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By Douglas E. Wolfe, Jogender Singh, Robert Miller, Dong-Ming Zhu, Jeff Eldridge

This paper discusses microstructural changes produced by two novel approaches using electron beam physical vapor deposition (EB-PVD) in which periodic strain fields/microporosity was incorporated within the large columnar grains of Zr02- 8wt.%Y2O3 (8YSZ). The traditional columnar microstructure of partially stabilized zirconia has been slightly modified to produce a lower thermal conductive thermal barrier coating (TBC) by periodically interrupting the condensing vapor resulting in microstructural modifications with diffuse or sharp interfaces and morphological changes on the sub-micron scale without changing the composition of the TBC. These microstructural modifications resulted in a 20-30% reduction in the thermal conductivity, 28-56% increase in hemispherical reflectance, improved oxidation cyclic life (over 100%), and better strain tolerance as compared to standard ZrO2-8wt.%Y2O3 deposited on platinum-nickel-aluminide and CoNiCrA1Y bond-coated MAR-M-247 test samples. The TBC with tailored microstructures were examined by various techniques including scanning electron microscopy (SEM), x-ray diffraction (XRD), steady-state laser heat flux technique, and hemispherical reflectance.

Jan 1, 2004

By Richard Samson

"RésuméComme l'exploitation d'un gisement à grande profondeur représente un défi de taille et que la profondeur à laquelle se situe celui d'Ansil varie de 1200 m à 1460 m, nous avons dû mettre en place une infrastructure de surface d'envergure incluant un treuil de production et un chevalement d'une très grande capacité. De même, l'infrastructure sous terre a été proposée en tenant compte de ce fait important; d'ailleurs, l'excavation de deux puits circulaires dont l'un est en beton et acier et l'autre exclusivement en béton en témoigne. De plus, la plupart des cheminées principales qui furent excavées sous terre sont de forme circulaire.L 'exploitation du gisement s'effectue par une méthode chantier ouvert (abattage par longs trous), remblaye immédiatement âpres avec un mélange de roche stérile et ciment. Un taux de minage de 1750 tonnes par jour est requis pour assurer la production.L 'utilisation d'une technologie de pointe tels: les ventilateurs et les portes de ventilation sous terre contrôlées de la surface, un système de relèves macroséismiques, de chargeuses-navettes contrôles à distance, en passant par le dessin et la planification assistes par ordinateur nous permet d'optimiser l'exploitation du gisement Ansil.IntroductionEtant donne la grande profondeur a laquelle le gisement Ansil se situe, no us avons à mettre en place une infrastructure souterraine et de surface d'envergure pour nous permettre d'atteindre nos objectifs d'exploitation.Infrastructure de surfaceLa mine Ansil dispose d'une infrastructure de surface d'importance possédant une grande capacité (Fig. I). Les deux facteurs qui furent déterminant pour le dimensionnement des infrastructures furent le taux d'extraction de 1990 t/jour et la profondeur a laquelle I 'exploitation s'effectue, puis que cette dernière affecte le temps de cycle et la capacité de hissage.La première composante principale de I 'infrastructure de surface est un treuil de production a 2 tambours de 3.65 m de diamètre et de 2.0 m de largeur chacun. Ce treuil de marque Fullerton, Hodgart & Barclay construit en 1970, opère avec 2 moteurs de 930 kW a une vitesse de 700 m/min. et il a une capacité maximale de 32000 kg. Deux câbles d'acier de 45 mm de diarnètre et de 160 000 kg de résistance a la rupture servant au hissage des bennes d'une capacité de 12 tonnes. De plus, un moteur/générateur de 3000 kW (M.G. Set) raccorde au treuil de production sert a stabliser son alimentation électrique."

Jan 1, 1991

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By Lluís Fontboté, François Lieben, Robert Moritz, Massimo Chiaradia

"Abstract - The Las Cañas stratabound Pb-Zn deposit, in northern Chile, is hosted by the Lower Cretaceous back-arc marine carbonate and subordinate andesitic volcanic and volcaniclastic rocks of the Chañarcillo Group, one hundred meters above a thick pile of magmatic arc-related basaltic to andesitic lavas of the Bandurrias Formation. The deposit is not obviously related to local intrusive rocks, which include an Upper Cretaceous granodiorite batholith and dacite dikes emplaced along normal faults. Stratabound Pb-Zn-Ba mineralization is constrained within several porous stratigraphic units, including a 50 cm thick lapilli-tuff and less well mineralized algal-laminated limestone. Veins that locally carry some Pb-Zn occur along normal faults that displace the stratabound orebodies, and this study shows that they represent a different type of mineralization.Fluid inclusion microthermometric data for ore-stage quartz and barite indicate saline fluids (6 to 30 wt% NaCleq) and a formation temperature in the range of 80°C to 160°C for the stratabound mineralization. Two types of fluid inclusions occur in the veins. The type I vein fluid inclusions indicate less saline (average 7 wt% NaCleq) and slightly higher temperature fluids, in the range of 110°C to 220°C. The type II vein fluid inclusions indicate highly saline fluids (25 to 40 wt% NaCleq) which might be related to minor copper mineralization.206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios for galenas from the stratabound mineralization, with mean values of 18.42, 15.59, and 38.25, respectively, fall within the range of stratabound polymetallic deposits of northern and central Chile, and indicate a Lower Cretaceous magmatic rock source. Galenas from veins have slightly more radiogenic 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios, with mean values of 18.47, 15.61, and 38.34, suggesting two distinct episodes of mineralization.?34S values for galena and barite range from negative values (-31.2‰ to -12.5‰ and -7.7‰ to +12‰, respectively) in the mineralized tuff to higher values in the algal-laminated limestone (-2.5‰ to +1.2‰ and +13.2‰ to +17.4‰, respectively), close to Lower Cretaceous marine sulfate values for barite, and homogeneous values for the galena from veins (-12.0‰ ±1‰). Changing redox conditions can partly account for ?34S variations in the tuff. Sulfur sources include magmatic rock sulfur (-1.5‰ to +9.7‰) as well as sedimentary sulfides and marine sulfate."

Jan 1, 1999

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved

Jan 1, 1979

By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

By H. Wotruba, K. Neubert

Dual-energy X-ray transmission (DE-XRT) imaging is known from safety luggage inspections at airports. The use of DE-XRT technology for sorting applications in the primary raw materials industry has been the subject of numerous investigations. Beside other metal ores, X-ray transmission sorting is already used for the preconcentration of tungsten ore, gold ore and coal. The applicability of DE-XRT sorting is limited to ore types where differences in metal concentrations are measurable, based on an interpretation of X-ray images. Metal contents in particles occur in large varieties in terms of concentration, grain sizes, spatial distribution and mineralogy and therefore influence the X-ray absorption. As a result, each ore has to be tested individually for its suitability for DE-XRT sorting. The objective of current research at the Department of Mineral Processing (AMR) at RWTH Aachen University is to assess parameters influencing the detectability of rare earth oxides. Two approaches were followed: (1) Practical test work, based on artificial ore samples of defined compositions and (2) Computer-based simulation of absorption features of identical particle compositions. In total, more than 300 artificial samples of various compositions and metal grades were produced and X-ray images from DE-XRT sorting were analyzed. Results from the DE-XRT sensor were put into correlation with metal grades and particle sizes, to analyze influences and limits on the detectability of rare earth oxides. In addition, a new approach was tested in which the X-ray absorption of particles of various compositions was determined based on a Monte Carlo (MCNP) simulation. During the simulation, similar compositions, as used for the artificial samples, were tested and the X-ray absorption behavior during DE-XRT sorting was determined. A comparison of results from both approaches is used to assess the applicability of the MCNP-simulation for the prediction of the X-ray attenuation behavior during DE-XRT sorting.

Jan 1, 2016

Adaptive processing is often related to the mineral composition of the mining block currently processed. The portions of waste, ore and secondary product minerals considered are always positive and typically sum to 100% (i.e. a composition). A typical solution to predict block averages of spatially dependent quantities would be block kriging. However, kriging is based on spatial correlations and it has been repeatedly shown that correlations of compositional data are spurious and blurred by the constant sum constraint. Aitchison (1982) proposed a general solution for compositional problems, based on transforming the compositional data to a set of logarithms of ratios of components, and analysing the transformed scores. The transform is chosen to be invertible to ensure that no information is lost in the process. This methodology avoids spurious correlation problems and ensures coherence between results obtained with different subcompositions. Pawlowsky-Glahn and Olea (2004) adapted the approach for point-support geostatistics, allowing the prediction of point compositions from spatially neighbouring data, without the artefacts induced by standard multivariate cokriging. Unfortunately upscaling the results of this approach with block cokriging is not straightforward, because of the nonlinearity of logratio transforms. Furthermore, we have to consider those nonlinearities created by the dependence on the block composition of extraction efficiency and processing costs of the possible processing choices. This paper proposes a solution for predicting the conditional expectations of the benefit of processing the block with each processing choice using geostatistical simulations of the local values of the composition and the resulting block integrals. The computation for a large number of blocks can be done efficiently using Cholesky decomposition. The approach also allows the calculation of prediction errors for expected compositions and expected benefit at almost no additional computational cost. Such compositional approach is necessary, for example when processing choices depend on proportions of certain minerals after other components have been removed; or if processing alters the composition in a multiplicative way, by partially removing a portion of some components.

Aug 1, 2013

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015

By Mikael Ramström

The IREDES Special Interest Group (SIG) for Drill rigs has been active since its inception at MineExpo 2000, in Las Vegas USA. The SIG for drill rigs is responsible for the development of a IREDES Drill rig profile. This includes the exchange of production planning, performance and quality reporting data between various kinds of drill rigs and the databases used by the operating mine. During year 2001 a first draft of the drill rigs profile was jointly prepared by drill rig suppliers, mining companies and third party suppliers and reviewed during several SIG meetings. In mid 2002 the profile was released for prototyping projects and since then, feed back received from these projects has been used as input to the first official IREDES release. LKAB and Atlas Copco decided in 2002 to start an IREDES prototyping project using the Simba L6C production drill rig as target equipment. The goal was to verify the drill rig profile and identify possible problems prior to the official release. This was done by implementing the IREDES prototype version in the LKAB?s production planning system and Simba rig control system. The Simba rig control system was designed to handle drill plan and logging information coming from the mine planning system. In parallel to this the mine production system was adapted for drill plan export and logging data import on IREDES format. This paper presents the most recent results of this prototyping project. Result from late 2002 show that the basic architecture of the drill rig profile works and that a common language for data exchange, IREDES will be a central issue for future mine automation. As a result from this and other IREDES prototyping projects the official IREDES release will be available in 2003. Soon after that release IREDES compliant products can be expected. This will include drill rigs and mine production planning systems.

May 1, 2003

By G. W. Diehl, G. A. Griffiths

"Gentlemen, one week ago, I attended the University of Minnesota's Annual Symposium on Mining, in Duluth. A good part of this symposium was dedicated to mill linings of rubber.At this symposium, three mining companies published results from long time full scale tests with rubber linings in mills at four different mines. These were the Republic and Empire Mines of Cleveland Cliffs Iron Company, the Groveland Mine of Hanna Mining Company and the Eagle Mountain Mine of Kaiser Steel Corporation. These papers will be printed in due time and I will not endeavour to relate their full contents, let me only say that in three of the plants, the linings were found to be very economical compared wi.th steel, and that these three are converting over completely to rubber linings, while the fourth, Empire Mine, reported no economical results as far as the shell lining goes, whereas the grates showed promise of becoming economical. The authors of the Cleveland Cliff's paper, however, stated that design improvements in the rubber lining possibly could result in an economical lining also for Empire Mine.That rubber linings in mills, in most cases, show better wear life than steel linings, is known by most of the audience. But, one thing that has not before been disclosed by the endusers is the effect of rubber linings on the grinding economy. All three papers mentioned above reported no change in capacity or grind and two of them reported a decrease in power consumption per ton ground. Hanna Mining reported an average decrease over a three year period for one mill of over 10%. This, of course, puts the economy of a rubber lining in a completely new light. Finally, a point of interest at this meeting was that all three papers emphasized the design aspect, Thus the industry has acknowledged what I believe to be a very important fact - the design of a lining is often more important than the material it is made of."

Jan 1, 1970

By Xiaoxing Hu, Guibing Zheng, Yangge Zhu, Xingrong Zhang

"In China, more than 90 percent of titanium resources are reserved in vanadic titano-magnetite deposits. In this type of ore, the same elements such as Ti, Fe, Ca, Mg exist on surface of both ilmenite and titanaugite (the gangue mineral) because of isomorphism, which makes selective flotation difficult. Therefore, how to enlarge the floatability difference between these two minerals has always been a research emphasis and still needs to be studied further. In this paper, the pre-treatment methods using ultrasonic wave were proposed. The results indicate that ultrasonic treatment shows beneficial effect to enlarge the floatability difference, and the effect will be strengthened by extending the ultrasonic treatment time or increasing the ultrasonic power. The mechanism was investigated through infrared spectroscopic (FT-IR) analysis. Collector interacts with Ca and Mg which results in titanaugite flotation, after ultrasonic treatment, the dissolution of Ca and Mg is intensified, which leads to the lack of active points on mineral surface, so the floatability of titanaugite is depressed. Meanwhile, collector mainly interacts with Fe which results in ilmenite flotation, and the present of ultrasonic might promote its oxidation (Fe2+ to Fe3+), so the floatability of ilmenite after sonication is increased.INTRODUCTIONUltrasonic is the sound wave with frequency of 2 × 10-4 Hz~2 × 10-9Hz. Since the first International Symposium of Sonochemistry in 1986, the application of ultrasonic wave is more and more extensive. In researches about mining and metallurgy, various investigators have shown that intensive acoustic fields can modify the state of a mineral, leading to chemical or dispersive effects. Generally, the effect of ultrasonic vibration depends upon the nature of the mineral and also the way ultrasonic wave is applied (Celik, 1989; Ozkan, 2002). In addition, ultrasonic treatment usually plays roles of removal of reagents adsorbed layer from minerals and emulsification of flotation reagents when it is used in flotation (Nicol, Engel, & Teh, 1986; Slaczka, 1987; Djendova & Mehandj, 1992; Farmer, Collings, & Jameson, 2000; Gurpinar, Sonmez, & Bozkurt, 2004)."

Jan 1, 2016

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By P. A. Verhey

"This paper describes a series of wear-resistant ceramic materials which have been successfully used in the mineral processing industry in Canada. Applications include use with metallic ores, coal, potash and asbestos, and in other processes where wear degradation is of major concern. The paper will also deal with considerations involving the selection of the different ceramic materials available. It will cover the installation of ceramic materials on support structures under varying process ' conditions, as well as the other physical and chemical factors which have to be taken into account.IntroductionIn the mineral processing industry, large volumes of ores tailings and other materials are handled. The abrasive nature of most of these materials results in extensive wear to both handling and processing equipment.Wear ratios versus cost, production losses due to down time and wear-resistant material suitability for a given application all demand particular attention when viewed against the need for increased efficiencies in existing processes. As a consequence, a very active continuous search for materials with improved wear resistance has been carried out for many years.In this search, starting about 20 years ago, dense ceramic materials were tested and evaluated in certain applications, notably in the iron ore and asbestos operations in Eastern Canada. As a result of substantially better performance both in continuous extended life and ultimate economics realized , wear-resistant ceramic applications developed progressively in many other processing applications, replacing traditionally used materials.In the vast majority of wear-resistant ceramic applications, considerable extended life over previously used materials was established. This invariably was not just a fractional increase but, in most cases , in factors of double, triple and often all the way up to 18 and 20 times the life of alternative materials used previously. In certain applications, extended life could not be measured and appears to be indefinite.Obviously, as a result of such experiences, the progressively wider use of wear-resistant ceramic materials is now an established trend."

Jan 1, 1981

By S. Pietruszczak, G. Su, T. S. Nguyen, E. Haghighat

"In this paper, the mechanical properties of Tournemire argillite are modeled using a mathematical framework which employs the microstructure tensor approach (Pietruszczak & Mroz, 2000). The experimental data incorporates the results of a series of triaxial tests (Abdi & Evgin, 2013) conducted at different orientation of bedding planes relative to the direction of loading. First, a plasticity framework is presented which involves the specification of the conditions at failure as well as the description of the irreversible deformation process. Later, a systematic procedure is outlined for identification of material functions/parameters involved. The paper is concluded by presenting the results of numerical simulations of the triaxial tests. It is demonstrated that the model can adequately reproduce the primary effects of anisotropy in the stable deformation regime as well as the onset of fracture.INTRODUCTIONThe understanding of the mechanical behaviour of argillaceous rocks is important in many types of geotechnical projects, including petroleum extraction, carbon dioxide sequestration as well as deep geological disposal of radioactive waste. In all these cases, the primary concern is the onset and propagation of damage due to excavation, transport of pore fluids and/or elevated temperature. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long-term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URL). Such an URL is situated in Tournemire, France, in an argillaceous rock formation, the Tournemire argillite. The Tournemire argillite is characterized by the presence of closely spaced bedding planes and exhibits a strong anisotropic behaviour, so that its strength as well as deformation properties are directionally dependent."

Jan 1, 2015

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

By I. R. Muirhead

"One approach to making new technology available is to demonstrate its value under full-scale operating conditions. Studies were undertaken to assess the feasibility of this approach to introducing a longwall mining system to the western Canadian coalfields.The longwall method of mining coal is described, world and Canadian usage is reviewed, and the merits of the system in comparison 10 other coal mining methods are discussed.The rationale for a longwall demonstration in western Canada is presented, along with a proposed organization for the design, operation and dissemination of the findings from such a trial. The factors which must be considered in the design of the demonstration, and in the assessment of a potential site are highlighted. It is concluded that a demonstration of this technology is both timely and essential to prepare the way for the western Canadian coal industry of future prospects for coal.IntroductionFor many years CANMET has encouraged research work organized on a cooperative basis. This requires that a working consensus must be negotiated by researchers and operators at the beginning of the project and continuously refined as work proceeds. The result is usually a more relevant selection of research problems, improved direct ion and con duct of experiment al work and often a validation phase in which research concepts are tested in an opera ting environment. All this tends to narrow the gap between obtaining research results and applying them.Even under the best of circumstances cooperative projects require a good deal of coordination and enthusiasm to maintain focus and the pace of work. The working perspective of a research scientist in a government laboratory is substantially different from that of a mine operator at a producing mine, and a common ground must be found. This is difficult to do and cooperative projects typically evolve over several years as experimental results progressively define the potential solutions to mining problems."

Jan 1, 1985

By J. F. Dorion

This paper presents the results of on-going investigations on the performance of support systems in Québec underground mines. The focus of these investigations is on site observations complemented by laboratory investigations. Of particular interest is deducing the corrosion rate, at selected mine sites, as determined by the installation of monitoring coupons.

May 1, 2009

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By Fidelis T. Suorineni

HydraboltTM is a Swellex-type dowel support element developed and manufactured by New Concept Mining in South Africa. Like Swellex, the HydraboltTM is a folded tube which can be inserted into a larger diameter hole without pushing. It is then activated by injection of high pressure water which inflates the folded tube to intimate contact with the walls of the borehole at a set pressure, normally 25 MPa. Unlike Swellex however, the set water pressure at the end of the inflation is maintained throughout the life of the dowel. An integral non-return valve makes this possible. The HydraboltTM is being investigated as a possible stress change measuring cell. This paper presents the results of closed form solutions, numerical modeling and laboratory test to date. Preliminary results indicate that the HydraboltTM can be used as a stress change monitoring cell in addition to its conventional role as a rock mass reinforcing element. If successful, the HydraboltTM will supplement microseismic monitoring systems in rockburst-prone ground conditions where they will give quantitative stress change data for both mine design model calibrations and means for proactive safety measures.

Oct 1, 2010