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By D. A. Brown, C. Lowe

"Abstract -A multi-sensor (electromagnetics, magnetics, gamma-ray spectrometry, and VLF) geophysical survey was recently conducted in the Purcell Basin of southeastern British Columbia in an area encompassing the world-class Sullivan Sedex deposit. The purpose of the survey was to geophysically characterize the known mineral occurrences and to develop strategies to enhance future mineral exploration in the basin. Follow-up investigations of geology and measurements of rock physical properties helped constrain interpretations of the geophysical data sets.Despite extraction of more than 90% of the ore from the Sullivan deposit, it is clear that the mineralization there, as well as at other Sedex occurrences surveyed, is characterized by high conductivity values, strong bedrock conductors, and elevated magnetic anomaly values. The albite-sericite alteration which accompanies this mineralization yields high potassium and low thorium-potassium ratio values. Associated Moyie gabbro is characterized by low electrical conductivity and radioelement concentrations and by high magnetic anomaly values. The study has also aided exploration for other mineral deposit types including stratabound Cu-Ag, placer gold, vein and disseminated basemetal deposits. In addition, the geophysical data have helped constrain geological interpretations of the basin."

Jan 1, 1998

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By S. V. Burr

"IntroductionOne of the more puzzling geological enigmas, in the writer's opinion, is how rock can move sideways with respect to other rock. In the writer's study of regional northwest-southeast folding in North America (Burr, 1980), he may have found the answer to horizontal offset.Horizontal OffsetSideways movement or horizontal offset does not mean that the movement was, or is, horizontal. As indicated below, the actual movement may be at a high angle from the horizontal. However, it is the horizontal VECTOR, or offset, which is measured on surface by geologists. Vertical movements (thrust, normal, reverse) can be understood, as they involve blocks of rock , generally separated on four to six sides, which have been pushed up or subsided. Vertical faulting across dipping strata can produce APPARENT horizontal offsets. However, this thesis deals only with ACTUAL offsets.The ProblemFigure 1 is a plan view of a simple hypothetical horizontal offset. Three vertical dykes are intersected by a fault lineament. Two dykes exhibit no movement; the middle dyke has been offset a distance (a). Vertical faulting would have produced no horizontal offset. How can a horizontal distance (a) disappear or appear? Rock expands or contracts in infinitesimal amounts.SolutionThe map (Burr, 1980) shows the writer's interpretation of regional northwest-trending folds in Ontario. The writer made two observations about horizontal offsets during his thirty year study of these folds:1) All major horizontal fault lineaments strike at a high angle to the northwest fold axes. Many of the northwest-trending lineaments are fault s, but their movement is essentially vertical.2) Close to many of the known horizontal offsets (and several lineaments), there are areas where plunge reversals are so frequent and close together it is impossible to draw in all the fold axes at a scale of 1 inch = 4 miles, and, in the highly faulted Espanola area southwest of Sudbury, Ontario, all the indicated folds cannot be easily separated at a scale of 1 inch = 1 mile. The writer has observed folds less than 30 feet apart next to the strong Puskitamica-Chibougamau fault in northern Quebec."

Jan 1, 1982

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By Z. D. Hora

Sedimentary phosphate-bearing rocks are found over a considerable area of so utheastern British Columbia that extends from Fernie east to the Alberta-British Columbia boundary and from the International Boundary northward to the headwatei: s of the Elk River. Phosphatic beds occur at the following four stratigraphic levels: 1. lower part of the Banff-Exshaw sequence of Mississippian age; 2. lshbel Formation of Permian age; 3. base of the Fernie Group of Jurassic age; 4. belemnite bed within the Rock Creek Member of the lower part of the Fernie Group. To date, considerable tonnages of phosphate rock have been proven in the area. However, no commercial production has been initiated because of a relatively low P2O5 grade. Data on assays and thicknesses of the phosphatic beds are in part recalculated from the paper by Telfer (I 933) and in part from assessment reports filed at the British Columbia Ministry of Energy, Mines and Petroleum Resources.

Jan 1, 1984

By S. D. Normani

A Deep Geologic Repository (DGR) for Low and Intermediate Level radioactive waste has been proposed by Ontario Power Generation for the Bruce Nuclear site in Ontario, Canada. The DGR is to be constructed at a depth of about 680m below ground surface within the argillaceous Ordovician limestone of the Cobourg Formation. The objective of this paper is to apply paleoclimate boundary conditions to a regional-scale groundwater flow model for the DGR site and to describe the influence of glacial loading and unloading on flow system evolution using the FRAC3DVS-OPG flow and transport model. The regional-scale domain encompasses an area of 18,775km2 extending from Lake Huron to Georgian Bay in southwestern Ontario, Canada. From a hydrogeologic perspective, the domain can be subdivided into a shallow zone, an intermediate zone, and a deep zone comprised of the low-permeability units of Ordovician and the more permeable Cambrian where present. The deep groundwater zone is characterized by units containing stagnant water having high concentrations of total dissolved solids (TDS) that can exceed 300g=L. The high TDS values at depth require density-dependent coupled flow and transport calculations within FRAC3DVS-OPG. The computational sequence involves the calculation of steady-state density independent flow that is used as the initial condition for the determination of pseudo-equilibrium for a density-dependent flow system that has an initial TDS distribution. The 1,000,000 year pseudo-equilibrium heads and brine concentrations are used as the initial condition for the paleoclimate simulations. Over the past 900,000 years, the Canadian Shield has experienced approximately nine episodes of complete glaciation. During the glaciation cycles, the entire Canadian land mass has been covered by a series of continental ice-sheets whose maximum thickness reached 4 km and whose southern extents reached, in some cases, beyond the present-day Canada-U.S. border. The glaciation phase of a single glaciation-deglaciation episode is typically 90,000 years in duration, while the deglaciation portion proceeds relatively rapidly and has an average duration of approximately 10,000 years. Output from the University of Toronto Glacial Systems Model, a continental scale North American glacial reconstruction of the most recent 120,000 year glaciation event developed by W. R. Peltier, is used to supply the paleoclimate boundary conditions used in this paper. Permeabilty reductions due to the presence of permafrost are also considered in the paleoclimate simulations. This paper will demonstrate that the choice of rock properties can significantly affect residual pore water pressures within the rock matrix, as well as the migration of glacial meltwater.

May 1, 2009

By H. C. Gunning

The Privateer is the major mine of the Zeballos mining camp; with a total production from May 1937 through the first half of 1946 of $5; 610; 423 from 139; 254 tons of ore. This includes a small production from the connected Prident mine. The entire operation was closed from October 1943 to November 1945.

Jan 1, 1954

By W. H. Mathews

"The Hardie group of cinnabar claims is in the interior of British Columbia; 25 miles northwest of the city of Kamloops. It is one of a number of mercury; properties scattered along a north trending belt 20 miles long and up to 5; miles wide. In all but one of these properties cinnabar is associated with; dolomite veinlets in zones of carbonate alteration in bedded rocks of Triassic; and Cretaceous (?) age; or in intrusives cutting these bedded rocks. No dolomite alteration or cinnabar mineralization is known in the undoubted Tertiary rocks adjacent to the mercury belt.The mercury showings of the Hardie group lie for the most part in a granitic stock cutting Cretaceous (?) volcanics. The rock in this intrusive shows marked variations in texture and has been described in earlier reports as granite and granodiorice, granite porphyry, and trachyte or dacite porphyry. At Hardie mountain the cinnabar mineralization, unlike that of the other properties, is associated with a fine-grained, almost chalcedoni c, quartz; carbonates, though present, are of minor importance. Some of the most interesting showings are found in an adit in the southeastern part of the property where cinnabar mineralization shows a very distinct structural but not a genetic relationship to a brown porphyry dyke 2 to 8 feet wide cutting a phase of the stock that may best be described as aplitic"

Jan 1, 1954

By R. C. Wallace

Introduction At a time when the mineral-bearing areas in Manitoba are being fi very keenly explored because of the major developments which are now taking place in that Province, it may be timely to give an analysis of the mineralization in the two major types of deposits, with a view particularly to assist in the intensive prospecting to which the mineral-bearing areas in the Province are now to be subjected. As is already well known, there are two principal types of mineral deposits in the territory- copper-zinc and gold; and attention will be confined almost exclusively in this paper to these two types, with some indication of such modifications of the main types as may be found to be of economic value. The details of the paper are drawn from what is yet a small part of the area of the Province available for prospecting. Enough is now known of the types of mineral deposits which are described in the following pages to justify the expectation that these types may serve as criteria in the search in the newer districts. Doubtless new types will also be found as investigations proceed.

Jan 1, 1928

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By Norm Clegg

The Plant Engineering and Maintenance Association of Canada PEMAC is a national, not-for-profit industry association for plant and facility maintenance, engineering and physical asset management in all industry sectors in Canada. Our mission is to provide professional development for our members and the profession in Canada

Feb 1, 2008

By Alisa M. Caswell

Outline: 1. Syncrude: Who are We? 2. Energy Use at Syncrude 3. Historical Energy Focus at Syncrude 4. Case Studies for Process Variable Monitoring 5. Extraction Flood Water Temperature Management 6. Fired Heater Tuning 7. Critical Factors for Success Syncrude: Who are We? ?Syncrude is a Joint Venture Operating Company with one product: Synthetic Crude ?Production Capacity: 350 kbbls/day ?Primary Energy Sources: ??Fuel Gas + Natural Gas ?? Coke ?? Electricity ?? Diesel

May 1, 2008

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By Michel Dagbert

"In their paper, Marcotte and Boucher (2001) cast some new light on the old problem of 2D estimation of vein-type deposits with thickness and grade of intercepts. Using a theoretical approach, some extensive simulation experiments and the Walker Lake data, they show that the direct approach (interpolation of grade at points on a regular grid) gives better estimates of the true grade at those points than the indirect approach (interpolation of grade x thickness or accumulation and interpolation of thickness) when there is some positive correlation between grade and thickness and that this better performance increases with the correlation of grade and thickness as well as the variability of both variables.We would like to bring some reservations to that conclusion by showing that even if direct point grade estimates are better than indirect ones, it is not necessarily true for block estimates and in particular for the estimated grade of the whole orebody itself."

Jan 1, 2001

By W. Dan Hausel

"Abstract-Hundreds of diamonds have been found in the United States. The majority of the discoveries occurred during the 19th century as a by-product of placer gold mining. Most of these early diamond finds have no known source, and in many cases are situated in areas unfavorable for diamond exploration based on current models that require kimberlite or lamproite to be emplaced in a stable Archean craton or Proterozoic craton margin.Diamonds have also been recovered in situ from lamproite at Murfreesburo, Arkansas, from kimberlite in the Lake Ellen region of Michigan, and in several kimberlites in the Colorado-Wyoming State Line district. Unverified reports also suggest that diamonds may have been recovered from other related intrusions at a number of localities in the United States."

Jan 1, 1995

By C. Jay Hodgson, Adrienne C. L. Larocque

The Mobrun VMS deposit in northwestern Quebec does not fit the classic Noranda type model, but exhibits characteristics more consistent with a Mattabi-type deposit. The orebodies are underlain by fragmental volcanic rocks indicative of explosive volcanism in shallow water. Felsic volcanic rocks are more abundant than mafic rocks. Alteration assemblages comprise chlorite, carbonate, sericite, and quartz. Broad semi-conformable alteration occurs high in the footwall to the 1100 lens. Mobrun occurs higher in the stratigraphic sequence than most of the other deposits in the Noranda camp. In this part of the stratigraphy, zones of pervasive carbonatization may be more useful guides for exploration than zones of silicification.

Jan 1, 1993