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By I. J. Wu

China’s land area, comparable in size to United States or Canada, contains diverse geological environments and mineral resource potential. The diversity in geological environments is such that the potential for developing many world-class mineral deposits in China is good. However, China’s mining sector was not open to foreign investment until the1990s. The long-term prospect for Chinese resource development is attractive because of China’s enormous population and cumulative demand for minerals. Approximately 33 foreign mineral companies, including 11 major internationals, are to various degrees active in China. Chinese mining laws and regulations pertaining to joint ventures with foreign companies are, from the international investment prospective, evolving slowly, but positively. This positive trend is continuing under the current government reform process, which is moving China towards a freer market economy. Although improving the enforcement of relevant laws and regulations is an ongoing process, the environment for mineral investment and joint ventures is increasingly more accommodating to foreign companies.

Jan 1, 2000

In the last few years a number of mineral laboratories were established in Indonesia coinciding with the increase in gold exploration in the region. Prior to this, much of the analytical work was sent outside the country,however this is no longer neccessary.

Jan 1, 1990

By Ralph Loyd

One of the principal responsibilities of the California State Geologist is to provide local governments with maps and information regarding mineral resource occurrences within their jurisdiction. The primary objective of this effort is to furnish basic data that is essential in planning for and accommodating wise development of mineral deposits that are important to the economic well-being of the region, state, and nation. Local government agencies are required by law to incorporate the information provided by the State Geologist into their general plans and formulate mineral resource management policies that emphasize conservation and development of mineral deposits. The Mineral Land Classification program was initiated by the State Geologist in 1977 under authority of the California Surface Mining and Reclamation Act (SMARA). To date, about 33,000 square miles of land have been classified for mineral resource potential. Most of the mineral land mapping has been conducted in three principal areas: (1) metropolitan areas of the state where urban encroachment has greatly diminished available supplies of construction aggregate; (2) Sierra Nevada foothills, a region that is undergoing dramatic population increases; and (3) the Mojave Desert and Great Basin regions, where large Federal land withdrawals are pending that could preclude mining. Mineral land classification studies address the overall mineral potential of a region through the identification of local and regional geologic factors that control or influence the formation of mineral deposits. These studies are field-intensive surveys that enable project geologists to gain first-hand knowledge about the nature and distribution of mineral deposits in a given area and portray that information accurately in map form. This paper summarizes the progress made in the Mineral Land Classification program in the metropolitan, Sierra Nevada foothills, and the Mojave Desert/Great Basin regions of California. Selected projects from each area are discussed in detail.

Jan 1, 1995

By P. G. Tzeferis

Factory beet molasses media were used as cheap sources of sucrose for microbial leaching of Greek nickeliferrous laterites using strains of Penicillium and Aspergillus sp. Nickel recoveries of up to 62% and cobalt recoveries of up to 50% were obtained by leaching in a two-phase system in which bioacids were produced by fungal metabolism in molasses ferrocyanide pretreated media. The addition of potassium ferrocyanide to the molasses substrates prior to leaching was found to have a beneficial effect by increasing the level of citric acid bioproduction, thus improving the leaching efficiency of the fermentation liquid. The metals known to interfere with citric acid production (i.e., Fe, Cu, Ca and Mn) were those most efficiently precipitated. Considering the much lower commercial price of molasses in the industrial market compared to sucrose and glucose carbohydrate media, molasses could prove to be a promising alternative, despite the cost of the required pretreatment.

Jan 1, 1995

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By G. Barbery

In Mineral Processing, the objective of most processes is the separation of mixtures of minerals, which are originally associated in composite particles. Feed preparation processes grinding for instance, which take place before beneficiation or separation processes do not usually break particles at the boundary between mineral phases. They produce composite ("middlings") as well as liberated particle. It is therefore necessary, in a particulate system, to determine the proportion of particles which are liberated as well as, ideally, the size distribution of minerals which remain associated in composite particles. Up to now, there has been a lack of experimental techniques to characterize completely composite particulate systems. Heavy liquid separation which is commonly used to obtain information of this type can only be applied to simple binary cases for which one mineral has a low density (lower than e.g 2.8 ). The technique which is proposed in this paper involves the measurement of parameters on polished sections of particles mounted in a matrix, and the use of mathematical transformations to reconstruct in three-dimensions the information obtained from these measurements .

Jan 1, 1977

By R. P. King

INTRODUCTION It is now 21 years since Wiegel and Li published their paper on a random version of Gaudin's model for the mineral liberation phenomenon (Wiegel and Li, 1967). This paper was to revitalise interest in North America in one of the most fascinating, difficult and important problems in the field of theoretical mineral processing. Gaudin had many years previously (Gaudin, 1939) already presented a penetrating analysis of the problem and Wiegel and Li based their analysis very closely on the Gaudin model but they realised that the indeterminate geometrical structure of mineralogical materials demanded that only probabilistic models could provide the necessary quantitative information when working with real materials. They proposed and solved a randomised version of the Gaudin model but retained the essential geometrical simplicity of cubic mineral grains and a cubic fracture pattern. Although their model met with some limited success it was to be superseded in due course. During the 1940's and 1950's the classical field of geometrical probability spawned the mathematical discipline of integral geometry and as early as 1965, Bodziony (1965, a,b) showed that the techniques of integral geometry could accommodate the problems associated with the indeterminate nature of the geometrical mineralogical structure, provided that these were couched in probabilistic terms. In particular he showed that the quantitative description of the comminution process and that of liberation could be decoupled with the resulting economy of effort. This idea has profoundly influenced the course of research in liberation theory and has greatly facilitated its application and the measurement of liberation in a practical way. Bodziony demonstrated also that any theory that required the specification of the mineral "grain

Jan 1, 1989

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills' grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By Rodrigo Fina Ferreira

This paper presents a mineral liberation study on two iron ore samples from the Quadrilátero Ferrífero, in Brazil: compact itabirite of low-grade metamorphism (CI) and friable itabirite of high-grade metamorphism (FI). The quartz liberation spectrum for both samples have been obtained through QEMSCAN analyses, carried out for several comminution degrees, to compare the liberation characteristics and to evaluate the evolution of the quartz’s liberation degree after fragmentation. The results have shown significant differences in liberation spectrum between the itabirite samples studied. The liberation process of FI was easier than of CI, due its high porosity and larger crystal size compared with CI, which has shown more complex mineral assemblages with low porosity and smaller crystals. The quartz liberation spectrum has shown that grinding at P95 of 0.210 mm for the FI sample, and of 0.045 mm for CI sample, should result in satisfactory liberation for subsequent concentration step.

Aug 1, 2018

By Schneider CL

The calculation of the liberation spectrum in the product from continuous milling operations is a problem of considerable importance, and it is difficult to solve because the population balance equation must be integrated in two-dimensional space. Complete solutions require a very detailed knowledge of the complex interactions between the fracture patterns and the mineralogical ore texture when brittle particles are subject to impact fracture. Most of the liberation models that have been developed to date apply only to batch comminution processes and under these conditions the liberation problem can be studied in isolation. When the comminution is continuous and forms a unit operation in a flowsheet that includes classification and separation operations, the situation is very different, and then the liberation of the minerals must be described when single particles of known mineralogical composition are fractured. Important industrial examples are conventional milling circuits closed by hydrocyclone and regrind mills in flotation plants. This paper presents an efficient computational algorithm for the calculation of the liberation spectrum produced by continuous milling operations. The algorithm relies heavily on the detailed internal structure of the Andrews-Mika diagram. The modifications that are required to make this diagram apply to practical ore minerals, and the internal structure of this diagram can be established using single-particle fracture on mono-size, mono-grade material but suitable liberation models are essential to interpret the data in terms of the cross transfer coefficients required for the population balance procedure. Models proposed by Leroux (1992) and King (1990) are compared to experimental data.

Jan 1, 1993

By Pina P, Pereira MJ

The increasing exhaustion of raw materials entails the exploitation of poorer orebodies where the target mineral occurs frequently in a very fine dissemination. Consequently it is necessary to grind more and more fine to achieve an adequate mineral liberation. In other words, it is of fundamental importance to know what size one should grind in order to avoid the following detrimental situations: 1. Excessive grinding - giving rise to the generation of ultra-fine slime particles which may be lost in the ulterior concentration process and simultaneously leading to higher energy consumption. 2. Incomplete grinding - giving rise to insufficient liberation and consequently leading to considerable losses of the valuable components in the tailings. Although this issue constitutes one of the most important steps in mineral processing, little research has been done compared to other processes, mainly due to the fastidious experimental work required. This paper describes a complete and integrated system of image analysis, where some algorithms to determine automatically the degree of li beration, for different levels of grinding, are proposed. These algorithms, mainly based on mathematical morphology theory were tested with images obtained from polished sections of different grain size fractions. Cases studies on a complex sulphide ore from an important copper and tin deposit located in the South of Portugal are discussed. Samples of the unbroken ore are also studied by image analysis to predict the degree of liberation obtained according to the fineness of grinding.

Jan 1, 1993

By J Addai-Mensah, W Skinner, C Kelsey, J R. Kelly, E Baawuah

Comminution continues to be the most capital-intensive unit operation in mineral processing. The fundamental purpose of comminution is to liberate the valuable minerals so that they can be economically concentrated into saleable products. Declining ore quality characterised by lower grade and increased complexity requires significant energy consumption for comminution. Low-grade magnetite ores are typically fine-grained and require fine to ultra-fine grinding (P80 ~ 30 - 40 µm) to enhance its liberation from the typically siliceous gangue matrix. Historically, this has been achieved using multi-stage crushing and grinding technologies, which require high energy consumption with low energy efficiency. This motivated innovations in energy efficient technologies for comminution. Such technology has been developed in the IMPTEC super-fine crusher. It is an innovative, dry (with the potential to be operated wet), media-free, energy efficient crusher that can to reduce 10 mm feed particles to 19 – 30 µm with very low recycle loads. In this study, the mineralogical and physicochemical characteristics of crushed magnetite ore using the IMPTEC super-fine crusher have been investigated in comparison with those of rod milling. The super-fine crusher generated higher liberated magnetite minerals in the – 300 + 212 µm and < 45 µm size fractions compared to rod mill. Both comminution devices generated large low-grade hematite and goethite middlings. However, the rod mill produced higher locked/unliberated hematite and goethite compared to that of the super-fine crusher. Quartz mineral had the highest liberation irrespective of the comminution device used. The super-fine crusher generated higher entrapment of other minerals within the silica matrix compared to the rod mill. The breakage mechanism of the super-fine crusher which is predominantly through high compression with shear, generated improved mineral liberation in the coarse size fractions compared to the predominant abrasion and attrition breakage mechanisms of rod milling. The higher mineral liberation generated by the rod mill is potentially due to the prolonged batch milling of the ore compared to the single-pass open circuit of the super-fine crusher.CITATION:Baawuah, E, Kelsey, C, Kelly, J R, Addai-Mensah, J and Skinner, W, 2018. Mineral liberation studies of IMPTEC super-fine crusher – 130 crushed product, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 313–326 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Timothy J. Napier-Munn, David M. Weedon

A model of mineral liberation was developed using back calculation techniques to determine breakage/liberation parameters in a similar manner to the way breakage parameters are determined in the Population Balance Model (PBM). Comminution and liberation data was collected from grinding mills operating at Pasminco lead/zinc mine Broken Hill, and Mt. Isa Mines copper concentrator, Mt Isa, Australia. Laboratory scale single particle breakage tests on ore samples from these sites were undertaken using a twin pendulum breakage device. Break- age/liberation parameters were then determined for several mills using back calculation techniques. The liberation/breakage parameters were then used to simulate mill liberation performance under varying conditions.

Jan 1, 1996

By M Thomas, M Caccetta, C Laukamp, A Hacket, M Jones, A Rodger, M Verrall, R Hewson

A mineral systems approach was used to interpret precompetitive airborne mineral mapping geoscience data for iron oxide copper gold (IOCG) exploration in the Starra area, Eastern Succession, Mount Isa Inlier. Selected minerals were chosen to map possible source rocks/fluids as well as intersecting structural/fluid pathways that could have transported mineralising fluids into domains of contrasting rocks/fluids where there was potential for physicochemical gradients to precipitate metals. Ferric and ferrous iron contents and white mica abundance were useful mineral criteria to identify theMount Dore Granite of theWilliams-Naraku Batholith as a potential source of æoxidisedÆ fluids rich in Fe, K and potentially Cu-Au. The Mount Dore Shear Zone (MDSZ) intersects the western margin of this granite with the highest contents and changes in composition of the white mica are peripheral to this contact within the granite. This together, with the fact that the entire N-S length of the MDSZ in the study area (~16 km) is abundant in white mica are evidence of K-rich fluids had preferentially moved along this pathway. To the south, the MDSZ intersects a domain comprising massive ironstone bodies as well as numerous graphitic horizons. This interpreted æreducedÆ domain is well mapped using the æopaqueÆ mineral products, as well as by white mica, which is pervasively developed and extends 2 km either side of the MDSZ fault into the meta-sedimentary sequences. The chemistry of this white mica also changes progressively away from the MDSZ, becoming more Si-rich (longer wavelength) towards the contact with massive ironstone bodies in the west and the graphitic units in the east, both of which represent sites of known Cu-Au mineralisation. Beyond these contact zones of interpreted æoxidised fluidsÆ with reduced rocks/fluids, there is either a rapid change to Si-poor white mica and/or no white mica developed, ie major æchemicalÆ gradient change. These mineral mapping results provide evidence for a direct link between possible source rocks and sites of IOCG metal deposition as well as extending the associated alteration zonation which had previously been mapped/published at the metre-scale to the kilometre-scale. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

The mineral matter has been isolated from a selection of Australian bituminous coals using low temperature (radio-frequency) oxidation or hydrogen peroxidation techniques and the species present identified by x-raydiffraction. Quartz, kaolinite, and a range of mixed layer clay minerals are the dominant constituents of the coals studied, with carbonate, sulphate, and phosphate minerals abundant in some samples. The clay bands thatoccur within these coal seams contain similar mineral assemblages to the coals themselves, but the lutites that form the inter-seam strata have a markedly different mineralogy, characterized by abundant quartz andillite and a low kaolinite content.The kaolinite is thought to have formed chiefly by interaction of silica and alumina in the waters of the coal swamp, aided by the catalytic action of organic acids, while most of the other clay minerals are probablydetrital. The absence of illite from Australian coals is not fully understood, but it may reflect the action of organic acids on the detritus in the swamp, coupled with deposition in freshwater rather thanmarine conditions. Pyrite, although present in some coal samples when fresh, may undergo oxidation during storage to form a number of sulphate minerals, some of which may interact with any calcite present toform gypsum.The mineral matter assemblage in the coal determines to a great extent the fusion characteristics of the ash.Unless abundant carbonates are present, coals with kaolinite-rich assemblages have a very refractory ash, while those rich in chlorite or montmorillonite have ash fusion temperatures between 1000 and 1300°C. Theinfluence of the minerals on coal preparation and coking properties is also brieflY discussed, as well as the potential of mineral matter studies in coal seam correlation.

Jan 1, 1978

By Jack E. Thompson

Thank you Tom and JM for that nice introduction. The remarks I am about to make rely on a large way on comments made by Barrick's Chief Counsel, Patrick Garver, to an internal meeting of Barrick's senior staff. I plagiarized so much from his notes that I thought that I should provide attribution. I did get his consent to borrow so freely. What I have done is take his general comments and used my conversations with CEO's and other participants in the industry to enhance the message with concrete examples that underscore the points I wish to make. What you are about to hear is my personal view – I am not speaking as a representative of any company. With that introduction, now would be a good time to give you the main theme of my talk: The SEC should change its rule making to a more public cooperative approach. If that were to happen the SEC would avoid some of the harm it has been doing to the companies in this sector and the very shareholders it seeks to protect.

Jan 1, 2003

By Frank R. Field, Joel Clark, Walter C. Labys, William A. Vogely

Mineral models provide a systematic and comprehensive approach for analyzing and fore- casting the behavior of mineral markets and industries.' They also permit the analysis of a wide range of policy decisions. Obviously such models cannot capture all of the intricate relationships that shape the behavior of a mineral market. However, such models have become extremely useful and in many cases support the decision making approach of judgmental analysts. They tend to narrow the range of likely outcomes and thus reduce the risks and uncertainties of investing, trading, and speculating in minerals. Mineral models provide not only answers to "what-if" questions, they also inform analysts of the benefits and costs associated with mineral investment decisions. More recently they have been applied to specific mineral issues of the possible impact of buffer stock stabilization schemes and of import supply restrictions. Mineral Models Defined Because mineral models are so diverse, we must begin with a fairly broad definition. A mineral model is a formal representation of a mineral market, industry or system where the behavioral relationships included reflect the underlying economic and engineering factors as well as the political and social institutions. Of ten, but not always, a mineral model will consist of some combination of the following components: demand, supply, inventories and prices. Modeling of demand behavior normally begins with an interpretation of basic demand responses to prices and income (i.e., the associated price and income elasticities). Price elasticities vary among different minerals and among their diverse uses. They tend to be lower for minerals without close substitutes than for those where such substitutes exist. In addition, these elasticities vary with time as well as with the actual excess demand or excess supply. Variations like these, coupled with the relative instability of prices for a number of minerals, make explanations of demand behavior difficult. The degree to which demand responds to changes in income depends on the income elasticity of the end products to which the minerals serve as inputs. Those products with a relatively low income elasticity tend to experience proportionally smaller swings in sales than those with higher elasticities. The transmission of demand cycles to minerals producers comes through a series of stage-of-process effects. Demand measurement also is influenced considerably by mineral substitution patterns. The cross-price elasticity of a competitive or complementary commodity also varies with minerals, markets, and time. Where minerals easily substitute for one another, as in the case of cop- per and aluminum in electrical conductor applications, cross-price elasticities are relatively high. Modeling of mineral supply behavior normally involves consideration of resource development, economic conditions, geologic

Jan 1, 1985

By JOHN R. SUMAN

IT appears now that the conflict with the totalitarian states will be a long-drawn-out struggle. The course of this war up to now indicates that this may well be the first major conflict where man power has not been the vital and determining factor. Mechanized warfare has made it possible for relatively small, well-equipped groups to outmaneuver and defeat large armies which lack the necessary modern equipment. Under these circumstances, ultimate victory becomes a matter of resources and productive ability. The important question is not how many soldiers can he put into the field, but the volume and speed in producing the armaments essential to ensure a victory. The resources available to the opposing nations and the efficiency of their systems of enterprise and production will be primary factors in determining the ultimate outcome. Germany had a head start of eight years in the armament race, and it is not easy to overcome such an advantage overnight.

Jan 1, 1942

By Charles W. Merrill

Obsolescence in the mineral world is virtually nonexistent if the term is taken to mean that a mineral commodity, once established in commerce and industry, subsequently has fallen into disuse. We are living in an age of minerals. Each generation puts an increasing array of mineral-based commodities, in larger quantities, to more uses than ever before. Bastnasite, a museum mineral and a collector's item a few years ago, is now produced in quantity at Mountain Pass, Calif. Uranium, a minor byproduct of vanadium mining in the Rocky Mountain plateau area before World War 11, has grown to be a leading mineral product in several western States. And finally the total quantity and value of minerals both in the United States and in the World establish new records almost yearly. Surely the mineral industry as a whole is not obsolescent in our economy. Nevertheless, there are particular uses for particular minerals that are obsolescent and some applications have been supplanted entirely. Tin does not occupy the prominent place in foil manufacture that it once did, and the schoolboy's slate left most classrooms before the oldest of us were born.

Jan 9, 1964

By F. J. Alcock

The Appalachian region of Canada comprises the three maritime provinces; Nova Scotia; New Brunswick; and Prince Edward Island; and that; part of the Province of Quebec lying south and east of Logan's fault. This; major thrust runs in a gently curving line from lake Champlain to Quebec; city and thence down the valley of the St. Lawrence to pass between Anticosti; island and Gaspe peninsula. To the northwest lies the St. Lawrence; Lowland division of the Interior Plains geological province; a region underlain; largely by early Palxozoic strata; which for the most part lie horizontal; or with low dips; where faults occur they are predominantly of the normal; type; and only locally are the beds cut by intrusive rocks. To the southeast; on the other side of the fault zone; an entirely different set of conditions is; encountered. There; Lower Devonian and older strata stand at high angles; are sheared and thrust faulted; and are intruded in many places by granitic; igneous bodies. The present paper is designed to outline briefly the geological; and structural history of this geological province and to emphasize; the part that structural conditions have played in connection with mineral; deposition.

Jan 1, 1954