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By C Fischer

The introduction of digital communications technologies into the underground mining industry, in both coal and hard rock mining, has enabled high bandwidth applications to be applied in the mining industry. Digital networks based on 802.11 b/g/n open Wi-Fi standards have allowed numerous applications to be run over a single communication backbone. One of the many important applications is the tracking of personnel and equipment via RFID Tags. This tracking application has formed the basis of a Proximity Detection System or Collision Avoidance System (Schiffbauer and Mowrey, 2001; Kent, Fischer and Schiffbauer, 2011) thereby improving safety and increasing control in the mining environment. This paper discusses the growth of digital technology as the backbone for communications in underground mining applications. This growth has allowed the ‘convergence of technologies’ (occurring in the general business world) to be available to mine operators in general and underground mine operators in particular. Mine Site Technologies’ involvement with major mining companies and mining equipment manufacturers (OEMs) in developing and supplying their communication systems is also discussed.The latest technical requirements and specifications for communication systems for underground and open cut mines will be reviewed.

Nov 22, 2011

By A Roshal

It is anticipated that many future uranium mines in Australia will be using the in situ leaching mining process. It is fair to say that close to one third of uranium production will be generated by this method, whilst the other two thirds will fall on the uranium generated from hard rock mining and other mining methods, such as traditional open cut mining. For other types of deposits the in situ leaching mining method will remain the best technological, commercial and environmental alternative. It is important to identify and prevent all risks involved in uranium mining. The expertise in this subject is limited. Over the years there was only one mine using the in situ leaching process for uranium extraction in Australia. Computer simulation of propagation of leachate during and after the uranium in situ leaching is a crucial factor, not only for addressing the environmental concerns, but also for the most efficient recovery of the deposit. The decontamination can be modelled for a period of up to 100 years, with the acid neutralisation forecast for a period of up to 400 years. The results of the modelling are paramount for definition of the reserves, efficiency of the mining method and the environmental impact statement. The accuracy of the hydrogeological modelling and carefully selected environmental management program enables a mining company to quantify and minimise the impact of the mining activities on the regional aquifer and to prevent environmental disasters. In the study, the completed hydrogeological model allowed the client, the authorities and the community to make an informed decision about the environmental impact of the in situ leaching of uranium. In particular, the model proved that neither during the mining, nor during the neutralisation the toxic elements would interact with the local catchment area.

Jan 1, 2008

By S Grimsey, E Janetzki, J Emery

Floor failure on the longwall face is a complex problem due to the dynamic interaction between the surrounding strata and powered roof supports involving multiple variables. It can also be highly problematic and costly when not well understood as there are significantly less remedies available post event. This was the early experience at the case study mine where significant lost time was incurred due to unplanned delays in the first two panels. To detect and prevent such occurrences is clearly the best approach, hence a tool to predict both floor failure occurrence and magnitude prior to mining was developed. Several parameters were determined as the key drivers for the failure events that had been experienced at this site. These parameters were, in list of influence from highest to lowest, material strength, retreat rate and the presence of water. The parameters were evaluated using a semi quantitative risk rating system ‘Heave Risk’ and given a weighting per their apparent influence. This ‘expert system’ methodology was selected as the use of risk rating systems in underground coal mining is well established. The heave risk model was first applied to previously mined panels. It accurately identified all areas of known major floor heave, with clearly defined areas of low and high risk apparent. The heave risk model was then used prior to mining and evaluated post mining based on observed conditions. It was found to also be highly accurate for prediction. The variability of each parameter and its influence on the overall risk rating is illustrated and discussed.

Nov 29, 2022

By W Zhu, J H. Zhao, H Ma

The permeability coefficient is an essential parameter for the study of seepage flow in fractured rock mass. This paper discusses the feasibility and application value of using readily available RQD (rock quality index) data to estimate mine water inflow and grouting quantity. Firstly, the influence of different fracture frequencies on permeability in a unit area was explored by combining numerical simulation and experiment, and the relationship between fracture frequencies and pressure and flow velocity at the monitoring point in fractured rock mass was obtained. Then, the stochastic function generation program was used to establish the flow analysis model in fractured rock mass to explore the relationship between flow velocity, pressure and analyse the universal law between fracture frequency and permeability. The concepts of fracture width and connectivity are introduced to modify the permeability calculation formula and grouting formula. Finally, based on the on-site grouting water control case study, the rock mass quality index is used to estimate the mine water inflow and the grouting quantity. The results show that it is feasible to estimate the fracture frequency and then calculate the permeability coefficient by RQD. The relationship between fracture frequency and RQD and the relationship between structure surface frequency and permeability follow an exponential function. The calculation results are in good agreement with the field monitoring results, which verifies the rationality of the calculation method. The relationship between the rock mass RQD index and the rock mass permeability established in this paper can be used to invert the mechanical parameters of the rock mass or to evaluate the permeability and safety of the rock mass, which is of great significance to the prediction of mine water inflow and the safety evaluation of water inrush disaster management.

Nov 29, 2022

By B Jones, M Chappell

Permanent rock bolts used to support rock tunnels are required to perform for the design life of the structure as a minimum. Quality of installation is critical to the performance over the life of the rock bolt.This paper will present the findings from an in investigation into the integrity of rock bolts installed in an underground hydroelectric power station cavern and access tunnel. The 25?mm diameter rock bolts were installed 50 years ago, tensioned and post cement grouted. Due to a major machine upgrade the whole facility was subject to an asset survey. The owners are responsible for managing the risks associated with the failure of these rock bolts and ensuring the structural integrity of the tunnels and caverns is maintained to continue operations, protect machinery, assure production and more importantly maintain a safe working environment for all employees and visitors.To help manage risk a proactive approach is desired. To this end a test schedule using a non-destructive testing (NDT) system was carried out by Independent Integrity Testing Pty Ltd (i2t). The system used in this application was RokTel™. The system operates by applying a small axial impact to the rock bolt end and measuring the resultant acceleration response. The rock bolt characteristics affect the acceleration response.The data output from the system is analysed principally using Fourier Analysis (FFT) and sinusoidal waves. The energy generated in the bar, the rate of damping and changes in frequency are all assessed. Testing was carried out on 70 rock bolts within the tunnel and cavern. A selection were then over cored, photographed and documented. The data gathered from the testing is then correlated with physical evidence to establish a calibration for the remainder of the rock bolts and assess if this is a viable method for identifying defective elements, and what degree of accuracy can be achieved. The findings will assist with the future assessment of similar hard rock underground?facilities.CITATION:Jones, B and Chappell, M, 2014. The use of non-destructive testing to identify defective rock bolts – a case study, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 275–280 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By R Durchholz, A-J Heiertz, R Schmitz

Mining of lignite is the largest bulk materials handling activity in Europe. In order to mine this lignite, with an average calorific value of only a third of bituminous coal in an economical way, highly efficient opencast mining technology is mandatory. The total continuous mining of overburden and lignite was introduced more than 60 years ago and was subsequently developed stepwise into the largest mass transport system of the world. In 2011, the Inden Mine, one of three RWE Power mines, stripped 90 Mbcm of overburden to produce 22 Mt of lignite. In total, nearly 100 Mt of Lignite was produced from the three mines of RWE Power in Germany. Beside bucket wheel excavators (BWE), several high-performance in-pit crushing and conveying (IPCC) systems, which allow the adoption of continuous mining systems, even for typical shovel and truck (S&T) operations, are available today. RWE Power assists operators considering a change from the S&T to IPCC technology, both in the planning process involving large-scale belt conveyor systems and later with operational know how transfer. In a number of cases, the challenges associated with this system change have been addressed and solved successfully. One key challenge is managing the development of skills for operating the belt conveyor systems efficiently. This paper compares the effectiveness of S&T to different configurations of continuous mining operation for an up to 170 m deep mine with a total annual output of 117 Mbcm. From the mine operatorÆs point-of-view, the quantity and skill level of staffing required for operation and maintenance are discussed in detail. The main conclusion of this paper is the larger the operation becomes and the longer the mine life is, the earlier fully continuous mining systems should be planned and implemented.CITATION:Schmitz, R, Durchholz, R and Heiertz, A-J, 2012. Change challenges for large open pit mines, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 103-110 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By M Edhammer

In 2007, Atlas Copco introduced an integrated tunnel scanner/profiler. The tunnel scanner, which is integrated into the control system, is mounted on the drill rigs, and replaces the previous variants of non-integrated scanner equipment. The Atlas Copco Tunnel Profiler, which is the name of this system, is currently being used by several contractors and mines on various projects in Scandinavia, Finland and Australia. Atlas Copco Tunnel Profiler can scan a tunnel of 65 m2 in just five minutes and is integrated with the computerised control system for the drill rig. This integration means that the results of scanning are immediately available for analysis on the computer screen both in the drill rig and in Tunnel Manager; a software for tunnel and drift planning.In 2008, a method was introduced for locating the drill rig with a total station navigation (TSN) system, integrated into the control system. TSN systems are used by a number of contractors in Scandinavia and Finland, as well as elsewhere in the world. Using a TSN for navigation is in itself not new, but when this is integrated with the control system it provides the opportunity for individual drill rig operators to use this method, without the direct assistance of a surveyor. TSN gives a very precise indication of the drill rig’s position in relation to the tunnel design. An accuracy of ±1 cm compared with the ±10 cm which is normally obtained with the traditional method using tunnel laser and sight plates on the drill rig’s feeder. The closer a tunnel is blasted to its planned profile, potentially the more is saved in terms of less shotcreting, extra rock bolting and other corrective work. A better quality tunnel is the key to better overall economy and today’s technology makes it possible to achieve that goal in every type of tunnelling and mining project.In addition to total station’s ­navigation and Tunnel Profiler, the concept of ‘high precision tunnelling’ also includes:•Software tunnel planning: Tunnel Manager, Tunnel Manager Pro and Tunnel Manager Measure while drilling.•Measurement While Drilling (MWD)collects the various drilling data and the interpretation of these for the early identification of variations in the rock.•Rig Remote Access (RRA) is a support for wireless or wired communication between drill rig and planning office. The result is being able to send planning data to the drill rig and to simultaneously have the facility for logged files to be sent from the rig to the office. There is an option of an external computer logging in to the drill rig’s control system to view menu screens and settings, and remotely troubleshoot and plan appropriate action.

Mar 21, 2011

By L Chaffey, M Buckland

The minerals industry has enormous potential to positively contribute to sustainable development and many leading companies have concluded that their long-term success is directly linked to their ability to leave a lasting positive legacy. While there are many examples of success, there have been failures as well and much work has been done in recent years to define the role of the minerals industry in sustainable development and identify the key elements for success. In the past, our sector could point to the taxes and royalties it paid, the exports it generated and employment it created and felt confident that its contribution would be recognised and duly acknowledged. This is no longer the case. Critics of the industry have highlighted resource-rich countries that have failed to capitalise on their resource wealth and have arguably lower standards of living than their resource-poor peers û the æresource curseÆ hypothesis. Recent research has done much to clarify the factors that contribute to a countryÆs success or failure and all stakeholders in the industry now need to include these learnings in their approaches going forward. We know that our long-term success relies on embedding a company- wide approach to sustainable development into all aspects of our business operations. In this paper we highlight BHP BillitonÆs experience in the development and implementation of policies and systems designed to enhance our contribution to sustainable development. We detail the business drivers for excellence in this area and the key external codes and initiatives that have shaped our approach. The values-based BHP Billiton Charter, Sustainable Development Policy and associated Health, Safety, Environment and Community (HSEC) Management Standards are central to our approach. Implementation is reviewed through our HSEC audit program. One area in which we have placed particular emphasis is our approach to community development. BHP Billiton has a corporate target to contribute one per cent of its pre-tax profit on a three year rolling average to voluntary community programs. As our profit stream has increased with the minerals boom this is approaching an A$100 million commitment. In our paper we detail how we are working to ensure we maximise the value of this contribution for our communities and our shareholders.

Jan 1, 2006

By G Guy, J Summerville

Over the past five years in coalmine slope evaluation the application of 3D modelling has increased significantly as software has become more user friendly but also areas requiring evaluation have become increasingly complex. Often simplistic 2D Limit Equilibrium modelling and analysis has been poorly used to solve slope stability issues by back analysis and subsequent forward predictive analysis. A plane strain condition with slope movement perpendicular to the slope strike is assumed where in reality the problem is more complex. This often leads to a misinterpretation of the failure mechanism because the failure mechanism being modelled in 2D does not generally represent the actual failure mechanism observed in the pit, with 2D modelling often oversimplifying a slope. This paper presents a case study where the initial slope assessment and remedial design evaluation was undertaken as a 2D Limit Equilibrium model which led to an overly conservative and costly remedial solution being implemented. Subsequent modelling of the slope using both 3D Limit Equilibrium and Finite Element methods were able to provide a better understanding of the structural complexities associated and correlate well with slope monitoring data to create a more realistic outcome.

Nov 29, 2022

By O van Baalen

The Ernest Henry Mine is a copper-gold open pit operation situated in northwest Queensland, Australia. It is owned and operated by Xstrata Copper, with a current throughput of 11 Mtpa, however, open pit operations are scheduled to cease in mid 2011. The deposit dips approximately 45º and extends for at least another 400 m vertically below the final 530 m deep pit design.Construction and development of a sublevel caving (SLC) operation beneath the open pit was approved in December 2009. The feasibility design requires 39 km of development to be completed prior to production, which will commence in the fourth quarter of 2011. Initial ore production will be trucked and will increase to 3 Mtpa by the end of 2012, after which a hoisting shaft will be used. Ore production will then increase to 5 Mtpa in 2013 and ultimately to 6 Mtpa in 2016.Two 3000 kilo watt of refrigeration (kW(R)) modular refrigeration plants will be installed, as well as two 1600 kW mixed-flow fans capable of a combined flow rate of 780 m3/s at a total pressure loss across the mine of 2000 Pa. The main fans will be installed underground and will exhaust into the base of the pit.The following challenges were faced in the development of the ventilation and refrigeration network:•a relatively steep geothermal gradient,•tropical ambient conditions,•working under a wide pit shell, and•a large underground trucking fleet prior to shaft commissioning.A considerable number of ventilation studies were conducted with later studies extensively using Ventsim Visual™ mine ventilation software to complete the design process of the ventilation and refrigeration networks, including the comparison of several alternative designs. The paper focuses on design challenges prior to the commissioning of the hoisting shaft, and discusses resistance optimisation and occupational hygiene-related design parameters, such as heat and diesel emissions, production level ventilation, main fan selection and location, and refrigeration requirements.

Mar 21, 2011

By J Kwak

Driving sustainability concepts and practices into the heart of the design process is the key to achieving a successful, sustainable plant design. Engineering design practices, tools, systems and methodologies should be prepared around true eco-efficiency parameters, adopt wholesystems-thinking and consider life-cycle impacts for the design task. Experience dictates that the application of sustainable plant design practices is most likely to succeed if: The principles are well documented and explained. All stakeholders agree on what sustainability means. Sustainable plant design is treated as a core process. The principals of sustainable plant design are equally applicable in brownfield and Greenfield environments. Although brownfield situations provide the designer with less latitude for change, these types of projects do allow easier measurement and demonstration of relative impacts. This paper further develops the above points by drawing on case studies from HatchÆs repertoire.

Jan 1, 2004

By J Moffatt, T Payten, N Spooner, L Teixeira, L A. Balzan, G Wilkie, G Tsiminis

Fluorine is a penalty element due to its reactive nature. In acidic environments many fluorine minerals dissolve to form hydrofluoric acid (HF), changing processing conditions. When smelted HF can be released, causing negative effects to nearby people and the environment, as well as potentially damaging the smelter. Sale of ore with high fluorine levels elicit a financial penalty or are banned outright. Real-time sensors create the opportunity for instantaneous decisions on ore processing due to changing conditions. A fluorine sensor would allow rises in fluorine concentration in a processing stream to be flagged, and decisions on processing conditions or diversion to stockpile before processing could be undertaken. As fluorine is a light element, it is difficult to detect with in-field XRF devices and does not work well with PGNAA. There are currently no existing sensors to quantify the presence of fluorine in real-time, and thus decisions based on fluorine grade cannot be made at minute- or even hour-scales. Sensors designed to measure the presence of minerals that contain fluorine are a possible avenue to enable the real-time detection of this element. Mineral-based sensing may also give an added advantage of additional information about how the fluorine will react under different processing steps. The authors were given a grant under CRC ORE II (project number P1–005) to search for mineralspecific signatures suitable for real-time analysis. The work focused on novel regimes and applications of fluorescence as a means to detect specific minerals. The aim was to exploit fluorescence responses unique to minerals of interest in mining systems in order to produce sensors that address gaps in existing capability. After the successful discovery of signatures specific to two major fluorine minerals an additional grant (P1–014) was funded to develop the research into a prototype on-belt sensor, in partnership with Scantech International Pty Ltd. This paper details the development of a sensor package through multiple Technology Readiness Levels (TRLs) through collaboration with government/industry grant schemes, academics from university, and a sensor-focused Mining Equipment and Technology Services (METS) company. We give a brief description of the new sensor technique and provide a case study of multi-disciplinary collaboration.

Aug 24, 2022

By M J. Noy

The automated measurement of rock fragmentation particle size distribution in the muck during muck excavation has been developing over the last 16 years. The introduction of stereo camera imaging of the muck has provided improved automated particle segmentation for image-based measurement algorithms. Recently, a new vision system processing algorithm has been developed. The inclusion of 2D texture in the analysis has provided a significant improvement in the definition of the finer size fractions, which has resulted in the automated analysis no longer requiring calibration.The previous stereo vision system algorithm required analysis calibration to account for poor ‘small particle’ definition in the 3D surface profile. This was because of the depth perception limitations of the stereo camera system at greater than 8 m. The new algorithm has been implemented on a number of shovel-installed vision systems, and the algorithm’s performance in automated analysis has been assessed against a diligent manual analysis of the same fragmentation images. The new algorithm provides improved distribution resolution and accuracy.CITATION:Noy, M J, 2015. Evaluation of a new vision system algorithm for automated fragmentation measurement from a shovel, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 721–726 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

There is no doubt that the mining sector is considered to be the backbone of many countries. Furthermore, it has played an important role in the prosperity of nations, whether developed or developing. Saudi Arabia is one of these countries that has a large variety of metallic and non-metallic mineral resources that range in size and value occurrences of limited potential to deposits large enough to sustain profitable exploitation. Therefore, the Saudi government needs to reinforce the capacity of the sectoral institutions to better regulate and promote the sustainable development of the sector. The ability to overcome the administrative and legal complications that constrain private sector participation in the minerals sector, through new mining code which will streamline the procedures for obtaining licenses and will add more predictability and transparency to the application process, are proposed for increasing the sustainable development. This paper will outline how the Saudi government is tackling the major challenges that face the minerals industry. This paper provides the background to the Saudi Arabian mineral sector and its industrial base. Finally, the paper identifies the problems and constraints that face the minerals sector in Saudi Arabia and provides an assessment of the effects of government policies and planning efforts in the minerals sector, particularly during the period of the development plans which started in 1970.

Jan 1, 2009

By W Y. Guo, L X. Chen, D X. Zhang

To obtain the rock type-I crack propagation process accurately, a novel fixture is used to make the prefabricated crack of rock propagation along the predetermined direction. In this study, the crack propagation process of rock is monitored with the digital image correlation method (DICM), and a mechanical model of crack directional propagation was established. The results show that the simple crack directional propagation device can effectively realise the stable propagation of type-I crack along the predetermined direction, the crack initiation angle is less than 10°, and the deviation between the peak strength of crack propagation calculated by a simplified mechanical model and the tensile strength of Brazilian splitting is 22.76 per cent and 7.53 per cent, respectively. According to the deformation field evolution law, crack propagation can be divided into three stages: microcrack development, main crack propagation, and main crack propagation. As for the rock type-I crack initiation and propagation mechanism, before reaching the peak strength, the prefabricated crack tip is subjected to maximum tensile stress; the elastic energy increases rapidly, and the dissipation energy increases slowly; after the peak strength, elastic energy exceeds its energy storage limit and released rapidly, and most of the input energy is converted into dissipation energy, which makes the crack propagation rapidly. The crack directional propagation device will be further optimised and improved, and it is expected to provide a new method for the study of crack propagation mechanism, rock failure precursor information and crack arrest principle, etc. It will also provide theoretical references for the optimisation of coal strata directional blasting, fracturing, fracture arrest, and other related technologies in geotechnical engineering.

Nov 29, 2022

By S Sullivan

A recent review of resource reports lodged to statutory bodies found geological models with oversmoothed or unrealistic lithological boundaries, many of which do not represent geological appearance in the field, pit or underground drive. The underlying data is often too complex or messy to be incorporated into the resource model and is thus a simplification of reality, to the detriment of the mining operation and its shareholders. Volumes can be over- or underestimated and subsequent grade predictions can be misplaced, combining to cause over- or understatement in resource reporting to stakeholders and statutory authorities. Domain models can be improved with new modelling techniques such as machine learning. However, with poor data or improper use of machine learning techniques, the conclusions can be just as misleading as with current techniques. Machine learning rarely offers a single ‘right’ outcome, rather a range of possible outcomes from the data provided. But importantly it can take advantage of the full richness of data for more informed models. Machine learning also provides confidence in its predictions so that uncertainty in the resultant models can be quantified and passed through for risk assessment during mine planning and operation. This paper will discuss the factors accentuating complexity in deposit modelling: data diversity, structural controls, chemistry, data volumes, process workflows and external non-geological constraints. A case study illustrates the risk of reducing or ignoring complexity, which can result in an overly simplified geological model.

Mar 22, 2022

By D Bush, F Goddard

The electrification of Australian mine sites will see a boom in the use of batteries of all chemistries. Lead acid batteries, a traditional mainstay of the mining industry, are expected to nearly double by 2030, however their use will be eclipsed by the explosive growth in lithium batteries. By 2030 the lithium battery market is forecast to be nearly four times the size of the lead acid battery market. Unfortunately, this will result in a corresponding avalanche of waste batteries to be disposed of. Barely a day goes by without battery generated fires being reported in the media and they have become an increasing nightmare for waste management companies and waste facilities. The safe recycling of batteries will also become increasingly important for mine sites to achieve their sustainability goals and reduce their environmental footprint. What are the risks posed by waste batteries, what are the regulatory requirements and how can you manage or eliminate these risks? What current practises does your mine site currently have for the safe management and disposal of batteries from your site? How prepared are you for the coming avalanche of waste batteries?

Apr 16, 2024

By J Heyes

Historically mining engineers haven't spent enough time planning waste dumps, but waste movement costs often outweigh ore haulage costs. There is a real incentive to plan waste dumps right the first time to minimise rehandle and final closure costs. At BHP Billiton Iron Ore there has been an increasing sophistication in waste dump design and they are becoming as important as the pit design. Closure landforms are now included in mining studies. Closure is embedded in the business planning cycle. The results from the recent life of mine study at Whaleback is a case in point where a base case of the shortest hauls with no closure constraints was compared against a closure case. A properly planned and executed waste plan revealed that no rehandle was required and haulage costs were eight per cent less if closure design implementation was carried out concurrent with mining. At cessation of mining the landforms were such that decommissioning of critical acid rock drainage dams and coverage of exposed pyrite areas could occur straight away, without the need for additional rehandle.  The paper also covers design and scheduling elements of waste design both in-pit and ex-pit, management of potentially acid forming material (PAF) and trends in PAF management and designing for final landform closure. This paper illustrates that there is value in terms of costs savings, sustainable outcomes and reputation if the mine planners are involved in the closure planning process.

Jan 1, 2009

By R J. Hardy

The aim of this study is to examine the volumetric and mass movement characteristics of load and haul operations using statistical modelling of relatively large samples of bucket loads that are transported as small samples in the form of truck payloads. Generally, the factors influencing bucket load variability are random, difficult to predict and to control. In the process of loading trucks the underlying variability of individual bucket loads will determine the variability of truck payloads. Bucket loads of material prepared by drilling and blasting for loading into trucks are fundamental quantities in open pit mine production. A study of payload data from a large surface mining operation indicates that bucket loads and truck payloads that are a small sample of bucket loads are normally distributed. Truck payloads have a reduced dispersion compared with bucket loads that is an inverse 0.5 power function of the number of passes per truck payload. Comparison of statistical modelling results with the æ10/10/20Æ policy promoted by Caterpillar Global Mining Inc, indicate that compliance with the æ10/10Æ part of the policy, applying to truck overloading is facilitated, as the coefficient of variation of truck payloads decreases, as a result of the increasing number of loading passes. Compliance with the more stringent æ20Æ part of the policy, relating to safe steering and braking is also facilitated, albeit at lower coefficient of variation for similar reasons.

Sep 26, 2011

By Lawson F

Chrome chemicals are commercially produced by the alkali roasting of chromite ores with sodium carbonate. Results of tests conducted in a laboratory furnace indicated that the sodium carbonate reacted rapidly with part of the gangue material to form a metastable intermediate that later reacted further with the chromite. For the conditions used, the recovery of water-soluble sodium chromate was able to be described empirically as yield % = a tn with a = 0.24 T - 241.3; n = 3.90 - 3.12 × 10-3 T and t is the reaction time in hours.The major rate limiting step in the overall reaction sequence appears to be the rate at which oxygen can get to the reaction sites across the liquid film coating the solid reactants.Sodium sulfate alone was found to be an unsatisfactory source of alkali for reaction with chromite. However when limestone also was added in quantities sufficient to allow the reaction CaCO3 + Na2SO4 + H20 ? Ca SO4 + 2NaOH + CO2 to take place, the results obtained were comparable to those found when sodium car-bonate was used.For chromite particles in the size range -124 + 105 µm, the use of stoichiometric excess of sodium carbonate did not appear to increase the yield or the reaction rate significantly. However, with smaller sized particles, - 53 µm, increased yields of water-soluble chromate were obtained when roasted with more than the theoretical quantity of sodium carbonate.

Jan 1, 1984