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By C Li

Removal of gangue minerals from ilmenite concentrates can beaccomplished by relatively low temperature roasting in controlled gasatmospheres to selectively enhance the magnetic separationcharacteristics of the ilmenite. At roasting temperatures below 800¦C the magnetising reactions are often not consistent with phase equilibria considerations. Metastable phases can nucleate and control the roasting products. In weathered ilmenites the phase assemblages and microstructures in the altered ilmenite grains can influence the roasting reactions. In this paper we give an overview of the phase chemistry of chemically weathered ilmenites and of metastable phases formed by low temperature roasting. We also report the results of roast experiments conducted in a neutral gas atmosphere. Major increases in magnetic properties after short roasting times at low temperatures were obtained for a range of ilmenite concentrates. For example heating a secondary ilmenite concentrate from Western Australia for 15 minutes in nitrogen at 600¦C gave an increase in the three kilogauss magnetic fraction from three to 92 wt per cent. The solid state phase changes accompanying the inert atmosphereroasts were characterised by combining elemental analyses withquantitative phase analyses of the ilmenite concentrates and their roast products. It was found that the phase reaction that is principally responsible for the increase in the magnetic properties of weathered ilmenites involves a transformation of disordered ferrous-containing pseudorutile to an ordered ilmenite-hematite solid solution containing typically ten to 35 mole per cent of the hematite component. Examples are given of the application of the inert atmosphere roast to effect separations of ilmenite from gangue minerals.

Jan 1, 2001

By Djona M. Gaballah I.

Selective chlorination of unroasted and roasted spent hydrorefming catalysts was studied between 300 and 600°C using the following gas mixtures : C12+CO, C12+N2 and CI2+air. Such materials contain Co, Ni and Mo compounds supported by alumina and/ or silica. They also contain variable amounts of V compounds, C, S, etc., accumulated during the life time of the catalyst. Direct oxychlorination of the C+S rich sample allows higher extraction rates than those obtained by the carbochlorination of the same roasted one. It seems that the roasting step doesn't favor the economic metals' recovery. Results of the chlorination of C+S poor spent catalysts, in the presence of CO, in the chlorinating gas mixture, or of carbon added to the sample, were comparable. Cobalt and nickel chlorides were .extracted from the chlorination residues by their dissolution with acidified water, whereas molybdenum and vanadium chlorinated compounds were recovered by selective condensation from the vapor phase. The recovery rates of valuable metals as well as the selectivity were higher for the chlorination of spent catalysts than results obtained by the hydrometallurgical processing of the same sample. Results of the scale-up of the oxychlorination of the unroasted sample confirmed those of the laboratory scale. The global recovery rates were about 88 pct of cobalt, 93 pct of molybdenum and 76 pct of vanadium. The carbochlorination was applied to the recovery of W and Ti from Denox catalyst that is a carbon and sulfur free one. Recovery rates higher than 99 pct at temperatures lower than 500 °C could be obtained. This may indicate that the chlorination process can be applied to the treatment of various industrial wastes or by-product containing transition and/or refractory metal compounds A flow - sheet for the pretreatment of these materials is proposed.

Jan 1, 1995

The effect of temperature, time and SO2 concentration in the atmosphate have been studied for a complex Pb-Zn concentrate, which contained four sulphides and some organic material, in order to determine optimum roasting conditions. Under static roasting conditions virtually complete sulphation was achieved after roasting at 650¦C.2 hours in 10% SO2 in air. Both zinc ferrite and zinc silicate were observed to form early in the roasting, but continued exposure to SO2 -containing gases caused decomposition of these as the roasting time increased. Water and acid solubilities of iron, silica, calcium, magnesium and aluminium in the calcine were determined, as a function of roasting time, temperature and atmosphere composition.

Jan 1, 1970

By C. S. Barrett, O. R. Trautz

PREVIOUS investigations have shown that lithium is body-centered cubic from near its melting point to the temperature of liquid air1,2,3 Nevertheless there was an incentive to search again for a transformation at low temperatures: C. Zener4,5 has remarked that the low value of the elastic modulus (11 - C12)/2 of body-centered cubic metals and alloys implies a rapid increase in free energy with decreasing temperature, which would favor the occurrence of a transformation; also the shear movement to which this modulus applies is one that can transform a body-centered cubic structure into a slightly distorted face-centered cubic structure. It was confirmed that lithium does not transform spontaneously at liquid nitrogen temperature, but it was found that a transformation can be induced at this temperature by cold working the metal,6 and at slightly lower temperatures a different transformation occurs spontaneously. Transformations were also found in solid solutions of magnesium in lithium. THE NATURE OF THE TRANSFORMATIONS Before presenting a detailed treatment of the technique used and the specific data obtained, it would be well to give a brief survey of the general characteristics of the transformations. A new crystal structure begins to form spontaneously in a specimen when it is cooled below a critical temperature. In lithium the structure appears to be close-packed hexagonal; in the Li-Mg alloys most of the diffraction lines (but not all) are near those for hexagonal lithium. The transformation proceeds as the temperature is lowered and soon stops if the temperature is held constant or raised. The course of the transformation on cooling is indicated by the curve at the lower left of Fig I. This curve is drawn in stepped fashion because the transformation goes by discrete steps with audible clicks. Because of the similarity to the decomposition of austenite into martensite in steels, it seems appropriate to designate the beginning of the spontaneous transformation on cooling as the Ms point. On heating to room temperature after the low temperature treatment only the usual BCC structure is found. On heating, the low temperature modification begins to disappear at a temperature which will be designated as Ac. The transformation on heating is halted when the rise in temperature is halted. The temperature must be raised 40 to 50°C above Ac before the reversion is complete-an interval which is sensitive to the rate of heating and to the time of holding at temperatures above Ac. This behavior on heating thus has similarities also to the formation of martensite in the cooling of steels.

Jan 1, 1948

By Thomas C. Rube, T S. Bajpayee

The Bureau of Mines conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) saves energy, reduces oil imports, and reduces mining costs.

Jan 1, 1996

Productivity of mines can be improved by taking fewer, but larger blasts. The initial blasts taken in starting a mining block are restricted by the low amount of void or space to fire into. Block cave mines are using a blasting technique to blast areas that have less than the normally accepted minimum void to establish drawbells for their orebody development. This technique used in block caving mines can be used to improve productivity in mining operations that utilise other mining methods. Some larger blasts have been done in mines, using open stoping methods, which have had void ratios as low as 13 per cent. This has been possible with the use of the explosive gases to transport the broken rock out of the area normally considered to be available to blasts. This trapping of the explosive gases in the broken rock has allowed rock to be moved over 30 m, horizontally, to allow for more void to be available in the blast area. This gives the necessary void ratio allowable to fire larger blasts. This paper will discuss the blasts where this technique has been used in mines to increase the tonnes fired in low void situations. It will also discuss where this type of blasting may improve the productivity of underground mines. Figure 1 shows the how explosive gases have enabled the broken rock to flow out of a draw point without the typical air blast and fly rock that would normally cause a rope suspended sign to be damaged beyond use.

Jan 1, 2008

By H. B. Pulsifer

ONE of the most common basic open-hearth furnace products is a simple carbon steel with a carbon range from 0.05 to 0.15 per cent. The material is widely used for sheets, tubes, bars, wire and the innumerable special objects of secondary fabrication. The properties of the material vary over wide ranges, depending on the more exact composition and details of manufacture or treatment that affect its structure. The present paper is a review of those properties and structures that have been found by studying this steel as used in the cap screw industry. At first glance this might be thought a narrow application of the steel, but, since the industry uses the material in the cold-worked, annealed and heat-treated conditions, the title of the paper may be excused for its comprehensiveness. Yet, in studying the wide ranges of properties and structures that preclude a more specific title, there can be no suggestion of completeness or finality. Even a summary of a few years' work is no more than a preliminary survey of a field that will be fertile in scientific data and industrial products for many years to come. An outline of the structures will be given first, then a list of the previous contributions that are at hand and finally some details of the work and related problems, especially concerning this low-carbon steel in the surface-hardened condition.

Jan 1, 1931

By S. W. Evans, G. Pienaar

Weldable steel plate with a good combination of strength and toughness is currently produced from 0,12 to 0,28 per cent carbon low-alloy steel heat-treated by roller quenching and tempering. Alternatively, steel plate of the same strength can be produced at a lower production cost by the use of very-low-carbon steel (0,03 to 0,08 per cent carbon) processed by in-line quenching without tempering. This paper reports the results of experimental work on these steels, and compares them with the properties of conventional steel. On thinner sections, it was found that the properties of the experimental steels compare favourably with those of conventional grades.

Jan 1, 1989

By D. Tsweleng

In the Evraz Highveld production process, iron ore is prereduced in rotary kilns prior to charging into submerged arc furnaces (SAFs). Owing to the highly aggressive slags that are formed within the combustion zones of these kilns, chrome-oxide-containing lowcement castables have been used for some years in the kiln lining. Due to concerns around the potentially harmful effects should Cr(V1) be present in the spent linings, Highveld and its suppliers of kiln castables devoted time to developing alternative chrome-free lining materials. Such materials needed to be cost-effective and ensure good performance and improved kiln availability. This paper discusses all the parameters surrounding this development. Keywords Low-cement castable, chrome-oxide free, chrome (VI), titaniferous magnetite ore, rotary kiln, submerged arc furnace, open slag bath furnace, Evraz Highveld Steel & Vanadium Limited.

Aug 1, 2013

By J. Langwaldt

Ammonium-nitrate is a main component in blasting agents and dissolved ammonium residues may be discharged with mine water. The European Union aims to reach a good state of the water quality and recommends ammonium content below 0.5 mg/L for drinking water. Natural zeolites adsorb ammonium from water. In this work, the removal of low-concentration ammonium by commercial natural zeolites was studied in continuous tests. Natural zeolites made up between 83% and 95% of the mineral composition. The major zeolite minerals were chabazite and clinoptiolites and minor amounts of erionite and mordenite were as well present. The five natural zeolite samples, 500~710 µm, were conditioned to obtain zeolites in the Na-form. Ammonium adsorption onto natural zeolites depends mainly on the zeolite mineral type. The chabazite containing zeolite was superior over the four clinoptiolite samples for the removal of low concentrations of ammonium from water (pH of 7.5, flow 5 mL/min, room temperature). The adsorption capacity of chabazite was 48.3 mg NH4+/g zeolites, i.e. 73% of the theoretical exchange capacity 69 mg NH4+/g, during duration over 107 days and almost 6700 bed volumes exchanged. The four tested clinoptiolites had an ad-sorption capacity of 15.7mg to 25.0 mg NH4+/g zeolites. The natural zeolites were rapidly regenerated by an alkaline sodium chloride solution fed to the columns.

Jan 1, 2014

Forty-three years ago a record for low cost was made at the Spanish mine, in Nevada county, California. In 22 days of September, 1887, there was mined 2796 tons of ore at a cost of 37.5 cents per ton, of which 32.4 cents was for labor and 5.1 cents for supplies. The mill treated this ore for 23 cents per ton, of which 12.3 cents was for labor and 10.7 cents for supplies. Thus the total operating cost was 60.5 cents per ton. The yield was $1.16 in gold per ton, leaving a profit of 56 cents per ton, or 48 per cent of the yield. The mine was an open-cut in a schist formation on a hillside and the work was done by Chinese laborers that were paid $1.40 per shift. The ore was soft, and could be ground effectively in four Hunting- ton mills, supplemented by silvered amalgamating plates.* The engineer in charge was F. W. Bradley, a student from the University of California. As has been indicated, the conditions were unusually favorable in respect of softness of ore, accessibility to the mill, metallurgic simplicity, with cheap labor and power, but even at that the results were so remark- able as to attract general attention, which, as might be expected, was magnified, for advertising purposes, by the manufacturers of the Huntington mill, the firm of Parke & Lacy, at San Francisco. The record made at the Spanish mine therefore found its way into many textbooks on mining published at that time. The editor of the 'Mining and Scientific Press'† (at that date, Charles G. Yale) evidently took a warm interest in. the

Jan 1, 1932

By Jennifer Ward

The primary objective of this paper is to establish how a low cost, high definition (HD) camera can allow for easy sustainable recordings of blasting operations. The subsequent analysis of each video can be utilized to monitor what type of performance was achieved and aids in improving blasting performance.

Jan 1, 2015

By D. A. Sloan

THE Young Davidson mine is of particular interest because of the extremely low costs and also because of the novel method devised for pillar recovery. The outstanding feature of the mining system is its simplicity and regularity. The successful operation of this property was de-finitely assured by the rise in price of gold in 1934. The mine is situated in the southeastern part of Powell township, about forty-five miles southeast of Timmins, Ontario. The local town, two miles distant, in Matachewan, which is twenty-five miles northwest of Elk Lake, the terminus of a branch line of the Temiskaming and Northern Ontario railway. Mining is confined to one of a group of five claims. The ore occurs in a body of syen.ite porphyry which is intruded along a contact of Timiskaming conglomerates with Keewatin altered ruffs and greenstones. This intrusion extends in a north-easterly direction from Davidson creek for 3,300 feet, of which length 700 feet lies within the Matachewan Consolidated property. The maximum width of the mass is 700 feet; it tapers off as it extends east-ward. The Orebody.-The syenite porphyry is of three types, probably all differentiates of the same magma, but only one of them is gold bearing. This is a cherry-red, coarsely crystalline type which forms the central part of the mass. It is more brittle and more fractured than the others, and consequently has allowed easier access to the gold-bearing solutions. The gold has been brought in by a branching system of quartz veins and along minute fractures. It is mainly in the form of very fine 'free' gold, but also occurs in pyrite, which is the chief metallic mineral.

Jan 1, 1942

By Marco Silva

Underground mines are complex environments that require continuous control and monitoring actions in order to have a safe and efficient operation. At Nexa, the goal of achieving "zero harm" promotes the constant search for in its operational processes. Currently, there are manual activities that reduce the agility and precision when working with information from inside the mine, using mostly radio communication and management by sight of badges as an operational standard. This project was born in the context of increasing the operational safety of underground mines, bringing gains to the entire process involving the underground.

Sep 29, 2023

By Nagel, Theodore

USE of oxygen in metallurgical operations was investigated by a committee of unusually able engineers more than ten years ago. A record of their work appeared under the title "The Use of Oxygen or Oxygenated Air in Metallurgical and Allied Processes," Serial 2502, Report of Investigations, U. S. Bureau of Mines. Shortly thereafter the A.I.M.E. published "Use of Oxygenated Air in Metallurgical Operations," based on a symposium at the New York meeting, February 1, 924. Quoting from the Bureau of Mines report In view of the many recent developments in oxygen manufacture, and considering the increasing cost and decreasing quality of our raw materials, the Bureau of Mines has taken the matter of the application of oxygen or oxygenated air to the metallurgical centers for consideration and has appointed an advisory committee to study the problem.

Jan 1, 1935

Blasting in a gold mine has to satisfy the following set of techno economic conditions: good fragmentation, minimum stopped width, minimum number of rock falls, cost effectiveness. Results of a comparative study of the performance of a Low Density Anfo (LDA) and a conventional Anfo (ANFEX) are discussed. LDA appears to be more cost effective. The same borehole volume can be charged with material of reduced specific gravity. The velocity of detonation (VOD) is increased in the case of LDA resulting in more breakage as a result of shock energy than from the energy in the gas phase. This leads to less damage to the excavation and more favourable breakage of the excavated rock. As a result the overall economics of the mining operation is improved.

Jan 1, 1995

By C. E. Rodgers

WHEN I was asked to prepare, for presentation at the 1938 Annual Meeting of the Institute, some data concerning low-discharge grinding at the Sylvanite mill, it seemed entirely reasonable to expect to have at my disposal the results of at least four full months' operation after the last unit, as then proposed, was installed. Delays in delivery of equipment, nevertheless, shortened the interval, as will be shown herein. In submitting the data contained in this discussion, I wish distinctly to state that the intention is not to claim that final conclusions can be reached at this time concerning our operation. Test periods, in certain instances at least, have been too short for this purpose, although some, where so stated, have been extended through March and April. It is hoped, however, that an advantageous trend in practice can be shown and that the experience related may be of interest to others who are now operating, or who are considering the operation of, low-discharge grinding mills. In the plant under review, four mills are in use: one primary and three secondary. Present mill capacity (grinding, as shown by screen test, about 99 per cent through-200-mesh and approximately 88 to 89 per cent minus-325-mesh with infrasizer giving about 90 per cent of the latter) averages about 525 tons per day. A brief description of each unit will be given and comments will also be made relating to operation. This will be followed by certain test data from which, in conclusion, operating results are summarized.

Jan 1, 1938

By King R. L

Low-enthalpy geothermal groundwater resources occur at relatively shallow depths in the Upper Cretaceous/1'ertiary sedimentary sequence in the on-shore Gippsland Basin. The main stratigraphic unit containing hot groundwater is the Latrobe Group. Groundwater temperatures in the range 30 to 70¦C have been recorded from depths between 500 and 1000 m. The hottest groundwater is in the Latrobe Valley and Lake Wellington depressions. Geothermal gradients in these areas range from less than 2¦C/100 m to over 10¦C/100 m (compared to a world average of about 3¦C/100 m). A number of theories have been advanced to explain the geothermal anomalies including exothermic reaction such as oxidation of coal, mixing with deeper, hotter groundwater and high geothermal fluxes along fault zones. Variations in geothermal gradients can also result from type and thickness (and hence thermal conductivities) of the sedimentary pile, depth to consolidated basement rocks, and influence of groundwater flow patterns including proximity to recharge zones. The hot groundwater in the Gippsland Basin has substantial potential as a source of energy for direct heat applications such as process heating, space and water heating for buildings, and agricultural and aquaculture. Geothermal energy has a number of environmental advantages over traditional sources of energy. It is clean, safe, causes minimal land disturbances and in most cases is naturally renewable.

Jan 1, 1992

By Mark S. Stagg, David E. Siskind, Stephen V. Crun, Willard E. Pierce

The USBM is studying the impacts of low-frequency blast vibrations on residences to assess both response and cracking potential. Complementing coal mining sites monitored in the midwest and east, vibrations were analyzed at a major construction site in southern Florida where potentially serious low-frequency blast vibrations were believed to exist.

Jan 1, 1996

By Bruce R. Lipin

Chromite, the only ore of chromium, occurs almost exclusively in mafic-ultramafic rocks and their weathering products. However, not all kinds of mafic-ultramafic rocks are favorable hosts for possible low-grade chromite deposits. For instance, chromium-bearing basalts are not favorable because they commonly contain <0.3% Cr203, and chromite is almost always less than 50 mp in diameter, if it is present at all. Chromite-bearing ultramafic rocks in stratiform and alpine complexes tend to be either ore grade (>25% chromite) or very low grade (<2% chromite); intermediate rocks are scarce. In most complexes, large tonnages exist only in the <2% chromite rocks and the composition of the chromite in those rocks may be unsuitable for metallurgical use. Some nickel laterite districts contain more than lo8 tons of material with 2.0 to 5.5% Cr203, and hence, chromium could be a byproduct of nickel in some laterite districts. In addition, some chromiferous sand placers may contain tens to hundreds of millions of tons of material between 2 and 5% Cr203

Jan 1, 1983