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By J. A. Finch, G. Labonté

"A long-standing objective has been to obtain interpretable measurements of the oxidation-reduction potential in mineral slurries. For this purpose several sensing electrodes (black platinum wire, platinum foil and spiral, gold foil and spiral, and sulphide minerals such as chalcopyrite and galena) were investigated to determine their response to the presence of sulphide minerals in the pulp, and to the addition of reagents commonly used in flotation. The observed discrepancies between the electrodes may be explained using a combination of the classical mixed potential model for complex solutions and the probability of contact between the mineral particles and the sensing electrode. It is shown from laboratory testwork that gold spirals are preferred over platinum electrodes. Finally, some of the practical aspects of using the electrochemical measurements in a plant environment are discussed.IntroductonThe interpretation of flotation of sulphide minerals in terms of electrochemical (electron transfer) processes has brought new possibilities for process control of selective flotation. Investigations on massive and compacted particulate bed electrodes have shown that the flotation of a given mineral in the presence of a collector can be controlled by the potential induced on the mineral surface. Also, phenomena such as collector less (self-induced) flotation, activation by heavy metal ions, and natural selectivity sustained by galvanic coupling during flotation might also be controlled by electrochemical means.The technique for measuring electrochemical potential in slurries is an adaptation of that used for solutions. The measurement of the oxidation-reduction potential of a solution (ORP , Redox, Eh) is usually carried out by immersing a noble metal electrode (platinum, gold or silver) and a non-polarizable reference electrode: Standard Hydrogen Electrode (SHE), Standard Calomel Electrode (SCE), or silver/silver chloride (Ag/AgCl) in the solution. (The abbreviation Eh implies the SHE is the reference electrode.) The potential difference between the two electrodes is measured using a high impedance electrometer. ASTM standard D 1498-76 (revised 1981)(1) covers the practical details of such measurements; however, it does not deal with their meaning either in complex solutions or in mineral slurries ."

Jan 1, 1988

By Knud Sinding

Mining firms are widely criticised for their adverse impacts on the environment. At the same time many firms in the industry devote extensive resources, both financial and managerial, to the reduction or elimination such impacts. Very considerable improvements have been made, although these are sometimes overshadowed by a few high-profile accidents, such as the occasional collapse of a cyanide-containing tailings dam. In parallel, much effort is also directed at projecting a positive environmental image, as witnessed by extensive environmental reporting, both on paper and increasingly through web-platforms. Mining projects today almost invariably involve some form of environmental protection. In industrial countries regulations in this area are extremely stringent, as is enforcement. In less well developed countries, regulation and enforcement may be weaker, but firms are in many cases and for a number of reasons committing themselves to high levels of environmental protection, even if they might get away without doing so. Research in the area of environmental performance of mining firms has so far paid much attention to concepts such as sustainability indicators and the sustainability of individual firms. Given the still raging debates about the appropriate way to determine the degree to which any given firm is sustainable (Welford 1995) as well as the usefulness of what will in the final analysis be a value judgement, anyone on the sidelines of the debate will come back to the fundamental issue, how is knowledge that a particular firm has been judged ?sustainable? going to be made use of. This issue remains unresolved, which may explain the lack of progress in formulating a useful definition of a sustainable firm The question addressed in this paper is not so much about what firms are doing on the ground or in any particular case of environmental protection, but more in the subsequent use of these efforts - and by extension - on the overall direction of corporate environmental strategy. The fundamental problem facing all mining firms is that they cannot easily benefit from unilaterally reducing their environmental impact. The firm can of course avoid liability and keep a variety of stakeholders happy and hence experience lower costs of obtaining the [input] resources they need (in a broad sense, not just minerals), but this represents only part of the opportunities available form pursuing an environmental strategy (Reinhardt 2000). The other part, which may have an enormous potential, involves the concepts of competitor management and product differentiation. The logic of keeping stakeholders happy has been most forcefully argued by Pfeffer and Salanchick (1978) who link the behaviour of firms in all domains to their ability to obtain the resources they need, at a cost that is lower than it would otherwise be (Pfeffer & Salanccik 1978). Several varieties of strategy can be included under this heading, including cost reduction and risk management. The alternative logic is to convince customers that they want to pay more for minerals supplied by mining firm X or directly attributable to mine Y, or by making all mineral users pay more. These two strategies, which may be referred to as product differentiation and competitor management, respectively (Reinhardt 2000) are related to the demand side of mineral supply, whereas cost reduction and risk management are related to the supply side. Mining firms have not pursued the demand side very much, if at all. This is probably due to the extreme difficulty of moving mineral products, bulky and unglamorous as they are, away from their

May 1, 2003

By T. M. Morris

The forces acting between a small rod, one end of which was made water repellent, adhering to a much larger air bubble in water were measured. An equation is deduced which correlates these forces and the influence of each force is discussed. The importance of the size of bubbles in a flotation cell is emphasized.

Jan 1, 1950

By Johnson N. W, Manlapig E. V, Alexander D. J, Franzidis J. P

The importance of the froth region on flotation performance is often emphasised in the literature. It is well-known that decreasing froth depth or increasing air flowrate results in increasing cell recovery at the cost of lower concentrate gra

Jan 1, 1997

By R. V. Kumar

"The use of sensors to monitor gaseous species in industrial processes is discussed. All of the existing systems have disadvantages. Sensors, based upon solid electrolytes, which can be placed directly into the gas stream are attractive but many also respond to oxygen, need to be sealed at high temperatures and require a separate reference. This paper describes sensors, usually based upon two electrolytes, which do not respond to oxygen and do not require high temperature gas seals or separate references. The application of these sensors to the measurement of carbon dioxide, sulphur dioxide and trioxide and hydrogen chloride is described. These sensors can be placed directly into the gas stream at elevated temperatures.IntroductionOn-line gas sensing is becoming more important as concerns regarding the environment mount. There are many established techniques for monitoring gases in industrial processes, with applications in safety monitoring, chemical analysis or process and emission control. Flue gas analysis involves the greatest technical complexity, requiring several sophisticated capital-intensive spectroscopic instruments for different species as well as needing highly skilled operators. There are also several instruments, based upon aqueous electrochemistry, which are available for the analysis of the gases S03, S02, N02 but these require that the gases are sampled at high temperature and cooled, prior to analysis. These instruments cannot be considered as giving on-line measurements of the gas composition. Furthermore, the power requirement of these instruments frequently precludes battery operation for field and domestic use."

Jan 1, 1997

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

The velocity of gas passing through a flotation cell can be estimated by collecting bubbles by natural buoyancy in a closed tube and measuring the rate of pressure increase. The governing equation is derived and verified. Single- and two-tube gas velocity sensors are described. The latter design permits a correction for bulk density and level change during signal collection.

Jan 1, 2003

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

"The dispersion of gas into bubbles is an essential feature of flotation machines. Three measurements have typically been used to describe the dispersion: superficial gas velocity (Jg), gas holdup and bubble size along with the derived quantity, bubble surface area flux. Measurement devices continue to be developed. The McGill Jg sensor based on accumulating bubbles by natural buoyancy comprises a tube with a valve and pressure transducer (Figure 1). The tube is immersed at a desired location and depth (H1) in a flotation cell. On closing the valve pressure increases to a maximum (P1) when the tube is full of air. The Jg is estimated from the slope of pressure-time curve (dP/dt).The relationship between Jg and dP/dt is derived from first principles. Testing the relationship is difficult in a flotation machine as the spatial variation in Jg is generally not known. This problem is overcome using a specially designed experimental setup and the estimated Jg is shown to equal the known Jg.The derivation reveals the importance of bulk density (?b). The sensor was modified to provide an estimate of ?b (Figure 2). A second tube was added immersed to a different depth (H2) and kept full of accumulated air giving a pressure P2. The estimate of ?b is given by (P1-P2)/(H1-H2) (i.e., at the end of collecting the pressure-time data). This two-tube sensor also helps dampen process noise as illustrated by a sudden change in level when collecting the pressure-time curve. Both the original and modified versions have been widely used in plant test work."

Jan 1, 2003

By Elisabeth Tønnesen, Lloyd Tunbridge

"SUMMARY Injection grouting in rock around tunnels is used to reduce or stop water inflow. Little is known about the distribution of pressure within the rock mass during and after grouting. Instrumentation was developed to record pressure at the back of the packers inside the rock mass during injection grouting in order to improve our understanding of the process. Using this equipment measurements inside multiple injection holes during injection pumping have been made during several rounds of injection grouting in a tunnel. The data has been compared to the data recorded on the grout pumping rig and analysed to gain an understanding of the behaviour of grout injection process in the rock mass. The initial results are reported in this paper. INTRODUCTION Construction of a tunnel in soil or rock below the ground water table frequently results in the flow of ground water into the tunnel if the ground is permeable or fractures conductive. The injection of cement or chemical based grouts is frequently used during tunnel construction to reduce flow of water into a tunnel. Significant water flow into a tunnel is undesirable for several reasons: • there is a high cost in pumping out water over the lifetime of a tunnel; • drips and flows of water have to be diverted from the roadway or track; • where freezing conditions occur there is the possibility of ice build up and; • ground water levels may be changed possibly affecting surface water such as causing drainage of lakes and ponds, and changes in vegetation. Grout injection is most effectively done ahead of excavation to ensure that the grout penetrates the ground. Where heavy flows of water already occur into a tunnel the grout may be washed out before it sets. Normal practice in ground where water flows are encountered is to inject grout in a number of long holes ahead of the face with outer holes forming a ring around the proposed tunnel excavation – eventually forming a shield of grouted rock around the final tunnel, Figure 1. The holes may be sealed off a couple of metres into the rock with an expandable rubber plug around a pipe through which the grout can be injected, Figure 2. A one-way valve in the plug stops the grout from flowing back out of the hole when pumping stops and avoids grout flowing out through neighbouring holes. The rubber packer with a one-way valve permanently installed in the injection hole precludes the measurement of pressure down the hole when pumping is stopped."

Jan 1, 2016

By A. J. Davidson

A novel sensor is described for the measurement of the copper content of copper matte. Due to the high copper concentrations found in matte, potentiometric sensors are not sufficiently sensitive. A highly sensitive sensor has been developed based on a modification of the amperometric technique using a copper ion conductor, Cusicon. The results correlate closely with the theoretical predictions.

Jan 1, 1998

By David J. Dunn, Richard G. Martin

Of many physical parameters critical to design of grinding processes, impact of grinding media is among the most difficult to measure or predict. Yet impact of falling grinding balls, pebbles, or rods accomplishes the fine grinding essential to metallurgical recovery of most important minerals. Unfortunately, the same impacts that break ore fragments deform or crack grinding mill liners. A project was undertaken at Climax Molybdenum Company to measure impact forces in operating ball mills so that they might be used to calculate stresses in liner materials and be correlated with service performance of mill liner alloys. Towards that end, a method of measuring impact forces on ball mill liners using an instrumented grinding ball has been developed. Preliminary tests show that impact forces and contact stresses imposed on bare mill liners are quite high but are greatly reduced by cushioning when coarse ore particles are crushed between balls and liners.

Jan 4, 1978

By David J. Dunn, Richard G. Martin

Of many physical parameters critical to design of grinding processes, impact of grinding media is among the most difficult to measure or predict. Yet impact of falling grinding balls, pebbles, or rods accomplishes the fine grinding essential to metallurgical recovery of most important minerals. Unfortunately, the same impacts that break ore fragments deform or crack grinding mill liners. A project was undertaken at Climax Molybdenum Company to measure impact forces in operating ball mills so that they might be used to calculate stresses in liner materials and be correlated with service performance of mill liner alloys. Towards that end, a method of measuring impact forces on ball mill liners using an instrumented grinding ball has been developed. Preliminary tests show that impact forces and contact stresses imposed on bare mill liners are quite high but are greatly reduced by cushioning when coarse ore particles are crushed between balls and liners. Compressive and shear stresses induced in liners not protected by coarse ore are so severe that deformation or minute subsurface cracking are inevitable in all but the small production grinding mills, regardless of mill liner alloy strength or hardness.

Jan 1, 1979

By David J. Dunn

Of many physical parameters critical to design of grinding processes, impact of grinding media is among the most difficult to measure or predict. Yet impact of falling grinding balls, pebbles, or rods accomplishes the fine grinding essential to metallurgical recovery of most important minerals. Unfortunately, the same impacts that break ore fragments deform or crack grinding mill liners. A project was undertaken at Climax Molybdenum Company to measure impact forces in operating ball mills so that they might be used to calculate stresses in liner materials and be correlated with service performance of mill liner alloys. Towards that end, a method of measuring impact forces on ball mill liners using an instrumented grinding ball has been developed. Preliminary tests show that impact forces and contact stresses imposed on bare mill liners are quite high but are greatly reduced by cushioning when coarse ore particles are crushed between balls and liners. Compressive and shear stresses induced in liners not protected by coarse ore are so severe that deformation or minute subsurface cracking are inevitable in all but the small production grinding mills, regardless of mill liner alloy strength or hardness.

Jan 1, 1977

By N. Kumar, A. K. Dhawan, A. Varughese, S. K. Khullar

Abstract The in-situ stress field is one of the primary parameters influencing the performance of underground structures particularly in the Himalayas where there is strong influence of topography and geology on in-situ stresses. It is always advisable to measure the in-situ stresses, in whatever best way possible. Hydrofracturing is one of the methods by which in-situ stress can be measured. This paper briefly describes details of the concept of Hydrofracturing in arriving at the in-situ stresses of the rock mass at Pancheswar Project. The data obtained from the tests has been analysed, interpreted and the results are presented in this paper. Kurzfassung Das Spannungsfeld an Ort und Stelle ist einer der wichtigsten Parameter, die das Verhalten der Untergrund-Struktur beeinflussen, insbesondere in den Himalayas, wo die Topografie und die Geologie einen grossen Einfluss auf die oertlichen Spannungen ausueben. Es empfiehlt sich stets die Spannungen an Ort und Stelle so gut wie moeglich zu erfassen. Die Hydrofraktur bzw hydrografisches Zerstueckeln ist eine der Methoden, die bei den Messungen der oertlichen Spannungen verwendet werden koennen. Diese Abhandlung beschreibt kurz Einzelheiten ueber das Konzept von Hydrofraktur bei der Bestimmung der Spannungen an Ort und Stelle von der Felsmasse bezueglich des Projekts Pancheshwar. Die gewonnenen Daten aus den Messungen wurden analysieret und ausgewertet. Die Ergebnisse werden dabei vorgelegt. Sommaire Le champ de contraintes in-situ est un des paramèters principaux influencant l’exécution des structures souterraines particulierèment en Himalaya où les forces in-situ sont fortement influencées par les caractéristiques topographiques et géologiques de la région. La fracturation hydraulique est une technique qui permet de mesurer des forces in-situ des massifs rocheux. Cet article décrit brièvement le mécanisme de fracturation hydraulique et présente les résultats de mesure des forces in-situ des roches au site du projet hydroélectrique de Pancheswar.

Jan 1, 2003

By J. Butra

The underground research presented in this paper was carried out in the two Polish copper mines: Rudna and Polkowice-Sieroszowice. The aim of the research was to determine stress field parameters. The measurement method and measuring positions are described as well as the measuring technique adapted to the geological and mining conditions of the Rudna mine and the Polkowice-Sieroszowice mine. The identified values and directions of principal stresses and horizontal stresses and their importance for optimization of mining operation and safety improvement are discussed.

Aug 1, 2013

By K. Sugawara, H. -S. Jeong, Y. Ishiguro, J. Otani, Y. Obara, A. Hirata

A series of measurements of induced stress by the Compact Conical-ended Borehole Overcoring (CCBO) technique was performed within rock mass around a tunnel excavated in a region that an underground powerhouse is constructed under high initial rock stress. In the measurements, a phenomenon of core disking was observed during overcoring. The selecting method of strain data uninfluenced by the core disking was proposed, using X-ray CT scanner. Then, the state of induced stress determined from the selected strain data was discussed, comparing with the state of initial stress. Eine Serie von Messungen von induzierter Belastung mit kompaktem konisch-beendetem Überbohrverfahren (CCBO) wurde in Felsmassen um einen Tunnel ausgeführt, der in einer Region gebohrt wurde wo ein unterirdisches Kraftwert unter hoher anfänglicher Felsbelastung gebaut wird. Bei den Messungen wurde beim Überbohrverfahren ein Phänomen des Core Disking beobachtet. Die gewählte Methode der Belastungsdaten, unbeeinflusst durch Core Disking wurde vorgeschlagen, unter Verwendung von Röntgen-CT-Scanner. Dann wurde der Zustand der induzierten Belastung aus den gewählten Belastungsdaten diskutiert, unter Vergleich mit der ursprünglichen Belastung. Une série de mesures de contrainte induite effectuée avec la technique de forage de sur-carottage compacte à embout conique a été exécutée dans la masse rocheuse autour d'un tunnel excavé dans une région de construction d'une centrale électrique souterraine sous haute contrainte de roche initiale. Au cours des mesures, un phénomène de discage de carotte a été observé pendant le sur-carottage. La méthode de sélection des données de contrainte non influencée par le discage de carotte a été proposée, en utilisant un scanneur de tomographie calculée aux rayons X. Il s'ensuit que l'état de contrainte induite provoquée et déterminé à partir des données de la contrainte sélectionnées a été traitée, en effectuant une comparaison avec l'état de contrainte initiale.

Jan 1, 2003

By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By R. H. Brown

EARLY workers attempted to study the structure of alloys by measurement of equilibrium electrode potentials in aqueous solutions containing ions of the metals from which the alloy was made.1 The method was subject to such limitations (e.g., the difficulty in attaining electro-chemical equilibrium at low temperatures) that it has not been widely used by metallurgists. Recently, Seltz and co-workers have introduced a greatly improved method for studying alloys by measurement of equilib-rium electrode potentials in molten salts.2-4 The mathematical treatment is the same, of course, as for equilibrium potentials of amalgams in aqueous solutions.5 This method will probably find extensive use, since it makes possible not only the deter-mination of phase fields of equilibrium diagrams but also the determination of certain thermodynamic quantities which can be used advantageously in metal-lurgical calculations. However, the method presents difficulties. With many metallic and alloy electrodes, reversibility is not readily obtainable. Also, the difficulty of obtaining suitable material from which to make the cells is increased as the temper-ature is increased. Moreover, the necessity of carrying out measurements in a vacuum requires additional apparatus and intro-duces considerable difficulty, especially at the higher temperatures.

Jan 1, 1940

By William A. Hockings

Methods for the measurement of liberation of finely ground iron ores are described. The general method consists of separating a sample of the ground ore into a number of size fractions, followed by measuring the liberation of each fraction. The size separation has been done using electro-formed screens of 20-, 10-and 5-micrometer apertures, and also by air elutriation. Liberation (i.e., the distribution of compositions of individual particles) has been measured by optical microscopy. A computer pro-gram was used to adjust the raw count data so that it agrees with the chemical analyses of the size fractions. Various ways of presenting the results are given, and Some applications of the results to flotation processing are discussed.

Jan 1, 1981

By J. A. Bakken, M. Tangstad, P. A. Eidem

In the submerged arc production of ferromanganese, sillicomanganese and ferrochromium, the coke bed characteristics play an important role. The basic mechanisms of electric current conduction in the coke be dare not yet fully understood, but important parameters are the material resistivity of coke and the contact resistance between the coke particles. Preliminary tests indicate that the contact resistance is of great importance to the bulk resistance of the coke bed. An apparatus measuring the material resistivity and contact resistance of carbon materials has been developed. Both graphite and industrial coke have been tested. The material resistivity tests were performed on single particles to ensure that the effects of pores and cracks were included and the contact resistances were excluded. Two geometries were tested to obtain the contribution of the contact resistance to the total resistance of two connecting particles. The tests were performed in an inert atmosphere at temperatures and current levels found in industrial submerged arc furnaces. The results show that the method has a satisfactory reproducibility. It was found that the contact resistance is about 10 times higher than the resistance of the material when two particles are in perfect contact and that the resistivity of SSAB coke is more than 10 times higher than that of the graphite at room temperature, but with increasing temperature the difference decreases. For SSAB coke the general trend is that both the resistivity and the contact resistance decrease with increasing temperature.

Jan 1, 2007

By B. Xu

Keywords: Magnetic damping, g-jitter, Hot-film anemometry Results from an experimental study on natural convection induced by temperature gradient in molten gallium contained inside a rectangular container. The damping effect of the convective flow from an externally applied static magnetic field is investigated. Induced velocity and temperature fields are mapped using a standard constant temperature hot-film anemometry and a thermocouple with and without the applied magnetic field, respectively. Detailed experimental setup and procedure are depicted in the present paper. Obtained velocity and temperature profiles are examined against previous numerical simulations and reasonably good agreement has been achieved. Obvious damping effect can be observed in both the temperature and the velocity profiles when the external magnetic field presents.

Jan 1, 2005