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By Ma Shao Xian, Li Dong, Li Zhen Guo

"The new type shaft calciner ( SK-10 Serials) is developed and designed by CADRE itself on the basis of the conventional shaft calciner. The actual application in a number of calcinations plants have proven that they are of very good effect. Calcined coke calcining heated by the shaft calciner has a high quality, lower lost by fire. The shaft calciner needs no additional fuel when it is working. Anode Carbon Plant and calcined coke Plant commonly used the shaft calciner in domestic. The waste heat from the shaft calciner can be recuperated to generate electricity and to make the steam for produce. Exhaust waste heat is recovered by 90% or more. The new type shaft calciner's structure is optimized by computer simulation for fire-wall structure, combustion air to fuel ratio, volatile combustion is fully in use, furnace cooling zone structure, the exhaust smoking structure and calciner heat balance. Furnace structure and production operating parameters has been got the best optimized results. This paper introduces the working principle and characteristics of the shaft calciner - the equipment for calcining of the petroleum coke. It also demonstrates measured process parameters of the new type shaft calciner. Through comparison with the rotary kiln and conventional shaft calciner, it proves its own technical characteristics and advantages: higher capacity, high quality products, provides more energy for power generation, equipment operation and maintenance costs lower.IntroductionChina's petroleum coke market is mainly dominated by the delay raw petroleum coke. Rotary kiln and shaft calciner are the main process equipment for calcined petroleum coke. As the shaft calciner burning less, no external fuel, waste heat utilization is high, long service life, the utilization rate in China is more extensive than the rotary kiln."

Jan 1, 2012

By R. L. Bruening, N. E. Izatt, S. R. Izatt

"Rare earth elements (REE) are essential and unique components of many high-technology products without which functioning of modern society would be greatly impaired. Commercial deposits of REE are limited to a few geographical locations. Largely untapped sources of REE are available in endof- life (EOL) magnets, rechargeable batteries, and electronics. Presently, < 1% of REE in EOL wastes is recycled. Conversion of EOL wastes to liquid streams allows use of IBC’s Molecular Recognition Technology (MRT) process to selectively recover, separate, and purify target REE and associated metals at g/L to mg/L or lower concentration levels. The MRT process together with its applications to separations of REE and associated metals in recycling as well as in mining are described. Economic and environmental advantages of MRT are presented. INTRODUCTIONRare earth elements (REE) include the lanthanide series (La-Lu), Y, and Sc. These elements are not rare, but concentrated minable deposits are scarce (Cordier 2012; Haxel, Hedrick, & Orris, 2002). Over 95 % of the world’s supply of REE is controlled by China (Hanson, 2011a) where they are mined, processed, and the pure elements incorporated into a growing number of consumer and military products. The consumer products are marketed worldwide. Since REE are vitally important in consumer and military products, this situation has caused other nations to scramble to develop the capability to produce their own supply (Cordier, 2012).In the U. S., Molycorp has reopened the Mountain Pass REE mine in California and production has begun (Goldenberg, 2010). Development of a reliable internal source of REE is of high national priority in the U.S. (Hanson, 2011b; Hess, 2012: “Obama Announces”, 2012). These elements have in recent decades been incorporated into new consumer and military products that are essential to our economy and defense. These products range from wind turbines, high performance magnets, hybrid car rechargeable batteries, energy efficient lighting electronics, flat screen televisions, and smart phones to advanced weapons systems (Haxel et al., 2002; Levkowitz & Beauchamp-Mustafaga, 2010)."

Jan 1, 2012

By Mori Fresko, Stuart M. Jones Jr

"This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded.A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.INTRODUCTIONThis paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide. The list is maintained by Stuart M. Jones, Jr. (author), and is included in the appendix. This list has been the inspiration for similar papers in the past several SAG Conferences. Updates have been solicited from all major mill manufacturers and most have responded. Information from this list is compiled to illustrate the growth of the AG/SAG mill market and the use by industry and selected geographic areas. It covers the market growth through the end of 2010."

Jan 1, 2012

By A. E. Voigt

Iron ore samples representing the input and output of several jigging experiments were analysed to determine the effect of particle size, shape, and density on jigging performance. Traditionally, the manual measurement of the size and shape of individual particles is very tedious and prone to inaccuracies and inconsistencies. Using a novel multi-view imaging technique the 3-dimensional representations of each particle in the sample was determined. From this representation several size and shape measurements were extracted, and these were correlated with the individual particle density measurements. A rigorous investigation into the confidence associated with density and the size and shape features as a function of sample size was conducted, thus allowing the significance of correlations in the data to be determined. The jig?s performance was seen to be clearly sensitive to density and markedly so to particle size, while the results for shape indicated the need for continued work in the definition of particle shape.

Jan 1, 2012

By O. A. Olaseinde

The 2101 lean duplex stainless steel has wide potential application in storage, heat exchangers, and in the oil and gas industries. This work investigates the electrochemical behaviour of 2101 duplex stainless steel with an addition of 0.15 wt% ruthenium, using potentiodynamic techniques in 1M H2SO4 at 25º, 40º, 60º, and 80ºC. The microstructures of samples were characterized using optical metallography and scanning electron microscopy. The results showed that the ruthenium addition moved the corrosion potential of alloy 2101 to a more positive potential. All samples containing ruthenium displayed longer passive regions at 25°C and 80°C compared to those without ruthenium. Alloys without ruthenium had higher critical current density (icrit) values when compared to the alloys with ruthenium. Ruthenium additions decreased the passive current densities and inhibited anodic dissolution. At room temperature the corrosion rate of alloys with ruthenium was lower than these without ruthenium.

Jan 1, 2012

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By G. Van Weert, O. Wang

"As part of a general review of processing double refractory ores through Barrick Gold’s autoclaves / CIL facility at Goldstrike, blanking the preg robbing native carbon in the process solids with hard (m.p. 55 - 60 º C) paraffin wax was studied, specifically in relation to pressure oxidation. The improvement in CIL gold extraction was found to depend on the wax addition point, with hot, dry contacting of the ore in the presence of wax - prior to POX - yielding the largest, most consistent improvement in gold extraction.INTRODUCTIONDouble refractory gold ores present two barriers to gold extraction. The first is generally a physical barrier: the gold is encapsulated or dispersed in a matrix which is impervious to the gold lixiviant. In most cases, including Carlin Trend, NV, deposits, this involves a pyrite or arsenopyrite matrix, although minor gold may also be dispersed in competent silica (quartz) or iron oxides. Gold can be rendered accessible by oxidative destruction of such sulphide matrices. At Goldstrike this is practised by roasting and autoclave oxidation (Thomas, 1994). It is the latter route to which this paper refers.The second barrier refers to the actual gold recovery. Gold may be extracted from the pressure oxidized solids with cyanide, forming a gold cyanide complex. One characteristic of this complex is that it adsorbs on graphitic surfaces. This is taken advantage of on a large scale by gold millers, who use manmade activated, i.e., graphitized carbon particles to remove the gold from solution during leaching: the Carbon-In-Leach, or CIL process. The gold cyanide bearing carbon particles are larger than the ore solids and can be separately recovered by screening. Goldstrike uses the CIL technology to recover gold. The second barrier becomes problematic when the ore naturally contains graphitic orcarbonaceous material, hereafter referred to as native carbon (versus the man-made activated carbon). This material may also adsorb gold cyanide in competition with the activated carbon. Since the native carbon is ground with the ore it is much smaller than the activated carbon. Any competition between the two carbons may produce a loss of gold from the pregnant leach liquor to the process tailings. This phenomenon is called “preg robbing”. Goldstrike ores come from the Carlin trend, which is known for the occurrence of native carbon (Adams & Burger, 1998; Schmitz, Duyvesteyn, Johnson, Enloe & McMullen, 2001; Tretbar, 2004)."

Jan 1, 2012

By Douglas M. Matson, Rongbiao Gu, Christopher San Marchi, Anil Saigal

"Hydrogen embrittles most structural metals, although the form and magnitude of embrittlement depends on the source of the hydrogen as well as the stress in the metal. Hydrogen fuel cell systems typically store gaseous hydrogen fuel at high-pressure, which provides both a source of hydrogen and high stresses in the containment materials. Understanding and measuring the effects of hydrogen on the mechanical properties of common structural metals, especially fatigue properties, is important for safe, long-term operation of such systems. This work explores the use of thermography to efficiently and quantitatively evaluate hydrogen-assisted fatigue of type 304 austenitic stainless steel. In particular, thermographic analysis was used with rotating-beam fatigue testing and shown to provide repeatable results which are in general independent of test cycle frequency while reducing test times by several orders of magnitude. The effects of hydrogen were studied by thermally precharging fatigue test specimens in gaseous hydrogen prior to thermography-assisted fatigue testing and then compared to testing of non-charged specimens. Hydrogen-precharging increased the strength of this type 304 austenitic stainless steel and increased the fatigue life by a factor of about 50-100.IntroductionThe world is facing a severe energy and environmental challenge: how to provide competitive and clean energy for its citizens in light of an escalating global energy demand and concerns over energy supply security, climate change and local air pollution. As a carbon-free energy carrier, hydrogen provides a promising vector for storing and distributing renewable energy. Hydrogen is an important industrial gas that is used extensively in many industries. However, with growing demand for clean energy, hydrogen fuel cell systems are being developed for use in consumer products, such as fuel cell vehicles, which changes the landscape for safe design of high-pressure gaseous hydrogen systems."

Jan 1, 2012

By Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio, Adriana Johanny Murcia Santanilla

"Increasing volumes of solid waste are generated worldwide, due to the continuous technological advances, the electronic scrap is part of these waste, requiring the study of recycling processes to stimulate this activity or the reuse of its components. The separation of nickel from sulphate leach solution, which also containing iron, zinc and aluminium was carried out using bis-(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272) as extractant, in order to determinate the effects of pH and temperature. The number of stages required for extraction was also assessed. The results showed that the metal extraction increased with increasing pH. On the other hand, increasing temperature was not favorable for all metals. However, under conditions used in this paper the purification of solution containing nickel was possible.IntroductionIncrease in the demand of metals in the world for use in industry causes a great exploration of natural resources. One outcome of this is increased investigations for the recovery of metals from industrial wastes. Nickel is found in wastes, such as batteries and electric and electronic devices, this kind of waste becomes a significant source for metals recovery. Since nickel is also present in printed circuit boards, which are associated with electric and electronic equipment, it can be recovered from this kind of waste through different techniques. It is important to highlight that iron is generally associated with this scrap [1] and for its removal chemical precipitation is often used. On the other hand, the solvent extraction process is widely used for treatment of leach liquors, because it can be produce high purity solutions [2, 3]. This technique is based on the purification of solution using contact between a liquor leaching and the immiscible organic solution, which contains an extractant that promotes the desired metal transfer [4]."

Jan 1, 2012

By Haile Manteqi

In longwall coal mines, estimation of roof strata condition, sequence of loading, and supporting requirements are of a high degree of importance, and they are directly related to production and safety. Also, a prediction of the initial caving distance is rather complicated to calculate, because there are many parameters that effect caving process?roof and floor strata conditions, thickness of immediate roof, depth of cover, excavation geometry, and magnitude, and direction of principal stresses. This paper presents the results of 3D numerical modeling of the initial caving mechanism using the finite difference code FLAC3D at the E1 longwall panel of the Parvade 1 underground mine located in the Tabas area in the central part of Iran. The initial caving distance obtained was 10.4 m. Also, the results of numerical modeling have been compared to the analytical methods, such as Peng?s method. The results show good agreement with each other.

Jan 1, 2012

By A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia?s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By Carla L. Zenti

In recent years, considerable advances have taken place worldwide in the design and construction of first tunnel linings. With these advances, there is a tendency to move away from traditional support that includes heavy open profiles of rolled steel arches, to a lighter solution with the use of an optimized tubular steel cross section rib, and shotcrete reinforced with steel mesh and/or steel fibers, providing a continuous support (Lunardi, 1982). The development of tubular ribs has provided greater design options, increasing flexibility to engineers and contractors while providing a efficient and cost effective construction method. In this article, the authors describe numerical and experimental investigation on this problem, suggesting as a new first lining steel arch design approach by using tubular ribs cross section as new technical solution for first lining underground support.

Jan 1, 2012

By John Sakala, Jeyapandian Sasikumar, Sydney Kwalela

The Isasmelt Furnace was commissioned in September 2006 with a concentrates treatment capacity of 850,000 tonnes per annum. However, the converter section became a bottleneck to the high throughput. Over 25% of the Isasmelt Furnace down time was attributed to lack of converter space. Factors that affected converter operations were low tuyere line campaign life (an average of 150 blows), high reverts generation, low conversion rates, and high converter cycle time. As a result of efforts carried out to improve converter operation, the average campaign life has increased to over 250 blows and reverts generation has been reduced from 22% of concentrate treated to 15%. Blister copper conversion rate has increased from 15 tonnes per hour to 19 tonnes per hour and blowing time per cycle has been reduced from 5.7 hours to 4.7 hours.

Jan 1, 2012

By C. Liley

Open cut blasting at the Ernest Henry mine has the potential to cause damage to nearby underground workings. This paper is a case study of the blast vibration management project which was conducted to ensure pit blasting did not adversely affect the stability of upper production levels or cause damage to the underground primary fan units.

Jan 1, 2012

By Thomas Gliick, Jianming Lu, David Dreisinger

"The Boleo project of Baja Mining (Vancouver) will process a mixed oxide-sulfide ore using an acid oxidation and reduction process in seawater to extract copper, zinc, cobalt and manganese. Copper will be extracted via SX-EW as copper cathode, zinc will be recovered as a zinc sulphate monohydrate crystal and cobalt will be produced as a cobalt cathode product after phosphinic acid extraction. Manganese may be recovered from the final solvent extraction raffinate by precipitation as manganese carbonate.The development of the cobalt recovery process (solvent extraction and electrowinning) will be discussed. The pilot plant solvent extraction circuit and subsequent bench and small pilot testing of cobalt electrowinning will be discussed. The Boleo project will produce approximately 1708 tonnes per armum of cobalt metal when fully commissioned.INTRODUCTIONThe Boleo property is held by the Mexican company, Minera y Metalllrgica del Boleo S.A. de C.V. (MMB). MMB is owned 70% by Baja Mining Corp. and 30% by a consortium of Korean companies consisting of KORES - Korea Resources Corporation, LS Nikko Copper, Hyundai Hysco, SK Networks and Iljin Copper. The project is fully financed and is now under construction with an expected startup in early 2013 .Average annual production, for the first six years for each of the metals is forecast as: 56,697 tonnes of copper cathode, 1,708 tonnes of cobalt cathode and 25,364 tonnes of zinc sulphate monohydrate. The project has an average life-of-mine cash cost (based on the three year trailing average metal prices, as of December 31, 2009, in accordance with SEC guidelines) of -$0.29/lb Cu, net of by-product credits for cobalt and zinc and with no credit for manganese production. There is the potential to produce up to 220,000 tonnes per armum of manganese carbonate (- 100,000 tpa contained Mn) via the relatively simple addition of a small number of unit operations to the proposed plant. The recovery of manganese metals from the manganese carbonate intermediate material is discussed in a separate paper in this proceeding."

Jan 1, 2012

By S. Perkins, E. Young, L. Dufour, K. McVey, L. Rolandi

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

By Katragadda Sarveswara Rao

"In view of the increasing importance of processing lean ores as potential future resources, efforts are being made worldwide to develop suitable technologies for the recovery of both nonferrous, base and precious metals. There are various types of low grade ores present in many countries. Gradually, the mineral reserves for production of metals have undergone complex changes with regards to their grades and particularly the physical and chemical properties of the minerals to be separated from each other. So, there is a need for new processing routes or the upgrading of existing technologies to recover metal values that are otherwise unutilized. Accordingly, an overview of the different types of mineral resources and economical processes, based on ore horizons, consumption of energy and reagents and environmental concerns, is made in this paper. In addition, the paper provides a summary of metallurgical and engineering challenges to be overcome when implementing new technologies and concepts with regard to base metal extraction and sulphur removal efficiency.IntroductionLow grade multimetal complex sulfide ores are likely to become an importance source for nonferrous as well as precious metals in the near future. The principle metallic minerals are chalcopyrite, sphalerite, galena, pyrite, pyrrhotite, arsenopyrite, tetrahedrite, boulangerite and cassiterite. Such ores are located throughout the world as multi-pocketed reserves which have present complex challenges with regard to their grades and particularly the physical and chemical properties of the minerals to be separated from each other. Their compositions can vary widely from one deposit to another and even from one location to another in the same deposit, and this poses a problem for the recovering metals present therein. Successful aqueous processing of complex sulphide ores depends on the composition and mineralogy of the raw materials and on their leaching behaviour."

Jan 1, 2012

By Ehsan Vahidi, Fereshteh Rashchi, Ataollah Babakhani, Alireza Zakeri

"The synergistic effect of Cyanex 302 on solvent extraction of nickel and cadmium from sulfate solution with D2EHPA diluted in kerosene was investigated with the aim of increasing separation efficiency. Experiments were carried out within a pH range of 0.1-5.0 using sole D2EHPA and D2EHPA-Cyanex 302 mixtures in different ratios. Increasing Cyanex 302 to D2EHPA ratios in the organic phase caused a left shifting of the extraction isotherm of cadmium and a right shifting of the extraction isotherm of nickel. As a result, optimum separation was found with a Cyanex 302 to D2EHPA ratio of 0.1M:0.5M. In the present system, effect of a modifying reagent such as TBP was studied. The influence of various diluents including kerosene and carbon tetrachloride was also investigated.IntroductionBatteries are popular sources of portable energy. Ni-Cd batteries are manufactured in two main groups of small domestic cells and large industrial batteries with 80% being in domestic use. Ni-Cd cells have various uses, for example in cordless electric utensils, cordless telephones, airplane engine starters, and communicational distribution systems [1].Depleted Ni-Cd batteries are classified as hazardous waste since nickel and cadmium are heavy metals and suspected carcinogens. Given the risk associated with uncontrolled disposal, directions for issuing legislation on disposal and recycling of used batteries have been made in industrialized countries [2]. Recycling of Ni-Cd batteries is important from both economic and environmental points of view. Different methods have been used for recycling these wastes through pyrometallurgy [3], biotechnology [4,5], and hydrometallurgy [1,2].Due to the advantages of hydrometallurgical processes, several studies have been implemented on leaching and solvent extraction (SX) of the used Ni-Cd batteries. Leaching of batteries is usually done in sulfate or chloride media; while solvent extraction has been used in different extractants: two-stage solvent extraction by D2EHPA and Cyanex 272 [6]. Solvent extraction of Cd from leach solutions has been studied using various extractants; Cyanex 301 [1], D2EHPA [7], Cyanex 302 [8], Cyanex 923 [9], Cyanex 272, Tops 99, PC88A [10]. Application of phosphorus based extractants for the solvent extraction studies of Ni such as TOPS 99 [11], D2EHPA [12], Cyanex 272 [2], has been investigated. Separation of Cd(ll), Ni(II), and Co(ll) from chloride leach liquor of spent batteries [13], were explored in the earlier studies. Cd extraction with D2EHPA involves co-extraction of both Ni and Co [14], which causes issues in the separation process efficiency."

Jan 1, 2012

By H. Fayed

Two-phase (water and air) flow in a self aerated WEMCO flotation machine has been investigated using computational fluid dynamics (CFD). A 0.8 m3 model is considered. The flow is modeled by Euler-Euler approach, and transport equations are solved using a commercial software ANSYS-CFX5 [1]. Because of the lack of circumferential periodicity in this machine, the entire machine is modeled and unsteady simulations are conducted in the whole volume of the bulb. Uniform bubble diameter is specified, and the effects of bubble diameter are determined by conducting simulations for three diameters of 0.5, 0.7, and 1.0 mm. The unsteady air flow rate through the machine is predicted as an outcome of the simulations. Air volume fraction contours and velocity field in different parts of the machine are presented and discussed.

Jan 1, 2012

By Alan A. Campoli

The mining industry has long been searching for an effective structural application that prevents weathering and falls of loose rock, debris, and sediment. J-Crete is a fiber-reinforced, engineered, cementitious composite rock application that is designed, tested, and successfully utilized as such a material. Laboratory evaluation of J-Crete material properties has shown the final compressive strength to be in excess of 7,300 psi (50.34 MPa), with 24 hour strength in excess of 1,500 psi (10.34 MPa). The flexural tensile strength is in excess of 600 psi (4.1 MPa) and is provided through a unique combination of polyvinyl alcohol (PVA) fibers activated by a proprietary liquid additive that prevents them from clumping and enables even distribution throughout the grout. Tensile bond strength in excess of 350 psi (2.4 MPa) at 28 day cure tightens the strata and holds loose material in place. Practically impervious to gas and liquids, J-Crete protects strata against long-term weathering, does not require screening to be effective, and has proven to be a successful waterproofing material. J-Crete has demonstrated the potential to alleviate coal mine roof cutters in soft, wet clay formations. J-Crete reinforces coal mine ribs by bonding directly to the rib, conforms to the strata, strengthens the rib, and eliminates sloughing due to long-term weathering; stabilizes coal mine entries by bonding directly to the brow and roof, and creates a monolithic shell with double reinforced corners.

Jan 1, 2012