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By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By D. Royston

In SAG mills fed with a variety of ore types, hard packing between the shell lifters can come and go depending on rock type and rock size distribution and the presence of a binder. Packing can appear in all sizes of SAG mills, and can be tenacious. High ball impact forces (depending on ball size) in larger mills may compact and encourage packing. Packing can have a negative impact on milling performance and a change in shell liner design may be required to remove it. However shell liner design changes need to be managed with care to ensure liner reliability. In smaller mills control of packing can extend shell plate wear-life and may help to maintain milling performance in fixed-speed mills through the liner wear-cycle.

Jan 1, 2012

By L. A. Cornish

Pt-based alloys for high-temperature applications in aggressive environments have been under development for over 10 years, and are targeted to be used as either as bulk, or as coatings. The alloys comprise Pt, Al, Cr, and Ru, and the microstructure has been improved by composition to a best possible analogue of the nickel-based superalloys, which these alloys could partially replace. This was necessary because the previous best alloy had a strengthening precipitate volume proportion of only approximately 40 vol.%, whereas the nickel-based superalloys have around 70 per cent, and a lower volume would mean that the strength would not be the best that could be obtained. The microstructures were assessed using electron microscopy, and have been related to the alloys? hardness values. The current microstructures are much more like those of NBSAs, with a high proportion of the strengthening ~Pt3Al precipitates. Since the samples have to be small (platinum is expensive), hardness has been used as an indication of strength. Nano-indentation studies showed that the hardness and Young?s modulus were higher for ~Pt3Al than the (Pt) matrix. More extensive oxidation studies have been undertaken on the previous optimum sample, and the effect of cooling rate after heat treatment has also been ascertained. In addition, the samples were studied after different heat treatment times, and cross-sections were made in order to characterize the alumina scale that formed. The oxide scales of Pt-11Al-3Cr-2Ru (at.%) up to 100 h exposure did not spall, and were at least as good as those of the ternary alloys. There was no discernable Al depletion zone in the substrate, although it could have been at a greater depth than thickness of the samples studied. Further additions to the Pt-Al-Cr-Ru alloys have been studied, to increase the melting temperature as well as to reduce the platinum content without compromising the properties. Reduced platinum content would have the benefits of reduced density and cost. The target elements include vanadium and niobium, of which vanadium is of special interest, since it is a South African product. Before these additions could be made, phase equilibria studies were undertaken so that the maximum addition could be ascertained, and also to check any possible ternary phases, which could be deleterious. Work on the Pt-Al-V system revealed a ternary phase, ~V27Pt54Al19 (at.%), which has a eutectic reaction with (Pt). The maximum V addition is likely to be around 15 at.%, otherwise ~Pt3V or the ternary phase will form, and not the required (Pt)/~Pt3Al phases.

Jan 1, 2012

By C. Musingwini

The South African mining industry continues to be a major source of employment at a time when at least 25 per cent of the working age population is unemployed. At the same time the industry faces a skills shortage in many of the disciplines necessary for its future health. The University of the Witwatersrand, University of Pretoria, University of Johannesburg, and University of South Africa have historically produced mining graduates for the South African industry, with any shortfall being met by the recruitment of overseas graduates. More recently the global shortage of engineers and other mining industry professionals has seen a reversal of this trend and a very significant emigration of well-educated and highly skilled personnel. The traditional career path for mining graduates is in production and mine management. However, there is the parallel and possibly more pressing need for specialized skills in such fields as ventilation, rock engineering, mine planning, mineral resource evaluation, and mineral asset valuation. It is in these essential areas that chronic shortages continue to hamper the development of the industry and may well frustrate its ambitions to be safe, healthy, and profitable into the future. The permeability of skills across sectorial boundaries within the mining industry requires that skills shortages in the platinum sector are not looked at in isolation, but within the context of the entire industry. This paper reviews the efforts being made by the universities at both undergraduate and postgraduate levels to meet the needs of the South African mining industry, in terms of the required numbers and the range of specialized skills.

Jan 1, 2012

By B. X. Huang

Hydraulic fracturing technology is presented as a solution to improve permeability and thus solve the extraction problem of coal seam gas in low-permeability gas-bearing coal seams. Given an existing group of original cracks, the propagation of main hydraulic cracks and hydraulic wing cracks was simulated using realistic failure process analysis software. The process represents the structural transformation of hydraulic fracturing and permeability improvements caused by it. In addition, a field test for improving the permeability of gassy coal seams by hydraulic fracturing was also conducted. The propagation of the main cracks and wing cracks by hydraulic fracturing forms a network of original joint cracks, hydraulic wing cracks, and main hydraulic cracks, which improve the permeability of the coal seam. High-pressure water in the drill hole and in the main hydraulic cracks permeates the two flanks of the hole, forming the permeating water pressure. With an increase in drill water pressure and an extension of the main hydraulic cracks, the permeating water pressure on both sides of the main hydraulic cracks in the coal mass also increases. Hydraulic cracks tend to form connections through rock bridges. The extension of hydraulic wing cracks through connections in the rock bridges between the cracks transforms the rock mass to a fractured structure and improves its permeability. Hydraulic fracturing technology for improving permeability in underground conditions can increase the amount of gas drainage by a factor of 15. A stress relief area develops at a radial distance of 10-2.0 m from the hydraulic fracturing drill hole, while an area of rising stresses, called the pressurized area, develops a further 15 m away from the pressurized hole. Practice has proved the existence of the stress transfer phenomenon and the high stress area after fracturing. This kind of hydraulic fracturing technology is more effective in holes drilled from underground than in surface drill holes, with respect to costs and controllability, and is therefore the major trend in gas drainage development in coal mines.

Jan 1, 2012

By Michael Burrell

This project involved the protection of an historic landfill located on the site. Construction blasting was for a permanent access road to carry traffic to and from a new metal processing plant being constructed nearby. The landfill contained materials disposed of during the closure of a Phosphorus plant that had previously occupied a portion of this site.

Jan 1, 2012

By Antonio Martin, Jesus Hurtado, Francisco Jimenez

"Atlantic Copper is one of the largest copper producers in Europe. Its production facilities, including a primary copper smelter and an electrolytic refinery, are located in Huelva, on the southwest coast of Spain. These installations enable the smelting of over 1 million tpy concentrates to produce up to 260,000 tons per year of cathodes and 900 ktpy of sulphuric acid.Since 1970, several improvements have been made at the Converters Area such as modifications of primary hoods, operations with an OPC system, installation of scrap chargers, the recent installation of the secondary hoods and other environmental projects. All these modifications have been aimed at increasing the capacity of our smelter while keeping our continuous environmental commitment.This paper describes the modifications and improvements carried out at the converters area and our proposals for future developments."

Jan 1, 2012

By M. Ge

Pattison Mine is a small sandstone mine located in Iowa. The sandstones produced by the mine are not common construction and aggregate materials. The stones are used to produce a special type of sand for hydraulic fracturing, a critical technique for recovering tight gas and shale gas. These sandstones are very different from the minerals and rocks which have been studied extensively in mining. On the one hand, they are brittle as characterized by an unusually high friction angle, up to 69°, and steeply curved failure envelopes. On the other hand, they are friable, possessing extremely low, and in most cases zero cohesion. The scarcity of the ground control techniques for this particular mining environment has created many difficulties for the mine operators. In order to resolve these problems, a research program was set up by the mine and Missouri University of Science and Technology. This paper discusses the preliminary results of this investigation.

Jan 1, 2012

By Allen G. Taylor

High-value materials, such as gold, platinum and other precious metals, are subject to loss through unauthorized removal from mines, smelters, refiners and other places where such materials are processed. A study by Gastrow (2001) determined that between 1994 and 1998 an average of 603 kg/a (1,330 lb/year) of gold was stolen from South African mines and subsequently recovered. This does not include the gold that was stolen but not recovered. At 2011 prices, 603 kg/a (1,330 lb/year) of gold would be worth approximately $33 million. Mine security personnel believe that the unrecovered stolen gold far exceeds what is recovered (Gastrow 2001). Traditionally, metal detectors have been used to screen personnel leaving secure areas to discourage such unauthorized removal. However, with the current near-record prices of gold, platinum and other precious metals, it has become worthwhile for people exiting a facility to walk out with quantities of product that are too small for ordinary metal detectors to register, resulting in substantial financial losses.

Jan 1, 2012

By A. Mahmoudkhani

There has been a continuous interest in chemical aids for processing Canadian oil sands by hot water extraction process since the first commercial industry operation in 1967. Several inorganic and organic chemical systems have been introduced, of which sodium hydroxide is the most widely used extraction process aid by major producers. Use of NaOH, however, results in accumulation of sodium ions in recycled water, causing higher clays dispersion and producing tailings with poor geotechnical properties that turn into mature fine tailings. This is especially true for low grade and oxidized ores, which present the greatest challenges in bitumen recovery and produce the major portion of fine tailings. In this paper, we are presenting a novel method based on use of inorganic polymers as process aids for various low grade oil sands ores. Denver flotation cell and a laboratory scale hydrotransport loop were utilized to evaluate the effect of chemical dosage and operating parameters on the processability of oil sands samples from Athabasca region. Process tailings were examined for properties such as water chemistry, suspended solids, settling rate and the ease of tailing treatments. Our results demonstrate that the use of inorganic polymers during the froth process lead to a significant improvement in bitumen recovery from low grade oil sands and can improve further tailing treatments. This offers a viable solution that can be easily incorporated into current processing facilities and deliver several operational and economical benefits. Advantages in use of inorganic polymers versus sodium hydroxide are presented in details.

Jan 1, 2012

By Reza Kamali, Mohsen Bashiri, Hadi Fanisalek

"Nomenclature: A: area (m2), C: heat capacity (WIK), cp: specific heat (J/Kg K), d: internal tube diameter (in), F: correction factor for multi-pass and crossflow heat exchanger, h: convective heat transfer coefficient (W/m2K), k: thermal conductivity (W/mK), L: length (m), m: mass flow rate (Kg/s), W: flow rate, N: number, Q: heat rate (W), R: thermal resistance, T: temperature (°C), U: overall heat transfer coefficient (W/m2K), ;1,,P: pressure drop (Pa), ;1,,T: temperature difference (°C), p: density (lb/ft3), N: number of tube passes, U,: velocity in tubes, iJh: head loss in feet of flowing fluid, Up: velocity in the pipe leading to and from the heat exchanger (ft/sec), µ: viscosity ( cp ), Llpf frictional pressure loss (psi/l 00 equivalent ft of pipe) Subscripts: b: baffle, c: cold, cf counter flow, ex: exchanger, f: fouling, h: hot, i: inlet-inner, ib: inlet baffle, lm: logarithmic mean, m: mean, o: outlet-outer, s: shell, t: tube, w: wall AbstractThe main bottleneck for primary aluminum production industry is dealing with a huge amount of input energy. The fact is that part of provided energy to aluminum production smelters will be lost as waste heat and it never used for aluminum production. One part of waste heat is escaping from the potroom exhaust gases, which was studied for possible recovery in a desalination plant to produce distilled water and the paper was presented in 2011 TMS Annual Meeting. However, it was shown that waste heat recovery plant to produce distilled water is highly profitable but the main fact is that the exhaust gases from potroom are highly corrosive, abrasive and dusty. The main challenge for desalination plant construction, which is using aluminum smelter exhaust gases as the main heat source, is the highly corrosive environment that makes the situation difficult and complicated for equipments design and plant construction. In this paper, we are trying to study a detailed investigation regarding the heat exchangers fouling, corrosion in heat exchangers including heat exchangers' material, how often we need to shut down the plant for maintenance or cleaning, and plant thermal efficiency with considering fouling."

Jan 1, 2012

By D. W. Alexander

Researchers from the U.S. Office of Mine Safety and Health Research (OMSHR) of the U.S. National Institute for Occupational Safety and Health (NIOSH) completed field trials during coal mine rescue contests using simulated gas detectors in place of placards. The gas monitor simulator (GMS) devices replaced static, paper placards to deliver gas concentration data. Eleven teams were observed during the field contest, which was approved by the Mine Safety and Health Administration (MSHA). GMS devices were given to three team members (the captain and both gasmen). Observation of teams revealed that team members changed behavior by acknowledging and sharing information more often while using the GMS. As a result of this research, it has been demonstrated that under the existing contest format, the newly developed GMS device may be used with no adverse impact on team contest performance. Furthermore, when GMS technology advantages are used, contest realism is improved. In the future, competency assessment may be incorporated.

Jan 1, 2012

By Junhong Noh, Kug Sun Hong, Jung-Kun Lee, Bo Ding

"The photocatalytic splitting of water into H2 and O2 by oxide nanoparticles has received much attention. However, the full potential of photo-catalysts for efficient hydrogen generation out of water has not been fully realized yet due to unresolved limitations including the low electrical conductivity and ineffective carrier extraction. Here, we report composite oxide materials consisting of 1-dimensional (1-D) transparent conducting oxide (TCO) core and TiO2 shell. Highly conductive ITO nanowires were grown on a flexible SUS mesh as a core component. The photoelectrodes consisting of these 1-D nanocomposites have increased carrier mobility due to the TCO core, while the TiO2 shell provides the photocatalytic functionalities. In addition, the built-in-potential at the interface between TCO core and the TiO2 shell improves the collection of charge carriers from TiO2 to TCO. These factors altogether contribute to increasing the photocurrent of the device under light.I. IntroductionPhotocatalytic behavior of semicondcutors has been extensively explored since it was discovered in TiO2 in 197Os. When TiO2 is exposed to UV light, the light is absorbed and electron/hole pairs are generated in the conduction and valeence bands. Holes in valence band will oxide/mineralize pollutant target directly or indirectly (via mediator hydroxyl radical). If the adsorbed A is O 2, O 2 will react with electron from conduction band to generate hydroxyl radical as described in the second set ofreactions. The photocatalytic reaction is schematically explained in Figure 1.Photoelectrochemical (PEC) cells using the photocatalytic reaction have attracted emerging interest as a potential route to convert solar radiation into useful forms of energy by reaction such as water splitting to generate hydrogen1 or the reduction of carbon dioxide.2 Another application ofphotocatalysis is water splitting and CO2 reduction, both of which utilize the electrons that are optically excited to the conduction band. 3•4 For this purpose, the conduction level of the semiconductor should be higher than hydrogen production level (EHZ1HZO) while the valence band should be lower than water oxidation level (Eo21112O). Electrons and holes will be generated on the semiconductor site, and holes generate O 2 at semiconductor site, while electrons will migrate to counter electrode to execute reduction forming H2. In addition to that, materials should be chemically stable to resist photocorrosion and have long lifetime of electron/hole pairs. TiO2 is a suitable material from the viewpoint of band arrangement and chemical stability requirement"

Jan 1, 2012

By C. A. Nogueira, F. Margarido

"A research work has being carried out annmg at evaluating the possibility of treating simultaneously several electrochemical systems of spent batteries using the same process, in order to overcome the high costs and difficulties of selective collection and sorting. Zn-Mn02 systems, representing more than 75% of portable battery market, shall be treated in dedicated processes. The treatment assessment using a single hydrometallurgical process of the other major systems (NiCd, NiMH and Li-ion), having Ni and Co as main metals, was the aim of the research work here reported. Sulfuric acid leaching was demonstrated to be adequate for dissolving more than 90% of the metals of interest contained in batteries. The subsequent separation of metals by solvent extraction, using organophosphorous extractants like DEHPA and Cyanex 272, allowed the production of pure solutions of rare earths, cadmium/manganese, cobalt, nickel and lithium, enabling their further recovering.IntroductionRecycling is the best approach for end-of-life management of spent batteries mainly by environmental reasons but also motivated by resources conservation and, in some cases, by economic profits. Most relevant electrochemical systems of portable cells are Zn-Mn02 (ZMB, alkaline and saline), nickel-cadmium (NiCd), nickel-metal hydride (NiMH) and lithium-ion (LIB). These batteries are collected, sorted and usually treated separately, applying for pyrometallurgical or hydrometallurgical technologies, the former being the most common.Several processes have been developed and some of them industrially applied, as described in some available review papers [l, 2]. In Europe for ZMB systems the oldest processes are Batrec [3] and Citron [4]. Although having differences in details, both are based on pyrometallurgical recovery of zinc by distillation, in metallic or oxide forms, being manganese retained in the slag together with iron. Hydrometallurgical alternatives are also available, like Zincex [5] and Recupyl [ 6] processes, both using sulfuric acid solutions as leachant. The application of the existing technologies to battery recycling, instead of using dedicated processes, is other alternative already tested, being the Waeltz furnace or the Imperial Smelting some examples."

Jan 1, 2012

By A. Taylor, J. Shelegey, H. Sullivan, J. Doucet

"Historically, performance at Vale’s Clarabelle Mill was measured by Mill throughput and Mill recovery. After the economic collapse in 2008, a series of reviews were performed to drive improvements in business efficiency. These identified that product quality (e.g., concentrate grade, variability in concentrate grade) had a profound impact on downstream processes and suggested that improved control of these parameters would generate the greatest value for the customer (the Copper Cliff Smelter) and the company (Vale). Consequently, a movement was initiated to transform the Mill operating philosophy to consider customer needs as paramount. Systems and strategies used to drive the transformation are described. In 2011, an unexpected furnace failure resulted in decreased capacity at the Copper Cliff Smelter. In response, a two-stage change in production strategy was developed at Clarabelle. The first stage was to modify the ore blend feeding Clarabelle so that the concentrate grade could be significantly increased with minimal impact on recovery. The second stage was a circuit modification to ensure the elevated concentrate grade could be sustained. Execution of the first stage was complete five days after the failure and the second stage was complete within 10 weeks. Steps involved in each stage are outlined and the overall benefits are presented.INTRODUCTION Clarabelle Mill is located in Copper Cliff, Ontario, Canada (approximately 350 km north of Toronto). The Mill treats copper (Cu) and nickel (Ni) sulphide ores. The primary diluents are pyrrhotite (Po) and non sulphide gangue rock (Rk). The process description of the circuits at Clarabelle is documented in the paper by Taylor, Doucet, Blanchette, Barrette & Lawson (2012) in this Proceedings and will not be repeated. The Mill treats ore containing Cu, Ni and platinum group elements (PGE’s) and produces two concentrates; a Cu concentrate and a bulk Cu/ Ni Concentrate (referred to as nickel concentrate). The Cu concentrate is sold to market while the Ni concentrate is thickened at the Mill and pumped to Vale’s smelter complex in Copper Cliff Ontario for further processing. Since commissioning in 1971, Clarabelle Mill has undergone many circuit changes to suit the changing needs and wants of our customers, both internal and external. The Mill processes ores of varying quality, based on mineralogy and size and until 2009 the Mill daily performance was primarily based on throughput. The second key performance indicator (KPI) of “good” or “bad” performance was quality of the concentrate and third; Mill metal recoveries. There were other plant level KPIs such as flotation feed grind size, slurry densities and mass flows to the separation circuit, but for the most part each day was good or bad depending on how many tons were processed through the Mill."

Jan 1, 2012

By J. L. Havenga

South Africa produces about 400 Kt zircon (ZrSiO4) per annum. This represents about 30 percent of the global demand. However, very little is beneficiated locally and more than 95 percent is exported with little or no value addition. Zircon is a very inert material and needs to undergo high-temperature alkaline melting processes to produce valuable zirconium products. The conversion of zircon to plasma-dissociated zircon (PDZ) produces a chemically reactive species (ZrO2.SiO2) which consist of finely divided submicron monoclinic ZrO2 crystals dispersed in a SiO2 matrix. In this paper, an in-flight, non-transferred arc pilot plasma plant with a capacity of 100 kg/h and which consists of three 150 kW DC plasma torches, is described. The optimization of the plant, which includes the use of different zircon concentrates, the influence of particle size, feed rates, plasma gas, and energy utilization, is discussed.

Jan 1, 2012

By Kenneth Maas

The Bureau of Mines devoted portions of the 1987-1988 field seasons to investigate the mineral aggregate industry in Juneau, Skagway, Haines, and Gustavus, Alaska, as part of the Juneau Mining District study. Statistics compiled for current suppliers include location, activity, reserve estimates, expected mine life, and types of commodities available. Each population center, except for Gustavus, is well endowed with suitable mineral aggregate to last at least 20 years. The Bureau of Mines quantified the mineral aggregate resource in many large potential sites within each area. Sampling, engineering and soil-index testing, site descriptions, deposit dimensions, and gold recovery information is described. Refraction seismic studies performed at three localities revealed gravel thicknesses in excess of 40 to 80 feet. In the Juneau area the Herbert/Eagle Rivers outwash area, East Fork Lace River. Antler/Gilkey Rivers, and Grizzly Bar (Taku Inlet) individually contain in excess of 60 million yd3 of excellent-quality aggregate with minor accessory gold credits. Haines is also well endowed with aggregate resources; large, quality deposits occur along and at the confluences of the Chilkat, Katzehin, Klehini, Tsirku, and Kicking Horse Rivers. Large deposits of granitic aggregate exist in the Skagway River and East Fork Skagway River.

Jan 1, 2012

By H. M. Lima, L. A. Gomiero, C. A. de Morais

ABSTRACT The Caetité-Brazil uranium facility produces approximately 400 tonnes U3O8 per year from an ore averaging 0.29% U3O8. The process steps are ore crushing, heap leaching with sulphuric acid, uranium separation and purification by solvent extraction (SX) with a tertiary amine, followed by stripping with a sodium chloride solution, precipitation as ammonium diuranate (ADU), and product drying. A change in the milling process is being evaluated to increase production and uranium recovery. Heap leaching will be replaced by conventional agitated tank leaching of the –590 µm ground ore slurry in a sulphuric acid medium. Replacement of the stripping reagent is also being considered.

Jan 1, 2012

By Robert Benedetti

This paper describes various mitigation methods in order to reduce the maximum acceleration of the floorboard of hulled vehicles when explosive charges buried in water saturated sand were detonated beneath them. The effects on floorboard acceleration of adding a vehicle hull, several types of floorboard bracing, the use of foam to fill the gap between the floorboard and hull, and the use of foam to isolate the floorboard from the hull have been investigated. Small scale testing was conducted, which used bar magnet velocity gages to measure the velocity as a function of time of the center of the floorboard, directly over the charge, where the acceleration was expected to be greatest.

Jan 1, 2012

By B. Balamurugan, D. J. Sellmyer, J. E. Shield, G. C. Hadjipanayis, Damien Le Ror, R. Skomski

"Rare-earth transition-metal (R-TM) alloys show superior permanent magnetic properties in the bulk, but the synthesis and application ofR-TM nanoparticles remains a challenge due to the requirement of high-temperature annealing above about 800 °C for alloy formation and subsequent crystalline ordering. Here we report a single-step method to produce highly ordered R-TM nanoparticles such as YCO5 and SmCO5, without high-temperature thermal annealing by employing a cluster-deposition system, and we investigate their structural and magnetic properties. Nanoparticles of size = 10 nm are monodispersed (s /d ~ 0.15) and have Hc values at T = 300 K of 8.0 and 4.5 kOe for YC05 and SmC05, respectively. Alignment of the easy axes is performed via a field applied to the clusters before deposition. These processing steps are highly desirable to create and assemble R-TM nanoparticle composites for future permanentmagnet applications.IntroductionMagnetic nanoparticles with high magnetocrystalline anisotropies (Ki > 1 MJ/m3) are required for permanent-magnet, recording-media, and other significant applications [1-3]. In this regard, bulk rare-earth transition metal alloys (R-TM) especially RC05 (R = Y and Sm) crystallized in the hexagonal CaCu5-type structure have shown a large Ki = 5 MJ/m3 (YC05) and 22 MJ/m3 (SmCo5) along with an appreciable saturation-magnetic polarization (Js, > 10 kG) and high curie temperatures (Tc > 1000 K) [2]. The challenges in controlling the size, sizedistribution, phase purity and crystalline ordering, however, limit the research on RCo5 nanoparticles [4,5]. The conventional arc-melting technique requires high-temperature annealing for alloy formation and subsequent crystalline ordering, which causes excess growth and thus results in nanocrystalline powders of particles sizes larger than 30 nm [6, 7]. Low-temperature wet-chemical techniques yield SmC05 nanoparticles of sizes smaller than 20 nm [5], but the control of phase purity is challenging due to the presence of surfactants and formation of other secondary phases [8]."

Jan 1, 2012