Search Documents

By G Williams

Somewhat to the surprise of many heavy mineral sands (TiO2 and zircon) producers, there are important geological structures within their typical placers and aeolian sands deposits that affect plant metallurgical performance. After many years of operations, even experienced producers have encountered unexpected changes in production, product quality and recovery. After looking in all the obvious (but wrong) places, it is recognised that the mine has advanced into ore with different separation characteristics. Metallurgical process response can vary significantly between ore sourced from different geological domains. The mineral characteristics that are exploited for effective separation may be associated with differences in the depositional environment, or be post-depositional in origin. Surface coatings that interfere with electrostatic separation might be associated with paleo-water table movements. Major storm events in the deposition history can also leave distorted mineral assemblage through stranded formations or incisions in older deposits.Apart from the influence on capital and operating costs, geometallurgical variances add another dimension to orebody modelling. Each domain could have specific recovery, mineral assemblage and product quality values to be considered in the value model. Project success is often directly dependent on understanding the geometallurgy of the resource. Tailoring the exploration and early process flow sheet development programs to account for such variances should be standard practice. Such practices have had a chequered history in the mineral sands industry, with sophisticated processes having been developed, only to be shelved for ‘economic’ reasons, and then once again ‘discovered’ when problems re-emerge.It is clear that knowledge gained through a higher level understanding of the changing mineral separation characteristics and advance warning of mineral behavioural differences can mean the difference between lost recoveries and disappointed customers or well timed capital plans and maximised revenues.

Oct 5, 2011

By J M. Nel

Richards Bay Minerals (RBM) has recently undertaken an exercise to improve orebody basal definition. Older mineralisation bases (pre-2005) were highly erratic using old protocol reverse circulation (RC) (also known as Air Core) drilling and interpretation. The erratic nature of this estimation tool, resulted in impractical modelling towards the end of mineralisation (EOM), difficult mine design and unrealistic reconciliation. New protocol drilling, which includes high definition SONIC drilling data, has provided more data to be available for more accurate interpretation. Recent advances in drilling methodology has allowed for better penetration depths for SONIC drilling, which was previously restricted to approximately 80 m (pre-2005). This improved data set allows more emphasis on geological interpretation with factors such as lithology, slime content, and mineral species distribution. These factors when in unique combination enable more accurate and realistic EOM data points. These points are modelled into surfaces using conditional simulation techniques and result in a vastly smoother surface and consequently, a more representative resource.

Oct 5, 2011

By S Doudle

The Iluka Resources Ltd Jacinth-Ambrosia heavy mineral sand mine (South Australia) is located in an undisturbed semi-arid landscape consisting of sparse trees, shrubs and grasses. The soil interspaces are covered with biocrusts, a living soil cover also found worldwide in arid regions. Biocrusts are composed of lichens, cyanobacteria, algae, mosses, liverworts, fungi and bacteria, and live on and within the first few millimetres of the soil surface. Biocrust organisms bind soil particles, sequester carbon and many fix atmospheric nitrogen making them important structural and functional components of ecosystems. Despite their important role in ecological processes, biocrusts are susceptible to disturbance; nevertheless they can recover provided sufficient inoculum is present. Cyanobacteria are the early colonisers and they capture atmospheric and landscape resources and establish conditions that subsequent successional seres can capitalise on. Research conducted in countries including China, Spain and South Africa has been focused on methods to either encourage rapid regeneration of cyanobacterial remnants or to introduce new material from cultured cyanobacteria. We have been investigating the extent and diversity of biocrusts across the 4500 ha mine lease and their potential to improve mining rehabilitation outcomes. Approximately 46 per cent of the soil surfaces are colonised with biocrusts and 33 taxa have been identified. Laboratory experiments were designed to mimic massive soil disturbance and treated with a range of water qualities. Within 22 days, treatments irrigated with fresh water were colonised by new cyanobacterial filaments with a mean surface coverage of 65 per cent. Secondary tests revealed that differences in the photosynthetic yield of the crust were dependent on the salinity levels of the irrigation water used. In 2011 this program is expanding from the laboratory into field scale trials designed to assess both the potential and practicalities of up scaling these techniques to provide crushed biocrusts and cyanobacterial bio-inoculum for use in mine rehabilitation.

Oct 5, 2011

By P Ramsaywok

The use of saline water for mineral beneficiation in arid regions is general practice and also the case with Exxaro Namakwa Sands, situated on the west coast of South Africa. Although it is ‘cost effective’ to use sea water for mineral beneficiation, downstream process separation efficiencies may be negatively affected. This is more specific to surface dependent separation techniques such as electrostatic and high tension (HT) separation. If minimal fresh water is available then, proper washing is often neglected. Salt crystals can form on particle surfaces during the drying process before electrostatic separation.This paper describes a study that has been conducted to determine the effect of upfront salt water processing on downstream electrostatic/HT separation. The study indicated that minor quantities of salt can cause the separation efficiency to decrease substantially.

Oct 5, 2011

By R Kjar

Globally, it is anticipated that the mineral sands industry will enter a period of short supply. Demand for both titanium dioxide and zircon is forecast to continue increasing, with new projects needed to come on-stream to fill the supply gap. Victoria is well placed under this scenario as a source due to the high quality of its mineral assemblage, its excellent resource grade and the globally significant size of its mineral sands resources.Australia’s mineral sands rich Murray Basin remains under-developed, especially at its extensive Victorian margins. Development to date has not progressed adequately for the reasons of technology difficulty, history of competition with other jurisdictions and the absence of a platform that requires development as a consideration for security of tenure. Victoria’s mineral sands potential is not just about the Murray Basin, in addition, there have been discoveries in the Gippsland Basin and prospective sites in the Gippsland Basin remain under-explored. Key problems included the lack of available ground for potential developers and the intellectual property of solutions to technological problems associated with the fine grained mineral deposits belonging to a previous developer (with patents now expired).As such, the timing is right to re-visit the potential of the Murray Basin as a site for long-term development with high returns based on current and predicted prices.In order to understand why Victoria’s earth resources in general, and mineral sands in particular, remain under-explored and undeveloped, the Department of Primary Industries initiated an internal review of its role in encouraging and supporting investment in the earth resources sector.As a result, the Victorian Government has committed to taking action to encourage effective ground turnover and acknowledges that a new focus on engagement with industry is needed to bring new investment to the State. The revision of the Mineral Resources (Sustainable Development) Act 1990 provides an opportunity for the government to better align its legislative processes with industry project lifecycles and facilitate access to valuable resources that currently remain undeveloped.Victoria has a track record in assisting projects reach development stage. Iluka currently has two operations in the State in addition to its mineral separation plant that is capable of processing HMC from its South Australian operations. Iluka is expected to ramp up its Murray Basin Stage 2 operations with the WRP mine scheduled to come on line in early 2012. Meanwhile, Astron is actively seeking partners for its Donald Mineral Sands project. The project is becoming increasingly attractive given the recent price hike in zircon; Astron has access to an estimated five to 6 Mt of zircon in its Donald WIM 250 deposit.Given its substantial and valuable mineral sands endowments, the State of Victoria should sensibly be the centre of future investment in project development. However, as previously mentioned this is currently not the case. The Government is therefore committed to implementing new measures that protect security of tenure but ensure that genuine companies can access endowments where they have a clear intent to work those resources.

Oct 5, 2011

By B Hou

The Eucla Basin in southern Australia is emerging as an important global source of zircon from heavy mineral sands. Understanding the geological evolution of the basin and movement of heavy minerals down peripheral paleovalleys and along paleocoastlines is essential to effectively refine exploration strategies for heavy minerals in the basin. Integration of geoscientific datasets in a Geographic Information System (GIS) environment has proved to be effective in reconstructing depositional environments along the Cenozoic basin margin and in tracing the buried paleorivers that once drained broad areas of the Archean-Paleoproterozoic Yilgarn and Gawler cratons, the dominantly Mesoproterozoic Musgrave and Albany-Fraser Provinces, and the Neoproterozoic-Early Paleozoic Officer Basin. Sea level highstands during the late Middle Eocene (39 - 36 Ma) are associated with formation of the Ooldea coastal barrier complex and the zircon-rich heavy mineral deposits at Jacinth, Ambrosia and Tripitaka. More extensive transgression during the Late Eocene (36 - 34 Ma) built the complex Barton shorelines that host the Cyclone deposit and the extensive ilmenite-dominated occurrences of the Barton West prospect. Multi-generation reworking of the source sands is indicated by the high proportion of deposits that are zircon-rich relative to titanium minerals. The age distribution of zircon grains in heavy mineral concentrates from the Ooldea and Barton barrier systems points to the Musgrave Province as the predominant ultimate zircon source. Paleorivers discharging along the northern basin margin presumably carried a sediment load that was then redistributed by easterly longshore drift to build the extensive coastal sand deposits along the northern and eastern basin margin. The south-eastern extension of these deposits was reworked during Miocene-Pliocene (15 - 2 Ma) times into a series of regressive strandlines that show angular discordance with the Eocene coastlines. This discordance is consistent with evidence for long-wavelength tilting of the Australian continent from Middle Miocene times, as the continent drifted toward a dynamic topographic low induced by convective mantle processes associated with the South East Asia subduction systems. The Dromedary and Gulliver’s deposits probably formed at this time. Ongoing research is focused on the geological features of the basin that influence heavy mineral transport, concentration and preservation, and the processes leading to deposits with high zircon content.

Oct 5, 2011

By M I. Pownceby

High temperature roasting studies on chrome-spinel contaminated ilmenite concentrates showed that sulfur, introduced through a sulfidising roast treatment, selectively reacted with the chromium in the spinels. The roast treatments were carried out in a laboratory scale rotating drum kiln using a standard Becher-style heating profile (10 h, 1075ºC), char as the reductant, and variable amounts of added elemental sulfur (0 - 3 wt per cent).After roasting, bronze-coloured grains were visible representing chrome-spinels that had undergone selective sulfidisation. SEM imaging of the products showed that sulfur was preferentially concentrated in ~5 - 15 µm thick rims fully enclosing the chrome-spinel grains. The sulfur-rich rims became a sink for manganese (Mn) from the ilmenite resulting in the rims being rich in Cr-Mn-Fe-sulfides. Quantitative electron probe microanalysis of phases present within the rims identified two sulfide phases. The first sulfur-phase (S-phase) was low in Mn (1 - 3 wt per cent) and high in Fe, Cr and S, while the second S-phase was considerably higher in Mn (30 - 35 wt per cent Mn) and lower in Fe and Cr. The dramatic change in the composition of the chrome spinels after sulfidisation is likely to significantly alter their physical properties (eg hydrophobicity, conductivity, etc). This should make their physical separation from the ilmenite potentially easier than roasting/magnetic separation methods.

Oct 5, 2011

By E J. B van Etten

Pit lakes may form when open cut mining leaves a pit void that then fills with ground and surface waters. This often replaces terrestrial ecosystems that existed prior to mining with an aquatic ecosystem, affording an opportunity to improve regional aquatic biodiversity values through targeted aquatic restoration (McCullough and van Etten, 2011). Restoration theory provides guidance when restoring disturbed systems towards landscapes that are of regional value and relevance. But how do we identify a restoration target for a novel aquatic habitat that only exists in the new post-mining landscape? This paper presents a process of first identifying and then surveying local representative aquatic systems, to provide a direction for pit lake restoration efforts and achievement criteria for pit lake relinquishment, using a case study from a sand mining operation amongst wetlands in south-western Australia.The company mines silica sands following mechanical removal of topsoil and then extraction of the ore from below the watertable by dredging. Assessment of wetland and riparian vegetation was achieved through the establishment and measurement of temporary monitoring transects across five natural wetlands in the Kemerton area. Several more regional wetlands were also visited and observations made to supplement and validate these data.Distinct vegetation zonation was found across each wetland, although typically wetland basins were unvegetated or filled with younger woody plants with patchy distributions. Fringing riparian vegetation consisted of few species (commonly the paperbark Melaleuca rhaphiophylla and the sedge Lepidosperma longitudinale), but community composition and structure were variable between wetlands. The pattern of vegetation seen across natural wetlands was best explained by topography and soil chemistry, with low lying wetland areas more likely to experience regular flooding and accumulate organic matter and nutrients.In conclusion, where they are available, regional natural waterbodies may constitute the best valid restoration goal. Nevertheless, the goal may need to consist of a range of closure design opportunities, rather than a single target.

Oct 5, 2011

By M C. Ackland

The Grande Côte Mineral Sands Deposit (GCMSP) is located on a coastal mobile dune system in Senegal on the west coast of Africa. Senegal is a stable, democratic republic, having gained its independence from France in 1960. It has a population of about 12.5 million people. The dunes begin about 25 km north-east of Dakar, the capital city of Senegal, and extend northwards for more than 140 km. The mineralised dune system averages about 2 km wide with some areas extending to up to 4.5 km wide.Mineral Deposits limited (MDL), a Melbourne-based company with over 60 years operational experience in mineral sand mining in Australia, holds, through its Senegalese subsidiary MDL Senegal SARL (MDLS), a 25-year Mining Concession covering the deposits. The main heavy mineral (HM) areas identified to date are, from south to north, Mboro, Fass Boye, Diogo and Lompoul. Within the Mining Concession there is potential to identify additional resources beyond the limits of present drilling. The dunes are mobile or semi fixed, pale yellow in colour and overlie older white marine sands. The dunes range between 5 m and 30 m in height and the mineralised zones, which are essentially flat-lying, average around 15 m in thickness. The mineralisation consists, principally of ilmenite with accessory zircon, rutile and leucoxene. Zircon and ilmenite are the main commodities of interest.Independent consultants AMC estimated mineral resources for the four main deposits in 2006 of 1330 Mt of sand averaging 2.0 per cent HM at a cut-off grade of 1.5 per cent HM. At a cut-off grade of one per cent the resources were 3200 Mt averaging 1.5 per cent HM. All of the estimate was classified as Inferred Resources under the 2004 Australasian Code for Reporting of Exploration Results, Mineral Resources and Ore Reserves (JORC, 2004).Subsequent completion of infill drilling, sampling and assaying of the initial mining area, centred at Diogo, was completed in 2008, enabling a final dredge path to be designed and ore reserves estimated, based on a JORC compliant Measured and Indicated Mineral Resource. Infill drilling is continuing in the Lompoul and the results of this campaign will be included in the JORC compliant data base by AMC in April 2010 to enable the 15 per cent year dredge path and mine plan to be finalised.Development studies have shown that the project can be optimised as a dredging operation, with mineralised sand being treated in a conventional floating spiral preconcentrator, wet concentrator and dry mineral separation plant. Engineering work now substantially completed by Ausenco Limited (Ausenco) has developed the combination of some existing plant from MDL’s past operations, and new plant for the complete process from dredging to final product separation and grading. Testwork on a series of bulk samples has determined that the project can yield a high quality zircon product and an ilmenite product along with minor rutile and leucoxene.Work to date indicates a likely output of around 80 000 t of zircon in various quality streams (Primary, Secondary, Standard and Foundry Grades), around 550 000 t of ilmenite plus around 15000 t of rutile and around 12 000 t of leucoxene/secondary ilmenite. Planned zircon output would represent around 7per cent of the total world production, which would make the GCZ&IP a significant producer on a world scale.The studies have indicated capital costs to be in the range of US$400 M total operating cost (after completion of ramp-up) of around US$50 M - $55 M/a. Revenue is expected to be in the range $127 M - $157 M/a.

Oct 5, 2011

By J M. Shekiro

In the chloride process to manufacture TiO2 pigment, feedstocks containing higher TiO2 contents (high-grade ores or HGOs) are favoured in order to minimise production of undesirable by-products. Most of today’s HGOs are produced through the smelting or reduction and leaching of ilmenite, processes which consume significant energy and/or produce large volumes of non-titanium materials that may have to be landfilled. In order to improve the economic and environmental sustainability of its TiO2 business, the DuPont Company, working with Kobe Steel Ltd, has developed an innovative process called TiRON for making HGO. Using a rotary hearth furnace, the process reduces ilmenite to a high TiO2 slag and metallic iron granules. The TiO2 slag is suitable for TiO2 pigment manufacture, and the iron is suitable for steel making. TiRON can process sand or rock ilmenite of varying compositions and particle sizes. Fossil fuel instead of electricity supplies the energy for the reduction. Dusts and off-spec materials are recycled. These process attributes, together with capital requirements estimated to be significantly lower, give TiRON substantial economic, environmental, and process flexibility advantages over conventional ilmenite upgrading processes. TiRON has been demonstrated at the semi-works scale, and preparations are being made to bring it to the pilot scale.

Oct 5, 2011

By J D. Grobler

In the heavy minerals industry wet high intensity magnetic separators (WHIMS) are widely applied for primary magnetic separation of magnetic minerals and non-magnetic minerals. This piece of equipment is well known for its robustness to handle a wide range of feed conditions and still produce stable product qualities and yields. A heavy mineral production plant aimed to increase production through their WHIMS plant containing 11 duties and 26 units. Instead of adding new units an alternative approach was followed to firstly maximise the efficiency of the current circuit and secondly to consider possible reconfiguration of the circuit to produce additional product tons for minimal capital investment. In order to characterise the current circuit’s efficiency, identify pockets of excellence and determine the areas for improvement the whole circuit was surveyed several times and mineral mass balances were drawn up.This paper aims to: discuss the modelling process of the WHIMS circuit,explain the calibration and validation process followed to ensure the accuracy, anddemonstrate the sensitivity analysis performed on the different options. From this analysis an efficiency criteria was developed to compare different circuit configurations that enabled the production plant personnel to make an informed decision on the way forward.

Oct 5, 2011

By J Ledgerwood

Namakwa Sands is a mineral processing company based on the West Coast of South Africa and is solely owned by Exxaro Resources Limited. Mineral ore is mined and processed, concentrated and both chemical and mechanically upgraded before being sent for electrostatic and magnetic separation units. The final high value mineral products report as Zircon, Rutile and Ilmenite.The recovery of non-magnetic material is largely dependent upon a number of factors, including but not limited to dew point, ambient temperature, feed rate, mineral size distribution, specific gravity and mineral content in head feed. One important limiting factor to recovery in typical dry mill operations is the particle size distribution of the feed. Variance in the particle size has catastrophic consequences for recovery. This is the reason for this study. Until recently large variances in non-magnetic production were viewed to be a function of machine operation. This view was later rejected with the feed size distribution determined as the major driver of low recoveries, for Namakwa Sands orebody 50 per cent variance in particle size distribution can be noticed within one day. This is because of the successive mining blending techniques employed.The predicament is that the two modes were so closely placed together that recovery of a single mode is almost impossible without the consequence of greatly reducing recovery. The second mode was found at 125 µm while the first was at 90 µm. Interestingly, for the mentioned feed type a cumulative size distribution of a unimodal feed type is almost exactly the same as for a bimodal size distribution. Thus a plot of cumulative size distribution will show no difference due to the modes being so close together. This is the reason why this phenomenon was not noticed before.The study also found that, using an high tension roll (HTR) or rare earth roll, a fine stream with a single mode at 90 µm versus a coarse stream with a single mode at 150 µm would yield completely different results interms of yields. Larger conductive particles are thrown from the roll while small particles loose charge faster (entrainment). Results in terms of the bimodal size distribution show that even though 25 per cent of the feed type is greater than 150 µm the yields followed a similar pattern to that of the coarse particles rather than that of the majority (75 per cent) fine particles. This confirms what was published by M Ziemski and P N Holtham in 2005 on charge decay rates; they mentioned that particle bed effects played a major role in recovery.

Oct 5, 2011

By D McCoy

Titanium feedstocks are the building blocks of the titanium value chain. They can be mined directly, as is the case for ilmenite, leucoxene and rutile, or manufactured from ilmenite by extracting various quantities of non-TiO2 components from the ore by chemical and/or thermal processes.While feedstocks can be grouped into categories of materials with similar characteristics, they are essentially unique products from very different mining locations around the world. In fact, no two feedstocks are exactly the same. As such, the variations between the available feedstocks, in combination with the permutations in processing technologies to turn the feedstocks into titanium pigment or metal, mean that choices between feedstocks are specific to the location in which they are utilised.In this paper, the authors examine the key requirements of titanium feedstocks to the TiO2 pigment and metal sectors. Apart from the well known differences between feedstock choices for the sulfate and chloride process, the more opaque considerations in feedstock sourcing are examined.

Oct 5, 2011

By A Sadough Vanini

In this paper large deformation of smart functionally graded beams with initial imperfection and under thermal loadings is considered. Smart beam consist of two types of layers. One layer is made from functionally graded materials and a layer or a set of layers from active materials that usually is made from piezoelectric materials that are bounded on the surfaces of beam. An active controller is used for controlling the deformation and stress in functionally graded layer of beam. A simple Euler- Bernoulli beam theory is used for analyzing of beam. In functionally graded layer the material property vary continuously through the thickness direction and power law model is used for the variation of elastic modulus, heat expansion and heat conduction coefficients. Poisson ratio is assumed to be constant in functionally graded layer. The effects of varying the power law constants and the Gain of controller is considered here. The results are reduced and compared with smart functionally graded beam without initial imperfections.

Oct 1, 2011

Resistance spot welding is the most common type of welding in the automotive industry. In RSW the size and shape of welding nugget is one of the most effective factors on mechanical properties, such as tensile shear strength and fatigue strength. so properly adjusting the variables of the welding is necessary .in this study the effect of different parameters of RSW including time, current, electrode force, geometry of electrode so diameter and angle of electrode tip in the shape and size of welding nugget evaluated. for experimental procedure, low carbon steel sheet st12 is used. the process is simulated with finite element method by using ANSYS software. for the formation of welding nugget a 2 dimensional symmetrical model electrical-thermalmechanical is used and for elevate the accuracy ,we determined the properties of material related to temperature. The results show that increasing the time and current of welding, the diameter of spot weld also increased and the role of current is more impressive. and also increasing the electrode force decrease the diameter of the nugget due to increasing the contact area and decreasing the resistance .increasing the diameter of electrode tip cause increasing contact area and decreasing the resistance and decreasing the diameter of the nugget. furthermore, changing tip angle and electrode diameter don't show sensible change in the geometry of the welding nugget. comparison between simulation and experimental result show a good adaption.

Oct 1, 2011

By N. Maleki

Magnesium matrix composites are widely used in automotive and aerospace industries for achieving higher performance due to their light weight. The Mg2Si intermetallics compound in Mg/Mg2Si composite exhibits many excellent properties such as high melting temperature, high hardness, and low thermal expansion coefficient. However, under normal cast conditions, the primary Mg2Si phase exhibits coarse Chinese script or dendritic morphologies and the eutectic structures is very brittle resulting in the low ductility and strength of the alloys. Modification treatment is a very effective method to obtain fine microstructure and improve the mechanical properties of the alloys due to low production cost. In this investigation various amount of bismuth addition have been carried out on Mg?5wt %Si alloy to refine and modify the morphology of coarse Mg2Si in order to improve the corrosion resistance of the composite product. The effect of Bi content on microstructure of Mg2Si/Mg composite was investigated by optical and scanning electron microscopy followed by EDX analysis and X-Ray diffraction. In order to compare corrosion resistance of unmodified and modified specimens, Immersion test and potentiodynamic polarization (PD) were used. The results showed that by Bi addition, the size of primary phase Mg2Si was considerably reduced and the morphology was modified from a coarse dendritic shape to a polyhedral shape. The results also indicated that the corrosion resistance of Mg?Si alloys was improved by the addition of 1%wt of Bi due to the reduction, refinement and evenly distribution of Mg2Si phase. Indeed, both the morphology and distribution of Mg2Si intermetallic had a great influence on the corrosion behavior of Mg/Mg2Si composite.

Oct 1, 2011

By Wencheng Gao

An attractive way to beneficiate magnesium chloride and aluminum chloride is to prepare Mg-Al spinel, an excellent refractory material. Mg4Al2(OH)14?3H2O, the precursor of spinel, can be prepared using a co-precipitate method from aqueous MgCl2-AlCl3 solutions. The co-precipitation process of magnesium-aluminum from acidified chloride solutions by using NaOH or NH4OH as base neutralization agent was studied. Co-precipitation was conducted from different mixed solutions ? at initial CAl=0.0625M and Mg/Al molar ratio from 0.5 to 10, the temperature range from 30 to 90 °C. The effect of other parameters, including base type, method of base addition, base addition rate, aging time, background electrolyte and concentration were also investigated. The co-precipitation process was monitored by potentionmetric(pH) measurements. The experimental pH curves were characterized by two platforms separated by a steep jump in pH at Mg/Al molar ratio 0.5~6. The first platform was centered at about a pH of 3.8 and the pH of second platform was varied with different conditions. When the Mg/Al molar ratio was up to 6~10, the first platform in pH was almost disappeared. Furthermore, the shapes of pH curves were also affected by base type, base addition rate and method of base addition. Experimental results showed that the first platform in pH was connected with Al precipitation, and the second platform was involved with Mg. The final co-precipitates were characterized by XRD, TGA-DTA, particle size analysis, SEM and TEM. We found both Mg/Al molar ratio and temperature proved to be the key parameters controlling the formation of Mg4Al2(OH)14?3H2O phase. At solution Mg/Al ratio=0.5~4, the main precipitate phase was Bayerite (Al(OH)3) admixed with Mg4Al2(OH)14?3H2O; at Mg/Al ratio=4~6, the main phase was Mg4Al2(OH)14?3H2O admixed with some Mg(OH)2; while from Mg/Al ratio=6~10, the systems were mixtures of Mg(OH)2 and Mg4Al2(OH)14?3H2O.

Oct 1, 2011

By Amin Jafari

Macrosegregation has always been an important issue with the solidification processes, particularly in Direct-Chill Casting of Aluminum alloys, where uneven properties, surface and bulk defects and limitations in productivity can be arisen due to macrosegregation in the cast product. Following the global attempts to practically predict the macrosegregation, in the present work, a numerical model was developed based on an industrial scale DC casting process to simulate the solidification and macrosegregation in an Al-4.5%Cu billet. Interesting aspects of this investigation are concerned with an efficient numerical scheme to keep simplicity, consistency and desired physical resolution of the solidification phenomena together. In the mathematical model, coupled conservation equations of mass, momentum, energy and species were solved numerically using finite volume method. A different numerical scheme, called SIMTLE, was introduced to link the energy and species equations with the phase diagram of the alloy. Calculations were performed on an industrial case and obtained results were compared to available experimental data to assure the performance of the model. Different macrosegregation features were predicted and discussed on the solidifying Al-alloy billet.

Oct 1, 2011

By S. A. Sadough vanini

In this paper the influence of temperature on the flow behavior and rheological characteristics of an A356 alloy in the semi-solid state using backward extrusion process are studied experimentally and numerically. Simulation process is done by dynamic explicit in ABAQUS software for each forming condition. A cooling slope treatment was employed in order to obtain a non-dendritic microstructure. Experiments were performed in 5 temperatures and 4 different wall thicknesses. In the low forming speeds, liquid fraction had time to escape from solid phase forward the samples? wall. This condition was the main reason for the segregation phenomenon seen in the base and walls. Viscosities were determined using the force-displacement graphs obtained form back-extrusion tests. As observed experimentally, in a constant temperature, increase of shear rate resulted in decrease of alloy viscosity exponentially. Raising the temperature increases the liquid fraction hence reduces the semi-solid alloy viscosity. The results of experimental and simulation are compared and there is a good adaptation.

Oct 1, 2011

By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011