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By Donald J. Farrish

"Mr. Chairman and fellow CMP members, most of these remarks will be made with particular reference to copper concentrate but the basics apply generally to other metal concentrates as well.For very good reasons, using copper as an example, smelting capacity usually is located either close to mine production or close to areas of high copper consumption. The mine producer can add on smelting capacity to insure that the copper in his concentrate can be processed into a marketable form under more or less controlled conditions including costs. On the other hand, the consumer wishing to assure a better supply of copper likewise can build smelting capacity and offer treatment charges attractive enough to discourage mines from investing in their own facilities. In this regard, freight is an important factor. Bulk shipments from the heart of Africa with a large overland component are uneconomic whereas concentrate movements from Australia or South America compare favourably with smaller metal shipments.A mine project which incorporates smelting capacity, will often, through the presence of this capacity, encourage active exploration and development of additional concentrate production in the vicinity. The usual result is that new mines within reasonable distance of the smelter will be able to avoid the capital required to build their own smelting and refining facilities and that the existing facilities will expand to appreciate economies of scale."

Jan 1, 1978

By Matthew S. Bingham, David H. Searle

"One of the most significant developments in environmental law has been the development of mandatory project review processes, at both the federal and provincial levels.FederalWhile, in the past, project review processes have, f or the most part, been spelled out in guidelines, the guidelines have not had the force of law. All that has changed, particularly at the federal level, with the Federal Court decisions commonly referred to as the Old Man River and Alameda and Rafferty Dam cases. These decisions, taken as a whole, are authority for the proposition that the Environmental Assessment and Review Process Guidelines Order, SOR 82-487 is a law of general application, not a mere guideline which may or may not be applied. This federal environmental assessment process first provides for a screening, and, depending upon the results of the screening process, the possibility of a public review. This federal process only applies, however, when the proposal is being undertaken by a federal department, or where the Government of Canada makes a financial contribution, or where federal lands are involved, or where a federal licence or permit is required.Bill C-78, the Canadian Environmental Assessment Act, will replace the Federal Environmental Assessment and Review Process Guidelines Order once it has been passed by Parliament. Currently the bill is being widely discussed, both between governments as well as public interest groups.ProvincialOn the provincial scene, there are three project review processes, one concerned with new mines, the second with energy projects and the third with all other major projects. The most recent initiatives taken by British Columbia are twofold. First, the Mine Development Review Process which was in the form of a guideline, has been replaced by the Mine Development Assessment Act. Second, the Major Project Review Process has been formulated and is to apply to four main categories of major projects:1. Pulp and paper production;2. Mineral smelting and refining;3. Chemical products; and4. Major ports and marinas.Energy projects are governed by the Energy Project Review Process which is legislatively mandated under the Utilities Commission Act."

Jan 1, 1991

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By Neri Roux, Ross Gilders, Yemi Oyediran, Leo Cheung

Quest Rare Minerals Ltd. is developing their Strange Lake B Zone REE deposit located in Northern Quebec. An extensive batch bench scale testing program was launched to investigate open circuit rougher flotation performance under different conditions. The objective of the flotation study was to demonstrate the effectiveness of rejecting gangue minerals to flotation tailings while concentrating rare earth elements as well as yttrium, zirconium, and niobium into a concentrate suitable for further hydrometallurgical processing. Mineralization of interest at Strange Lake occurs within peralkaline granite-hosted pegmatites and minor aplite. The REE and high field strength element (HFSE)-bearing phases are hosted primarily in pegmatites as relatively fine-grained phases or pseudomorphs. The gangue phases comprise of quartz, feldspar, amphibole, and pyroxene. Potential ore minerals comprise predominantly of kainosite, gerenite, gadolinite, zircon, pyrochlore, and gittinsite. These complex mineralogical characteristics increase the difficulty for processing and provide a challenge for choosing the correct reagent scheme in rougher flotation. Process options including reverse flotation to reject the gangue minerals and de-sliming prior to the direct rougher flotation were investigated. Optimization trials were conducted using various reagent regimes and under different flotation conditions. Encouraging results were found using a combination of collector reagents supplied by Cytec Canada Inc.

Jan 1, 2014

By C. Paulo, W. N. Wheeler, M. Kalin, M. P. Sudbury

Many researchers have tested the addition of various phosphatic materials, including Natural Phosphate Rock (NPR), to mining wastes. It was assumed that iron in the waste would form FePO4 precipitates, restricting oxygen access to pyrite surfaces and reducing oxidation. Phosphate additions were based on stoichiometry (phosphate mass to sulphide content of waste). Although some interesting, positive results were obtained with low dosages, these were considered accidental, not having followed the expected stoichiometry. In 1991, we began experimenting on tailings and waste rock with NPR, postulating that if chemo-lithotrophic microbes on the mineral surface accelerate oxidation, then heterotrophic (oxygen-consuming) microbes would reduce oxidation. All wastes with NPR produced effluents with elevated pH and low metal acidity. Later, microscopic investigations of the rocks found an organic layer on the mineral surface, which was confirmed by independent research organizations repeating experiments with very low NPR mass additions to sulphidic wastes. In 2013, heterotrophs were identified and quantified as they grew on German lignite with NPR. These data conclusively showed that the development of heterotrophic biofilms is a consequence of adding waste NPR leading to a reduction of sulphide oxidation and improved effluent from sulphidic mining wastes. We document our gradual understanding of the effects of NPR on the reduction of sulphide oxidation, covering 23 years of research.

Jan 1, 2014

By Enrique Rubio

Several mining operations are currently evaluating the feasibility of changing their mining method to Block Caving. There will also be several deep low-grade ore bodies that will face the need to go underground in following their ore to depth. There are two main reasons why Block Caving is attractive: firstly, it offers the lowest operating costs amongst all the mining methods; and secondly, it is truly a massive mining method, offering the highest potential production capacity. Despite its longstanding popularity, there are still significant components of the method that are not clearly understood. Also, the lack of availability of key geomechanic information still presents a major obstacle to developing mine planning and production scheduling. There are several key issues in block caving that can make it feasible such as cavability, fragmentation, stresses will condition the way that a block caves and the way that material is drawn from the draw points. Consequently Block Cave mining method is a good example where the ore body has to be related to design and mine planning. The concepts of dilution, draw control as well as sequence definition are reviewed in this paper to illustrate the idea of integration. There have been some examples of mines where some of the components of mine planning have not been integrated causing a disaster in terms of economics or safety. Different layouts configurations might give a different result in the planning of the mine

May 1, 2002

By Francis Breton, Lei Pan, Kun Liu

"Effects of Fe, Cu and Mg minor alloying elements on creep properties of 8xxx aluminum conductor alloys were investigated by conducting compressive creep tests at 100 ºC under a constant load of 69 MPa. The microstructural evolution was studied using an optical microscope and electron backscatter diffraction technique. The creep properties were characterized by the primary creep strain in the first stage and the minimum creep rate in the second stage of creep deformation. Results showed that additions of all three minor alloying elements (Fe, Cu and Mg) demonstrated a beneficial effect on the creep resistance but individual alloying elements exhibited different impacts on creep properties. The additions of Fe and Mg showed a strong impact on both the primary creep strain and minimum creep rate, while the Cu addition displayed a favorable effect on the primary creep strain but no impact on the minimum creep rate. Microstructure observation revealed that with increasing Fe contents, the volume fraction of fine intermetallic dispersoids gradually increased while the subgrain size and misorientation angle became smaller, providing strong barriers to the dislocation and grain boundary movements. The addition of Cu moderately reduced the subgrain size and misorientation angle and in combination of solid solution strengthening it promoted the retardation of the creep deformation during the primary stage.INTRODUCTIONThe 8xxx aluminum conductor alloys offer significant advantages such as low density, high conductivity to weight ratio and low price over copper conductors and become an attractive candidate in electrical engineering and building wiring (McQueen, Chia, & Starke, 1986; Birol, 2009; Engler, Laptyeva, & Wang, 2013). The mass resistivity of aluminum conductors is one-half of copper conductors. Thus, only one-half the weight of aluminum is required for equivalent capacities. Therefore, this unique property coupled with a relatively low price of aluminum offers significant economic advantage to develop aluminum conductor alloys for electrical applications in the electrical wire industry."

Jan 1, 2016

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019

By R. D. H. Wigmore

"The title of this paper probably sounds quite simple and self-explanatory. The problem, however, was not a simple one, and proved somewhat baffling and expensive over a period of years. After outlining the problem, and the methods which were used to overcome it, we will present our solution, or perhaps it would be more accurate to say the partial solution which we reached.We have in the cyanide circuit at Upper Canada two Dorr Single Tray Thickeners with 30 ft. diameter wood stave tanks 12 ft 4 1/ 2 in. deep. In the years prior to 1948, when the tonnage was 250 to 280 tons per day, two stage thickening was practised. As the tonnage was increased to 450, 500, and finally 560-600 the thickeners were used in parallel.Some settling problems were encountered, and in those days the means to combat these problems were very few. The only remedy was to dump in pounds and pounds of lime. Then along came a few reagents, and the writer remembers one in particular, - 11 Carboxel11 (carboxymethlycellulose). When water or solution was added to this reagent, the result was a gooey mass somewhat resembling tapioca. One drawback was that it stayed in this state, and didn't go anywhere. A method was finally developed of containing the mass (or mess) on a fine screen, and dissolving some of it was a fine spray of solution. The only thing the writer recalls was that it was not a very effective settling agent.Shortly after this time, along came the new flocculents, first a few, and then many, and our settling problems were over.But when the settling problem was solved at Upper Canada, some other problems were creeping up on us."

Jan 1, 1965

By Garth D. Kirkham, James P. Siddorn, Hendri Falck

"Abstract - As an integral part of the Geological Survey of Canada’s EXTECH III Project, a threedimensional computer model has been created of the Con and Giant gold mines in the Yellowknife Greenstone Belt. The Yellowknife Mining Camp has produced a great deal of gold (over 15 million ounces, or 400 000 kg) in the past sixty years and the prevailing assumption is that the mines are at the end of their lives. However, the potential for discovering additional resources using new ideas and technology, and maximizing use of existing data, offers an opportunity to sustain the old mining operations and maintain their contribution to the community.The objectives of this study included the compilation and creation of a three-dimensional Geographic Information System model (combining 3D subsurface data with surface information) to provide a framework for concurrent structural and alteration studies, and to encourage new exploration in the area. A secondary objective was to retain the data in digital format as a historical reference for future remediation efforts, and to document a portion of Canada’s rich mining history.The end result is a database and set of models that have been instrumental in facilitating further exploration in the area, as well as in developing targets for future exploration and mining activities. In addition, the EXTECH III 3D GIS model has made a valuable contribution toward the understanding of the arsenic remediation issues at the Giant mine, and has served as a tool in support of a variety of highly technical engineering studies and for communicating information and problems to the layman and community as a whole."

Jan 1, 2003

By Z. Liang, Z. Q. Liu, X. F. Li, H. L. Zhang

"Dynamic characteristics of frozen soil is important for the safe, effective and rapid construction in cold regions and artificially frozen engineering. In this paper, dynamic characteristics of frozen clay with various low temperature and different strain rate were studied by using Split Hopkinson Pressure Bar (SHPB) test and numerical simulation test. Variation of dynamical parameters and dynamic stress-strain curves of frozen clay were obtained and analyzed. The results of these test show that: Frozen clay exhibits temperature effect and strain rate effect that the failure type tends from plastic failure to brittle failure with the increase of strain rate or decrease of temperature; Under impact loading, frozen clay exhibits three typical dynamic stress-strain curves as strain rate increases, and the maximum strain of frozen clay only linear increases with strain rate.INTRODUCTIONArtificial freezing technology has been widely used in the construction of underground engineering, such as the coal mine shaft, the deep foundation pit, the urban metro and subsea tunnel, etc. Research on dynamic mechanical behavior of artificial frozen soil will provide supports for these artificially frozen engineering (Xu et al. 1998; Ma 2009). However, the dynamic mechanical research on frozen soil is mainly carried out at low frequencies or small amplitudes of the waves, behavior of frozen soil under impact loads or high strain rate loads has not been made clear."

Jan 1, 2015

By J. F. Hazzard, R. J. Chalaturnyk, C. Khazaei

"Various measurement, monitoring and verification (MMV) techniques are used to ensure the safety of operations in petroleum projects. One of these techniques is microseismic (MS) monitoring of the caprock. A challenge in MS monitoring of caprock is that unlike projects such as tunnelling in hard rocks, the number of recorded events are much smaller and also wide spread through the rock mass which makes interpretation of the physical meaning behind the events very difficult.In this paper, a numerical technique is introduced and validated for coupling a finite difference code, FLAC3D (Fast Lagrangian Analysis of Continua), with a discrete element code, PFC3D (Particle Flow Code). Then, a similar approach is adopted for modeling microseismic events in the caprock. For this purpose, the underburden, reservoir and overburden layers are modeled by FLAC3D. A rather small section of caprock above the reservoir is nulled in the FLAC3D model and substituted by a PFC3D inclusion. The reservoir pressures are then applied to the reservoir section of FLAC3D. Once the FLAC3D cycles, there will be induced pressures in the caprock due to its undrained response to the change in pressures within the reservoir. These induced pressures are transferred to PFC3D as boundary velocities. Then the PFC3D cycles and sends back the boundary forces to FLAC3D. This back and forth process continues until equilibrium is reached. During this process, there will be bond breakages within the PFC3D inclusion that can be regarded as MS events. An algorithm for recording the microseismic energies based on a change in local strains is also implemented. The results are then compared with real data. The effect of injection fluid temperature is also studied. No significant appearance of microseismic events was observed due to injection of CO2 in both cases (i.e. with or without considering temperature). However, this continuum/discontinuum approach seems promising for understanding the microseismic response of caprock in more detail and also using the MS data for validation of geomechanical models."

Jan 1, 2015

By E. Poiate, P. A. L. P. Firme, D. Roehl, M. A. Carrion, A. M. Costa

Drilling high-pressure/high-temperature wells in salt rock formations is still a challenge for the energy industry. Creep and solubility is part of the salt rock physical-chemical behaviour, which must be considered in the design of the wells. The stress redistribution caused by drilling, in addition to thermallyactivated processes, triggers creep deformation, leading to borehole closure and the imposition of loads on the casing. The drilling fluid is designed by computer modeling in order to control the creep strain rate to a limit which allows the drilling operations and the casing setting. Depending upon the composition of the drilling fluid, chemical reactions on the salt wall may occur, especially in case of water-based fluids in highly soluble salt rocks. In those cases, cavities by dissolution (washouts) can be generated and the casing column remains uncovered by the cementation and laterally unconfined along the cavity length. This scenario is propitious to the loss of integrity of the casing due to phenomena such as plastic collapse, buckling and non-uniform loading on the casing provoked by the closure of salt formation around it. The casing should remain intact during the wellbore life-time. In this work, a section of a typical well crossing salt formation composed by halite and carnallite is considered. An idealized-cylindrical washout cavity inside a highly soluble salt layer is assumed. The purpose here is to evaluate the effect of the dimensions of the cavity on the integrity of the casing. Several typical diameters and lengths of the cavity are adopted. Numerical analyses are carried out with an in-house finite-element system composed by the pre-processor MTOOL 3D®, the simulator ANVEC 3D® and the post-processor POS 3D®. Salt rocks are modeled as visco-elastic materials. Creep is simulated by the Double Mechanism Creep Law, widely employed in Brazilian salt rock mechanics research. Cement and casing (steel) are modeled as elasto-plastic materials described by the Mohr-Coulomb and the von Mises criteria, respectively. Casing integrity is evaluated with respect to vertical and horizontal displacements. Vertical displacements imposed to the casing can provoke the failure of the column by plastic collapse or by buckling. Besides that, horizontal displacements of salt due to creep closure shall lead to the undesirable contact with the casing. Failure envelopes based on displacements are generated. The results of the simulations have shown that the casing failure by plastic collapse occurs preferentially in short columns, as well as buckling occurs in long and slender columns. The occurrence of both failure modes is more frequent in large-diameter cavities. Additionally, failure caused by contact between salt and casing occurs preferentially in short-diameter cavities.

Jan 1, 2015

By K. Sasaki

Ventilation measurements were carried out in a shallow underground-quarry space with relatively large internal volume of 14,600 m3 in order to evaluate its effective ventilation characteristics. Based on air velocity measurements with an ultrasonic anemometer in the exhaust airway connected to the space, it was found that the space was ventilated by natural ventilation airflow with intermittent changes in direction. It was difficult to measure the ventilation flow with typical methods of flow measurement provided from the intake portal and throughout the mine, because the cross-sectional area and volume of the openings were too large and the flow was variable. In the present study, a tracer gas method was applied to evaluate the effective ventilation airflow rate in the space. A photo-acoustic infra-red gas monitor, highly sensitive to SF6 gas used as a tracer gas, was set in the space to determine air exchange rates from gas concentration-time decay curves. The seasonal variations of airflow and thermal environment in the space were investigated through 13 sets of measurements taken over 15 months. Airborne rock dust concentrations were also measured at same time in the opening. The correlations between the effective ventilation airflow rate, thermal environment and dust concentrations in the opening space were analyzed and are discussed based on the presented measurements taken during year. It is concluded that seasonal variations in effective ventilation flow and the dust concentration are mainly due to differences in air temperature in the space, as affected by the rock?s surface temperature and atmospheric temperature. In summertime, the air temperature and associated air density difference generated lower natural ventilation flows resulting in higher dust concentrations.

Aug 1, 2013

By G. A. Sutton

This paper, describes a case example from San Manuel mine, where in situ copper leaching of the supergene zone was done over a 14 year period (1986–1999) in conjunction with underground and open-pit mining operations of a copper porphyry deposit. In 1993–1994, testing of well fields was done to determine the amount of copper that would be recovered from in situ leaching of the supergene zone, which was composed primarily of chrysocolla and copper-clay minerals. It was determined that the leach fluid would reach 70% (‘sweep efficiency’) of the copper minerals and that 75% of them would be leached for a recovery of 52% of the acid soluble copper. However, the final results from Zone 6, which had the longest leach history, showed that approximately 42% of the acid soluble copper was recovered, indicating that the `sweep efficiency’ was closer to 55%. Comparison of drill-core assay data from two holes, one drilled before (ARM158) and the other after (SMO9607) leaching, also indicate that approximately 42% of the acid soluble copper was recovered. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to a combination of factors, including difficulty in maintaining fluid saturation, channeling effects and gypsum precipitation. INTRODUCTION In situ copper leaching at the San Manuel mine, Arizona, was initiated in 1986. It was recognized that some of the copper oxide resource was not going to be economically recoverable by conventional open pit and heap leach methods using solvent extraction and electrowinning (SXEW). A high stripping ratio would be required to access part of the resource. At the time, in situ leaching was becoming popular in the uranium industry but the approach was virtually unknown in the copper industry, especially not at a large scale.

Jan 1, 2019

By Bert S. Hall

"IntroductionThe purpose o f this paper is to review the evidence at hand concerning the earliest centuries of cast iron in Europe, from roughly 1400 A.D. until the second half of the sixteenth century. For the most part it is concerned with the relationship between two technologies which emerged first in China and then later appear in Western lands, gunpowder weapons and iron founding. We should not assume, as I hope to show later in this discussion, that weapons constituted the only product for which the iron founder had any market, but it is clearly true that attempts to produce weapons constituted the most severe technical challenge for the early founder. Firearms appear for the first time in Europe in the 1320s and develop into significant weapons on the field of battle by the end of the century. Theirs is a complex history, subject neither to easy summary treatment nor to simplified models of development. I hope to be able, through the analysis of the evidence concerning cast iron, to show that one important strand in the fabric of gunpowder's history concerns the materials from which cannon could be made. This question is subject to a number of shades of meaning, because ""cannon"" can be made for many purposes under a profusion of different names, and under sharply varying conditions of use. As a result, the question of materials is frequently really a question of competing materials, and involves a complex set of factors, of which production costs and the ultimate safety of the user seem the most important. Judged in this manner cast iron was an important but unsatisfactory metal for weapons purposes until 1543, at which time English founders learned to make iron muzzle-loading cannon which could rival bronze ordinance in most important performance criteria, but which cost much less to produce. With that event, the history of cast iron and the history of weapons entered into the close relationship that persisted until the advent of rifled artillery made of steel in the middle of the nineteenth century."

Jan 1, 1983

"Since the publication of a literature review on this topic (McIvor and Finch. 1986), the author has been involved in more than thirty rod milling efficiency tests at seven different milling operations. There have also been several interesting additional articles on rod milling found in the literature. This update describes the most important findings from investigations carried out since the previous review, as well as developments in the techniques used to evaluate the grinding efficiency of rod mills.Rod Mill Power DrawA series of power draw versus charge level measurements were taken on the rod mills at Leg Mines Selbaie and Kidd Creek Mines Limited (McIvor. 1989). These revealed a significant (about 10070) loss in power draw with the installation of new liners, a common observation among rod mill operators. This loss in power draw depends on the liner design, particularly the average thickness and lifting face profile of the new liner. The theoretical power usage of both mills was approximately 5070 lower than that given by the Allis-Chalmers power draw formula (Rowland. 1982).The shape of the power draw versus charge level curve suggested an opportunity for reducing media consumption. By increasing mill speed, power draw could be maintained with a smaller mill load, most significantly for mills operating with high charge levels. Analysis of data from 62 installations confirmed this (McIvor, 1989). On average, a 10 percentage point increase in critical speed results in a 15070 in specific media consumption (Le. kg of steel consumed per kWh of energy consumed). Table 1 lists a number of relatively high speed rod milling installations. No negative effects on the drive train, liner life, or the tendency for rods to tangle have been reported. A reduced lifting angle of the new liner leading face (e.g. 45 versus 90 degrees from the mill perimeter) is recommended for higher speed rod mills (Leclerq, 1990)."

Jan 1, 1995

By W. B. Boggs

This is a rather comprehensive subject and cannot be thoroughly covered in the short rime allowed for its presentation. This article will touch only upon a few of the chief points of the difficulties encountered in recovering copper from brass shell cases in a primary smelter which was not designed to treat scrap metals. Owing to the fact that the plant is at present (Dec., 1946) closed, and our tests were not completed, full details of the results are not available. As is well known, most primary smelters are situated near the mines in the interior of various countries and are not close to seaports or large industrial and railway centres. Consequently, iris unusual for a primary smelter to be asked to treat scrap metal of any kind. When so required, iris obvious that the primary smelter is at a great disadvantage, for the simple reason that it probably has to pay the freight on the scrap from the seaport or industrial centre to the smelter and then also pay the freight on the recoverable metal from the smelter to the refinery, or seaport or industrial centre. Another disadvantage is that a primary smelter is not equipped to sample and unload the scrap nor bas it usually the equipment adaptable for treating the scrap efficiently, as the plant bas been designed to handle large tonnages of ores and concentrates. This short paper will describe some of our difficulties> and how they were corrected. However, it might be advisable to state briefly some of the methods used in treating brass shell cases in other plants. In the first place, a brass plant producing new brass- especially those producing brass billets for extrusion to make brass tubes or rods, or to be drawn into wire, or making brass cake to roll into brass sheets- generally insists upon using new electrolytic copper and zinc and is opposed to using any scrap or secondary brass . Consequently, such a plant usually will not treat brass shell cases. Therefore, the usual procedure is to ship brass shell cases to a secondary smelter, where it is generally sorted, melted, fire-refined, and returned to the market in the form of a high or low brass ingot which can be sold to brass foundries for making brass castings. This evidently is the cheapest and simplest method. Another method is to ship to a smelter which is a combination of a primary and secondary smelter attached to or near an electrolytic refinery. In plants of both these types, that is a primary smelter with Cottrell dust collectors or a combined primary and secondary smelter with Cottrells or a bag house, the zinc may be wasted. However, if a bag house is used, some of the zinc is recovered, but it is usually contaminated with other metals and further processing is required to recover it.

Jan 1, 1947

By Jian Deng, Haitian Sun, Zengqian Hou, Shuhe Song

"Abstract - Volcanogenic massive sulfide (VMS) deposits, an important base-metal deposit type in China, occur widely in submarine volcanic districts of variable magmatic affinities. These VMS deposits range in age from Archean to Mesozoic, but most are in Proterozoic and Paleozoic sequences. More than 60% of VMS deposits formed in the Paleozoic, the most important metallogenic eon. Three important Paleozoic VMS-metallogenic provinces include Northern Qilian, Sanjiang and Altai provinces. The Proterozoic constitutes the next important era, but with no VMS deposits in the middle Proterozoic. VMS deposits associated with the Proterozoic volcanic rocks occur around the Yangtze Platform and in the western Kunlun-Qinling. The Triassic is third in importance, with VMS deposits concentrated in the Sanjiang Tethys. The Archean has only one VMS deposit, on the northern margin of the Sino-Korea Platform.Five distinct compositional classes of Chinese VMS deposits have been distinguished: Cu, Cu- Zn (or Zn-Cu), Cu-Fe, Zn-Pb-Cu, and Pb-Zn (-Cu). The Cu, Cu-Co, and Cu-Zn types of deposits occur sporadically from the Archean to Paleozoic, and are closely associated with mafic and ultramafic volcanic sequences. The Zn-Pb-Cu and some Cu-Zn type deposits are restricted to the Paleozoic and Triassic, and are hosted by calc-alkaline felsic rocks in bimodal basalt-rhyolite sequences, whereas Cu-Fe and Pb-Zn type (except for the Laochang deposit) deposits are restricted to the Proterozoic and occur in calc-alkaline volcanic sequences. As large quantities of marine mafic volcanic rocks were deposited in western China, Cu and Cu-Zn deposits are major types of Chinese VMS deposits.Chinese VMS deposits formed in a wide range of paleo-tectonic settings and depositional environments, such as island-arcs, rifts, aulacogens, and ocean ridge hot spots. Among these, the rift and back-arc environments are the most important, containing about 60% of Chinese VMS deposits. Aulacogens are a subordinate environment where most of the Proterozoic VMS deposits formed. The oceanic ridge and hot-spot systems are common in the tectono-magmatic domains in China, but contain only a few small Cu and Cu-Zn type VMS deposits.The Chinese VMS deposits have usually been influenced by both deformation and metamorphism to various degrees, resulting in changes in the shape and metal distribution. Seven representative deposit styles have been recognized: sheets, sheet plus strata-bound stringer, cyclically zoned deposits, mounds, mound-like deposits, strata-bound stringer-disseminated, and stockwork-disseminated deposits. The formation of these various styles of deposits is controlled by several key factors, such as lithology and permeability of the host rocks, focused or unfocused discharge, temperature and chemical composition (e.g., salinity) of hydrothermal fluids, as well as depth of seawater."

Jan 1, 1999

By Glenn Ferguson

BACKGROUND Metals Risk Assessment at Contaminated Sites ? The field of metals risk assessment has advanced rapidly over the last five years ? Significant uncertainties and data gaps remain that require additional research if accurate assessments are to be conducted ? Research is being conducted by regulators, external institutions and academia ? Risk assessment practitioners are in need of answers or solutions TODAY

Apr 1, 2005