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By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012

By A. S. Choudhary

Most of the coal reserves in India are of drift origin and have very poor washability characteristics and a high level of near gravity materials. At least 30 new coal wash plants are expected to be set up in the next 5years.In such a scenario, adequate sampling followed by sink float test work for washability analysis becomes very critical for designing these new plants. For coal sampling purpose, stipulations of different standards are sometimes formidable and on the border of ?impracticality?; sometimes are self contradictory in terms of gross sample weight vis-a-vis minimum number of particles required in each size fraction and in each relative density fraction and also the minimum mass in the latter. Validation of the generated data is another important aspect of washability analysis. These issues can easily be addressed by using straight forward mathematical relationships, well known RR plots and by using simple MS Excel tool, etc.

Sep 1, 2012

By W. Y. Liu

A sulfate reducing bacteria strain (named SRB-A) is isolated from sanitary wastewater by using anaerobic technology of Hungate. The studies of physiological, biochemical and phylogenic of the isolated strain are carried out. The colonies of the strain are circle. Cells that are slightly curve, rod-shaped with the size of 1.0~3.0µm in length and 0.8~1.0µm in width. The optimum temperature for growth of the organism is 30~35°C. The optimum pH for growth is 7.0~7.2. Strain SRB-A can use sodium lactate, sodium citrate, sodium acetate, ethanol and acetone as electronic acceptor but can not use glycerol, glucose, sucrose and sodium oxatate. The isolated strain reduces sulfate, sulfide, sulfur, DSMO and FeCl3, then nitrate and nitrite can not be used. The strain has higher tolerance of NaCl, and the optimum growth occurs in the presence of 5%~8% (w/v) NaCl. The result of 16S rDNA sequence analysis indicates that the isolated strain SRB-A is the most similar to Desulfo-vibrio halophilus, and the level of the similarity was 98.4%. The isolated strain has a stronger ability to reduce sulfate, and the level of sulfate reduction reaches about 90% at pH 7 in the liquid medium. 0.6 to 0.8 is the optimum COD/SO42- in the medium for the isolated strain to show better ability to reduce sulfate. At pH 2.5 the level of removal of Cu2+ reaches 96.3%. Under the condition of pH 3.5, the level of removal of Zn2+ reaches 92.6%. When the value of pH reaches about 7, the Fe3+ is precipitated by the formation of Fe(OH)3, and Fe3+ is removed up to 89.4% at last.

Jan 1, 2014

By A. P. Chaves, D. Jose Neto, M. G. Bergerman, E. S. Mano

"More complex ore comminution and concentration operations have found increasing application in the mining industry due to lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. They allow removing a significant mass of material with little or no content of the relevant mineral before the ore is fed into the processing plant, with the consequent reduction in the mass to be processed in downstream operations. Significant benefits arise out of the use of pre-concentration, such as higher contained metal output without the need to increase the grinding or flotation capacity, and longer mine life. The grade of marginal ores could be enhanced to a level that would make their exploration economically feasible, which would result in increasing exploitable reserves. Nevertheless, few studies to date have assessed the resulting impacts on ore grinding energy consumption and wear after the gangue is removed through pre-concentration operations. This study evaluated the energy consumption and wear of grinding circuits in Brazilian mining operations in which the feed has gone through a pre-concentration stage. Such assessment was based on different samples of sulfide and oxide ores. Laboratory tests were carried out to investigate the power consumption and wear of grinding circuits with and without a pre-concentration stage. Laboratory test results were used to simulate industrial grinding circuits based on both alternatives and illustrate the environmental and economic benefits of each one.INTRODUCTION Increasingly complex ore concentration operations in several stages have found broadening application in recent years in view of lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. Different ore processing technologies can be used for that purpose, such as magnetic separation, density segregation, and separation methods based on high-tech sensors (ore sorting). Currently, the most common methods are gravimetric processes, in view of their low cost, particularly jigging and dense medium separation methods, such as the drum and cone separators manufactured by Western Machinery Company, Teska, Drewboy, Norwalt, Dynawhirlpool and Tri-flo, and dense medium cyclones (CAMPOS; LUZ; BRAGA, 2010). The use of dry ore sorters has also grown significantly in recent years (Jose Neto et al. 2017). The selection of the separator type depends essentially on the ore particle size, required flows, and operating density ranges. All these methods may even be used after preferential blasting in mining (Grigg & Delemontex, 2015)."

Jan 1, 2018

By Mauricio Guimarães Bergerman

At the regrind or secondary grinding stages of base metal ores, the concern about energy efficiency is usually extremely important. In general, the specific energy consumption at this stage is higher than during the primary grinding stages. In addition, a tendency of finer grinding has been observed in the new projects of metallic minerals, due to the finer mineral liberation, which leads to increasing capital and operational costs. At Vale?s new copper projects in Brazil, regrind sizes with a P80 of approximately 40 to 20 µm have been necessary. Conventional ball mills, adequate for primary grinding, usually bring about low energy efficiency with products bellow 50 µm. Vale is using the vertical mill on its copper projects ? Sossego and Salobo, in order to optimize the regrind of rougher concentrates and reduce energy consumption. This paper presents the results of industrial surveys carried out on the Vertical mill circuits of Sossego plant during its initial years of operation, and compares these results with the design criteria and laboratory regrind tests used for the mill scale up. Keywords: grinding, regrinding, copper, vertical mill, stirred mill

Sep 1, 2012

During incineration of municipal solid waste (MSW), various environmentally harmful elements and heavy metals are liberated partly into bottom ash, and partly carried away with the off-gases and subsequently trapped in fly-ash. If these waste incineration residues are not properly processed and immobilized, it can lead to secondary environmental pollution to the air, soil and water. The stricter environmental regulations require a higher immobilization efficiency of the waste incineration residues, which is the main objective of the present cooperation research. Within the present project, a systematic scientific research on various MSWI residues has been carried out, including sampling, low or high temperature processing and leaching tests. In the present paper, the major results have been summarized. The research results reveal that through appropriate combined pre-processing and high temperature vitrification, the bottom ash and fly ash can be efficiently stabilized. The results achieved provide a valuable alternative route to treat the solid residues from incinerators, and to make efficient recycling and safe utilization possible.

Jan 1, 2014

By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By M. Surracco, M. C. Tilocca

"Mineral comminution is often a costly process which also requires high level of energy. In the course of the studies carried out by the researchers of the Department of Civil-Environmental Engineering and Architecture at the University of Cagliari, aiming at the optimization of the reduction processes, it has been experimented, among of others, the effects of high-speed water jets on minerals grinding. As far as coal is concerned, some of the solutions initially adopted are presented in this paper, which essentially relied on the water jet power only, with secondary use of mechanical actions, to reach the most modern solutions that envisage the use of mechanical energy, normally used in traditional grinding machines, in synergy with hydraulic energy transferred by water jet.INTRODUCTION Mineral comminution can be rather expensive and demand a high-energy consumption, especially for fine sizes (Austin, 1979). Further interesting perspectives in this area may be offered by comminution means aided by high pressure water jets (Ciccu 2007), whose crushing potential is currently used for several operations such as cutting different materials, rock digging and industrial cleaning. The crushing action of water jets may induce a traction stress in materials where substances of a mineral nature, especially if characterised by permeable porosity, oppose a minor resistance (Griffith, 1920). The first solutions to this purpose essentially relied on the sole energy of water jets, with a secondary use of mechanical actions (Ciccu, 1993). Results were encouraging, despite the high values of specific energy for the low capacity of treatment. However, due to the difficulty in making the techniques mainly based on hydraulic energy practically applicable to solids comminution a solution was experimented, with some interesting results, consisting in the combination of mechanical energy, normally used in traditional grinding devices, with hydraulic energy transferred through water jets, in a synergic relationship (Ciccu, 1998; Tilocca, 2016)."

Jan 1, 2018

By F. N. Shi

Ore breakage characterization plays an essential role in the design and optimization of comminution circuits. Recently, the JKMRC comminution research team has developed a Rotary Breakage Tester (JKRBT). The JKRBT uses a rotor-stator impacting system, in which particles gain a con-trolled kinetic energy and are impacted against the stator, causing particle breakage. The first unit of industrialised JKRBT was installed at the Anglo Research in South Africa in March 2007, and five more JKRBTs are currently being fabricated for some of the world?s major mining companies. In addition to the JKRBT, an improved breakage model has been developed at the JKMRC, which more accurately describes the effect of specific energy, particle size and incremental breakage caused by repetitive impacts. The validation outcomes show that the JKRBT, together with the new breakage model, generate statistically similar breakage parameters to the traditional drop weight tester (DWT), but with significant advantages over its predecessor. The limitations of the DWT, specifically its lack of precision of the energy input, the lengthy time required to run individual tests and the challenges en-countered in testing small particles, have all been overcome by the JKRBT. The recent developments in the JKRBT and the new breakage model offer several prospective applications. These developments have the potential to revolutionize the ore breakage characterization in the years to come.

Jan 1, 2014

By A. F. Raschenko, Y. A. Golodcov, V. V. Elshin

"The autoclave noble metal desorption in apparatuses with a dense stationary sorbent layer is perspective for the technology of sorption gold and silver extraction from solutions and pulps by carbon sorbents. The study of the mechanism and optimization of the autoclave desorption process involve some difficulties. To overcome them it is necessary to use mathematical and quantum-chemical modelling. The given paper deals with a mathematical model for the dynamics of gold and silver desorption from active carbons by alkali solutions based on the physical-chemical notions of the process. The kinetics and the mechanism of the process were investigated using the mathematical model for gold and silver desorption.The calculation of the efficient mass-transfer coefficient (ße) for various initial and intermediate noble metal concentrations in carbon (Cy) made it possible to find that the dependence of ße on Cy in case of gold desoprtion shows a clear extreme character. The value of the initial metal concentration in carbon therewith does not influence the character of the curve the inflection point of which is changed essentially at elevated process temperatures only. The revealed characteristic property, in the author's opinion can only be indicative of the change in the mechanism of gold desorption under autoclave desorption conditions. The assumed [Au(CN)(OH)]- type intermediate that has a higher diffusion coefficient in comparison with the adsorbed complex [Au(CN)2]- can be considered as an intermediate compound in the process of gold desorption."

Jan 1, 2003

By Fang Liu, Xin Tan, Zhong-ming Wang, Yan-bo Shang, Jie Zhao

"The flotation separation of sulphides bulk concentrate containing Cu, Zn, Mo and Bi, which was obtained by both table-flotation of gross sand of gravity separation of wolframite and bulk flotation of wolframite slimes using butyl xanthate and oil No. 2, etc., has been conducted by using the cyanide process in the tungsten concentrator. The process has problems of high reagents consumption (25 tonne of cyanide dosage per year) and mineral processing cost (800~1000 RMB reagents cost per tonne of by-product concentrates), high mutual containing loss in the by-product concentrates and serious environmental pollution caused by lots of cyanide-containing wastewater. In order to solve this problem, a new cyanide-free separation technology is studied, which is used to process this sulphides bulk concentrate with 8.68% Cu, 8.98% Zn, 0.26% Mo, 1.58% Bi and 40.12% S. The results of the closed circuit test show that Cu, Zn, Mo and Bi can effectively be separated from this sulphide minerals concentrate by using the reasonable flotation-gravity flowsheet, high-efficiency collectors and regulators simultaneously. The metallurgical recovery and concentrate grade are as follows: molybdenum recovery is 94.63% with 50.62% Mo content; copper recovery is 85.18% with 29.29% Cu content; zinc recovery is 75.92% with 46.49% Zn content; total Bi recovery is 65.08% with 16.86% Bi content. The new technology is an alternative to the cyanide process due to its low cost for reagents, satisfying separation results and economic profits, and solves the problem of environmental pollution caused by the use of large quantities of cyanide. Some important parameters in separating the Cu-Zn-Mo-Bi sulphides concentrate are also introduced in this paper. This study provides pretty good technical support for separating the polymetallic sulphide ores containing Cu, Zn, Mo and Bi by cyanide-free technique."

Jan 1, 2014

By B. Rezai

Impeller speed and air flow rate are two influence parameters on coarse particles flotation and collision and attachment angles. So, in this research recovery of quartz particles at four diameter classes carried out and collision and attachment angles investigated. It is found that maximum flotation response was observed at Impeller speed of 1100 rpm and 15 L/h air flow rate. For either more quiescent (Impeller speed<1100 rpm) or more turbulent conditions, flotation recovery decreased steadily. Furthermore, amount of attachment probabilities is calculated using suitable equation. According to this study, with decreasing particle size, air flow rate and impeller speed, probability of attachment increased and with increasing contact angle, probability of attachment increased. For various air flow rates, impeller speed and particle size, collision angle has been calculated. Maximum collision angle obtained at with 15 L/h air flow rate, particle size of 256 µm and impeller speed of 700 rpm and minimum collision angle obtained at with 45 L/h air flow rate, particle size of 545µm and impeller speed of 1300 rpm. In this study, maximum attachment angle, , was around 75 L/h air flow rate, particle size of 256 µm, contact angle of and impeller speed of 1300 rpm and minimum attachment angle was with 15 L/h air flow rate, particle size of 545 µm, contact angle of and impeller speed of 1300 rpm. ?82.72 ?64 cr??33.39 ?90 ?13.0 ?60

Jan 1, 2014

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool, HeapSim. Some of the sub-processes that are modelled include mineral kinetics, particle size effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation. The interplay of these various sub-processes is illustrated in the paper.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. The first is focussed on chalcocite heap bioleaching, which shows that by nature of the reaction the process is strongly dependent on the initial supply of acid to the mineral site. In heaps this acid supply can be severely limited by the rate of diffusion from channels of flowing solution into stagnant zones of the heap, whereas in narrow-bore laboratory columns this effect is not observed."

Jan 1, 2003

By G. B. Abaka-Wood

"The versatility of froth flotation has made it vital in the beneficiation of rare earth elements (REE) minerals from either high or low grade ores of complex mineralogy. There has been a significant increase in the tonnage of rich iron oxide tailings obtained from extraction of primary commodities such as copper and gold in Australia, which have been identified to have very low grade rare earth oxides (REO) (= 1%). There is a vast knowledge gap in the upgrade of REO from such tailings. The aim of this research is to investigate the feasibility of the use of fatty acids for the upgrading of REO from selected iron-oxide rich tailings. Two forms of fatty acid collectors (oleic acid and sodium oleate) were employed in this investigation. Bench scale flotation tests were carried out using a Denver D-12 cell.The effects of pulp pH, fatty acid dosage, particle size distribution (-150 +75 µm, -75 +38 µm and -38 µm) and conventional depressants (sodium silicate and starch) dosage on flotation recovery of REO were investigated. A comparison of the flotation results indicated that sodium oleate was the more efficient fatty acid for REO flotation at all the pulp pH investigated. The flotation performance is demonstrated to be particle size-dependent. The results on the effect of depressants dosage indicated that both sodium silicate and starch were unselective in reducing the recovery of hematite (Fe2O3) and quartz (SiO2) with corresponding decrease in REO recovery. Generally, Fe2O3 and SiO2 formed substantial contents of the flotation concentrates obtained, both in the absence and presence of depressants, which indicates liberation is a major challenge in achieving selective REO upgrade and recovery.The flotation tests carried out on the iron-oxide rich tailings suggest the possibility of REO upgrade using fatty acids, although particle size distribution and minerals liberation are key limiting factors in achieving selective REO upgrade and recovery."

Jan 1, 2018

By U. A. Peuker, T. Mütze, F. Shayo, A. Wikedzi

"Buzwagi Gold Mine (BGM) is operated by Acacia Mining and located in the Lake Victoria Goldfields of central Tanzania. The mine treats a sulphide copper-gold ore to produce gold in form of doré bars and a concentrate containing gold, copper and silver. The BGM comminution circuit includes a primary crushing stage with a gyratory crusher and two grinding circuits using a Semi-Autogenous Grinding (SAG) mill and a ball mill. Currently, the grinding circuits are inefficient in achieving the aspired product fineness of xP,80 = 125 µm even at low to normal throughputs (450-600 t/h). An optimization study of the circuit performance was conducted to improve product fineness through circuit surveys, experimental lab work and simulations. The analysis of survey data revealed inefficient grinding operation characterized by ball mill product (xP,80 > 400 µm) coarser than designed and higher hydrocyclone cut sizes (xT > 200 µm), too. In MODSIM several options were simulated such as reduction of vortex finder and apex diameters, reduction of SAG screen aperture, and modification of cyclone feed density. An improvement of product fineness could be achieved by simulation of the cumulative changes but it was also concluded that the current equipment cannot achieve the target. Further simulations showed that a second ball mill might help to achieve the desired fineness as well as an increase of grinding throughput by up to 26 %. INTRODUCTION Simulation of comminution, particularly grinding and classification, has received great attention for many years, due to the fact that the unit operation is by far the most important both in terms of energy consumption as well as overall plant performance (King, 2001; Wills et al., 2006). The use of simulation is advantageous due to low cost as well as its ability to consider many variables simultaneously. Moreover, there are some benefits for optimizing grinding operations by simulation like decreased unit operating costs, increased capacity, and improved performance of downstream processes due to improved feed size distribution. This paper presents an optimization study for the grinding efficiency at Buzwagi Gold Mine. This was achieved through three full scale circuit surveys, lab work and simulations with MODSIM."

Jan 1, 2018

By J. T. Liu

Packing in a flotation column is one way to increase separation efficiency and effective descending flotation-column height. In this paper, the difference between filling packing and sieve packing is described, and the flaws of filling packing in flotation columns in industrial application are pointed out. A change of flotation process and its effect on flotation results are reported. Based on sieve-plate filling, a high-efficiency mixed packing mode consisting of screen-plate packing and honeycomb-tube packing has been proposed, with the packing mode optimized in the cyclonic static microbubble flotation column in the separation zone. In the mixed packing mode, the honeycomb tubes are used to reduce the vortex effect at the base of the column and weaken the radial dispersion of jetting bubbles, and the sieve plates are used to comminute bubbles in the separation zone, to lengthen the bubble migration path, and to stabilize the foam layer. The superiority of honeycomb-tube packing is analyzed using bubble-particle collision theory, and the dynamic equations of collision probability are derived. The role of mixed packing in guaranteeing mineral recovery is analyzed by the axial dispersion method, and a dimensionless axial dispersion model is derived. When a high-turbulence flow is maintained, a static separation environment is formed in which secondary mineral processing is rendered more effective. In this way, a nonlinear separation environment is formed in the flotation column. Finally, mixed packing was applied in an industrial test. A large vortex developed at the base of the column. It was observed that the bubbles in the radial flow were homogeneously dispersed, the residence time of the pulp was prolonged, and the froth layer became thick and stable. Based on the test data, it was found that the sieve packing has the potential to yield a product of approximately 25.83% copper concentration with 91.78% recovery from a feed concentration of approximately 0.727%. If mixed packing were used, the product concentration could be further increased to 27.60% from a feed of approximately 0.739% concentration with 93.38% recovery.

Jan 1, 2014

By Zhang Zhonghan

A domestic tungsten-tin ore presents very complex property. How to effectively recover the scheelite, wolframite and cassiterite in the ore has long been a difficult problem to be solved urgently. On the basis of process mineralogy study, a main flow-sheet for effective recovery of tungsten-tin minerals has been developed, which including ?fine grinding of feed?bulk flotation of all sulfides followed by their selective separation?iron recovery by LIMS?tungsten-tin minerals bulk flotation using new technique developed by our institute?tungsten-tin recovery by gravity from above tungsten-tin bulk flotation tailings?. As for the treatment of tungsten-tin bulk rougher concentrate, several flow-sheets of tungsten-tin separation by direct hydrometallurgy or a flow-sheet consisting of scheelite cleaning at elevated temperature followed by the gravity separation of scheelite cleaner tailing?separation of wolframite from cassiterite by dry HIMS or by direct hydrometallurgy are developed. For a low grade head ore, all valuable sulfide, magnetite, scheelite, wolframite and cassiterite are recovered with satisfactory in lab scale test. Keywords: micro-fine cassiterite, tungsten-tin bulk flotation, gravity separation-flotation-dry HIMS combined flow-sheet, hydrometallurgy

Sep 1, 2012

By S. H. Morar

Froth flotation is a physico-chemical separation process that takes place in two phases; pulp and froth phase. It is widely recognised as a complex process, due to the range of interactions present within the system. Of critical importance is the role of the froth phase within the system. The pulp kinetics governs the maximum potential recovery within a flotation cell, while the froth phase governs the selectivity via the froth?s stability. Higher froth stability improves recovery at the expense of grade, and lower froth stability improves selectivity. It is well known that the two major factors affecting froth stability are attached particles and solution chemistry. This paper looks at a flotation bank at different froth depth and frother concentrations. The air recovery to the concentrate is determined at each condition and relates the effect of the operating conditions on froth stability and transport to the amount of solids that are recovered to the froth and concentrate by true flotation. The results presented show that, for a given process objective, which in this case was a consistent mass pull profile, depending on the operating conditions, solids recovery in the pulp is affected by the air rate required to maintain the target mass pull. To a smaller extent, the changes in the pulp composition affect down-stream pulp recovery. The variation in solids recovered into the froth drives the froth stability at the start of the flotation bank, while the frother drives the froth stability at the end of the bank. The performance in between these two extreme conditions arises from an interaction of these two effects. The consequences of these interactions can give rise to counter-intuitive responses that can confound efforts to optimise the performance of the bank.

Jan 1, 2014

By F. Karakas

Organo-bentonite production enjoys important applications including solvent based paints and, more importantly, the production of polymer/bentonite nanocomposites. Quarternary ammonium salts in this regard are still considered as the most versatile reagents in the process of hydrophobization. In this study, a purified form of Resadiye region bentonites, which is one of the most significant sodium bentonite deposits in the world, was used. The raw Na-Bentonite was typically characterized by chemical analysis, XRD and DTA analysis and more importantly for its cation exchange capacity (CEC). Other technological properties such as swelling index, pH, apparent viscosity, water absorption, oil absorption were also conducted on the raw bentonite. The mineralogical analysis of the raw bentonite reveals that it contains about 80 % montmorillonite together with other associated gangue minerals including feldspar, quartz, calcite, dolomite, coloured impurities and other clay minerals. The raw bentonite was subjected to two stage processing involving a series of hydrocylones. Different apex and vortex diameters and different pressures were employed in order to produce a bentonite concentrate with 95 meq/100g CEC from a CEC of 71 meq/100 g. This high quality concentrate was used in the production of organo-bentontonite. The modification was performed with two different quaternary amines, i.e. Trimethyl Phenyl Ammonium Chloride (TPAC) and Hexadecyl Trimethyl Ammonium Bromide (HDTMA-Br). In the modification procedure, three parameters, i.e., adsorption density, zeta potential, swelling index and apparent viscosity were studied simultaneous-ly from the same suspension to identify both the mechanism of the process and also the degree of hydrophobicity. Adsorption measurements were made as a function of conditioning period, pH, and reagent concentration. Simultaneous examination of the adsorption density, zeta potential and apparent viscosity enabled us to pinpoint the optimum region of hydrophobicity which was subsequently tested by settling and critical coagulation concentration in both water as polar and toluene as nonpolar solvents. The results are analyzed in the light of experimental data.

Jan 1, 2014