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"Wet low intensity magnetic separation has been used for the recovery of magnetite for decades. As high-grade reserves continue to decline, low grade magnetite ores are being targeted for iron production. Low grade magnetite mineralisation is typically fine grained and requires fine to ultrafine grinding (P80 40 - 30 µm) to liberate it from, predominantly, silica/silicate gangue matrices. Grinding to such particle sizes requires high power consumption and produces excessive fines which impact negatively on wet magnetic separation and tailings dewatering. In addition, the dearth of fresh water for mineral processing in arid areas impacts negatively on the economic viability of low grade magnetite projects. These challenges have motivated innovation in dry magnetic separation technologies for the beneficiation of magnetite that can be economically applied on a large-scale. Such technology has been developed in the Cyclomag Planar magnetic separator (PMS) invented by South Australia-based Christopher Kelsey of IMPTEC P/L. The significant gangue mineralisation associated with magnetite ores in South Australia is quartz. In this study, the performance of the Cyclomag PMS on the recovery of magnetite mineral from magnetite-quartz blends was investigated. Magnetite-quartz blend were subjected to the PMS at varying control parameters - magnet discs rotation speed, inlet airflow and feeder speed. The study showed a successful dry separation of magnetic mineral from non-magnetics using the Cyclomag PMS. The PMS has potential to effectively recover magnetite mineral."

Jan 1, 2018

By Partha Patra

Numerous proteins of varying properties are available in extracellular bacterial proteins (EBP) isolated from Paenibacillus polymyxa. EBP was fractionated through ammonium sulfate precipitation in a controlled fashion and characterized through SDS-PAGE technique. Different groups of proteins, (Group A~D) exhibited varying degrees of surface affinity to minerals such as quartz, pyrite, chalcopyrite, galena and sphalerite. Interaction with mineral specific bioproteins rendered pyrite and chalcopyrite hydrophilic while surface of quartz, galena and sphalerite turned more hydro-phobic. Specific groups of proteins could thus be used for selective separation of galena, sphalerite and quartz from pyrite and chalcopyrite (as a mixed sulfide) through microbially-induced flotation or selective flocculation.

Jan 1, 2014

By S. Gaydardzhiev

Initial experiments towards preparation of hollow ceramic microtubes by dip-coating of fibrous plants with water based alumina gel-casting slurries using hemp and coconut fibres as templates have been done. It has been found that the wettability of fibres and accordingly the stability of the developed ceramic layer on their surface during slurry gelation varied significantly within the different fibre types. Good correlation between the diameters of the template fibres and the resulting channels has been found at the level of solids loadings used, 31 %. Hemp fibres used as bundles have led to formation of multi channel patterns while the coconut fibres-templated process resulted in uniform monochannel materials. The micro tubes have show good mechanical handling.

Jan 1, 2014

By Amir Hajizadeh Omran, Mehdi Irannajad, Sima Mohammadnejad, Fardis Nakhaei

"This study presents an experimental program performed to investigate the effects of flotation variables including gas flow rate, froth depth, slurry solids percent, frother/collector dosage and pH on the froth bubble size during desulfurization of an iron ore. These conditions were varied using a central composite design (CCD). Image analysis techniques have been developed and used successfully to characterize the froth bubble size. Results of the CCD experiments showed that the flotation variables have different effects on the froth bubble size. The froth height, air flowrate, pH and solid content had the most important influence on the froth bubble size. The interaction between the collector-frother, pH-collector, frother-air flowrate, solid content-froth height, pH-froth height and solid content-pH were also significant. Process state can be accurately deduced from the froth surface appearance, providing a convenient way to quantify the parameters as a function of the process control. INTRODUCTION Flotation processes are subjected to a wide variety of process disturbances, some of which are made by the change in mineral features and others to variation in operating procedures. Feed and air flow rates, densities, size distributions and shapes of particles, surface properties, and reagent dosages and compositions can all change, often with significant effect on the performance of the plant (Moolman et al., 1996a). Flotation process efficiency is governed by the wettability of the solid as well as the surface tension at the liquid-gas. Both of these properties are influenced by operational conditions encountering in a flotation process. The structure of froths developed on the pulp surfaces of flotation cells has a remarkable effect on both the grade and recovery of minerals in the concentrate (Shean and Cilliers, 2011)."

Jan 1, 2018

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By Rolf Lauten, Yongjun Peng, Yufan Mu

"Biopolymers, produced from cellulosic biomass, have promising prospects of application as depressants in mineral processing. In this study, three different types of biopolymers (i.e., DP-1775, DP-1777 and DP-1778) were used to study the effect of polymer structure on flotation of un-activated pyrite, copper activated pyrite and chalcopyrite. It was found that the depressing effect of DP-1775 and DP-1778 was much stronger than that of DP-1777, and pyrite was depressed to a greater content than chalcopyrite with the same biopolymer at the same dosage. The biopolymer concentration played a vital role in determining the degree of depression. For each biopolymer, the higher the concentration, the greater the minerals were depressed. The mechanism underpinning the depressing effect of these biopolymers was explored in this paper. The concentration of biopolymers could determine the properties of the adsorption layer and the confirmation of biopolymer chains on mineral surfaces. The biopolymer molecules may aggregate when polymer concentration was over a critical value. Molecular weight and functional groups of biopolymers were the key factors characterizing the depressing capability of different biopolymers. Differences between the tested biopolymers and features of the adsorbed layer might account for the observed trends in ability to depress pyrite and chalcopyrite flotation. The greater depressing effect of biopolymers on pyrite over chalcopyrite might result from the preferential adsorption of biopolymers on pyrite over chalcopyrite."

Jan 1, 2014

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Eberhard Gock

The worldwide implementation of corrosion protection of low alloyed automotive metal sheets by zinc coating has led to supply shortages of zinc free non-alloyed steel scrap in the foundry industry. In a collaboration project, partly financed by the German government, with partners from the automotive industry, zinc metallurgy, scrap trading, foundry industry, and plant construction, a new acid-based pre-dezincification process has been developed, and a pilot plant with throughput of about 100 t/d has been put into operation at the Clausthal Umwelt-Institut GmbH (CUTEC) together with the Clausthal University of Technology in Germany. During the treatment process, acid from a zinc metallurgical plant will be supplied, which can be recycled to the primary zinc extraction process after raising the zinc concentration to more than 130 g/L zinc. This way, the separation of small amounts of iron by precipitation and the electrolytic zinc winning are outsourced and, as a result, the pre-dezincification process runs waste-free. In Germany, the amount of zinc coated ?new scrap? is approx. 3 million t per year with a zinc content of approximately 60,000 t per year. The possible additional incomes for the dezincified steel scrap are in the order of ?40 to ?50 per ton of scrap, the gained zinc content during the acid dezincification defrays the costs of the process, if the throughput is more than 700 t/d. In comparison to conventional dezincification during the electro arc furnace process followed by upgrading in a rotary kiln (Waelz process), the acid dezincification process running at a maximum of 50°C will cut the energy costs by up to 74% and the CO2 emission by up to 88%. In fact, a demonstration plant is being designed right now and will be installed for processing a part of the zinc coated metal scrap from the Volkswagen AG in Wolfsburg, Germany. Keywords: steel scrap, zinc-coated steel, dezincification methods, acid

Sep 1, 2012

By T. N. Matveeva, L. B. Lantsova, N. K. Gromova

"Multimetal gold-antimony ores are complexed processing products, since they are characterized by veindisseminatedsulfide mineralization with fine-dispersed submicroscopic gold, low content and uneven distribution ofAu, which is concentrated together with iron sulfides (pyrite, arsenopyrite, pyrrhotite). Such ores are classified asrefractory ones and characterized by low gold recovery rates during cyanation. A particular feature of gold-antimonydeposits is the presence of antimony in industrial concentrations therein, along with gold that significantly increasesthe value of these deposits. The main antimony mineral is antimony sulfide - antimonite (stibnite). Gold-antimonyores undergo flotation concentration with producing collective gold-containing concentrates or gold sulfide andantimony concentrates. The purpose of the work is an experimental study of the flotation separation mechanism ofsulfide minerals of copper, antimony and arsenic using tannin-containing modifiers during processing of multimetalgold-bearing ores. During the research it was established that for the selective separation of antimony and arsenicsulfide minerals into concentrates of different kinds, it is possible to use vegetable reagents capable to be selectivelyadsorbed on the arsenopyrite surface. Using the laser KEYENCE VK-9700 and electronic LEO-1420 VP INCA-350microscopy methods, it has been established that the film of a vegetable modifier was not washed off with water andfixed firmly enough on the surface of the polished sections of arsenopyrite. In the X-ray spectrum there are C and Obands related to the reagent structure. The vegetative reagent is fixed both on the pre-adsorbed phase of the collectorand on the areas free from the collector. On the polished sections of antimonite before and after a contact with thetannin solution, only partial adsorbed tannin phases are detected, which disappear as a result of subsequent washingwith water.The reported study was funded by RFBR according to the research project ? 16-05-00646 ?."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

With significant increase in steel output in the world the price of iron ores has been soaring recently. Especially, there is a strong demand for iron ores in China, leading to more attentions paid to developing low grade iron ores. In this paper mineralogy of nm-of-mine hematite ore was deter-mined, and coal-based direct reduction-magnetic concentration was successfully developed to beneficiate low grade hematite ore. Mineralogy analysis indicates that this hematite ore is a super fine refractory ore, with the main valuable mineral hematite being closely associated with quartz and distributing uniformly and mostly occurring within the size of 3~5J.lITI,leading to being difficult to beneficiate due to super fine hematite and only grading 28.83% Fetotal. This hematite ore failed to be effectively upgraded by traditional processes in trial tests, such as reverse flotation, gravity concentration, and magnetic separation, or the integration of the above processes. In contrast with adoption of the coal-based direct reduction-magnetic separation process, concentrate was produced with high iron grade and metallization degree in the present work, which provides a theoretical basis for utilization of low grade iron ores. By optimization of direct reduction conditions, such as reduction temperatures, duration and mass ratio of reductant coal to iron ore, the reduced ore with 93.72% metallization degree was prepared, and then three-stage grinding-magnetic separation of the reduced ore were conducted, the final concentrate was manufactured, assaying 69.54% Fetotal and 98.01 % metallization degree, and with low content of impurities. This iron concentrate with high metallization degree produced by this process is a superior burden for converter instead of blast furnace. This process is enviromnent friendly by directly making iron using coal and iron ores instead of coke, resulting in less emissions and low production cost.

Jan 1, 2014

By L. A. Cisternas, R. I. Jeldres, C. Cruz, P. A. Robles

"Previous studies have shown that the floatability of chalcopyrite in seawater at highly alkaline conditions is significantly affected by the presence of clays. The reason is that the species of calcium and magnesium present in seawater under those conditions may act as a bridge between the surfaces of clay and chalcopyrite, generating massive aggregates that then depress. In this context, the objective of this work is to analyze the impact of pretreated seawater with low amount of calcium and magnesium ions on the recovery of a sulphide copper mineral with high kaolinite content as clay. The seawater pre-treatment is done by the addition of sodium hydroxide in a high carbon dioxide environment. The chemical reactions realized under these conditions lead to the formation and precipitation of calcium and magnesium species that are subsequently removed by vacuum filtration. The pre-treated seawater is then used in flotation tests at pH 11 for copper sulphide, where the mineral is synthetically prepared by mixtures of chalcopyrite, kaolinite, and quartz. When comparing the flotation results for different types of water, including seawater and pre-treated seawater, a significant effect is observed: as the seawater hardness decreases, which comprises the calcium and magnesium ions, the recovery of chalcopyrite is increased. However, the effect is markedly enhanced in the presence of kaolinite. Therefore, the results indicate that sodium hydroxide and carbon dioxide are able to remove different species of calcium and magnesium from seawater and could improve the chalcopyrite recovery with high kaolinite content. INTRODUCTIONIn many cases, mineral deposits are found in arid areas with little access to water resources. Water is a fundamental element to carry out the unit operations that achieved the separation of valuable minerals (especially in concentration operations). Seawater has acquired an interesting role in recent years (Cisternas and Moreno, 2014); in fact, it seems to be one of the few viable options to ensure the sustainability of the mining industry in arid zones. At present, there are numerous experiences of industries that use or have used this resource, either by submitting the seawater to a desalination treatment by reverse osmosis or by applying it directly, without desalting. The latter case may involve significant economic benefits (for example, by avoiding the investment of building a desalination plant) and in some cases some operational benefits. A positive aspect is that in general terms the foaming in the saline medium is much more efficient compared to fresh water (Quinn et al., 2014; Castro et al., 2010). Some reports show that the foaming doses required to achieve a certain quality of bubbles are remarkably reduced, reaching exceptional cases such as Xstrata's Raglan concentrator, where it did not even include foaming to carry out the operation. This fact is quite promising, considering that some researchers have stated that controlling the quality of bubbles and foam could float minerals through coarse particles. This would lead to multiple benefits, such as energy savings by avoiding excessive grinding and a lower presence of fine ore that causes major problems in water recovery operations by gravitation (such as thickening) and in tailings management. However, seawater also causes significant challenges in multiple operations (Jeldres et al., 2017, 2016; Castro et al., 2010), as for example in minerals with high clay content (Uribe et al., 2017). In fresh water, the presence of clays minerals in ores is already a major problem in the flotation stages since the operation becomes difficult to be controlled, and operators are commonly forced to increase the consumption of reagents because the collectors are deposited on the clays' surfaces reducing froth stability (Farrokhpay and Bradshaw, 2012). Sometimes the use of rheology-modifying reagents should also be incorporated since the pulps become more visc"

Jan 1, 2018

By K. C. Corin, M. S. Manono, J. G. Wiese

"It has been suggested that hydroxo species, particularly those of calcium, selectively adsorb onto gangue minerals. Such species enhance the depressive action of carboxymethyl cellulose (CMC) onto gangue via an acid-base interaction between the positively charged mineral surface and the negatively charged CMC molecule. Thus, the hydrophilicity of gangue minerals is enhanced, preventing the dilution of the concentrate. However, as there is little evidence to support these claims it is important to investigate. Adsorption data and mineral surface charge analyses will allow a fundamental understanding into how electrolytes and their ionic strengths affect gangue-depressant adsorption. It is strongly anticipated that decoupling these effects will allow process operators to tailor their process water quality needs towards best flotation operating regimes and in the long run effect closed water circuits. Thus, using talc and pyrrhotite as proxies, this work investigates the influence of the ionic strength of process water on the adsorption of CMC onto minerals in sulphide flotation.INTRODUCTIONThe phenomenon of gangue depression in mineral flotation is of critical importance as regards the attainment of a required concentrate grade. This thus suggests that the depressant of choice has to have a highly selective affinity for the targeted gangue minerals. This would ensure the necessary prevention of gangue from reporting to the concentrate without inadvertently depressing the value bearing mineral. The chemistry of the environment regulates the manner in which gangue depression occurs. In sulphide flotation, polysaccharides are used as depressants of choice to depress naturally floatable gangue which may in the case of Merensky ores exist as talc. The two widely used polysaccharides in the South African context are carboxymethyl cellulose (CMC) and modified guar gum. It is suggested that polysaccharides depress gangue by rendering the surface of gangue hydrophilic or by preventing the formation of hydrophobic layers on gangue mineral surface, forming large gangue aggregates and thereby increasing their heterocoagulative nature (Shortridge et al., 1999)."

Jan 1, 2018

By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

By Nilmara Dias, Maria Margarida Martins, Maria Teresa Carvalho

"The heavy residual fraction of the mechanical and biological treatment (MBT) plants treating undifferentiated municipal solid waste is mostly composed by inert materials, such as glass, stones, ceramics and brick. Glass, appearing in significant grade and amount, is not recycled today due to the high content in the other materials, mainly stones. All these materials have approximately the same density but stones have significantly different shape from other materials particles. In this paper it is presented the research developed to eliminate stones appearing in the fine fraction (2.8-8 mm) of the MBT plants heavy residual fraction (MBTr) using a shaking table operated in dry conditions. Two different samples from two different MBT plants were used. Firstly, the samples were characterized (materials content and particle size analysis). Then, laboratory work was carried out to optimize the operation of the shaking table, by changing the machine parameters, deck slope and movement frequency. The study showed that it is possible to upgrade the product in glass. The best results, obtained with one single stage of processing, were 82% content in glass with 84% in recovery, in the glass concentrate, when the coarser fraction (-8+5.6 mm) of one of the MBT plants was used. With the intermediate particle size fraction (-5.6 + 4mm), the glass concentrate attained 74% content in glass with 91% recovery."

Jan 1, 2014

By M. Panayotova

Most of the quantity of the water soluble xanthates, used in mineral flotation, is consumed in the process. However, the residue amounts are water contaminants downstream the mineral processing operations and can be toxic to aquatic biota at concentrations of 1 mg/L. In order to be able to discharge water from tailing ponds to natural water bodies the concentration of xanthates has to be decreased. The present paper studies the uptake of potassium ethyl xanthate by directly modified with copper and lead ions natural zeolitic rock, without passing through zeolite transformation into homoionic form. Modified zeolite exhibits high, comparable with powdered activated carbon of chemical purity grade, capacity to remove potassium ethyl xanthate from model wastewater, with pH in the range of 7?9 and pollutant concentration in the range of 10-150 mg/L. The pollutant immobilization is fast. Both Cu and Pb modified zeolite behave as selective with respect to xanthate in the model wastewater, and Cu-modified zeolite possesses higher selectivity. The equilibrium is best described by the Freundlich equation. Keywords: xanthate, wastewater, modified zeolite

Sep 1, 2012

By Vladimir F. Skorokhodov, Nikolay N. Melnikov, Svetlana P. Mesyats

"Among the problems of the civilization development, a problem of interaction between man and natural environment can be highlighted. In the twentieth century the human transforming activity had got scales of geological processes and defined the contradiction between the goal to increase the quality of human life and possibilities of the natural environment. Last twenty-five years after the World Summit on the Environment (1992) indicate that the development of civilization is still based on receiving super profits from the natural resources exploitation. This statement is confirmed by economy globalization rates, growing contradictions between consumption and production, depletion and degradation natural environment. A new technological order is formed at the time of growing world population, technological capacities, organizational complexity, from one side, and global scales of geo-resources consumption, on the other side. Sciences, determining the further civilization development, should take on the task to change the social worldview, since the preservation of human population consists in remediating and maintenance of biosphere functions as a regulator of ecological balance. The new worldview in the geo-resources exploitation is based on the Ecological strategy of mining development, which consists in reducing mining-induced loading on natural environment while increasing efficient mineral production and processing, and providing for a comprehensive solution of tasks on mineral deposit development. One of strategic trend of mining development is to increase complexity and completeness of useful component extraction from ore and mining deposits while reducing wastes and decreasing their stockpiled volumes. The implementation of the ecological strategy has shown that the future is determined by reduction of the environmental impact while improving the efficiency of mineral mining and processing.INTRODUCTION The global nature of environmental problems caused by the scale of consumption of natural resources, huge amounts of waste, and intensive man-made impact on the environment requires a revision of the strategy for the natural resources development. Many existing technologies are ineffective in achieving the ultimate goal. Direct output in the raw materials - the end product technological chain rarely exceeds 10%, which implies a huge amount of work to move the soil. In addition, the feature of scientific and technological progress at the present stage is the growth of power-to-weight ratio."

Jan 1, 2018

By Junji Shibata

In a present process to treat the tungsten carbide tool waste, the wastes are roasted in air and then an alkali leaching is carried out in an autoclave. An environmentally friendly process is required to recover rare metals (Co and W) from the wastes. The effect of mechano-chemical (MC) treatment on leaching of rare metals was investigated in this study. The solvent extraction and crystallization-stripping methods were applied to separate and recover tungsten and cobalt in the leached solutions. The MC treatment for the rare metal leaching is effective to dissolve rare metals from the wastes due to the change in crystalline structure of WC and oxidation of WC with KMnO4. Cobalt ions are extracted with D2EHPA by a cation exchange reaction. Tungsten in the leachate can be extracted by TOA (tri-octyl amine) as an extractant, because tungsten species exist as a form of anionic species in acidic solution. The rare metals in organic phase are recovered as insoluble salts such as oxalates and ammonium salts in the crystallization-stripping process. Keywords:unheated oxidation, solvent extraction, crystallization-stripping, recycling

Sep 1, 2012

By David Deglon, Martin Harris, Mehdi Safari

This paper investigates the effect of energy input on the flotation of galena in a novel oscillating grid flotation cell (OGC). Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Previous work was limited to quartz (-100 µm). Galena (-150 µm) was floated in the OGC at power intensities from 0.5 to 3 W/kg using 0.13, 0.58 and 0.82 mm mean bubble sizes (d10) and at three collector dosages. Results show that the effect of power intensity on flotation kinetics is strongly dependent on both particle and bubble size. For fine particles (-19 µm), increasing energy input increases the flotation rate at a low collector dosage but leads to an optimum at both the moderate and high collector dosages. For intermediate particles (+19-38 µm), increasing energy input has no effect on the flotation rate at the low collector dosage but leads to an optimum at both moderate and high collector dosages. For coarse particles (+38-150 µm), increasing energy input has no effect on the flotation rate at the low collector dosage and leads to a general decrease at both moderate and high collector dosages. Optimum conditions for fine particles are using small bubbles at a moderate collector dosage and an energy input of around 2 W/kg. Optimum conditions for moderate particles are using small bubbles at a high collector dosage and energy inputs of around 1.0 W/kg. Coarse particles do not benefit from agitation.

Jan 1, 2014

By A. V. Nguye, P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration. Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. A possible mechanism, based on the existence of the pre-existing submicron-sized gas bubbles, known as bubstons (i.e. bubbles stabilized by ions), present in water in close proximity to the hydrophobic coal surfaces is discussed in line with the early observation of flotation improvements by microbubbles “nucleating” on hydrophobic surfaces. In particular, the dependence of the bubble-particle attachment efficiency on electrolyte concentrations supports hypothesis on the salt-dependent and ion-specific existence of bubstons. However, a theoretical explanation of the transition salt concentration (at about 0.1M) is deficient at present. The existence of these submicrobubbles in close proximity to hydrophobic surfaces is not trivial. They can (as can individual gas molecules or other solutes) mediate and extend the range and magnitude of the attraction between hydrophobic macroscopic surfaces. These bubbstons may explain the curious phenomena of the socalled long-ranged hydrophobic attraction measured with the Surface Force Apparatus and Atomic Force Microscopy, and the slippage at hydrophobic surfaces. Finally, the coalescence of bubbstons affects the rupture of liquid films at a very large thickness (over 100 nm), observed, but unexpected, by flotation chemists.

Jan 1, 2003