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By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By F. L. Wang

The purification process of water-mining carnallite and rough potassium chloride concentrate from Qinghai Salt Lake Industry Group Co. Ltd. are investigated by the preprocessing-reverse flotation technology respectively. The results show that the impurities such as calcium sulfate and sodium chloride can be effectively removed from water-mining carnallite ore and rough potassium chloride concentrate by the new technology, the low-sodium carnallite is obtained and the final potassium chloride product greatly upgraded. The content and the recovery of KCl in the low-sodium carnallite are 25.78% and 97.50%, meanwhile the content of NaCl, CaSO4 in the low-sodium carnallite are 0.56% and 0.24%, and the removal of sodium chloride and calcium sulfate in the low-sodium carnallite are 97.48%, 85.10% respectively. The KCl content and recovery of high quality potassium chloride product are 98.25%, 96.70%, and CaSO4 content is 0.40% with 83.24% calcium sulfate removed in the high quality potassium chloride product.

Jan 1, 2014

By Z. Zhang, D. Bouchard, H. Blanchette, A. Lemieux

This paper describes quality control methodologies for the production of semisolid A356 aluminum slugs with the SEED process. A methodology based on destructive tests carried out with an apparatus measuring the force to slice the slugs is presented. The force measurements were correlated with the solid phase morphologies of the slugs and were validated against a non destructive methodology that consisted in monitoring the temperature evolution of crucibles to produce the slugs and the drained metal. Results from the destructive and non destructive methodologies are compared and discussed.

Jan 1, 2006

By Prakash Venkatesan, Yongxiang Yang, Seshadri Seetharaman, Aida Abbasalizadeh, Jilt Sietsma

Electrolytic production of metallic neodymium is carried out in fused fluoride salts containing neodymium oxide. Two major challenges pertaining to neodymium production are (a) low oxide solubility and (b) possible fluorine gas evolution. A novel iron-based reactive anode is proposed and tested to overcome fluorine gas evolution during electrolysis of neodymium oxide in molten fluoride salts.

Mar 1, 2017

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009

By Muhammad I. Kabir

The streamline method of recovery prediction reduces a two-dimensional problem to a bundle of one-dimensional ones. This paper presents the development and application of a novel scaling technique which, when used with a streamline model, causes s bundle of one-dimensional problems to further reduce to a single one-dimensional calculation. The one-dimensional calculation accounts for chemical-rock interactions and the streamline model for areal sweep. The scaling technique significantly reduces computation time, is readily modified to desk-top calculations, and can be applied to both absorbing and reacting species. The work was sponsored by the Interior Department&apos;s Bureau of Mines.

Jan 1, 1984

By M. I. Kabir, R. S. Schechter, L. W. Lake

This paper presents the development and application of a novel scaling technique that, when used with a streamline model, causes a "bundle" of one-dimensional (1-D) problems to reduce to a single 1-D calculation. The 1-D bundle is the streamline representation of a two-dimensional (2-D) problem. The 1-D calculation accounts for chemical-rock interactions and the streamline model for areal sweep. The scaling technique significantly reduces computation time, is readily modified to desktop calculations, and can be applied to both absorbing and reacting species. The work was sponsored by the US Bureau of Mines.

Jan 1, 1986

By D. Corrigan, A. Ahmad, R. Sood, J. Bratt, R. Holt

Zinc oxide based electronic ceramics are being used increasingly to protect electric and electronic circuits against transient voltage surges. Varistors are produced by sintering and annealing ZnO based powder compacts through long sintering and annealing cycles. Because of the length of these cycles, a manufacturing plant is saddled with expensive high temperature equipment with low throughput. Ceramics Kingston Inc. has developed a new technology that uses 2.45 GHz microwave energy for sintering and annealing. The new technology has the potential for increasing equipment and labour productivity very considerably. Additionally, the new technology will result in appreciable energy savings and add flexibility to the manufacturing process. Microstructural examination of varistors sintered conventionally and by microwave technology showed considerably smaller grain size in the microwave sintered materials. The electrical properties of the microwave sintered ceramics compare very favorably with those of the ones sintered conventionally.

Jan 1, 1990

By A. E. Voigt

Iron ore samples representing the input and output of several jigging experiments were analysed to determine the effect of particle size, shape, and density on jigging performance. Traditionally, the manual measurement of the size and shape of individual particles is very tedious and prone to inaccuracies and inconsistencies. Using a novel multi-view imaging technique the 3-dimensional representations of each particle in the sample was determined. From this representation several size and shape measurements were extracted, and these were correlated with the individual particle density measurements. A rigorous investigation into the confidence associated with density and the size and shape features as a function of sample size was conducted, thus allowing the significance of correlations in the data to be determined. The jig?s performance was seen to be clearly sensitive to density and markedly so to particle size, while the results for shape indicated the need for continued work in the definition of particle shape.

Jan 1, 2012

By E. S. Peterson, M. K. Harrup, K. A. Dolbeare, J. E. Wey

Efficient methods for the removal of copper from heap-leach solutions without mobile organic phases are a current mining industry need. To satisfy this need, a selective, high-capacity, durable solid material is required. The Idaho National Engineering and Environmental Laboratory (INEEL) developed a set of materials based on current solvent-extraction chelates that provide selective copper concentration in the presence of high concentrations of iron. In contrast to conventional solvent extractions, the author&apos;s strategy anchors the chelators to a nonpolymeric solid substrate through the use of a custom-designed linker molecule. The fundamental synthetic routes to these materials have already been established, and attachment to the solid surfaces have been achieved in an efficient manner. The author&apos;s continuing research is focused on the optimization of the synthetic pathways to these solid materials and the evaluation of their copper-capturing capabilities.

Jan 1, 2003

By E. S. Peterson, M. K. Harrup, K. A. Dolbeare, J. E. Wey

Efficient methods for removal of copper from heap leach solutions without mobile organic phases are a current mining industry need. To satisfy this need a selective, high-capacity, durable solid material is required. The INEEL has developed a set of materials based upon current solvent extraction chelates that provide selective copper concentration in the presence of high concentrations of iron. In contrast to conventional solvent extractions, our strategy anchors the chelators to a non-polymeric solid substrate through the use of a custom designed linker molecule. The fundamental synthetic routes to these materials have already been established and attachment to the solid surfaces achieved in an efficient manner. Our continuing research is focused on the optimization of the synthetic pathways to these solid materials and the evaluation of their copper capturing capabilities.

Jan 1, 2002

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Weathered crust elution-deposited rare earth ore is a specific rare earth resource in China that is rich in middle and heavy rare earths. From surface to bottom, the weathered crust elution-deposit rare earth ores can be divided into humic layer, completely weathered layer, partly weathered layer, and bedrock. The exchangeable rare earth ions mainly exist in the completely weathered layer and partly weathered layer, and the exchangeable aluminum ions mainly exist in the humic layer. A novel solution injection method for use in the in-situ leaching technology of weathered crust elution-deposit rare earth ores was put forward based on the different distributions of RE3+ and Al3+ in the four layers. Avoiding the humic layer, only the completely weathered layer and partly weathered layer were leached by controlling the height of the leaching solution liquid level. In this way aluminum, the primary impurity in the RE leaching solution, can be decreased and the purity of the RE product can be improved. Meanwhile, the choices of available leaching reagents were broadened and the possibility of landslide disasters could be reduced.

Jan 1, 2014

By Raymond F. Dalton

Despite the ready availability of numerous zinc sources, the process of solvent extraction- electrowinning (SX-EW) has as yet found little favour in the zinc industry. It is suggested that this is largely due to the previous lack of availability of suitable selective reagents having the particular features required to enable them to fit in to a solvent extraction-electrowinning based process for zinc, particularly with regard to strength and selectivity for zinc over iron. This paper describes work on the development of new selective extractants for the recovery of zinc from both sulfate and chloride aqueous solutions and suggests how they might be integrated into new zinc processes.

Jan 1, 1994

By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

By R. H. Grau

Improving the air quality in metal/nonmetal mines is important in protecting the health of miners. Air quality can be improved in metal/nonmetal mines by developing proper ventilation techniques. Mine ventilation systems require stoppings to direct the airflow and establish pressure differentials throughout the mine. Due to their large size, stoppings in large-opening mines are cumbersome and costly to construct and maintain. As part of its mining health and safety program, the National Institute for Occupational Safety and Health (NIOSH) designed and tested two novel stoppings (Super Stopping and the EZ-Up Curtain Stopping) at its Lake Lynn Laboratory (LLL). The Super Stopping is designed as a long-term permanent stopping for use in the main entries of the mine, while the EZ-Up Curtain Stopping, although very durable, is designed more for portability and ease of installation. This paper describes the design, materials, and construction methods used for these stoppings as well as their performance and durability when subjected to tests simulating actual production face blast pressures.

Jan 1, 2006

By G. V. Sullivan, B. E. Davis, T. O. Liewellyn

A technique was devised by the US Bureau of Mines to recover coarse [+1.2-mm (14- mesh)] North Carolina phosphate now discarded as waste. Concentration utilizes the difference in particle sphericity between the relatively flat calcite and the rounded phosphate pebbles. Sizing, treatment in a continuous hydraulic classification system, and grinding upgraded a 17% P,O5 reject to 4.5% P,05 with a phosphate recovery of 63%. The CaO: P2O5 ratio was reduced from 2.49 to 1.66.

Jan 1, 1987

By Suman Giri

Non-Intrusive Load Monitoring (NILM) is a method of extracting appliance-level power consumption information from aggregate circuit-level data with the goal of giving users feedback regarding their energy consumption so they can take control of their consumption habits. In this paper, we present a novel algorithm for classification of on and off states of appliances. We compare the performance of our algorithm in on state detection with a pervious paper that evaluated the same dataset and show that it performs up to 13% better. We also present the results of a case study where we collected data for different modes of a cooktop, microwave and dishwasher and used our algorithms to perform power estimation. The error on ten different setups in the test bed ranges from 1% to 32%. We discuss our results and lay out ideas for future work.

Aug 1, 2013