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By Ben Cottrell

In this paper technical drilling is referred to as the process of collecting engineering and metallurgical parameters for subsequent mine design considerations. Throughout the development of a mineral exploration property there are various opportunities to ?piggy-back? technical drilling onto the routine exploration drilling process, helping to reduce future costs and delays associated with re-drilling and missing information. This article is written from the engineers and metallurgists point of view, to outline some best practices for exploration borehole planning and technical data collection requirements.

Aug 1, 2013

By Colin E. Dunn

Abstract-Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By Colin E. Dunn

Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By K. Konigsman

"Representatives of various industries and the Canadian coast Guard formed a Bulk Cargoes Committee three years ago. In 1976 and 1978, I have attended the meeting which take place once per year here in Ottawa as representative of the Canadian Mineral Processors, Dave Hendricks from Granisle accepted the charge in 1977. Our Secretary, Bob Bruce, has suggested repeatedly that I report to the Membership on the deliberations to this group. Twice I found good excuses; this year I did not. I was reluctant to address you since the Committee's deliberation proceeded at a pace which might be identified as Government squared. The Committee advises a Government agency which in turn negotiates with foreign Government agencies.At the outset, I will describe the developments which led to the formation of the Committee and its purpose.The Canadian Mining Industry ships annually millions of tons of products to overseas customers; be it iron ore, coal, fertilizer, or base metal concentrates. Most loadings are in vessels of foreign registry and all will be directly affected by Canadian or International regulations of the transport of such bulk commodities. The major shipping nations are members of an Intergovernmental Maritime Consultative Organization (IMCO). This organization elaborates regulations which govern shipment of all cargo, bulk materials and concentrates included. At IMCO'S deliberations, Canada has one vote, one voice on the Consultative Committee and is represented by our Coast Guard. The Coast Guard has over the years been in contact with industries when discussions concerned shipment of bulk cargoes. In the early sixties, a ""Concentrate Committee"" did exist. It consisted of metallurgists from a number of mining companies and Government representatives. This committee was instrumental in the development of what became known as the ""Concentrate Code"", legislation which has evolved into the Canadian Bulk Cargoes Code as it is known today. The concepts of the flow moisture point and transportable moisture limit originated from its work. Incidentally, both criteria are widely accepted and utilized world-wide. The Concentrate Committee faded away once the Concentrate Code has been adopted."

Jan 1, 1979

By A. J. Sinclair

Abstract-Exploratory data evaluation is an essential part of every high quality, mineral inventory estimate. Efficient analysis involves a thorough organization of available quantitative data that are the basis of the estimate and perhaps the formation of composite grades. Data organization and evaluation can involve more than 50% of the time necessary to conduct a mineral inventory estimation. The principal purpose of exploratory data evaluation in mineral inventory work is to improve the quality of estimation by providing insight into characteristics of the variables under investigation. Specific aims include: (1) to recognize and eliminate errors; (2) to provide a comprehensive knowledge of the statistical characteristics of all variables of interest for resource/reserve estimation; (3) to document and understand the interrelationships among the variables of interest; (4) to recognize systematic spatial variation of variables such as grade and thickness of mineralized zones; (5) to recognize and define distinctive geological domains that require independent estimation of mineral inventory; (6) to identify and characterize outliers; and (7) to evaluate similarity/dissimilarity of various types of raw data, especially samples of different supports. These aims are not mutually exclusive but they can all have their own impact on resource/reserve estimation. Error must be minimized. Individual variables can have characteristics that lead to different decisions in the course of estimation. Similarly, interrelations of variables might contribute to the ease (or difficulty) with which estimates of several variables can be obtained. Trends can impose the need for two or more domains, each of which might be estimated independent of the others. Outliers, a perennial problem, require detailed evaluations because they impact on reserves much out of proportion to their abundance. Data, of widely different supports, generally must be standardized if all are to be used for purposes of estimation.

Jan 1, 1998

By Bernard Vigneault

Les critères de qualité de l?eau pour les métaux visant à protéger la vie aquatique sont présentement basés sur les concentrations totales. Cependant, la complexation (association de ces métaux avec des ligands en solution) peut diminuer de façon importante la toxicité des métaux sur les organismes aquatiques. Pour évaluer l?importance de la complexation pour diminuer la toxicité des métaux dans les effluents miniers et métallurgiques, nous avons étudié la spéciation des métaux et la toxicité chronique de différents effluents miniers et métallurgiques. La phase dissoute des effluents a été échantillonnée à l?aide de la dialyse in situ et la spéciation du cuivre, du zinc et du cadmium a été calculée à l?aide du modèle d?équilibre chimique WHAM. Les concentrations de métaux libres ont également été mesurées à l?aide d?une technique d?échange ionique. Les concentrations de métaux libres calculés et mesurés indiquent que la complexation est importante dans les effluents miniers, particulièrement pour le Cu. Pour relier la spéciation des métaux et la toxicité chronique, nous avons mesuré en parallèle l?inhibition de croissance de l?algue Selenastrum capricornutum et des larves du poisson Pimephales promelas de même que l?inhibition de la reproduction du cladocère Ceriodaphnia dubia. (tests de toxicité chronique inclus dans le programme de suivi des effets environnementaux du règlement fédéral sur les effluents de mines de métaux). En absence de thiosels, aucune mortalité a été observée pour l?ensemble de ces tests et il n?y a pas eu également d?inhibition la croissance de la larve de poisson P. promelas. L?inhibition de la croissance de l?algue S. capricornutum, n?est pas reliée aux concentrations de métaux traces mais plutôt par aux concentrations de calcium. Les inhibitions de la reproduction du cladocère C. dubia sont reliées aux concentrations de métaux dissoutes et libres et non pas aux concentrations totales de métaux, démontrant l?importance des effets de la spéciation chimique sur la toxicité des métaux. Nos résultats indiquent que l?inhibition de la croissance de l?algue l?algue S. capricornutum est due aux concentrations élevées de calcium retrouvées dans les effluents miniers et que les concentrations totales de métaux ne peuvent être utilisées pour prédire la toxicité chronique vis à vis le cladocère C. dubia.

Nov 1, 2002

By Haibin Wang, Zhiwei Huang, Zhixiang Cui, Wenzhao Cui, Zhi Wang

Fangyuan Two-Step copper smelting process was commercialized in October, 2015 and has been operating for 3 years and 5 months. As the unique continuous copper smelting process with simplified flow in the world, production parameters have been significantly improved after three years. In the first half of 2018, the feed rate was above 200t/h, availability reached 97.5%, operation cost was about 20% lower than the conventional three-step processes showing obvious economic advantages. The Two-Step process in Fangyuan is composed of 1 Submerged Lance Smelting furnace (SLS) and 2 Submerged Lance Converting& Refining furnaces (SLCR). Two SLCRs work alternatively to ensure continuous production. High grade and liquid matte from the SLS is introduced to the SLCR by sealed launder to complete converting and refining. The SLCR is an original and independent innovation of Fangyuan, for which Fangyuan completed lots of development and improvement. This paper will introduce the process and experience. INTRODUCTION China is the largest producer and consumer of refined copper. Most of the processes adopted in China are conventional "Three-Step" copper smelting processes, which are comprised of smelting, converting and refining. There exists some problems in the conventional processes, such as high energy consumption, large heat loss, low altitude emission of SO2, etc. To deal with these problems, Fangyuan developed the new copper smelting process with simplified flow, low cost, clean and high efficiency. The SLCR that combines converting and the refining process was also developed, which shortens the process flow from conventional three steps to two steps. The SLCR is of great significance in promoting the development of the copper industry. Development and industrialization of SLCR At present, copper concentrates are treated in three steps: smelting, converting and refining. Anodes are also produced by continuous converting processes such as the Mitsubishi process and the Double Flash process. Problems like matte transportation by ladle, capacity limitation, and low altitude pollution exist.

Jan 1, 2019

By Christoph Mueller

?Globalization and the impact on mine operations? is one of the themes of the 2003 annual CIM meeting. Global mining business in practice always means to act with local base material resources in order to reach the mining company?s global business goals. On the other hand these operations are characterized by cost pressure and cycling product prices. Driven by actual prices, local product markets and local production cost, one time one mine can be most efficient while under different circumstances another mine will be the most efficient producer for the same customer [PENSWICK, 2001]. Therefor in the future the most profitable mining companies will be those who have permanent ?real-time? control on their actual production cost level. Certain approaches are under way to provide reliable modeling tools for aiding mining companies in highly complex decision finding procedures. A high potential for enhancing efficiency is the integration of all single steps of the mining working chain into a production process structure to make advantage of an optimized flow of material and information through the ?moving ore factory? [WIGDÉN, 2001]. Crucial to all these activities is the ability of getting reliable, just-in-time information from the entire mining production chain. As modern mining machinery today is controlled electronically and even already operated autonomously, the theoretical preconditions for the data acquisition is already fulfilled. But up to now, there was no way of cost effectively exchanging the process information with databases, simulation tools and other enterprise level software. Any data exchange problem had to be solved by individual and expensive software development projects. To solve these problems, the International Rock Excavation Data Exchange Standard (IREDES) was launched in 2000 by major players in the industry. The task of this initiative is to define a ?common electronic language? for easy and standardized data exchange between mining machines and central computer systems. As in other industries, this standard is expected to have significant impact on the use of automated equipment. It shall provide easy ways of using multi vendor machine installations in data controlled mining processes. At the same time it reduces cost for individual development of interfaces for all parties involved. The standard?s technical architecture is flexible and open - also for future applications. It uses modern technology enabling easy data exchange with commercial databases as well as open on line networking.

May 1, 2003

By H. M. Howard

"The subject of Grinding Media is perhaps still quite controversial. Many people will state today that the spherical ball is the only way, and also will state that this was settled long ago others are not so sure, and I am in this second category. Over the years there have been many changes in grinding and in our evaluation of grinding media we should always be ready to review the overall situation at regular intervals. There is quite a lot of inertia in all branches of Hineral Dressing and this is particularly true of grinding or, more correctly, comminution.In order to understand some of the things which are done today, and to understand some of the thinking on grinding, it is desirable to go back some sixty years and trace the developments in comminution. In doing this we should consider perhaps three general categories with respect to daily tonnage. An arbitrary division would be under 500 T.P.D., 500-5000 T.P.D., and large operations which might have several parallel units, each with a capacity of about 5000 T.P.D. For the future, in the broad picture, this last category will be the important one because we will be more and more dependent on large-tonnage low-grade operations for most of the metals of the future. Some such division is necessary because the daily tonnage will have a very great effect on what we can and cannot do. It is also necessary to consider the entire flowsheet, and to remember in particular that grinding is not merely to make small particles but is also a conditioning process, to prepare the materi.al for the process which follows. The relationship of crushing to grinding must also be considered. It is logical to include the liners as part of the grinding media and we should try to distinguish between the wear of grinding media and the consumption of media by corrosion. Finally, the whole question of grinding media should be examined in relation to the possibilities of using some form of autogenous grinding."

Jan 1, 1970

By X. J. Guo, Q. K. Wang, S. P. Zhong

With depletion of traditional clean copper reserves and fast expansion of the global copper demand and smelting capacity in the past decade, more and more copper smelters have to treat copper concentrate with increasing content of complex arsenic-bearing minerals. Developing economically viable and environmentally reliable methods and approaches for arsenic control in copper smelting has become more critical for sustainable growth of the copper industry. This paper will report the recent effort of Zijin Mining Group Ltd. in developing processes for improving arsenic control and management in the Zijin Copper Smelter. The arsenic distribution and balance data for matte smelting, converting and refining operations in Zijin Copper Smelter is reviewed for understanding of the current challenges in arsenic control. The processes developed for treating the arsenic bearing waste acid bleed stream from the smelting-converting off-gases wet cleaning circuit and the arsenic sludge produced in the refining electrolyte purification circuit for arsenic disposal are discussed. INTRODUCTION With fast expansion of the global copper smelting capacity to meet the world copper demand and depletion of traditional clean copper reserves, more and more copper smelters have to treat copper concentrate with an increasing content of complex arsenic-bearing minerals. China is the world largest copper consumer and also has the largest copper smelting and refining capacity, but majority of its smelting capacity relies on supply of imported copper concentrate. In order to meet the increasing copper demand and ease the tight supply of clean copper concentrate, the Chinese copper industry has to look at the domestic opportunity of developing non-traditional copper resources, specifically those of lower grades, more complex mineralogy, and increasing level of deleterious elements especially arsenic and also process imported copper concentrate with increased arsenic content. Due to a significant and growing environmental issue associated with arsenic contamination, developing economically viable and environmentally reliable methods and approaches for arsenic management and control in unlocking the maximum value of such arsenic bearing copper resources has become more critical for sustainable growth of the industry.

Jan 1, 2019

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"Interest in the use of particle-based ore sorting has increased significantly with recent advances in sorting technologies and higher capacities per unit. Particle-based ore sorting has the potential to provide great value in processing lower grade ores from mines while delivering higher grades to the mill, as well as in upgrading waste rock into ore. Typically the focus is on the amenability of the ore to ore sorting and associated reductions in energy, water, and consumables utilization. However, layout significantly affects the installed cost of a processing plant, and the impacts on layout from fitting an ore sorting circuit into the plant plan need to be carefully considered. This paper examines processing plant layout considerations that play an important role in ore sorting projects, including additional crushing and screening requirements, transport of rejected material back to the waste stockpile (mine fleet requirements), and effects on the processing plant footprint. ¦ KEYWORDS Cold climates, Ore sorting, Plant layout RÉSUMÉ L’intérêt porté à l’utilisation du tri granulométrique du minerai a considérablement augmenté au vu des récents progrès réalisés en matière de technologies de triage et des capacités supérieures par unité. Le tri granulométrique du minerai offre une plus-value intéressante en termes de traitement du minerai à plus faible teneur extrait des mines ; il permet par ailleurs l’acheminement vers le concentrateur de minerai à plus haute teneur et la revalorisation des stériles dans le minerai. On met généralement l’accent sur la susceptibilité du minerai au triage et sur les réductions connexes en termes d’utilisation de l’énergie, de l’eau et de biens consommables. Cependant, l’aménagement physique de l’équipement a une incidence non négligeable sur le coût installé d’une usine de concentration, et les répercussions sur l’aménagement de l’installation d’un circuit de triage du minerai dans l’usine doivent être soigneusement examinées. Cet article étudie les considérations relatives à l’aménagement de l’usine de traitement qui jouent un rôle important dans les projets de triage du minerai, et notamment les exigences supplémentaires en matière de concassage et de criblage, le transport de matériau résiduel jusqu’à la pile de stockage des déchets miniers (nombre de camions requis dans le parc minier) et les effets sur l’empreinte de l’usine de traitement. ¦ MOTS CLÉS aménagement de l’usine, climats froids, triage du mineraiINTRODUCTION Ore sorting has been practised throughout history. An early report by Agricola in 1556 documents how metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade (Hoover & Hoover, 1950). The concept has not changed, but sorting technology has evolved significantly over the last 20 years"

Jan 1, 2019

By Jeffrey D. Eisenman

FRP is a proven material for the solvent extraction processes of copper production. There is a history of successful applications of FRP piping and equipment in hydrometallurgical processing. The performance of FRP equipment has not always been consistent, but at no fault of the material. Its non-metal attributes and behavior vary from those of more typical materials of construction, such as steel and alloys. FRP is a mainstay material in many areas of solvent extraction and electrowinning and yet not well understood by all. We will discuss the critical concerns, which are key to reliable performance of FRP systems. This paper will include discussion of key elements, which are fundamental to reliable FRP piping design and considered best practices. Essential design and construction considerations to maximize reliable service life of FRP equipment, such as thickeners and process vessels, used in copper extraction and processing, will be discussed. Additionally, we will expose potential pitfalls and share lessons learned from previous copper processing plant projects, which can aid and impact other copper processing projects to ensure best system performance and reliability. INTRODUCTION The corrosion resistant attributes of fiberglass reinforced plastics (FRP) make it an attractive and cost effective material of construction in corrosive service applications that are found in copper processing. FRP is used all over the processing plant in seawater, brine and sulfuric acid services where the corrosive nature of these services would challenge most ferrous materials and coatings. FRP is a fully customizable material to meet the specific needs of each service and process. FRP piping and equipment can be found throughout the hydrometallurgical process, in the acid plant, desalination, leaching processes, solvent extraction and electrowinning to name a few. Beyond its superior corrosion resistant characteristics, FRP can be made abrasion resistant by introducing particulate additives into the resin, such as silicon carbide and alumina oxide. Because many of these services have combustible organic elements in the flow streams with accompanying safety concerns, the linings can be made conductive with carbon fibers to dissipate static charges that might collect on the surface of the equipment otherwise. Further, FRP can be made flame retardant as well, where flammability may be of concern.

Jan 1, 2019

By R. Bridge

Mining companies are progressively finding themselves having to develop operations for more complex, deeper ore bodies, which require the use of more complicated mining and mineral processing methods. This coupled with the generally increasing trend of higher capital and operational costs have led to a need in the industry for improving ore body knowledge, mining and mineral processing. Geometallurgy is a relatively new concept that can link the three aspects, and when used effectively it is a method that can produce the necessary information for designing and building operations for reliable and optimum performance. Geometallurgy not only involves the integration of geological, mining, and metallurgical fields, but it can also be expanded to include environmental and economic information to produce a block model that can be used to obtain the best outcome in terms of plant response and plant sustainability. The geometallurgical program should not end once the block model has been populated. A detailed geometallurgical approach should be applied to all stages of the operation encompassing sample selection, through to equipment sizing and production forecasting. It can also become a useful optimisation tool thereby allowing the operation to be proactive rather than reactive against changes in the ore characteristics. With the development of metallurgical performance predictors it is possible to quantify how the ore will behave in the process plant in terms of throughput, recoveries, reagent consumption, etc. Therefore, in terms of responsible mining and sustainable resource development, a geometallurgical approach to operations is the logical step for plant development. In this paper we describe the state of the technology with respect to the application of geometallurgical modeling and its utilisation in the fields of design, forecasting and optimisation of mining operations.

Aug 1, 2013

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract—Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O signature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By J. J. Taute, O. S. Tinkler, G. Zárate, K. C. Sole, J. Steeples

Global practice in copper solvent extraction is reviewed, based on individual plant operating data for 2018. The survey respondents account for almost 40% of global copper cathode production by solvent extraction and electrowinning. Regional trends in operating conditions, as related to the prevailing ore mineralogy, leaching processes, and life of mine are evaluated. The adoption and expansion of this technology in the African Copperbelt and Asia are assessed, together with the associated challenges of specific orebody characteristics. Trends in feed and electrolyte compositions and flow rates, and extractant and diluent selection, together with their impact on copper recovery are reviewed. The evolution of equipment design and associated ancillary processes are discussed, and new projects identified. INTRODUCTION Continuing from similar surveys carried out in 1997, 1999, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Robinson, Sandoval, & Cook, 2003; Robinson, Moats, Davenport, Karcas, Demetrio, & Domic, 2007; Sole, Zarate, Steeples, Tinkler, & Robinson, 2013), global operating practice in copper solvent extraction (SX) in 2018 is reviewed. Contributing operations include established sites in the USA (8), Chile (9), Peru (2), Spain (1), Mexico (2), and Australia (2), as well as newer operations in Africa (7) and Asia (3). This survey represents 2018 copper cathode production of 1.91 Mt, or about 43% of world production by solvent extraction combined with electrowinning (SX–EW). Trends in operating conditions and performance, as well as equipment design and process technology choices are analysed. The significant expansion in production in the African Copper Belt is also discussed. There are currently about 130 operations worldwide producing some 4.6 Mt copper by SX–EW; of these, about half produced more than 10 000 t/a. Figure 1 shows global copper production by country. As it has for several decades, Chile remains dominant, with 36% of global production of cathode copper. Since 2005, the Democratic Republic of Congo (DRC) has increased production year on year, and now represents 23% of the global total (International Copper Study Group, 2017; Statistica, 2018). Copper production in Asia has grown significantly in the past decade, particularly since the ramp-up of Wanbao in Myanmar. There used to be numerous small copper SX plants in China (Schlesinger, King, Sole, & Davenport, 2011), although most of these have now shut down and Chinese production is lower than it was five years ago. The most important trend, however, is the rise of Chinese-owned mining companies, particularly in Central Africa, but also around the world more generally.

Jan 1, 2019

By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019

By J. Ji, A. Shi, B. Grcic

Floating copper minerals selectively against iron minerals such as pyrite has been challenging for most copper and copper/gold deposits, and many operations continuously strive to maximise copper recovery whilst meeting target concentrate grades. Maximising grade is achieved by selectively floating copper minerals and rejecting pyrite. This challenge is to minimise copper and gold losses in the roughers if this approach is used. A flotation testing program was conducted by Bureau Veritas Minerals on a high-level pyrite bearing copper/gold ore sample to establish the potential to reject pyrite in the rougher stage, but also maximise copper and gold recoveries, and ultimately final product grades. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. The main variables tested for achieving selective flotation of copper and gold were collector type and pH control, through lime addition. Grind sizes used in the rougher and cleaner tests had been established from previous test work. The collectors tested were SIPX, Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The two best performing collectors were then tested in open-circuit cleaner tests, with the optimum conditions examined further in locked cycle tests. INTRODUCTION Bureau Veritas Minerals Metallurgical Division was retained by Eldorado Gold Corporation to perform a metallurgical testing program on a high-level pyrite bearing copper/gold ore sample from a gold- copper porphyry deposit to optimize flotation reagent scheme to improve gold and copper recoveries and copper content in the concentrate. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. Initially, various collectors were screened in kinetic rougher tests, and over a pH range of 8.5 (i.e the natural ore pH) up to 11.5, using a primary grind size of 80% passing 120 µm. The collectors tested were SIPX (sodium isopropyl xanthate), Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The enrichment ratio, which is the ratio of copper to sulfur in the concentrate to that in the feed, was used as proxy for rating selectivity (i.e. degree of pyrite rejection or depression).

Jan 1, 2019

By Bryn Harris

Answer to the question is given as 42! Asked the wrong question So got the wrong answer How does this apply to the mining industry? And particularly to this session on Water? Water is just one aspect of mining/minerals/metals Should not be looked at in isolation Need to adopt a ?holistic? approach

May 1, 2013