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By Yasuhiro Konishi

Hydrolytic stripping is the process in which metal ions are simultaneously stripped from a loaded cation-exchange solvent extractant and precipitated as oxides or hydroxides. Hydrolytic stripping is usually effected by contacting the loaded organic phase with water at elevated temperatures. The possibility of using hydrolytic stripping to prepare ceramic powders with controlled size and morphology is now being evaluated for different systems, using carboxylic acid extractants. As part of this work, mathematical models were developed to describe the kinetics of nucleation and growth of nickel ferrite particles. This paper describes the development of the models, along with estimation of key parameters appearing in the rate equations from experimental data.

Jan 1, 1990

By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

By Anastasia Alksnis

Pyrrhotite is an iron deficient, low nickel content sulfide mineral that is commonly associated with pentlandite, a nickel-rich sulfide; and are both main components of the nickel ore mined in Sudbury. Pyrrhotite tailings generated in the concentration of Ni ores are stored in tailing reservoirs and presents serious environmental risks including acid mine drainage. This study investigated the potential of converting pyrrhotite into a valuable resource through the use of fluidized bed roasting, in which the mineral will be oxidized to produce iron oxide and SO2 gas. These products can then be used to create iron for high-grade steel and elemental sulfur. Thermogravimetric analysis of Sudbury pyrrhotite was performed to study the oxidation kinetics, supporting the feasibility of this process. Further, energy and materials balance was carried out to establish the basic parameters of a possible roasting process.

By Alexander E. Sobolev

The kinetics of oxidative dissolution of lead sulfide in solutions of nitric acid and sodium hypochlorite was studied using the rotating disk method and the factor experiment design. The dependences of the PbS dissolution rate on concentration of oxidant (HNO3 or NaOCl), temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific dissolution rate at any combination of values of the influencing factors were obtained. As a result of the complex analysis of kinetic parameters, the modes of the each process proceeding were established, their macromechanisms were determined, and the limiting stages of the oxidative dissolution processes were revealed. The dissolution kinetics of lead sulfide in solutions of nitric acid was found to have several regimes. At HNO3 concentrations below 0.5 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled. It is caused by low oxidative activity of HNO3 and considerable diffusional diffuculties at this acid concentration range. At the nitric acid concentrations more than 0.5 mol/L and less than 6.0 mol/L, the process was found to be kinetically controlled. The limiting stage of the interaction is the surface chemical reaction. The observed relatively high order of the dissolution rate with respect to the concentration of HNO3 was explained by the autocatalytic action of the acid reduction products. At nitric acid concentrations exceeding 6 mol/L, the process proceeds in a mixed mode close to a diffusion-controlled, and the dissolution rate sharply decreased that was explained by a decrease in the solubility of reaction products. When lead sulfide is dissolved in sodium hypochlorite solutions, at first time the amount of PbS transferred into solution remains close to zero. Gradually, as time goes, this amount begins to increase sharply. The dissolution rate rises and reaches the maximum value, further remaining constant. At the steady-state regime, the dissolution rate is independent of the duration of interaction and disk rotation frequency. The process was found to be kinetically controlled. The limiting stage is likely to be chemical reaction on the surface of solid lead sulfide. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulfides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of lead-bearing ores and concentrates. Keywords: lead sulfide, nitric acid, sodium hypochlorite, hydrochemical oxidation, dissolution kinetics

Sep 1, 2012

By I. Gaballah

The kinetics of oxychlorination of pure CI-2O3 with C12+02 gas mixtures is studied by ThermoGravimetric Analysis (TGA) in non and isothermal conditions up to 1000 °C. The reaction of Cr2O3 with C12+O2 chlorination gas mixtures starts at about 550 °C and the reaction product is CrO2Cl2. The oxychlorination rate of Cr2O3 is almost proportional to the chlorine partial pressure and to the fourth root of the oxygen partial pressure in the chlorinating gas mixtures. At 800 °C, the maximum chlorination rate is obtained using a gas mixture having a C12/O2 ratio equal to 4. The apparent activation energy of the oxychlorination reaction of Cr2O3 is 87 and 46 kJ/mol at temperatures lower and higher than 650 °C, respectively. By varying the chlorine and the oxygen partial pressures of the oxychlorinating gas mixtures at temperatures higher than 550 °C, it is possible to extract selectively the chromium chlorinated compounds from the chromium bearing materials. a. Laboratoire Environnemem et Minéralurgie, BP 40, 54501 Vandceuvre, France, b. École Nationale Supérieure de Géologie, Rue du Doyen Marcel Rouhault, 54501 Vandoeuvre Cedex, France, c. Centre National de la Recherche Scientifique, 3 rue Michel - Ange, 75794 Paris Cedex, France, d. Insritut National Polytechnigne do Lorraine, Rue de la Font de Haye. 54501 Vandceuvre Cedex, France.

Jan 1, 1997

By N. Kanari

The kinetics of oxychlorination of MgO by C12+02 was studied in the temperature range of 850 °C - 1025 °C, using thermogravimetric analysis. The effects of C12/02 ratio, gas velocity, temperature and partial pressure of reactive gases on the reaction rate were investigated. The oxychlorination process was characterized by an apparent activation energy of about 214 kJ/mol. The reaction orders with respect to C12+02, C12 and 02 at 950 °C were about 0.65, 0.98, and -0.37, respectively. Some data about oxychlorination kinetics of MgO, Cr2O3, and MgCr2O4 contained in chromite were compared. Efficiency of using oxychlorination for the removal of iron oxides contained in magnesia was demonstrated.

Jan 1, 1999

By S. Lu

The particle-bubble attachment and the rupture of formed aggregates in flotation cell were investigated in terms of turbulent regime. It was found that the particle-bubble collision rate is closely correlated to the energy barrier between particles and bubbles, and no adhesion takes place for the hydrophilic particle-bubble system due to the introduced ?capture efficiency? f(a) being zero. The values of an especially defined Weber number, i.e. the ratios of turbulent stress to aggregate strength in the inertial subrange of turbulence were estimated, the results showed that the detachment of a particle from a bubble involved in an aggregate is mainly caused by the turbulent stress only in the impeller zone, no bubble splitting occurs both in the impeller zone and in the bulk zone.

Jan 1, 1993

By D. J. M. Grodzian

Polymorphic transformations taking place in grinding processes, of massicot to litharge in PbO system, and of y to a in Fe203 system, were re-investigated. Grinding was carried-on in a steeel rotation mill charged with WC balls, under inert atmosphere. The kinetics of transformation in PbO was established by means of quantitative X-ray diffraction analysis. The resulting data fit a modified logistic growth function up to about 75% of transformed volume fraction, when a mixture at steady-state equilibrium is formed. The reasoning for the use of a modified logistic function is discussed. A sigmoidal growth function can be used if resulting data fit also an empirical power relationship between transformed volume fraction and time. However, it lacks the significance expressed by a modified logistic function. Assuming, the loss in magnetism is directly related to the amount of transformation in Fe 203, a quantitative analysis was performed using a magnetic balance method. The results fit only the modified logistic growth function, and transformation proceeds almost to completion. A wide literature survey of the subject is given. Available data from literature is compared with the results of the present study, and is shown also to fit a modified logistic grown function, with surprisingly similar slpes in a linear plot, independently of the material. The instrumentation effect on kinetics parameters, and the establishment of equilibrium mixture values, are discussed.

Jan 1, 1975

By M. D. Gibbs, T. N. Smith, B. Verbaan

When heated in the absence of oxygen, pyrite from refractory gold concentrates decomposes endothermically to pyrrhotite, releasing sulphur. The decomposition starts at the particle surface and progresses inwards, leaving an adhering layer of porous pyrrhotite. Use of the conventional shrinking-core model implicitly assumes a negligible partial pressure of sulphur in the bed, but this pressure is in fact at least equal to the equilibrium vapour pressure of sulphur over pyrite, constituting the principal control of the rate of decomposition. Further experiments showed a decrease in reaction rate as the conversion increased. Both phenomena are attributed to the persistence of non-isothermal conditions in the fluidised bed during pyrolysis, caused by the endothermic nature of the reaction and the relatively slow rates of heat transfer to particles and vapour removal from the bed. Equipment must be developed to maximise these two parameters

Jun 19, 1905

By S. Chander, A. Briceno

The properties of surface films on pyrite have been studied through electrochemical techniques of cyclic voltammetry and AC impedance, measurements. The characteristics of the surface films depend on the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance, showing a certain degree of passivity. Some pyrites show more passivation than others, however. On oxidation, meta- stable phases of Fe(OH)2 and Fe(OH)3 form that transform to more stable phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics that is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide because it is hydrophilic. This study has also demonstrated that AC impedance ,measurements can be used to study the growth characteristics of films at mineral/solution interfaces.

Jan 1, 1988

By S. Chander

The formation of surface films on pyrite has been studied through electrochemical techniques of cyclic voltametry and AC impedance measurements. The characteristics of the surface films depend upon the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance showing a certain degree of passivity. Some pyrites show more passivation than the others, however. On oxidation, metastable phases of Fe(OH2) and Fe(OH3) form which transform to more stable 3 phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics which is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide rather than sulfur because the later is expected to be limited to a monolayer in alkaline solutions. This study has also demonstrated that AC impedance measurements can be used to study the growth characteristics of films at mineral/ solution interfaces.

Jan 1, 1987

By J. A. Arias

The oxidation kinetics of pyrite and refractory gold concentrates in acidified ferrous sulfate solutions in the presence of oxygen-sulfur dioxide gas mixtures has been studied. The effect of temperature, pulp density and gas composition were determined. The optimum oxidation rate was obtained at 80°C and 2 percent sulfur dioxide in the gas mixture. The oxidation of the sulfide minerals is attributed to the presence of ferric ions, which are continuously regenerated by the gas mixture. The objective of this study is to find a new hydrometallurgical method to render sulfidic refractory gold ores amenable to cyanization.

Jan 1, 1993

By Kenneth S. Coley, Michael Pomeroy, Elaine Chen

Recent work on modeling of BOF steelmaking is reviewed, highlighting the critical aspects of each approach. It is concluded that the most successful models should be based on a deep understanding of the mechanisms and kinetics of the critical reactions. The importance of the decarburization mechanism is discussed with particular reference to its role in droplet swelling or bloating which has a profound influence on the droplet residence time in the slag. Conditions which cause bloating are discussed and the rate determining step is proposed to be primarily nucleation of CO bubbles inside the metal droplet with some influence from growth by reaction at the bubble/metal interface. The discrepancy in the super-saturation ratio required for classical nucleation is discussed and an approach using a surface tension modifying parameter is illustrated. Finally, the role of CO nucleation in controlling the driving force for dephosphorization is discussed.

Jan 1, 2014

By Marcelo B. Mourão

An experimental investigation was carried out to -study the rates of reduction of pellets containing iron oxides by carbon dissolved in liquid iron, at temperatures ranging from 1720 K to 1973 K. Several different pellet types were employed; the materials used in the pellet's manufacture were pure hematite, two kinds of commercial iron ores, and mixtures hematite/silica and hematite/lime: Reaction times were determined employing the constant volume pressure increase technique (CVPI). It has been observed that the reaction rate increases as the temperature and the pellet's specific surface area increases. The reaction rate is also affected by the oxide type: pellets made from commercial ores or from mixtures hematite/silica or hematite/lime show reaction rates lower than those made from pure hematite.

Jan 1, 1996

Kinetics of Reclamation of E-Waste by a Bioleaching Route

Sep 13, 2010

By Lawson F

The Australasian Institute of Mining and Metallurgy is a society of engineers and scientists formed in 1893 (incorporated by Royal Charter in 1955) to advance science and engineering in the mineral industries, and to facilitate the exchange of information and ideas to enhance the professional excellence of its members. The Institute has several grades of members. The professional members are linked with Student and Company Members, as well as an Affiliate grade covering other professionals and non-professionals with experience in the mineral industry. The diverse group covers all sections of the mineral industry, from exploration through production to marketing of minerals and petroleum. Corporate (professional) membership also covers science and engineering professionals from specialisms other than the "traditional" ones in geosciences, mining and petroleum engineering and metallurgy. The Institute has Branches throughout Australia, New Zealand, Papua New Guinea and Oceania, whose activities complement the corporate occasions arranged for the benefit of all members by Headquarters in Melbourne. Members are drawn from all sections of the industry - private enterprise, government, research, education, and the support sector, including consultancies, manufacturers and suppliers. Membership of The Institute allows professionals to contribute to their profession through participation in The Institute's seminars and conferences, its many committees and Branch meetings, and through contribution to its many high standard publications. The Institute is the main body for the accreditation of professionals in the minerals industry. The activities of The Institute are directed towards the achievement of professional excellence. It provides opportunitites for contact with, and professional support from, colleagues, and the interchange of information on the latest industry developments.

Jan 1, 1989

By Manoj Kumar, S. Ranganathan, S. N. Sinha

The reducibility of three different manganese ores with coke was studied. The three ores were reduced to different extents under the same experimental conditions. The investigations showed that in the temperature range of 900-1000 ×C, Fe2O3 in the ore was reduced to metallic iron. MnO2 was reduced to Mn3O4 in all cases except one in which it was reduced to Mn2O3. The kinetics of reduction was controlled by different mechanisms in the different ores. Temperature had a significant influence on the reducibility of the ores.

Jan 1, 2007

By B. S. Terry, C. L. Harris

Reduction kinetics from slags containing CuO(0.5), ZnO, PbO, NiO and SnO into a Cu-based metal phase were subjected to computer simulation using a previously developed model for the kinetics of metal-slag-gas reactions that assumes mass-transfer control in all phases. The effects were examined of changing bulk Fe oxide activity, gas reducing potential, temperature, Fe content of the Cu phase and metal/slag ratio. The results permit practical conclusions to be drawn about industrial slag-cleaning practice, but the model is still limited in terms of thermodynamic inputs and the idealisation of reaction conditions

Aug 1, 1995

By B. S. Terry, C. L. Harris

After measuring the kinetics of Ni reduction from a SiO2-saturated fayalite slag into a Cu-based metallic phase on a laboratory scale, a general model was developed that is capable of simulating mass transfer to and from metal-slag, slag-gas and metal-gas interfaces for multiple species. The model was used to simulate the reactions that occur when Cu and Ni are reduced from fayalite-based slags into a Cu-based metallic phase. Good agreement was achieved between model predictions and experimental data

Aug 1, 1995

By Vincent Canaguier

Methane is increasingly considered as a promising reductant for metal oxides, including chromite. To assess the possibilities of such reduction route, the gas-solid reactions between Ar–CH4–H2 gas mixtures and synthetic chromites are studied between 950 and 1050 °C. The influence of Mg and Al additions on the reduction-caburization of (Fe,Mg)(Cr,Al)2O4 solid solution is investigated thermodynamically, structurally and kinetically. The product phases are examined by x-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). The reaction rate is derived from real-time exhaust gas measurements and post-reaction product analyses such as oxygen analysis. Kinetic models are proposed based on the product phase morphologies and confronted with the empirical data.