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By K. P. Stricker, H. Keddeinis, K. Grebe

Recent investigations by Mannesmann Research have shown that disintegration of sinter with widely varying quality levels is subject to a much more complex set of influences than was previously assumed. It was confirmed that disintegration at temperatures between 300° and 600°C (570°and 1,110°F) is triggered by the degradation of hematite. The specific tendency of hematite to disintegrate is, however, not constant: sinters containing the same amount of hematite can show widely differing disintegration tendencies, depending on structural homogeneity, porosity, and gangue quantity. Sinters with heterogeneous structures transmit stress to the hematite phase and this favors disintegration. Another factor is the brittleness of the glassy silicate phase, which can be influenced even by small modifications of minor gangue constituents.

Jan 1, 1984

By Takeo Ueda, Masashi Nakano

We have developed a new blasting system remotely controlled by an electromagnetic firing method, which has proved advantageously applicable to sites where rapid tidal current or deep water may cause serious troubles in underwater blasting operation by a conventional method.

Jan 1, 1983

Minimize the risk of conveyor belt fires in underground coal mines by improving the accuracy of and means by which flammability data are acquired. Approach Develop a large, laboratory-scale flammability test for mine conveyor belting that realistically assesses its fire resistance. Background A conveyor belt fire in an underground coal mine is a serious threat to life and property. To minimize the risk of belt fires, the U.S. Code of Federal Regulations (CFR) for underground coal mines requires approved fire-resistant belting. Despite this precaution, about 25% of the reportable underground coal mine fires from 1983 through 1988 involved conveyor belting. In several instances, hundreds of feet of belting were destroyed. The current flammability test for fire-resistant belting is specified in 30 CFR, Part 18.65 and is conducted by (be Mine Safety and Health Administration (MSHA). The small-scale test is performed in a 21-in-cubical chamber with 6-in-long by 1/2-in-wide belt samples. To evaluate the flammability of conveyor belting under more realistic conditions, the U.S. Bureau of Mines conducted large-scale fire tests of belting. The large-scale data were then utilized in the development of an improved laboratory-scale flame test for fire-resistant belting.

Jan 1, 1991

By A. K. Mukherjee

In this apparatus closed sized particles are placed in a container and then fluidized by passing water through the load of particles. Water flow is adjusted to deposit particles in one or more layers depending on the specific gravity of each of the particles, after which the deposited particles are separated in portions of different specific gravity. The obtained portions represent different ore content of the closed sized fraction. The process is repeated for all other size fractions to generate washability curve of the feed. Three different types of iron ores and one coal sample are tested in this equipment. The theoretical yield-grade curve generated for iron ore feed is unique in absence of any such practice for ore minerals. Similar curve is generated for coal and it is compared with washability curve, an existing practice followed worldwide. This comparison validates the performance of the process and the equipment.

Sep 1, 2012

By R. S. Dean

ALTHOUGH it is obvious that in any flotation process we must have a froth, in recent years the development of collecting reagents has caused the possibilities of better frothing agents to be overlooked. Some investigators have even gone so far as to say that the number of satis-factory frothing agents was sufficient. A little consideration will show, however, that the reagents available in the past were far from ideal frothers. The properties of an ideal frother for flotation work may be set down as follows: 1. It. must form in low concentrations a copious but not too persist-ent froth. 2. It must be insensitive to hydrogen-ion concentration of the pulp; that is, it must froth equally well in an acid or alkaline medium. 3. It must be insensitive to salts, even in high concentration. 4. It must be absolutely noncollecting to both sulfides and nonsulfides. 5. Its frothing properties must not be affected by collecting reagents, including soap, the most generally used nonsulfide collector. 6. It must readily emulsify and disperse any insoluble collecting agent that is likely to be used. Clearly the existing frothers do not qualify. Pine oil, for example, is an acceptable frother for many purposes but if used in soap flotation a delicate balance between pine oil and soap must be struck because, as pointed out by Coghill1, these two reagents are incompatible in certain concentrations. The objections to soap itself as a frother are obvious, and the cresols and their substitution products all have some collecting Dower and very little emulsifying power.

Jan 1, 1935

By Colquhoun L

Flooding velocities were measured in a laboratory column (96 mm 4) provided with both bottom and side air entry Packings used were 6 mm glass rings and spheres and -16 +8 mm coke. Results showed that when air was introduced through side nozzles flooding velocities were much higher than those obtained when air was introduced at the bottom of the column. Significance of the results and application to blast furnace flooding is discussed from the viewpoint of assymmetric gas flow.

Jan 1, 1975

By J. Hanna, I. Anazia

Selective fatty acid flotation of carbonate gangue from sedimentary apatites was achieved under acidic pHs without a specific apatite depressant and without conditioning the pulp with the collector. Concentrates (35% to 38% P2O5, 0.8% to 1% MgO) with high recoveries (80% to 85%) were produced from Indian and Chinese dolomitic ores. The calcareous and/or dolomitic-siliceous phosphate ores of South Florida and Utah required two flotation stages: one for carbonate removal, as mentioned above, and the other for phosphate recovery from siliceous gangue. Preliminary tests on the South Florida ore gave concentrates analyzing 29% P2O5 and 0.8% MgO, with a P2O5 recovery of 76%. A concentrate obtained from the western US phosphate ore from Utah assayed 30% P2O5 and about 1% MgO, with a P2O5 recovery of 89%.

Jan 1, 1988

By I. Anazia

Selective fatty acid flotation of carbonate gangue from sedimentary apatites was achieved under acidic pH's without a specific apatite depressant and without conditioning the pulp with the collector. Concentrates (35-38% P205, 0.8-1% MgO) with high recoveries (80-85%) were produced from Indian and Chinese dolomitic ores. The calcareous and/or dolomitic-siliceous phosphate ores of South Florida and Utah required two flotation stages: one for carbonate removal, as mentioned above, and the other for phosphate recovery from siliceous gangue. Preliminary tests on the South Florida ore gave concentrates analyzing 29% P205 and 0.8% MgO with a P205 recovery of 76%. Data are also included showing the applicability of the process to the dolomitic-calcareous-siliceous Western U.S. phosphate ore from Utah. A concentrate obtained from this ore assayed 30% P205 and about 1% MaO.

Jan 1, 1987

By M. D. Amirova

Cyanide-free technology of complex copper-lead ores flotation may be improved through enlarged range of pH values, enhanced copper recovery into copper concentrates due to additional recovery of secondary copper sulfides, as well as through enhanced efficiency of lead sulfides depression in process of new flotation modifiers-based selective separation. Study of the effects of flotation modifier (of metal nature) on minerals surface conditions proved that the xanthate is practically not adsorbed on the galenite surfaces due to minerals hydrophilization. Joint effects of sodium sulfite and modifier enhance process conditions for intensive galenite depression and at the same time for effective chalcopyrite and chalcosine flotation within a large pH values range (from pH=8 to pH=10). Identified mechanisms carry inference that proposed chemical reagent treating method is very promising for selective copper-lead concentrates separation. Potential use of carbon-containing materials as zinc flotation modifier to enhancing zinc recovery in processes of lead-zinc ores treatment has been studied. In our flotation tests we used Shalkiya (South Kazakhstan) lead-zinc ores containing such impurities as carbon shales, which presence impedes the process of saleable concentrates production and gives rise to excessive consumption of flotation agents due to the xanthate adsorption on the carbon. Lead and zinc concentrates were produced by process stages as follows: ores milled to 95% Cl. -0.074 +0; lead and zinc roughing flotation and further recleaner and testing operations. Test flotation in open process cycle resulted in enhancing zinc recovery into zinc concentrates by 21.1% and increasing zinc content in zinc concentrates by 3.96% that evidences promising potentialities for use of carbon-containing products as additional zinc flotation modifier. Works were carried out under National Program 2003~2005 of fundamental researches ?Physical and Chemical Mechanisms of Interactions in Multicomponent Solid and Liquid Systems Specific for Integrated Processing of Complex Metal-Containing Minerals and Technogenic Raw Materials? and contractual Agreement 2005 Optimization of Production and Technology of Shalkiya Lead-Zinc Ores Processing at Kentau Dressing Works.

Jan 1, 2014

By S. Ling, T. Liu, Y. Shang

A new copper-molybdenum flotation technology developed for a certain coppermolybdenum ore is introduced. We achieved copper-molybdenum bulk flotation in lowalkali conditions. Locked-circuit test results showed that the bulk concentrate contained 21.05% Cu and 1.10% Mo, with copper recovery of 87.37% and molybdenum recovery of 77.07%. For the copper–molybdenum separation process of the bulk concentrate, we use a new depressant, BK511, to replace the traditional sodium hydrosulfide. We achieved copper–molybdenum separation through one rougher, nine cleaner, and two scavenger processes. The results of locked-circuit tests showed that the molybdenum concentrate contained 46.19% Mo and 0.75% Cu, with molybdenum recovery of 93.80%; the copper concentrate contained 21.50% Cu and 0.069% Mo, with copper recovery of 99.92%. This new technology overcomes disadvantages of using large amounts of lime, sodium hydrosulfide, and other reagents in traditional copper–molybdenum flotation.

Jan 1, 2023

By X. Cao, R. Wang, H. Han, Y. Hu, Z. Wei, W. Sun, H. Tang, J. Wang

Flotation reagents play a vital role in mineral flotation. In the past century, most studies focused on the modification of anion or cation collectors and the synergistic effect of mixed collectors, which have contributed to research. In this study, we reviewed brand-new reagents, metal-organic/inorganic complexes, with the functional group of metal ion, which are totally different from the traditional anion or cation collector and show absolute specificity for some minerals. For example, Pb-BHA complex collector was developed to realise the atmospheric flotation of scheelite due to the absolute specificity for calcium minerals. Calcium oleate collector was found to be the effective species in the flotation of calcium minerals, and has been employed to selectively separate fluorite from calcite. Selective adsorption of Al-Na2SiO3 polymer on calcite surfaces proved the self-assembly of H2SiO3 polymer using Al3+ had stronger selectively adsorption ability than Na2SiO3. Also that Fe3+-starch complex was a better depressant for iron minerals than caustic starch and contributed to a more efficient reverse flotation. In conclusion, metal ions are good templates for molecular assembly and can be used to control the structure of metal complexes and exhibit special properties, which provide possibilities for the design of new flotation agents. Keywords: Metal-organic/inorganic; flotation; collector; depressant

Jan 1, 2020

By C. E. Jordan

The fundamental characteristics of ultrafine chalcopyrite flotation were investigated by the Bureau of Mines to establish techniques to improve recovery of ultrafine chalcopyrite. Intense agitation during conditioning was found to improve flotation recovery of the ultrafine chalcopyrite. A split-circuit flotation design, treating the plus 38-µm-size ore by the conventional method and treating the minus 38-µm-size ore with intense agitation conditioning followed by flotation, recovered 95.6 pct of the copper in a 28.3-pct-copper concentrate, This was a 5-pct increase in copper recovery over the conventional chalcopyrite flotation method.

Jan 1, 1986

By Robert B. Parsons

"A t last the legal red tape which has tied up flow-through share financing has been cut. New rules effective for deals signed after 1986 simplify flow-through financing by removing the necessity f or cumbersome agency relationships. But there is no free lunch-the new rules require increased government reporting. And beware federal tax reform promises to have a good look at the new flow-through share rules. IntroductionFlow-through shares have always worked better in theory then reality as an effective financing tool. The concept is straightforward: a transfer of risks, tax deductions, and potential returns. But the mechanics of the old flow-through rules made the transfer of risk impractical to impossible by placing the responsibility for incurring Canadian exploration expense (CEE) on investors. The new rules are significantly more realistic, shifting that responsibility to the issuing corporation. However, every silver lining must have a few clouds around it. In the case of the new flow-through rules, the more obvious negatives are increased reporting requirements and reductions in CEE eligible for flow-through by amounts of assistance received. The new rules are effective for deals signed after 1986, however, so a few old-style deals are still around. Practical Difficulties with Old RulesThe old rules which applied to investments in flow-through shares were structured so as to make it the responsibility of the investor, rather than the issuing corporation, to perform the Canadian exploration expense for flow-through. Since most investors had neither the expertise nor the inclination to incur the CEE, this requirement necessitated the use of cumbersome arrangements whereby the investors would appoint an agent (usually the issuing corporation) to incur CEE on their behalf. Although the issuing corporation might consequently be the party which actually spends the flow-through share funds on CEE, the awkward legal structure of such an arrangement made the investor the ""principal"" incurring the CEE. As such, the requirements of the old rules were met and the investors could receive their flow-through share s."

Jan 1, 1987

By A. M. Marabini, V. Alesse, Belardi. G.

An alternative flowsheet was designed for the flotation treatment of a complex sulfide ore from the Sotiel Mine in Spain. The ore contains 0.71% Cu, 2.24% Pb and 5.63% Zn. Two specially developed synthetic collectors, methyl-mercapto-benzoxazole (MMBO) and 6n-propoxy-mercapto-benzo-thiazole (PMBT), were examined. MMBO exerts a specific action on copper and zinc minerals after treatment with copper sulfate, and PMBT exerts a specific action on Pb minerals. Flotation operating variables (pH, frother type, frother quantity and feed particle size) were examined by means of rougher flotation tests to determine the optimum conditions for the new collectors. Once the optimum conditions were determined, a series of open flotation circuits were run on feeds of various particle sizes (obtained by different types of grinding). The objective was to obtain high-grade Cu and Zn concentrates. The results of the open-circuit tests demonstrated that a Cu concentrate grading from 18% to 23% Cu and a Zn concentrate grading from 40% to 48% Zn can be produced.

Jan 1, 1996

By O. I. Platonov

The experience that has been gained by MMC ?Norilsk Nickel? at its Trans-Polar Division (PD) operations since 1981 in the field of recovery of elemental sulfur from off-gas generated by the Vanyukov and flash smelting through its reduction by natural gas is briefly outlined in the present paper. The key challenge the operators treating off-gas originated from autogenous smelting are usually faced with is the presence of sulphur trioxide in it. Furthermore, air inflows along the entire gas flue increase oxygen concentration in off-gas, thus leading to over-consumption of the reducer (natural gas). Another issue attached to the methane technology is a low yield of hydrogen sulphide largely preventing efficient downstream Claus conversion of the gas. The new flowsheet for treatment of autogenous smelting off-gases including dry dust-cleaning followed by the gas reduction in homogenous reactor developed by OAO Gipronickel Institute on the basis of industrial-scale production of elemental sulfur in Norilsk is presented.

Jan 1, 2006

By S. Harshaw, C. Doyle, A. E. M. Warner, D. Stremlaw

"In the Utility Nickel furnaces, the hearth and sidewalls are lined with high-Al2O3 bricks. During charging and thermal cycling (more so as the linings on these reverberatory furnaces age), pieces of brick spall or abrade from the refractory and collect on the top of the bath. These pieces are removed using a non-corrosive slag toward the end of the heat when the bath temperature is ~1600°C.This benign liquid can be generated by two methods. First and most obvious, suitable ingredients can be pre-mixed so that the flux (flux A) is isochemical with the non-corrosive slag. All that is needed to produce this targetted slag is heat. Second, in other proportions (flux B), the pre-mixed ingredients generate a corrosive slag that melts completely at -1200 °C and corrodes some but not all of the brick particles on the bath surface. As the reaction progresses, the slag changes composition eventually attaining the targetted benign composition. Using this option, additions are monitored to avoid overfluxing. In both cases, the generated slag/brick mixture can then be rabbled from the furnace. This practice has been successfully used for over two years and has been a factor in extending Utility Nickel furnace life to its current levels (about25% increase)."

Jan 1, 1993

By Zachary Q. Maassen

The purpose of this paper is to highlight the environmental benefits of properly managing slurry waste as it is generated on site. The following projects will be used to illustrate the importance of proper onsite waste management. Project: Jet Grout Backflow Dewatering The goal was to dewater the backflow directly onsite to produce a dry, solid waste and reusable water. The backflow spoil was pumped directly to the dewatering system as it was generated. Utilizing mechanical separation equipment and flocculation polymer the waste volume was reduced by 44%. Due to the site footprint and high volumes, slurry waste removal and onsite processing were the only two feasible options. Onsite dewatering proved to be the environmentally beneficial option as it eliminated the need for slurry waste hauling and disposal. The benefits of utilizing a dewatering system are listed below: Project: Soil Mixing Spoil Recycling for Slurry Wall Construction In this application the spoils generated contain bentonite mud, cement mixture and organic ground soils. The goal of this project was to process the backflow mixture to recover reusable bentonite mud and separate the soil as a dry, stackable waste product. The treatment system replaced the traditional method of vacuum truck extraction and facility disposal. The environmental benefits of properly handling the backflow is a decrease in fresh water usage, bentonite additive reduction, and the reduction of CO2 emissions. The paper will consist of a project scope, technical equipment and process description, environmental impact reduction calculations and lessons learned for each project.

Jan 1, 2018

A major highlight of Fiscal Year 1993 is the completion of a new research facility dedicated to the advancement of robotics research and development. This new facility brings to the U.S. Bureau of Mines one of the largest and most unique facilities of its kind in the world. Located at the Bureau's Pittsburgh Research Center, the facility consolidates under one roof, all of the resource requirements of a first class automation and robotics research program. The Mining Robotics Development Center (MRDC) is the result of a major renovation of a large under-utilized warehouse-type structure and brings together the laboratories and offices previously housed in five separate buildings scattered throughout the Pittsburgh Research Center's 238-acre site. This new facility will support the computer-assisted mining research program, a high priority, multi-million dollar program that is expected to have a high impact on the health and safety of miners and coal productivity.

Jan 1, 1993

By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By Wonn Soh

As for Earth, where human beings live, approximately 70 % of its surface is covered by oceans. Today, advanced technology has led us to understanding the abyssal ocean floor through the use of submersibles and ROVs (remotely operated vehicles) for the last 30 years. Furthermore, the oceanic crust beneath the abyssal floor still remains an unexplored scientific frontier due to the lack of a direct approach. Exploration of this frontier is required to enhance our understanding of the mechanism of the M.8 class plate-subduction-type earthquake, of generation of the big tsunami, that caused the disaster, and of the paleo-global environmental change as well as of the origin of life as viewed in deep water thermal vents.