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By B. Courtaud

Uranium plants are generally located quite far from conversion plants, resulting in high transport costs. One way of reducing such costs involves putting more uranium in each drum by increasing the final product?s bulk density, which can be achieved via mechanical compaction of the powder and/or improved precipitation. For most of its plants, AREVA has adopted the latter approach, involving a new precipitation process applicable to all kinds of yellowcake produced (via uranates, uranium peroxide, etc.) that achieves bulk density of 3 for soda uranate, for example, instead of the 1.5-2 density available via conventional processes. At present, this process is being undertaken on an industrial scale and will become the norm for precipitation processes at all AREVA U plants. In addition to producing dense yellowcake, the process also delivers a product with no fines, a spherical particle shape (which allows for high-quality powder flow) and superior post-precipitation filterability

Sep 1, 2012

By Stoyan N. Groudev, Ioannis Paspaliaris, Plamen S. Georgiev, Irena I. Spasova, Kostas Komnitsas

"The uranium deposit Curilo located in Western Bulgaria for a long period of time was a site of intensive mining activities including both the open-pit and underground mining techniques as well as in situ leaching of uranium. The ore was rich in pyrite and, apart from uranium, contained some non-ferrous metals. The mining operations in the deposit were ended in 1990 but since that time the deposit is a permanent source of acid drainage waters. The generation of these waters is connected mainly with the oxidation of pyrite and other sulphide minerals by the indigenous acidophilic chemolithotrophic bacteria.Laboratory and pilot-scale studies revealed that an efficient clean-up of the above-mentioned waters was achieved by means of passive systems of the wetland type. In 2001 a wetland was constructed in the deposit to treat a portion of the acid drainage waters which were discharged to a small ravine. This ravine reaches into the Teina, a small river that is a tributary of the upper reaches of the Iskar river.The wetland was constructed in the ravine and its bottom was located on intrusive rocks with a very low permeability. The rocks were covered by a 30 – 50 cm layer consisting of a mixture of soil, plant compost and crushed limestone. The wetland was characterized by an abundant water and emergent vegetation and a diverse microflora. Typha latifolia, Typha angustifolia and Phragmites australis were the prevalent plant species in the wetland but species of the genera Juncus, Eleocharis, Carex and Poa as well as different algae were also well present.The acid drainage waters treated by the wetland had a pH in the range of about 2.5 – 4.1 and contained uranium, radium, some heavy metals (iron, manganese, copper, zinc, cadmium, lead), arsenic and sulphates in concentrations much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The watercourse through the wetland covered a distance of about 0.2 – 1.0 l/s."

Jan 1, 2003

By Mikhail I. Khersonskaya, Mark I. Mantsevich, Andrey V. Tarasov

"Due to depletion of the existing ore deposits the content of non-ferrous metals in produced ores has an inevitable tendency to decrease. Processing of low-grade ores is associated with production of low-grade selective concentrates and poses serious problems for the non-ferrous industry relating to increasing losses and expenses for waste treatment and disposal.The main component contaminating selective concentrates is iron sulphides.Copper-nickel, copper-zinc and polymetallic ores have been discussed as most important types of ores requiring removal of iron sulphides.One of the promising directions for development of selective flotation technology is the use of lowmolecular organic depressors. An advantage of organic compounds is in the possibility of multi-variant structure of organic molecules, which permits selection of a most efficient reagent for the given conditions. Another way for improving the grades of concentrates is concentration of valuable constituents associated with iron sulphides in an intermediate product and upgrading of the latter by chemical and metallurgical techniques.In order to remove iron from nickel concentrates, specific process conditions have been developed for selective flotation of pentlandite with the use of an organic depressor for pyrrhotite. The use of a depressor for flotation of high-grade copper-nickel ores ensures an increase in the nickel content up to 14% in the nickel concentrate produced as compared with 7% when using conventional process conditions, along with a nickel recovery improved by 2-3%."

Jan 1, 2003

By Dave Deglon

"The Western Cape Mineral Processing Facility (WCMPF) is a collaborative educational initiative between the Departments of Chemical Engineering of the University of Cape Town, the University of Stellenbosch and the Cape Technikon. The primary objective of the WCMPF is to facilitate the education, development and graduation of suitably qualified engineering graduates and diplomates for the mining industry. The WCMPF consists of academics and Technical Officers in the Departments of Chemical Engineering of the three tertiary institutions. The Technical Officers are usually metallurgists, with several years of industrial experience. The main objective of the Technical Officers is to improve the practical education of mineral processing students. In addition, the Technical Officers are responsible for organising an annual mineral processing student field trip for students from all three tertiary educational institutions. In recent years the WCMPF has embarked on a number of additional initiatives aimed at improving the quality of mineral processing education. These include the development of several new pilot plant practicals, an initiative in pyrometallurgy, the introduction of novel ‘end to end’ or ‘integrated’ practicals and the use of mineral processing simulation packages to complement the practical training.The WCMPF has been functioning for well over a decade and, by virtue of this, might be considered a successful collaborative educational initiative. The WCMPF has played a key role in the education of over five hundred mineral processing graduates and diplomates. During this time period, the WCMPF has gained a body of internal knowledge which might be of benefit to other educational institutions, viz."

Jan 1, 2003

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By Paolo Bevilacqua, Paolo Antonini, Lorenzo De Lorenzi

"Italy is one of the major producers of ceramics in the world. Ceramic production requires large quantities of K-feldspar, which is commonly sourced from granites, alkali-granites, and “granitic” sands. These rocks contain other minerals, such as quartz, plagioclase and mafic minerals, which are undesirable for ceramic production. Due to the coarse mineral grains that constitute these rocks, a reasonable liberation is achieved at a relatively coarse grind size.This paper reports a study conducted on the separation of K-feldspar from quartz, plagioclase and biotite, from a feed of ground granite. The feasibility of the separation using a dynamic dense medium separation system has been investigated, as an alternative to the traditional flotation technique. The use of a two stages cylindrical vessel (Tri-Flo) was preferred to a conical vessel, due to the improved separation efficiency. Tests were conducted on two samples of crushed granite having size distributions of –3 +1 mm and –1 +0.5 mm.Heavy liquid analysis was performed on the two samples. As the rheological properties of the dense medium interact with the separation efficiency, the stability and viscosity of the dense medium were controlled and kept within an appropriate range; which was achieved with the addition of an artificial contaminant (clay) to the dense medium."

Jan 1, 2003

Poor floatability of fine particles is known to be the main cause of the low recovery of ilmenite in Panzhihua, which is the largest titanium mine of China. To get an optimum ilmenite recovery, selective flocculation, and flotation of fine ilmenite was investigated through flotation tests, particle size analysis, zeta potential tests and scanning electron microscopy. The results indicate that carboxymethyl cellulose (CMC) shows flocculation effect for both ilmenite and titanaugite without selectivity, while selective flocculation could be realized by the combination of water glass and CMC. It is because that competitive adsorption would take place on these two kinds of mineral when water glass and CMC are used together. On the surface of ilmenite, the adsorption ability of CMC is stronger than that of water glass, so that CMC can absorb to the same extent irrespective of the presence of a pre-adsorbed layer of water glass and ilmenite particles is flocculated by CMC. The same cannot be said of the titanaugite phase as water glass strongly adsorbs onto the titanaugite, and the adsorption of CMC is hindered. Therefore, the titanaugite particles keep dispersion. Furthermore, the flotation of fine ilmenite particles is feasible as the ilmenite floccules could react with sodium oleate. In the flotation separation of Panzhihua ilmenite ore, the recovery of TiO2 increased from 52.63% to 68.28% by selective flotation. Keywords: ilmenite, flotation, selective flocculation, adsorption

Sep 1, 2012

By Takashi Furuyama, Sukeyuki Mori, Ltd. Kyushu Metal Industry Co., Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

"Actually, the recovery of valuable metals such as iron, aluminium and copper is a nowadays practice in factories dealing with the processing of scrapped automobiles (Harder (WERG); Koga et al., 1997). This process has reach a recycling rate of about 75%, and generates a huge volume of waste (including cottons, sponge, plastics, rubber, etc…), locally known as “shredder dust”, which is commonly dumped on landfills; its recycling is either unsatisfactorily or not yet performed (Keller and Schebdat, 2000).The saturation and depletion of valuable disposal sites in the not-so-distant future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry.To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of a calibrated (–80+5mm) shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-weight materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively. A sedimentation tank is used to recover the light-weight materials deported in the heavy fraction stream."

Jan 1, 2003

By Atsushi Shibayama, Toyohisa Fujita, Luo Lin, Toshio Miyazaki

A novel process is developed in this study for separation of tungsten and vanadium from a leach solution of tungsten alloy scraps. Specifically, a magnesium salt combined ammonium solution is employed to precipitate vanadium and impurities in the purification of the leach solution. This separates vanadium from tungsten by rejecting tungsten in aqueous solution. Finally, tungsten is recovered as the form of ammonium para-tungstate (APT). Vanadium is recovered as the form of ammonium meta-vanadate(AMV).

Jan 1, 2003

By Leon Lorenzen, Charlene Gokhale

"In excess of 24 x 106 tons (Eskom, 1997) of coal-derived fly ash is produced annually in South Africa for the production of electric power. A large quantity of this ash is disposed of as a solid waste in landfills, thus posing a serious environmental problem. Due to the shortage of landfill sites, new ways of utilising fly ash are needed. Recently several authors have shown that various combustion fly ashes can be converted into zeolites to obtain industrial products with applicability in environmental management. Geopolymerisation has emerged during the last few years as a possible solution to some waste stabilisation and solidification problems. henolic compounds have been shown to be toxic to soil microorganisms at the parts-per-million level. Indeed several of the organic compounds classified by the U.S. Environmental Protection Agency as priority pollutants, are phenols. Immobilisation of phenols by adsorption on zeolites and encapsulation in a geopolymer appears to be a promising solution to this problem.This paper reports a technique for the production of a low-silica sodium zeolitic material from fly ash (zeolite NaP1), and its application for the stabilisation of phenols by adsorption and subsequent encapsulation in a geopolymer matrix. A commercial zeolite, clinoptilolite was also utilised as an adsorbent. Due to their uniform pore sizes and large surface areas, zeolitic materials are suitable for ion exchange and adsorption of certain organic substances. Adsorption data show that the commercial zeolite, clinoptilolite was an effective adsorbent for organics. Adsorption data showed that between 51.2 ppm and 74.3 ppm of chlorophenol or between 15.4 ppm and 32.5 ppm of phenol could be adsorbed. Physical encapsulation of the coated zeolite loaded with organic within a geopolymeric matrix increased the compressive strength of the matrix from 28.80 kN to 40.79 kN. Leaching data for the various geopolymer matrices with encapsulated and loaded zeolites show no organics being leached from the system at a detection level of 2ppm. According to the SABS these would have been acceptable organic concentrations within a waste water stream."

Jan 1, 2003

By J. B. Rubinstein

"The paper gives an overview of the history of flotation machine development. The laws of their evolution are stated and the place and role of column flotation are demonstrated.The major parameters of column cell diameter and height are discussed. Options are proposed for optimization of the hydrodynamic characteristics of large-capacity column cells. The high efficiency of columns with cell height of 4-6 m is demonstrated. The optimum parameters of multisectional column machines are determined. Their advantages compared to monocells are shown. A scaling-up procedure for column machines was developed based on flotation macro- and microhydrodynamics simulation."

Jan 1, 2003

By Francesco Montanari, Gianni Schena

"Recent improvements in X-ray computed tomography allow investigation of objects several tens of millimetres in dimension with spatial resolutions in the order of a few microns. These improvements are made possible by coupling the micro-focus technology adopted by some of the latest cone-beam X-ray sources with an increase in the efficiency of the detectors. The micro-focus technology allows the production of clearer images at high magnification by reducing the penumbra (fuzziness) associated with larger focal spot size.Even higher resolutions can be expected in the next few years with the commercialisation of nano-focus X-ray tubes. In practice one can inspect a system of fine composite particles and analyze the different mineralogical phases in each individual particle. Computed tomography allows accurate liberation studies, e.g. providing liberation spectra or washability data in tens of minutes. However, on-line application of micro-focus computed tomography is unlikely in the foreseeable future, despite rapid development.Dual-energy (DE) radiography is another X-ray technique, which allows retrieval of the volumetric content of valuable components in two-phase particles in a fraction of a second. A digital radiograph of a single two-phase particle produces a grey level image, where the luminosity of the pixels is determined by the sum of the attenuation levels of all the structures. Thus morphological and compositional effects concur to produce the radiographic image, which does not allow retrieval of the composition of the particle, as the 3D-structure of the particle is compressed into a 2D-image, with an obvious loss of information. Thus, in principle it is not possible to discriminate between thick, comparatively penetrable, and thin, comparatively impenetrable mineralogical components."

Jan 1, 2003

By Sarah K. DeBono, Alan J. Monaghan, Emmanuel V. Manlapig, Gregory J. Harbort

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber."

Jan 1, 2003

By Briony C. Ruse, David V. Boger, Fiona Sofra1

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.As environmental factors translate into economic issues, minimising waste production using dry disposal methods is gaining popularity. The use of rheological information is of high importance in evaluating the spreading characteristics, the transportation and the dewatering of thickened mineral tailings. The principles outlined may be applied to many industries encompassing a wide range of waste materials. The main obstacle to the widespread implementation of dry disposal methods has been the high initial capital cost of the methods due to the dewatering step, and the high cost of pumping thick suspensions across any great distance. Proper and thorough costing of tailings disposal activities combined with an accounting approach that shows closure and post-closure care costs on a per tonne basis of tailings disposed throughout the life of the tailings facility will show that dry disposal methods are more favourable than they might seem on initial appraisal."

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a generic global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. As a point of departure we propose that it is not possible to place metals in the context of the sustainable development of society without paying due regard to the entire metals value chain. Thus, the starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions around the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions. The aim of these case studies is to highlight to the minerals processing and metals refining industries their potential role in a more sustainable global society.

Jan 1, 2003

By Xie Jiyuan, Hu Yuehua, Yang Songrong, Zhu Zhansheng, Qiu Guanzhou

"By the end of 2000, the first bio-oxidation plant in China that designed by ENFI come successfully into commercial operation in Yantai Gold Smeltery. Its capacity is 50t/d of refractory gold ore concentrate. After the extension, the capacity of bio-oxidation plant reached 80t/d of refractory gold ore concentrate at end of 2001.The refractory gold ore concentrate treated is from different gold mines. After proportionate feeding, the feed typically consists of Au (52.7g/t), S (24.42%), As (3.58%).The bacterial culture used in the bio-oxidation circuit is taken from a mine in south of China, and has been grown over 20 years on a variety of sulfide concentrates in a laboratory of mineral processing, and has shown to be adaptive to growth in a high concentrations of arsenic. It is a mixture of mesophilic microorganisms. The nutrients used in the bio-oxidation process are (NH4)2SO4, KH2PO4, KOH.Before feeding to bio-oxidation circuit, the concentrate would be milled to minus 43µm. The biooxidation product is fed to solid/liquid separation system that consists of a thickener and two press filters, solid from the system is fed to CCD circuit, liquid from the system is fed to neutralization area. The neutralized product is fed to another solid/liquid separation system, and the solid from the system is disposed of on a wasted quarry pit, the liquid from the system is returned to bio-oxidation circuit for reusing."

Jan 1, 2003

By A. S. Choudhary

India is endowed with a reasonably large reserve of chrome ore, amounting to about 100 million tons in different grades and is one of the leading producers of ore/concentrate along with South Africa, Kazakhstan and others. Chromite production in India has registered a 10 times increase during the last 30 years. Till late 1940s, the practice was to mine the high-grade ore for making ferrochrome and charge chrome and export the same leaving the low and medium grade ores stacked around the mine as waste material. This practice was continued for quite some time till the increase in world wide de-mand of chromite initiated an increase in production of chromite ore in India and the aspects of ?economy of operation? and ?conservation of mineral? dawned on the producers and associated authorities. Recovery of chrome values from low and medium grade ore was initiated to produce high-grade saleable concentrate. Suitable legislation was made by Government of India to induce and provide incentives to the operators to do so. First large scale chromite beneficiation plant in India was commissioned about three decades back at Byrapore in the Southern state of Karnataka. The ore, rather simple in nature and relatively free from clay, was obtained from underground. The processing consequently was simple washing and wet tabling. Further more, some test work, on the samples from eastern coast particularly from Orissa, was carried out at an internationally reputed laboratory by a large private operator and the plant was set up. This consisted of a combination of crushing-grinding-de-sliming-classification followed by concentration in multi stage spiral concentrators and shaking table. The plant was commissioned and operated successfully. Soon a state owned company followed suit on the basis of test work carried out in a well equipped Indian laboratory. The plant worked satisfactorily after some initial teething trouble and the company plans to double the existing plant capacity by installing balancing facilities. This development prompted a number of operators, including industry leaders to join the fray and the chrome ore processing industry flourished in India. More and more operators are now in the process of adding capacities to their existing plants. This paper attempts to chart the evolution of chrome ore beneficiation industry in India through a case study with reference to an existing plant. The process technology adopted and modified to suit the altered requirements as well as the future trends are outlined.

Jan 1, 2014

By S. Sarioglan

The bleaching of edible oils, industrial oils, and some chemicals may be achieved using natural and acid-activated clays. These materials remove impurities and pigments from the oils. In this work, a bentonite clay from Turkey (Somas bentonite) was activated with different concentration of H2SO4 and HCl at 70~90°C and 5~8 hours. Under these conditions several cations were removed from natural bentonite (Al, Mg, and Fe) and DTA-TGA, FT-IR curves of the solids obtained after acid treatment were examined. Treatment time and acid concentration increased the degree of destruction of the bentonite structure which was determined by ICP. Activated samples were tested in order to verify their capacity to bleach soybean oil and compared to standard commercial bleaching clays. The experimental results indicate that treated samples with H2SO4 have the same efficient in bleaching crude soybean oil with the standards and treated sample with HCl is more efficient in bleaching than the commercial products.

Jan 1, 2014

Under the sponsorship of the U.S. Department of Energy, a project was completed in 2005, which studied the use of a special pneumatic capsule pipeline (PCP) system, driven by linear induction motor (LIM), for transporting minerals and/or mine wastes. In this study, the pipeline is a rectangular tube of 1m × 1m cross section. The capsules are similar to railroad cars running on small rails imbedded in the tube. A LIM is placed AT the entrance of the tube to transfer power electro-magnetically from the LIM to capsules. The capsules going through the LIM, propelled by the electromagnetic field generated by the LIM, move faster than the air and hence impart energy into the airflow. This in turn pushes the capsules in the tube forward. When the tube is long (say longer than 10 km), additional LIMs may be needed along the tube to serve as booster pumps. An advantage of using LIMs instead of blowers as used in ordinary PCPs is that capsules can pass through the LIMs unhindered. This enables the use of booster pumps for long tubes. It also enables PCP to achieve much higher cargo throughput than that of PCPs using blowers, thereby reducing unit cost ($ per ton-km). Advantages of using capsules with steel wheels running on steel rails in the tubes including: (1) contact friction is only about one-fifth of that using rubber tires, thereby conserving energy, (2) capsules can run at a much higher speed than those using rubber tires without overheating and damaging the tires, and (3) rails make capsule motion control simple; they restrict lateral movement of capsules, and make branching easy-by using standard rail crossing equipment. This advanced PCP system combines the advantages of LIM with the advantages of rails, resulting in a super-efficient tube system having throughputs an order of magnitude greater than that of conventional PCPs, and having an energy efficiency better than railroad transport. Analysis shows that the system is highly cost-effective when throughput is high-at least 5 million tons per year. The system is most suitable for long-distance transportation of minerals (including coal and flyash) and wastes (including both mine wastes and municipal solid waste).

Jan 1, 2014

By G. Belardi, N. Shehu, L. Passeri

"This paper illustrates the possibilities of applying what is essentially a physical soil-washing technique for treatment of soil contaminated by semi-volatile hydrocarbons in order to reduce the level of pollution to that permitted by Italian regulations.The ground around a factory producing lubricating-oil additives consists of silty-sandy soils which have long been contaminated by heavy hydrocarbons, especially branched alkyl benzenes and naphthalene derivatives. Pollution is particularly marked in some zones (hot-spots) where Total Petroleum Hydrocarbon (TPH) values are as high as 7000 ppm. The hydrogeological characterization showed the presence of a gravely soil in a sandy/silty matrix, with big stones making preferential paths to the water circulation. The permeability is 10-5 m/s and the water-table occurs at about 3 m below ground level.After laboratory and pilot-scale studies on representative samples of in-situ soils with TPH between 2700 and 7000 ppm a flow-sheet is proposed for reducing TPH values below the acceptable limits in Italy, namely 700 ppm for hydrocarbons with more than 12 carbon atoms and less than 250 ppm for those with fewer.On the basis of indications provided by laboratory tests a mainly physical treatment process of soil washing has been developed. This is used to clean-up soil from a site polluted by non-volatile hydrocarbons with a high TPH value. The process involves a high-density attrition stage followed by wet screening at 0.5 mm and then wet-gravity separation of the minus 0.5 mm fraction in the centrifugal field.The gravity separation products consist of a light fraction with particle size finer than 15 micron which contains most of the pollutants, and a heavy coarse fraction with TPH values conforming to the limits set by Italian regulations (less than 700 ppm hydrocarbons whose structure contains more than 12 C atoms, and less than 250 ppm of hydrocarbons with less than 12 C atoms)."

Jan 1, 2003