and 20 to 30 g/L Sn using stainless steel electrodes at a current density of 60 A/ft2. Tests were run with postconsumer scrap4 and MSW magnetics. Good results were obtained with MSW magnetics, after pretreatment by reshredding, magnetic separation, and air classification. The final Sn content of the MSW magnetics scrap was reduced from 0.18 to 0.017 wt pct. Heat and solvent treatments of MSW magnetics to remove coatings did not significantly improve Sn removal beyond that obtained with material that had only been mechanically pretreated.

Jan 1, 1984

By W. A. Grosh

In 1951 the Federal Bureau of Mines became interested in the reports of copper-nickel mineralization in northern Minnesota. Several outcrops on the north side of the Duluth gabbro in the Kawishiwi River area were sampled by the Federal Bureau of Mines and George M. Schwartz of the Minnesota Geological Survey. Because these samples showed appreciable amounts of copper and nickel, a 100-pound sample of an un-altered outcrop was obtained for metallurgical testing. Results from this preliminary work were all favorable; therefore, in the fall of 1953 the Bureau of Mines diamond-drilled three holes near the outcrop of the con-tact between the Duluth gabbro and the Algoma granite. A total of 686 feet of NX size hole was drilled, and 100 percent of the core was recovered. Each hole intersected the contact, and the strike and dip for that locality were established. The core was split, and half was used for analyses and further metallurgical tests; the remainder was retained for permanent record in the Bureau of Mines core-storage warehouse.

Jan 1, 1955

[In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 17 and 23, outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible. In view of publications recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 17 and condition 2 on page 23. An explosive or a blasting device enumerated in the permissible lists of thin Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.]

Jan 1, 1941