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By L. M. Nolan

Chemical Mechanical polishing, or CMP, has four components in the polishing interface; namely the polishing pad, the polishing fluid, the abrasives in the fluid, and the surface being polished. Understanding the way that load is transferred between these components is key to understanding and predicting wafer polishing. Numerous models of CMP and the different load sharing arrangements which occur between these four components have been proposed. These include models by Luo and Dornfield (1) and Fu, Chandra and colleagues (2). Other models focus on just one or two loading arrangements, such as `hydroplaning' when all load is transmitted by the liquid in the case of Runnels and Eyman (3). In this work, we consider four possible combinations of load transfer from pad to wafer in CMP. These combinations are listed below in Table 1 and are illustrated schematically in Figure 1. It is important to note the role of scale in this process; the illustrations in Figure 1 are drawn to scale from actual profilometer scans obtained over a length of 5 with particles of 150 nm in diameter. Table 1 - Load Transfer Combinations Load Regime Illustration Wafer - Fluid - Pad Figure la Wafer - Particles/Fluid - Pad Figure lb Wafer - Particles - Pad Figure lc Wafer-Pad Figure ld The interest in load-sharing between the system components is because some configurations are anticipated to achieve higher polishing rates than others. For instance, in hydroplaning, or hydrodynamic lubrication, the lateral force exerted on the polished surface by the particles can be no higher than the fluid shear force developed in the gap between the pad and wafer. This is not expected to generate high rates of material removal from the surface (4). For contact that is largely between the pad and the wafer, such as the regime depicted in Figure ld, the lateral load is transmitted to the wafer by the pad and is hence limited by the pad's low rigidity. This regime is not expected to generate high material removal rates either. The highest levels of material removal are expected from regimes where the mechanical load exerted on the system is transmitted by the particles, in combination with either the fluid or the pad. Under what circumstances does the polishing regime change from one to another? What must occur in order to initiate or terminate contact between the system components? This is an ongoing question in the field of tribology, and has traditionally been viewed in terms of the pressure and velocity applied to the system, the thickness of the fluid film between the two surfaces, and the roughness of those surfaces (4). In this paper, we propose a new mechanism ? that the load on the particles may be sufficient to totally embed them in the polishing pad, at which point they are no longer able to transmit load and polish the wafer surface. This is illustrated schematically in Figure 1(d).

Jan 1, 2010

By Uwe Wyink, Guenther Thiele, Isabel Gollnick, Klaus Thyrock

"The application of a thin spray on liner was implemented in longwall T-junction sections in 2009 for the first time. The development of the material and the application is based on a technical cooperation between RAG Deutsche Steinkohle AG and BASF Corporation. The report gives an overview of the first trials. The underground test occurred in a seam with a height of 1.5 m (5 ft) in a depth of 1,100 m (3,609 ft). The roadway is dual-use entry and the roof strata is composed of shale and sandy clay. In some sections geological faults impact the surrounding strata. The poor conditions induce separating and loosening of roof rock. Several remedial actions have to be implemented for decreasing deformations at the face entrance.The application of thin spray on liner (TSL) provides simplification and cost reduction of supporting work at longwall T-junction. The installation of TSL to avoid roof and coal fall operations for lagging are omitted.INTRODUCTIONFor safe operation of face retreat in dual-use roadways, the processes of securing and stabilizing the face end area are very important in order to minimize deformation and stress. Avoiding roof and coal fall are the main concerns for safe operation. For that reason different methods of reinforcement are tested in underground operation. In this paper the application of TSL is presented.The specifications of TSL are described, followed by the case study results. The underground study is located in one mine of RAG Deutsche Steinkohle. The extraction of the hard coal in this mine is characterized by great depth and high stress. There are poor geological and geotechnical conditions. The roadway used for the underground application was headed with the support system combination type A, which will be described later in the paper. After the first face retreat, deformation of steel arch support and bagging destroyed the roadway, so for the second face retreat remedial actions had to be undertaken. For this a new system of reinforcement, simplifying the supporting work at the longwall T-junction was tested. The reinforcement consisted of different parts that are described in the following report. Furthermore two different versions were applied. One method is the operation with TSL and the other one is the use of concrete for sealing. Both methods are compared in the text."

Jan 1, 2010

By Joe Zhou

"Mineralogical characterization and metallurgical extraction of silver is challenging due to its complex mineralogy and chemistry. Over 200 Ag-bearing minerals have been identified and a silver-rich ore body would typically contain 5 to 10 different silver minerals. Silver can occur not only as discrete microscopic (visible) silver minerals but also as submicroscopic (invisible) silver in other minerals. During processing, silver may form passivation compounds such as silver hydroxide, silver sulphide, jarosite-like silver sulphate, silver halide or silver cyanide precipitate, all of which may negatively impact on silver extraction. Knowing the deportment of silver in the ore and its metallurgical products is important in flowsheet design and plant optimization. This paper begins with the classification of silver ores and minerals and a review of processing techniques, and focuses on the major mineralogical factors to explain why and how these factors affect silver extraction. Case studies are provided to demonstrate the application of silver process mineralogy in flowsheet design and plant optimization.INTRODUCTIONSilver was known to and utilized by mankind since ancient time. Actually, it was one of the earliest metals discovered and utilized by mankind after gold and copper.Silver is the whitest metallic element. It is rare, strong, corrosion resistant, and unaffected by moisture, vegetable acids, or alkalis. Silver is also resonant, moldable, malleable, and possesses the highest thermal and electric conductivity of any substance. The chemical symbol for silver is Ag, from the Latin argentum, which means white and shining. Although silver does not react with many chemicals, it does react with sulfur, which is always present in air at trace amounts. The reaction causes silver to tarnish, and consequently it must be polished periodically to retain its luster.Silver possesses many special physical characteristics and qualities that make it useful to a variety of industries. The photography industry is the biggest user of silver compounds. Silver forms the most light-sensitive halide salts, which are essential to developing highquality photographic prints. Silver also has the highest electrical conductivity per unit volume of any metal, including copper, so it is used extensively in electronics."

Jan 1, 2010

By J. K. Whyatt

U.S. Bureau of Mines researchers reviewed an in situ stress estimate developed from measurements of overcore strain taken at test sites on the 7300 and 7500 levels of the Star Mine near Mullan, ID. Although the field measurements of over coring strain were found to be useful, significant deficiencies were found in the stress estimation procedure. A new stress estimate was developed incorporating statistical methods and an improved understanding of stress concentration factors for interpreting overcore strains recorded by doorstopper' cells. Spatial variability of overcore strains and the implications for stress field variability were explored.

Jan 1, 2010

By Andrew Lewis, Amarit Nitaramorn, Alexander Garcia, Peter Altounyan

"Indonesia is a major coal producer, the vast majority being sourced from opencast operations. Underground production to date has been constrained by unfavorable ground conditions and limited local experience. However, an underground trial in East Kalimantan has now shown that it is possible to successfully extract coal and mine safely, despite the technical challenges.A trial drift mine has been worked to a current maximum depth of 160 m (525 ft) in a dipping coal seam. The 3 m (10 ft) thick coal seam is overlain by very weak mudstone and sandstones. The mudstone forming the immediate seam roof strata proved a particular challenge given its adverse reaction to water and overall friability.Rock bolts were used as roadway support, the system being carefully selected to optimize effectiveness. An innovative method of partial extraction was trialed, which demonstrated the potential for productive mining despite the ground conditions. Roof falls have occurred within the working area, and roadways demonstrate reasonable stability over time.Throughout the course of the trial, strata behavior monitoring has been an important aspect, and a comprehensive ground control monitoring system is in place. This has enhanced the ability to increase the level of support where required and to react to deteriorating conditions. In addition, monitoring information has allowed a quantitative assessment to be made of the technical feasibility of future full-scale mining.INTRODUCTIONWith current production at over 200 million tons, much of this destined for overseas markets, Indonesia is the second largest exporter of coal (Ritschel and Schiffer, 2007). The majority of the coal is sourced from the Kalimantan coalfields. Mining is predominately opencast, yet in recent years there have been attempts made to introduce underground operations. This move would permit continued access to good quality seams that are beyond the reach of viable opencast mining."

Jan 1, 2010

By U. Srivastava

In the processing of manganiferous ore, it is useful to control whether the manganese (Mn) goes to the iron product to produce ferromanganese, or to the slag for extraction as a high Mn product. This can be done by manipulating the thermodynamic conditions for manganese oxide(MnO) reduction to control whether it remains as MnO or converts to metallic Mn. Results are presented showing that during production of iron nuggets, reduction of manganese oxide (MnO) can be controlled by changing the furnace temperature and reductant composition appropriately.

Jan 1, 2010

By S. Paul Singh

"The long-term viability of seismically active and/or deep mining operations hinges upon the industry's ability to maintain profitability in a climate of increasingly difficult conditions, escalating operating costs and fluctuating metal prices. Within this context, it is prudent to explore mining techniques that could provide means for safer and more profitable extraction of seismically active and/or deep seated deposits that are vital to the long term survival of the industry.The first step was to examine Penetrating Cone Fracture (PCF) and other relevant concepts with the objective of semi-continuous mining in deep underground hard rock mines. This was followed by an assessment of the current conventional drilling and blasting practice. Thirteen blasts were monitored in five different seismically active workings of an operating deep mine. The main concerns during the current drill and blast practice were identified.On the basis of the literature review, three short round blasting techniques were short listed for further review. These techniques were evaluated based upon the available literature and discussions with the persons associated with their applications. Justification, requirements and major challenges for the application of short round blasting have been discussed in this paper. Suggestions for improving the current drilling and blasting practice have also been outlined.INTRODUCTIONRock fragmentation is the key to mineral excavation and production. Increasing working depths, environmental concerns and trends towards continuous mining necessitate the development of new and improved rock breakage methods.The excavation of hard rocks is still dominated by the sequential routine of face preparation, drilling, charging explosives, blasting, ventilating for fume and dust removal, mucking and roof support. Worse still, drilling and mucking require specialized equipment that fills the end of the heading so that no other operation can be performed and the equipment must be removed from the face to protect it from fly rock."

Jan 1, 2010

By Ian Holl, Adam Hempstock, Rickardo Welyhorsky, Niel Morrison

"The Victor Diamond Mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario and was completed approximately 9 months ahead of schedule.The Victor Mine process plant flowsheet was designed to produce a 95 - 98% by weight diamond concentrate. Main processing steps include 3 stages of comminution, dense medium separation and proprietary x-ray technology for final recovery. Reagent consumption for this process is limited to flocculant, for thickening of fine processed kimberlite, and FeSi for the dense medium separation.The commissioning phase of the Victor Project was executed over a period of 6 months and commenced prior to substantial completion of construction. The approach used was to focus on and complete commissioning of the higher risk dense medium separation and recovery systems prior to construction completion of up stream systems.INTRODUCTIONThe development of the Victor Diamond Mine took place over a period of approximately 5 years and had a capital cost of CAD997 million. It was a greenfields project in an undeveloped region of northern Ontario, only accessible by winter road. Figure 1, below, displays the location of the project within Ontario.The main stages of the project included feasibility, environmental permitting, engineering, construction, and commissioning. At the onset of the engineering phase, the mine was scheduled to enter production in October 2008. Through a team effort between AMEC and DeBeers Canada, the schedule was advanced by 6 months towards the goal of project completion in April 2008. Production status was attained in January 2008, approximately 9 months ahead of the original schedule. This paper focuses on the commissioning aspects of the project and includes a less detailed discussion of the engineering stage."

Jan 1, 2010

By A. C. Smith

The U.S. Bureau of Mines conducted a study to evaluate the effect of underground mining conditions on the activation of automatic sprinkler heads. Sprinklers were exposed to liquid fuel fires in a rectangular tunnel at airflows of 0, 45, 90, 150, and 250 m/min to determine the effect of ventilation and fire size on the time to activation. As the airflows were increased, the time to activate the sprinklers for a given fire size increased. Also, as the fire size increased, the activation time decreased. Temperature profiles of the tunnel showed that the maximum temperature near the roof was shifted downstream as the airflow increased. Experiments to determine the effect of rated activation temperature and response time index (RTI) value on activation time showed that the time to activate increased with increasing activation temperature, and decreased with decreasing RTI value. Exposure to the mine environment showed little effect on the activation times in large-scale experiments, and no significant effect in laboratory experiments. The results showed that airflow can have a significant effect on the activation times of automatic sprinklers. This needs to be considered in the design of effective sprinkler suppression systems for ventilated areas.

Jan 1, 2010

By Thomas M. Barczak

This U.S. Bureau of Mines report describes methods to enhance the capacity, stiffness, and timber utilization of wood crib supports. Since stiffer supports minimize strata deflections that contribute to roof instability, efforts to maximize crib stiffness while maintaining stability through a wide displacement range should be a design priority. The stiffness and capacity of conventional crib designs, employing alternating layers of wood timbers that are loaded perpendicular to the grain, can be increased by increasing the interlayer contact area or by using higher strength wood. Contact area can be increased by using wider timbers or employing more timbers per layer. Concepts that provide parallel-to-the-grain timber loading will provide substantial increases in crib stiffness and capacity. Two concepts that utilize this principle are examined: (1) an original South African design that constructs wood cribs from preformed layers (mats) of timber where short blocks are oriented vertically between horizontal slabs; and (2) a design that employs full lengths of timber placed vertically in the interior of a conventional crib structure. These designs also provide more efficient timber utilization by providing greater support capacity per volume of wood used in the crib construction.

Jan 1, 2010

By M. J. Beus

Researchers at the U.S. Bureau of Mines have developed personal-computer-based data acquisition, instrumentation, and mine visualization and modeling techniques to evaluate a mine accessway in a deep hard-rock mine in northern Idaho. These techniques were applied to a mine shaft in a large silver mine that has been in operation for many years. A very deep, rectangular, timber-supported shaft extending to depths exceeding 2.3 km (7,500 ft) had been deforming continuously as a result of nearby mining, resulting in operational problems. Preliminary visual observations and rock and support monitoring confirmed that severe diagonal distortion was occurring. Extensive field measurements and data analysis confirmed initial observations, provided insights into the cause of deformation, and defined a general approach to structural modeling. Computer analysis of the problem was initiated by developing a three-dimensional model of the terrain. This represented a volume of rock approximately 80 km3 (40 x 1010 ft3) and an area on the surface surrounding the mine 9 km2 (3 square miles). Based on this model, a three-dimensional, finite- element analysis was conducted to establish boundary conditions for sequentially more detailed two- and three-dimensional submodels of the shaft area. Results from the computer study are being used to develop new approaches to mine design and to provide design guidelines for deep mine accessways subject to severe rock-mass loading conditions.

Jan 1, 2010

By Denis Rickman, Jon Windham, Stephen Akers, Byron Armstrong

The soil crater formed by detonation of an explosive charge is of considerable military interest because of the common use of explosives to create soil obstacles. The soil crater is also an important piece of forensic evidence for the investigation of terrorist bombings. With recent advances in numerical codes, modeling and simulation of explosively-formed soil craters is becoming an attractive means of analyzing this phenomenon. Consequently, the need exists to better understand the relationship between soil properties and the resultant soil crater. An extensive database has been developed for the case of explosives detonated in or above in-situ soils of various types. However, in most cases, the soil properties were either not adequately quantified or the soil materials themselves varied such that the gross properties were poorly understood. A research program is underway to improve methods of relating soil crater dimensions to soil identification properties such as USCS classification, particle-size distributions, and Atterberg limits, as well as to soil composition properties such as density, moisture content, and volumes of solids, water, and air. As part of this effort, both explosive detonations conducted over well-controlled and well-documented soil backfills and companion numerical simulations were studied. This paper presents an overview of the effort.

Jan 1, 2010

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By L. Martins

To increase zinc recovery in the concentrate, this investigation performed mineralogical characterization, dispersion studies, bench and pilot-scale flotation experiments and an industrial flotation trial. The objective was to verify the flotation behavior of the silicate zinc ore (calamine type) in the presence of slimes, with the aid of dispersing agents. Characterization studies identified the major minerals in the flotation feed as hemimorphite (calamine), quartz and dolomite. Dispersion tests showed that enhanced dispersion of the particles in the pulp in the absence of reagents occured at a pH range between 8.5 and 12.0. Bench-scale flotation experiments were planned using the statistical tool of complete factorial design at two levels, replicated once. These experiments showed, and were confirmed at the pilot-plant scale, that higher doses of sodium sulfide and polymeric dispersant combined with sodium silicate favored a higher metallurgical recovery. At 6,800 g/t (218 oz/st) sodium sulfide and 6,992 g/t (224 oz/st) polymeric dispersing agent combined with sodium silicate, a zinc grade of 38.4% in the final concentrate was achieved, at an average metallurgical recovery of 72.4%. The industrial trial confirmed the pilot scale results, leading to zinc recovery of 76.1% and a 37.3% zinc grade in the concentrate. Key words: Froth flotation; Flotation reagents; Flotation depressants; Zinc/ zinc ores

Jan 1, 2010

By X. M. Wu

The paper describes four different types of support for deep excavations, which are currently used in China. Local experiences were illustrated by presenting case histories for each type of support. For braced excavation in soft clays in Shanghai, the earth pressure against bracings were found to be in conformity with the trapizoidal estimation given by Terzaghi and Peck (1967). For tie-back support of excavations in Beijing and Shengyang, earth pressures were found to be much less than those predicted by ordinary rules. In the construction of a mining shaft in coarse sand below ground water level, high pressure jet grouting has been successfully used to form a circular impervious lining of the shaft. As an effective anti-slide measure, large diameter reinforced concrete piles constructed by open shaft method have been widely used with success.

Jan 1, 2010

By Huimin Lu, Min Li, Jinghua Zou

"Zeolitic imidazolate frameworks (ZIFs) are new type of porous materials, form inerratic polyhedral in three-dimensional with large cages and small apertures, and appear structural diversity. Their hole size can be adjusted. These materials have high selective adsorption capacity to carbon dioxide. In this paper, zeolitic imidazolate frameworks were synthesized by solvothermal synthesis method with dimethylformamide (DMF) as solvent and structuredirecting agent, divalent metallic ions as cation, and imidazole as ligand. The crystals were characterized with XRD, SEM for their crystal structures and physical properties, the adsorption of the crystals for carbon dioxide was also tested, and the result suggests that these porous materials have a capacity of 1.35ml/g for storing carbon dioxide at 273 Kelvin under ambient pressure.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the main environment problems, contemporary research has focused on ways to slow or stop this trend. CO2 capture has attracted attention due to the potential to trap and sequester large amounts of CO2 from concentrated sources such as power plants [1]. Traditional technologies in capturing CO2 include absorption by aqueous amines [2]. However, utilization of this process is energy intensive and expensive. Carbon dioxide storage materials investigated so far can be divided into two categories: chemical storage adsorbents and physical storage media [3]. The first kind of materials can chemically adsorb carbon dioxide within their structures and need thermal energy to release the adsorbed carbon dioxide. The examples of the chemical adsorbents include aqueous amines, gas-hyperbranched aminosilicas [4]. The physical adsorbents store carbon dioxide by physical adsorption of carbon dioxide at elevated pressure and release the adsorbed carbon dioxide at low pressure. The physical adsorbents that have been investigated for carbon dioxide storage include zeolites, carbonaceous materials and other porous materials. Until recently, a new type of microporous material, known as zeolitic imidazolate frameworks (ZIFs), has been reported as promising adsorbents for carbon dioxide storage [5 ~ 10]."

Jan 1, 2010

By Qingwei Wang

Heavy metal-containing wastewater from hydrometallurgical processes of lead-zinc was treated by biologics in a 200 m3/h industrial scale experiment. The result shows that Zn concentration declined from 50.28 mg/L~240.81 mg/L to 0.21 mg/L~1.98 mg/L, Pb from 1.00 mg/L~13.47 mg/L to 0.083 mg/L~0.71 mg/L, Cu from 0.24 mg/L~2.38 mg/L to 0.059 mg/L~0.40 mg/L, Cd from 2.12 mg/L~23.47 mg/L to 0.011 mg/L~0.071 mg/L and As from 0.50 mg/L~6.00 mg/L to 0.005 mg/L~0.10 mg/L. The concentrations of the above heavy metals in the treated water were lower than that in Integrated Wastewater Discharge Standard (GB8978~1996) in China. Furthermore, the treated wastewater was recycled and reused in smelter plant. Zinc content in hydrolytic sludge reached up to 34.04%, which indicates that this sludge can be used to recover valuable metals.

Jan 1, 2010

By J. K. Whyatt

Researchers at the U.S. Bureau of Mines collected and analyzed overcore measurements and other indicators of in situ stress characteristics at the Lucky Friday Mine, Mullan, ID. An analysis of these data revealed that significant local variations in in situ stress are present in this mine and that these variations existed prior to mining. High stresses were found to be associated with the most competent strata and a locked section of a fault. An estimate of the predominant stress field was developed for mine-wide modeling. The estimate shows that the greatest principal stress was oriented north of northwest. This information should provide a basis for mine-wide structural modeling of the Lucky Friday Mine and should generate important insights into localized stress conditions, which may significantly affect both local and mine-to-mine variations in seismicity induced by excavation.

Jan 1, 2010

By A. G. Belova

With the federal climate change legislation in progress, there is a need for demonstration-stage technologies aimed at providing clean energy from coal. Our research aims to experimentally illustrate the feasibility of capturing CO2 on a novel sorbent system from a gaseous stream. The gas is then released resulting in a regenerated sorbent and a pressurized stream of pure CO2 to be used for storage. The proposed sorbent is a ceramic honey-comb structured monolith coated with CaO supported on a high-surface area alumina. CaO is a natural acceptor of CO2 and our design ensures the physical stability and chemical reactivity of CaO over a large number of CO2 capture/release cycles. Furthermore, the use of the monolith ensures a uniform flow through the reactor, minimizes pressure drop across the reactor, and maximizes the surface reactive area. In this paper, we will present the results from a flow-through laboratory-scale reactor that establishes the efficiency of the proposed system to capture CO2. Future applications of the reactor include integration within the new-generation coal gasification power plants, such as IGGC, as means of providing decarbonized electricity.

Jan 1, 2010

By Essie Esterhuizen, Michael M. Murphy, Chris Mark

"The response of the surrounding rock mass to the creation of mining excavations determines the ultimate load on a pillar support system. In conditions where the ground is relatively soft and weak, the full overburden weight can be transferred to the pillar system. However, in stiffer and stronger rocks, a greater portion of the overburden load is transferred to the unmined coal barriers or abutments, and the pillar stress is reduced. This paper makes use of numerical models to examine the interaction between typical pillar systems and the surrounding rock mass for weak and strong geological conditions at various spans and depths of cover. The concepts of structural failure and functional failure of pillars are used to assess pillar performance when pillars are deformed beyond their peak resistance. The results show that the span-to-depth ratio is an important factor in determining the pillar stress and the ultimate deformation of pillars. The ultimate pillar strain appears to be closely related to the functional success of pillar systems.INTRODUCTIONThe National Institute for Occupational Safety and Health (NIOSH) was requested by Congress to study the safety of retreat pillar mining following the Crandall Canyon Mine disaster that took place near Price, Utah in August, 2007. As a part of this study, an investigation was made to better understand how the rock mass responds to the creation of mining excavations and how the loads are distributed among the pillars and the surrounding abutments or barriers. The outcome of these investigations contributed to the development of a modified loading model for the ARMPS-2010 (Mark, 2010) method ofretreat mining pillar design.Structural and Functional Failure of PillarsPillar design is typically conducted by estimating the pillar strength and stress, and then sizing the pillars so that an adequate margin of safety exists between the expected strength and stress. The pillar strength can be defined as the maximum resistance of a pillar to axial compression (Brady and Brown, 1985). If a pillar is loaded beyond its peak strength, load shedding or yielding can occur, and the pillar is considered to have failed as a structure. Structural failure generally refers to a loss of loadcarrying capacity."

Jan 1, 2010