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By J Ralston, G B. N Kaggwa, L Huynh

Three polymers of varying chemistries and molecular weights have been used to depress talc in a model sulfide ore consisting of talc, pentlandite, and chalcopyrite. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc (HP Starch > Polymer-H > Dextrin WY) but a different order of effectiveness for depression selectivity (Dextrin WY > Polymer-H > HP Starch). Adsorption isotherm determinations for the gangue and valuable mineral phases indicate that the differences in selectivity are partially due to adsorbed amount variations, with Dextrin WY adsorbing marginally less on the sulfides than Polymer-H. Contact angle measurements on packed particle beds have revealed that the polymers have differing abilities to reduce the contact angle of talc and the sulfide minerals. An explanation of the observed trends is given in terms of the binding mechanisms of the polymers on the talc and the sulfide mineral phases. Order of addition effects between collector and depressant were also investigated using adsorption isotherm determinations for the polymers in the presence of a pre-adsorbed layer of collector and vice versa. Adsorption of the polymers was not affected by the presence of the collector. Similar results were obtained for the adsorption of collector in the presence of pre-adsorbed layers of polymer.

Jan 1, 2005

Natural gas was introduced to the Melbourne reticulation system in April 1969 and since that date sales to industrial consumers in the Gas & Fuel Corporation of Victoria area of supply, have increased by over 50% This increase has occurred despite the fact that the areas in which the new fuel is available have been dependent on the progress of the conversion operation from manufactured gas. The half way mark for conversion was reached in May 1970. The reason for the adoption of natural gas by industrial users is usually the result of objective financial analysis leading to the conclusion that the new fuel will give the lowest overall production cost. Many factors are involved in such an analysis of which the price of the fuel is only one. Amongst other important elements in the cost calculation are:- -ò òò -(1) The effect of fuel on product quality (2) Maintenance and handling costs for alternative fuel. In addition to economic gains for the individual user, the use of natural gas should benefit the whole community through its effect on such things as, air pollution and overseas balance of payments.

Jan 1, 1970

By M A. Gontalves, A F. D C Varajpo, S A. Stachissini

Clays from the Santa Elena Peninsula, south-east of the Ecuador coast, were investigated with a view to identifying their main mineralogical, physical, chemical and textural characteristics as well as their potential for industrial use as adsorbents. Identified as calcic bentonites, two representative samples from the Tosagua Formation (Oligocene to Lower Miocene) were selected for acid activation trials. The selection criterion was based on the greatest amount of clay fraction (<2 ¦m fraction) associated with the greatest content of montmorillonite. For the activation treatments, HCl and H2SO4 solutions of 4, 6 and 8 N were used in a stirred glass reaction vessel with the clay sample under reflux during four hours at temperatures of 70¦C for HCl and 85¦C for H2SO4. Mineralogical analysis by X-ray diffraction (XRD), chemical analysis by X-ray fluorescence (XRF), differential and gravimetric thermal analysis and measures of density, surface area and porosity indicated the changes occurred in the crystal structure of the montmorillonite. The acid treated clays were utilised in trials of purification and decolourisation of soybean vegetable oil in a ratio of 2:100 (clay/oil) at 90¦C for 30 min, under constant stirring. After centrifugation of the suspension, the wavelength of the bleached oil was measured by UV-visible spectrophotometer and the bleaching capacity of the clays was determined. The best bleaching capacity of the samples was obtained with 6 N H2SO4 acid-activated clays. The bleaching capacity was compared to Tonsil, a commercial acid-activated clay and similar results between them evidenced the potential industrial application of the Ecuadorian clays to bleaching of vegetable oil.

Jan 1, 2008

By Wilson PH

A research programme sponsored through the Australian Mineral Industries Research Association investigated two aspects of mine aerodynamics on model scale. These were aero- dynamic losses in (a) shaft/airway intersections and (b) losses created by mine cages moving in a combined haulage/ventilation shaft. The shaft/airway intersections studied included base and intermediate levels for both upcast and downcast. shafts, with one to four rectangular airways intersecting a circular shaft. Changes in intersection geometry were limited to the installation of 45¦ conical brow cutoffs of varying size and the addition of simple flow control devices. The relative air- flows between the airways and the downstream shaft were varied over a range employed in Australian mining practice. In general, experiments revealed that a small brow cutoff was significantly better than none at all, and a simple device such as a cone can reduce losses and improve flow stability at an intersection. The mine cage studies determined the effect on aerodynamic loss of cage area blockage, height/length ratio, openings in cage walls and surface roughness due to external structural members. The results show that in a combined haul- age/ventilation shaft, when the relative air

Jan 1, 1978

By E R. Ramanaidou, M S. Piggott

Transport to and handling of iron ore at Port Hedland, Western Australia, results in the generation of airborne particulates that contribute to the atmospheric dust load, with concerns about potential local environmental impacts (eg mangrove swamps) and possible human health implications. Mineral and chemical characteristics of the Background soil samples were contaminated with particles of iron ore as martite octahedra and grains of micro-platy hematite as detected by scanning electron microscopy (SEM) in the 2.5 - 10 ¦m and 10 - 50 ¦m size fractions. Fossilized wood fragments similar to those observed in Yandicoogina fines ore were also detected in some background soil samples. With a predicted increase in demand of channel iron deposits (CID) ores and the inherently dusty Marra Mamba ores (eg West Angelas, MAC, OB29/30/35, Marandoo), in conjunction with particulate emissions from hot-briquetted iron and direct reduced iron (HBI/DRI) processing plants, there is the potential for additional sources of anthropogenic dust to contribute to background levels. Mineralogical and chemical characterisation of the entire range of particulates that could be produced is necessary for a complete understanding of their potential impact on the local environment.

Jan 1, 2002

The comparatively low winter rainfall, exposure to heavy salt laden coastal winds, and the consequent high evaporation rate, are important considerations in the rehabilitation of the Maslins Beach Sand Pit. The deficit of rainfall over evaporation is assessed at 1085 mm per annum. Such a coastal environment complicates the establishment of plants. The endemic flora found on the Sand Pit environs is mainly low wind-planed shrubs and mat plants. The dunes near the coast support an association dominated by Atriplex cinerea, Spinifex hirsutus, Scirpus nodosus, and Olearia axillaris. The coastal cliffs carry a more diverse vegetation dominated by Beyeria lechenaultii and Eutaxia microphylla. Overburden is used to develop a new landscape to screen operations, batter final faces, and cover rubbish at the nearby Council dump. The early overburden dumps were built with little regard for stability, but the more recent practice of using scrapers has resulted in more stable dumps. The erosion problems created by poor compaction have been controlled by contour banks, diversion drains, bitumen lined run-off drains, and hay mulching.

Jan 1, 1976

Kamhalda is located within the Yilgarn Craton of Western Australia, specifically in the Norseman - Wiluna greenstone belt. Numerous nickel sulphide deposits have been mined at Kambalda with I I mines currently operating. For several years, a program of in-mine geophysics has been operating at Kambalda, with downhole electromagnetics (UHEM) one of the key techniques used. Three case studies illustrating the uses of UHEM in mines are presented here. In the first example, the Helmut South deposit was discovered as the result of an extensional exploration program. The first drill hole in the program intersected ore width and grade mineralisation at around 760 in depth. Two subsequent holes intersected subgrade mineralisation. DHEM surveys were completed in each of these three holes, with anomalies recorded indicating that a large conductor was located directly south of the first hole. The next hole intersected this target, for an intersection of 21.6 in at 3.5 per cent Ni. DHEM continued to play a role as the exploration program proceeded, providing drill hole targeting based on anomalous responses recorded in each drill hole. In the second example from Carnilya Hill, old drill holes were surveyed with DHEM in order to search a large section of prospective contact for massive ore pods. An off-hole anomaly was detected and subsequent mining discovered a small but high-grade pod of ore which was extracted for a considerable profit. Carnilya Hill has limited reserves and discoveries such as this, assist in keeping the mine operating. In the third example from Victor, a program of drilling intersected thin ore profiles in an interpreted flanking position. Without massive ore close by, these intersections probably do not constitute economic mineralisation. DHEM surveys of three holes did not detect any conductors. The area is now regarded as sterilised of significant massive ore and exploration efforts and dollars can be focused in other areas. These three examples demonstrate the type of successes that can he achieved through the use of DHEM.

Jan 1, 1997

Victorian brown coals occur in massive deposits, the quality of which is determined in the first instance by means of samples taken from exploratory bores. As a number of important utilisation characteristics are connected, not with the relatively homogeneous organic mass of the coal, but with minor components such as the ash content and particular constituents of the ash, it is necessary to know how bore samples relate to coal finally used in the process concerned. Tests are described in which the statistical parameters associated with bore sampling, operational sampling and sample reduction and laboratory procedures including a range of coal analytical methods were determined. These indicated properties where analytical errors were relatively high and where sample reduction procedures contributed substantially to imprecision in results. They also showed the effects of the non-homogeneity of brown coals with higher than normal ash contents. A further experiment explored the relationship between samples taken at various stages in the course of test boring, digging, and burning a defined 'block' of coal, and demonstrated an apparent increase in the proportions of adventitious mineral constituents as the 'intensity' of sampling Increased.

Jan 1, 1976

By W Uhlmann, U Grnnewald, B Nixdorf

Flooding with surface water is the preferred technique for the abatement of acidification from pyrite oxidation in the lakes of abandoned Lusatian lignite mines. However, water resources of the region are limited and in addition, interruption of water inflow during the summer and the termination of the flooding process after reaching the final water level can lead to a re-acidification of the lakes. The development of three mining lakes with a surface-water flooding history of six to 28 years was analysed û in two lakes on the basis of fortnightly to monthly hydrochemical monitoring data. During summer flooding interruption, the younger lakes showed a decrease in pH from neutral down to pH 4. The degree of the pH decrease depended on the intensity of the groundwater inflow from the overburden dumps and this affected the hypolimnion more than the epilimnion. The third lake was flooded 28 years ago and up to now, interruption of the surface water inflow resulted in re-acidification. These three examples were able to show the benefits and limits of the surface water flooding technique for the abatement of Lusatian mining lake acidification.

Jan 1, 2003

By Sibson RH

The gold province of Otago occupies an area of upwarped basement, the Otago Schist, comprising predominantly quartzofeldspathic and volcanogenic metasediments. This assemblage is the product of collisional tectonic deformation and associated metamorphism, mainly to lower greenschist facies, during the Rangitata Orogeny (200-100 Ma). Historically this region has produced 240 tonnes of gold, 4% (10 t.) of which was from the mining of Cretaceous gold- quartz mineralised vein systems. Auriferous vein systems in the Otago Schist are mainly hosted within NW trending normal fault-fracture arrays, however NW trending reverse fault-hosted vein systems also occur. We propose that the Late Cretaceous-mid Tertiary Otago Schist structure represents a regional anticlinorium containing flexural folds of at least two wavelengths. The anticlinorium structure has been quantified by determining variations in angular discordance between schistosity and the Otago Peneplain, a Late Cretaceous-mid Tertiary erosion surface covering most of the Otago district. A structural model for the evolution of the post-collisional anticlinorium requires the cooling surficial zone (carapace) of a retrograding metamorphic belt to behave as an elastic lid. Erosion of topographic load on the carapace drove isostatic uplift, which was greatest in the tectonically thickened core of the orogen. In this way differential uplift produced flexural deformation in the elastic carapace, expressed as a large scale arching of the orogenic belt. Flexure created tangential longitudinal strains in the outer-arc, leading to extension and the formation of mineralised normal faults. These structures are separated by a neutral surface from shortening and associated mineralised reverse faults in the inner-arc. Our structural model predicts that the distribution of auriferous lodes should be localised about zones of maximum flexural curvature, where the tangential longitudinal strains are highest. As a result, NW-SE hinge regions separating schistosity dip domains in the Otago gold province may have new found significance as potential exploration targets.

Jan 1, 1995

Comprehensive occupational health and safety legislation in Australia is comparatively recent. It follows the examples set in U.S.A. and U.K. a decade or more ago. In Western Australia the Occupational Health, Safety and Welfare Act was proclaimed in April 1985. It still has a long way to go before it achieves all its objectives. The mining industry has developed a substantial body of health and safety regulations under the Mines Regulation Act. Considerable practical expertise in such matters already exists, much of it developed from hard won experience. As a result it would prefer not to become engulfed in the new legislation. It would prefer to build upon the cooperatively developed policies and workable practices in the field of occupational health and safety with which it is familiar. Associated Minerals Consolidated Ltd. is a leading mineral sands producer in Western Australia and has continuously developed its occupational health and safety policy and practices. Under the banner of "Resource Control", AMC seeks to provide a safe and healthy working environment at all times. This is being achieved through a strategy of a policy, a defined organisational structure and a detailed programme, which together comprise the "Resource Control System". Some of the activities and achievements of AMC in the field of occupational health and safety are compared with the objectives of contemporary legislation, and details of some of the specialised areas of the Resource Control Programme are discussed. The paper will also highlight and discuss impractical areas of potential legislation.

Jan 1, 1986

By Semple DG, Leach TM

A continued exploration programme has further defined the geology of the Tolukuma vein system, verified the resource indicated by Newmont, and identified potential for additional mineralisation. The resource at Tolukuma Hill, designated as Zone C, is a measured 440,000t @ 17g/t Au and 46g/t Ag with an additional indicated resource of 120,000t @ 16g/t Au. A diatreme breccia localised at an intersection of structures, and a relationship of gold to base metal sulphides, are highly indicative of a porphyry association. Typical epi-thermal features such as crustiform banded quartz and quartz pseudomorphing. platy calcite are also present and locally contain lesser gold mineral-isation. Pre-existing dilatant structures have acted as a host to the ore fluids, resulting in the formation of the semi-continuous Tolukuma-Gulbadi veins over a 1100m strike. A fluid flow model suggests that mineralising fluids were sourced from the diatreme margins and migrated laterally along dilatant structures. Bonanza gold grades are derived through fluid quenching in the flexure between a hanging wall split which hosts much of the Tolukuma Hill resource and the feeder graben structure. Thus, the relationship between the pre-mineral structural geometry and fluid upflow at the margins of a diatreme breccia, controls the ore setting. Potential for more ore remains within the Gufinis and the 120 veins as well as in the outlying Prospects.

Jan 1, 1994

THE absence of any locality maps of the district of Morobe has been seriously felt by mining engineers engaged on the goldfields, and as it was evident at the beginning of operations that the administration would be unable to make good this deficiency, ascheme for making rapid traverses was worked out, and in all subsequent travelling the necessary records were kept for the construction of a reliable reconnaissance map of the Bulolo goldfield and its approaches (see Plate 1.). Since all the field work had tobe carried out without encroaching on primary duties, the compilation of sufficient data was a somewhat lengthy business. It was found that in this r;ough country a pedometer was useless, as it was impossible to calibrate it for the variation in length ofpace between climbing semi-precipices and walking over level country. Further, the native tracks "meander" so excessively that the only method of calculating air-line distance is by timing, and a knowledge of what the timing represents, and until a 10kg experience had been gained in the time taken to cover known distances in various types of-country, one could not feel competent to estimate sufficiently accurately. It was found that reliability could be attained only when walking at nearly top pace. Inregard to aeroplane traverses, results were reliable only when the air was fairly still.BEARINGSIn arriving at the bearing between main traverse points, the method used was to keep a "boy" about two chains- behind when marching and sight back on him, standing, at about two-chain intervals. These bearings were averaged into the field book at the end of the day, each line being averaged separately. As the roads became known, it was possible to get a considerable amount...

Jan 1, 1928

By P Townsend, F Russell

Palabora Mining Company operates an integrated open pit mine, concentrator, smelter and refinery complex located in the Northern Province of South Africa. The Palabora open pit went into production in 1966, mining 30 000 t/d to produce some 62 000 tpa of copper. With continuous modification and improvement, a mining rate of 82 000 t/d, producing up to 135 000 tpa of refined copper, has been achieved. While these improvements have also enabled the mine life to be nearly doubled, the open pit will reach the end of its economic life by 2003. The Palabora orebody is vertical and the reserve extends to a depth of 1800 m over an area of 700 m by 200 m. Studies to assess the economics of mining the orebody by underground means began in the mid-1980s. These studies indicated that block caving is the lowest cost underground mining method that would generate a suitable return. In March 1996, a decision was made to develop a 30 000 t/d block cave mine that will extend the life of the Palabora Mining Company by a further 20 years. In terms of the relatively high rock strength and the resultant coarse fragmentation that is expected at the drawpoint, the Palabora cave can be considered rather unique when compared to other block cave operations. This paper describes the project in broad terms and details the mining method, particularly with respect to the cavability of the orebody and the design features to deal with the coarse fragmentation. The project commenced in July 1996 and final development of the undercut and drawbells is scheduled for completion in November 2003. This paper describes the status of the project and planning as of April 2000.

Jan 1, 2000

Agglomeration Drum Selection and Design A model has been developed by for drum agglomeration which allows selection of geometry and power input. Specific aspects considered are: calculation of total operating volume, solids residence time based on drum geometry and operating parameters, selection of the drum aspect ratio, selection of proportion of critical speed, calculation of rotating power requirements. The model uses solids total residence time to calculate the required operating volume. The burden density is calculated from the solids bulk density, agglomerate packing and the fluid density. Power is calculated using a modified Liddell and Moys correlation for burden position and shape, and the operating drum speed. A further power allowance is made to allow for accretion drop off during drum rotation. Results from the model (especially power and per cent operating fill) have been verified from industrial installations of significant size. Predicted and observed power draws are within five per cent when burden slip and bypassing are not significant. When these are significant (at fills above 15 per cent) the actual power draw will be less than the model prediction. Under these circumstances the quality of the agglomerates will be poor.

Sep 13, 2010

BHP is the world's largest copper concentrate producer with production from mines at Escondida (Chile), Ok Tedi (Papua New Guinea), and Island Copper (Canada). The entire concentrate production is further processed into refined copper by third-party smelters around the world. In anticipation of an expansion in the global copper concentrate production capacity and a corresponding increase in treatment and refining charges by copper smelters, BHP has continuously evaluated various opportunities for downstream copper processing. An expansion in the Escondida mine production, combined with BHP's interest in processing some of its concentrate production on-shore in Chile, ultimately resulted in the development of the Escondida Leach Process. This process was specifically developed for higher grade concentrates, such as from Escondida. An ammoniacal lixiviant and air are used under ambient conditions to leach less than one-half of the contained copper values. After solid-liquid separation, the solution is subjected to solvent extraction regenerating the ammoniacal lixiviant and the copper loaded organic phase is stripped in spent electrolyte returned from the electrowinning plant where ultra-high quality SX-EW copper is produced. The solid leach residue can, if required, be upgraded by flotation to produce a high-grade copper concentrate with improved fuel values and a pyrite tail for disposal. After an 18-month bench and pilot plant scale program and an engineering feasibility study, Minera Escondida Limitada decided to build an 80 000 tonnes of copper per year facility near Antofagasta, Chile. The installed investment cost amounted to around $160 million. The plant went into commercial production in November 1994 and better than 99.9995 per cent Cu cathodes were produced right from the start. BHP believes that the process and the commercial plant are an excellent example of a novel approach advancing the science of copper metallurgy in harmony with present demands for environmentally sound processes and high quality products.

Jan 1, 1995

By M Miller

Operators of nickel laterite pressure acid leach and gold pressure oxidation technology frequently employ a series of steam condensing heaters to preheat the leach feed slurry. The heaters are an economic pinch point û although the thermal performance of the heaters is critical to overall process viability and operating cost minimisation, they are also a significant capital item and must be sized accordingly. Despite this, discussions of the factors underlying heater design are conspicuously absent from technical literature, and existing operations feature a conflicting range of heater sizes and configurations. This variety would suggest that at least some of the chosen heater designs are oversized. As part of its detailed design stage, the Ravensthorpe Nickel Project (RNP) constructed and tested a pilot plant heater to develop an understanding of the heating process and to ensure that the RNP heaters were appropriately sized. This testwork used RNP slurry at design density and viscosity on a 450 mm diameter, 6500 mm high column. The pilot plant testwork demonstrated the intrinsic efficiency of the direct steam condensation heating process, which was essentially independent of slurry density and viscosity. Presence of non-condensable gases in the steam phase decreased the heat transferred in certain circumstances, but heater performance remained consistent with thermodynamic limitations. Stagewise heat transfer within the column was rapid, and suggested either a very high slurry surface area or excellent heat transfer within the slurry phase. While the testwork did not set out to distinguish between these effects, physical evidence pointed to droplet formation in the inter-tray shower zone, giving a high heat transfer area. For scale-up purposes, the key facts were that the heat transfer rate was not limited by using high viscosity slurries and heaters could be designed using the principles applied to the smaller of those in existing operations. This paper discusses existing slurry heater designs, the current understanding from open literature, the pilot plant testwork, results and analysis, and scale-up to commercial sized equipment.

Jan 1, 2005

The discovery of gold mineralization at the Manhattan mercury mine, Napa and Yolo counties, California in 1978 was the result of applying a new exploration ore deposit model in a region previously unprospected for gold. This discovery, the McLaughlin gold mine, owned and operated by Home-stake Mining Company, is a classic epithermal mercury-hot springs-gold deposit currently producing approximately 7,776,000 grams of gold annually.The exploration program that led to this discovery was based on a mercury-hot springs-gold genetic model. The model was developed using basic knowledge of ore-forming processes plus careful field observations made during examination of many known precious metal districts in. the Western U.S.A. Theoretically, hot spring systems could host gold deposits and, indeed, gold in these environments had been recognized for years. However, at the time of the McLaughlin discovery, it was not known to occur in sufficient quantities to inspire geologists to explore hot spring systems specifically for gold. Field observations recognized the presence of hot spring deposits and mercury mineralization asso-ciated with precious metal districts, (Bodie, California being a type example), and this associ-ation prompted the development of a hypothetical model. Subsequent exploration activities were directed towards the examination of mercury mines and prospects as potential targets for gold deposits. The model envisioned hot spring deposits (sinter) containing mercury mineralization at the surface with anomalous gold values grading downward into significant ore grade gold values.

Jan 1, 1990

This paper will examine the prospects for Queensland's non-fuel mineral industries as we approach the 21st century. The opportunity for growth is unprecedented. Exploitation of recent discoveries, proposals and developments in downstream processing are predicted to contribute to a doubling of the State's mineral exports to around $10 billion by the year 2000. In 1995 - 96 the value of Queensland's mineral production was $6 billion, comprising $1892 million metallic minerals, $127 million non-metallic minerals and $4 025 million total fuel minerals. For many years Queensland has been among the world's major producers of copper, silver, lead, zinc, bauxite and mineral sands. Recently Queensland has become an important producer of magnesia. Queensland's ability to compete results from its location close to rapidly developing Asian markets, the diversity of its major minerals and an increasing ability to add value to the resources base using competitively priced energy. Northwest Queensland is one of the richest base metal provinces on earth following the recent discovery of five world-class orebodies. Of these deposits, Osborne (copper-gold) has commenced production and Cannington (silver-lead-zinc) and Ernest Henry (copper-gold) are scheduled to be developed by 1997. Century Zinc Limited and the Queensland Government are negotiating with native title claimants on the development of Century (zinc-lead-silver). Expansion is in progress at the Mount Isa copper mine (renamed the Enterprise) and copper smelter and a high analysis fertiliser project may be developed based on Phosphate Hill. Korea Zinc Company Limited has reached agreement to construct and operate a 350 000 Mtpa zinc smelter/refinery near Townsville. There are future expansion prospects for the vertically integrated major industrial mineral operations based on Weipa bauxite and Kunwarara magnesite. Upgrading of the Boyne Island aluminium smelter will require a doubling of alumina consumption. Downstream processing options for Kunwarara magnesite are being investigated and are expected to lead to increases in production and the manufacture of a range of value-added products. At the Yabulu refinery near Townsville, nickel and cobalt production using imported ore is to be increased and a commercial cobalt plant is to be built. Additional opportunities for further processing and manufacturing are associated with proposed new mines at Ely (bauxite), Skardon River (kaolin) and Goondicum (ilmenite). Recently discovered resources of zeolite and perlite also offer exciting development possibilities. Other manufacturing opportunities such as glass and ceramics based on local and plentiful clay and silica sand could replace imports. Silica sand at Cape Flattery is currently exported and production is expected to double.

Jan 1, 1997

By Alesse V, Belardi G

A new class of collectors, Mercapto-Benzo-Oxazoles (MBO), exerting selective action on copper sulphides in the presence of Pb, Zn and Fe sulphides (galena, sphalerite and pyrite), has been synthesised in co-operation with Enichem's Donegani Insitute. The collectors have a mixed aliphatic-aromatic structure and contain functional groups which form chelates with copper. Some reagents of this class having hydrocarbon chains of various lengths have been laboratory tested on a complex sulphide ore containing chalcopyrite, galena and sphalerite in pyritic gangue. Comparative flotation tests have permitted selection of the best collector for chalcopyrite, namely Methyl-Mercapto- Benzoxazole (MMBO). Systematic flotation tests have been performed with this reagent, varying collector concentration, grain size of the feed, pH and flotation time. The results obtained show that the synthesised collector is much better than potassium-amylxanthate (KAX) as regards selectivity towards Pb and Zn. Moreover, it is possible to work at natural pH (6-7) and the flotation rate is higher. In fact in the rougher stage with 80 g/t of collector at natural pH, a copper grade of 7.14 per cent was obtained with a recovery of 73.87 per cent, while the grade with KAX did not exceed 2.11 per cent for a recovery of 73.54 per cent. The amount of Pb and Zn reporting in the copper concentrate was eight per cent and ten per cent respectively, while with KAX it was no lower than 24.34 per cent and 22.71 per cent in that order. After two minutes flotation a copper grade of 5.2 per cent with 52 per cent recovery could be attained, against a grade of 2.5 per cent and a recovery of 44 per cent in the case of KAX. The efficiency of this new collector has been ascertained on two samples of complex sulphide ores of diverse mineralogical composition.

Jan 1, 1993