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By C. S. Spirakis, A. V. Heyl

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The modified basinal brines, containing partly oxidised sulphur species, scavenged metals from basement rocks and sediments and transported them through the host rock, which contained local concentrations of organic matter. Reacting in various ways with the mineralising solution as temperatures at the sites of mineralisation changed, organic matter caused the precipitation and dissolution of a variety of minerals in the ore zones; it was organic matter that caused all of these reactions to occur at the same sites. Thus all components of the mineralising fluid - salt, water, heat, sulphur and metals - were obtained within the ore district. The siting of the mineral districts was related to the locations of faults through U- and Th-enriched granites beneath sediments containing basinal brines, and the locations of ore deposits within the districts were controlled by local concentrations of organic matter

Apr 1, 1995

By F. Karakas

Water based paint formulations consist of some industrial minerals with quantities varying from 20 to 50 %. Quality of paint is directly related to these minerals used as pigment or filler in the production. Titanium dioxide is the most important and expensive pigment in paint formulations. Other minerals such as calcite and calcined kaolin are used as filler and mainly as a substitute for TiO2. Consequently, particle-particle interactions including adsorption, coating and size distribution of pigment mixture directly affects the paint quality. In the present paper, a new type of pigment mixture for possible use in architectural water based paints was developed through grinding. The effect of different types of grinding methods on physical properties of TiO2 and calcite mixture and the quality of paint produced by these mixtures have been revealed. Three different types of mills; conventional ball mill, vibratory ball mill and high-speed attritor were used for grinding of TiO2 and calcite. Viscosity, zeta potential and particle size distributions were used to characterize the pigment mixtures obtained upon grinding. The quality of paint was evaluated by standards based on both wet and dry paints such as viscosity, density, opacity and gloss. The paint produced with the pigment mixtures prepared in vibratory ball mill and high speed attritor showed improvement in physical properties particularly in the distribution and dispersion of mineral particles. Keywords: grinding, pigment, paint, TiO2, calcite

Sep 1, 2012

By John C. Brower

The purpose of this paper is to examine the Gays in which- the policies of the U.S. government, mining companies and third world countries affect each other with regard to the availability of minerals. The interaction involves U.S. policy towards the mining industry, the policies of the companies themselves, and the policies of third world countries towards the U.S. and multinational companies. It is assumed in this discussion that U.S. policy will continue to be to seek certain minerals from abroad rather than attempt to develop domestic sources for all its requirements. This would seem to make sense both from the standpoint of cost, and for preserving what domestic resources there are so as to maintain some degree of market leverage. In today's jargon, this means greater dependency on the "third world", which, for this discussion, includes virtually all the nations in Africa, South America and Asia. Concern for availability raises the important distinction between dependency and vulnerability, and as the Director of the Bureau of Mines has pointed out, the two are not the same. Dependency is not neccessarily a bad thing; it is vulnerability that counts (Norman, 1980)

Jan 1, 1982

By D. Denton, C. Peppin, D. Tesarik, D. Bayer, J. B. Seymour

Hecla Mining Company and NIOSH cooperated in a study to document the safety of rock support supplied by reinforced cemented paste backfill at the Lucky Friday Mine. Data are presented on backfill modulus values from laboratory tests and compared with modulus values from in-mine wall closure on the backfill. It is theorized that a compressive zone is created in the backfill between the upper and lower bearing plates on the reinforcing bolts, and that the backfill remains stable as long as the compressive zones from adjacent bolts overlap.

Jan 1, 2001

By R. K. Dunham, A. N. Styler

The results of two studies into the effects of undermining offshore room and pillar workings by longwall faces are presented. The first study indicated no potential instability from undermining one level of room and pillar workings. On the basis of this it was decided to undermine two levels of room and pillar workings, again monitoring pillar stability. The results showed no signs of increased instability.

Jan 1, 1982

By S. Veeramasuneni

The interaction of soluble salt particles in their saturated brines is of interest from both a fundamental and practical perspective. The state of dispersion/aggregation of alkali halide particles as determined by optical microscopy can now be described based on non-equilibrium electrokinetic measurements for alkali halides. These results indicate that the sign of the surface charge has a significant effect on the extent of particle dispersion/aggregation. Atomic force microscopy (AFM) is now being used to directly measure the interaction forces responsible for the stability of these alkali halide aggregates observed in optical microscopy studies. These experimental results can be explained based on the interfacial polar interaction theory. In this regard the nature of such particle interaction forces at high ionic strengths are examined to improve our understanding of these systems.

Jan 1, 1997

By V. K. Paruchuri, J. D. Miller, J. Nalaskowski

An understanding of forces responsible for the stability of dispersions of colloidal particles when interacting with each other in aqueous solutions is of great interest academically and industrially. When water-soluble polymers are adsorbed onto colloidal particles, various effects on the stability of their suspensions can be expected ranging from steric stabilization to bridging flocculation. The possibility of detailed characterization of such systems using direct measurements of interaction forces between particles can help in further improvement of existing technologies of solid-liquid separation. An atomic force microscope (AFM) colloidal probe was used to measure the interaction forces between a silica sphere and a silica substrate in the presence of water-soluble polymers. Poly(ethlene oxide) (PEO) with three different molecular weights (7,000, 43,000, and 63,000), each with a very narrow molecular weight distribution, were used in this study. The interaction forces measured with the AFM over an extended time scale are discussed in terms of the adsorption kinetics measured through in-situ FTIR/IRS measurements.

Jan 1, 2003

By Falbo A, Quarestima S, Cozza C, Barbaro M

A new synthetic reagent of the mercaptobenzoxazole class, 5- methyl-2-mercaptobenzoxazole, has been studied. This reagent exhibits powerful selective collecting action towards copper sulphides present in several complex ores, as demonstrated both by laboratory and pilot plant tests. Industrial production is expected to start in the near future. The way this reagent reacts with pure chalcocite has been studied utilising in situ FTIR techniques, adsorption tests, electrokinetic potential measurements and Hallimond cell flotation tests. The FTIR studies have indicated the nature of the surface phase. Adsorption isotherms obtained by the rest method have revealed the quantitative evolution of surface products, permitting the determination of surface coverage at various reagent concentrations. The electrokinetic potential has been utilised to verify the stability of individual species in diverse concentration ranges. Correlation of the results obtained has provided indications on the chemical interaction of this reagent with the surface and on the surface Arrangement.

Jan 1, 1993

By Yujing Jiang, Xuezhen Wu, Bo Li, Tomomi Iura, Gang Wang

"Yielding bolt has been widely used for rock reinforcement in mining and civil engineering in high stress conditions. However, the interaction mechanism of yielding bolt and matrix mass is still not clear at present, and no analytical model is available to predict its reinforcement effect quantitatively. In this paper, the mainstream yielding rock bolts were reviewed firstly. After that, a coupling model is proposed to account for the interaction between yielding bolt and matrix mass. Based on the plane strain axial symmetry assumption and the incremental theory of plasticity, equilibrium equations and compatibility equations of matrix mass, and also the response of yielding rock bolt are deduced theoretically. The proposed method was programmed in Visual Basic development environment, and a semi-analytical solution for the coupling model is achieved. The reinforcement mechanism of yielding bolt in conventional tunnelling is clearly demonstrated through an illustrative case study. The reinforcement effect of yielding bolt is estimated quantitatively, and the distribution of axial force along the bolt is presented. In addition, the validity of proposed method is verified by numerical simulations. INTRODUCTIONHigh stress in surrounding rock mass can cause serious stability problems such as massive squeezing in soft rock and rock burst in hard rock. It is observed that many conventional rock bolts failed when experiencing large displacement, which implies that they are too stiff to sustain large deformation and dynamic conditions (Stillborg, 1994; Hoek et al., 1995). Yielding bolt, which can also be called energy-absorbing bolt, has been widely used for rock reinforcement in mining and civil engineering for these conditions (Neugebauer, E., 2008). This paper focuses on the static reinforcement effects of the yielding bolts with analytical method and numerical simulations."

Jan 1, 2015

By G. Meschke

"This paper reports on computational and experimental research, performed at the Collaborative Research Center “Interaction Models for Mechanized Tunneling” at Ruhr-University Bochum, Germany. Research covers a broad spectrum of topics relevant for mechanized tunneling in soft soil conditions. This includes advances exploration methods and models for the characterization of the in-situ ground conditions, the interaction of the face support and the tail gap grouting with the porous soil, multi-scale models for the design of fiber reinforced segmental linings with enhanced robustness, computational methods for the numerical simulation of the tunnel advancement, the soil excavation and the material transport in the pressure chamber, logistics processes and risk analysis in urban tunneling.INTRODUCTIONMechanized Tunneling has proven itself as an economical and flexible construction method that continues to undergo a dynamic evolution process. Shield diameters continue to increase, and the application range of tunnel boring machines is being extended to an ever-increasing variety of geotechnical conditions. In order to maintain economic viability and to ensure an environmentally friendly construction process, realistic and reliable numerical models are required in order to make informed decisions during planning and construction. To provide a reliable numerical prognosis, it is necessary to accurately assess and understand the interactions between the components involved in mechanized tunneling with the surrounding site, the ground, and any pre-existing structures. Heterogeneous geological conditions and often only approximated ground parameters create, in contrast to other engineering projects, special demands. This necessitates new insights to new problems that can only be effectively solved through truly interdisciplinary research. To address these challenges, the German Research Foundation (DFG) has established the Collaborative Research Center “Interaction Models for Mechanized Tunneling” (SFB 837) at the Ruhr-University in Bochum in 2010. Collaborative Research Centers are interdisciplinary scientific research groups in which cooperative research is conducted under the umbrella of a central research theme. With a research budget of ca. 10 Million Euros for the second 4-year funding period, and a research team composed of 13 project leaders along with approximately 35 scientific assistants the SFB 837 is currently one of the largest research groups conducting fundamental research in tunneling related topics worldwide.RESEARCH TOPICSThe research topics of the SFB 837 encompass a number of relevant planning and construction related aspects in mechanized tunneling (Figure 1). These research themes are each supported by computational models and laboratory investigations and are all included in an SFB overarching Tunnel Information Model (TIM). Interaction groups integrate and combine the results of different submodels through prototypical cause-and-effect relationships, and through the analysis of the Wehrhahn metro line (WHL) project in Düsseldorf, which has been adopted as the reference project for the SFB 837."

Jan 1, 2016

By Jeffrey D. Smith, William G. Fahrenholtz, Jose M. Soto

Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy.

Jan 1, 2004

By Y. Akin, M. Hancer, M. S. Celik, J. D. Miller

Flotation pulps with boron minerals such as colemanite and borax using primary amine collectors, e.g. dodecylamine, exhibit collector precipitation above a critical pH depending on the amine concentration. This was earlier attributed to the formation of a mine hydroborate. However, results from this current study indicate that the precipitate is dode-cylamine, rather than dodecylamine hydroborate. A systematic study involving solubility, zeta potential, microflotation, adsorption, and surface tension measurements is presented to elucidate the role of a mine precipitates in boron flotation systems.

Jan 1, 2000

By Felicia F. Peng

In operation of column flotation of fine coal, the smaller bubbles are required to effectively recovery of fine hydrophobic particles. However, smaller size bubbles alone does not ensure an efficient flotation for fine particles. The sufficient available bubble surface area per unit column are essential for effective column flotation. The experiments are conducted in a lab-scale column using two different bubble size distributions and three different particle size distributions for flotation of Pittsburgh No.8 seam coal. The interaction between particle size, aeration rate, feed rate and wash water addition are examined in this investigation to establish the optimal operation conditions for flotation of fine coal. Despite of wide range of operation conditions used in this study, it is found that the experimental data fall in a single characteristic recovery-ash curve for a given bubble size distribution and particle size distribution. The major parameters affect the flotation performance points along -the characteristic recovery-ash curves are aeration rate/frother dosage, feed rate and wash water rate-.

Jan 1, 1994

By A V. Nguyen

Spherical calcium dioleate particles (~10 ¦m in diameter) were used as AFM (atomic force microscope) probes to measure interaction forces of the collector colloid with calcite and fluorite surfaces. The attractive AFM force between the calcium dioleate sphere and the fluorite surface is strong and has longer range than DLVO (Derjaguin-Landau-Verwey-Overbeek) prediction. The repulsive AFM force between the calcium dioleate sphere and the fluorite surface does not agree with the DLVO prediction. Consideration of non-DLVO forces, including the attractive hydrophobic force and the repulsive hydration force, was necessary to explain the experimental results. The non-DLVO interactions considered were justified by the different interfacial water structures at fluorite- and calcite-water interfaces as revealed by the numerical computation experiments using molecular dynamics simulation.

Jan 1, 2005

By Marcelo B. Mourao

Interactions of carbonaceous materials with liquid Fe-C melts have been investigated experimentally by determining the volatile yield due to rapid devolatilization (Flash Pyrolysis) and rates of dissolution at temperatures ranging from 1623 to 1873 K. The volatile yield increased with increasing the temperature. The comparison of results of different types of carbonaceous materials was possible by expressing the volatile yield in terms of Enhancement Factor, fE. The rates of dissolution of spectroscopic graphite and an industrial coke seemed to obey the correlation for natural convection under turbulent conditions. The experimental data for the graphite suggested that the rate of dissolution was controlled by the mass-transfer in the liquid boundary layer adjacent to the solid sample. The value for the empirical parameter correlating the dissolution coefficient and the operating variables was found to be 0.19 which was close to that reported in the literature. The comparison of the results obtained for the coke samples with those for the graphite revealed that the impurities and the porosity of the samples can effect the dissolution rates.

Jan 1, 1992

By R. Perez

The consumption of grinding media forms a significant part of the operating cost of a mineral processing plant. An estimated half billion pounds of steel in the USA and over one billion pounds in the world are consumed each year in wet grinding alone. However, there is some conjecture as to the interacting roles of abrasion and corrosion. In order to provide a more complete picture of the conjoint action of abrasion and corrosion, marked ball tests were conducted on different grinding ball compositions in a laboratory ball mill and the metal losses were measured on varying the conditions, i.e., pH, PO2, in wet grinding a Cu-Ni gabbroic rock and compared with taconite grinding. Ball wear rates ere discussed with respect to ball composition and microstructure and the varying conditions used in the grinding tests.

Jan 1, 1984

By Allen J. Sobczak, Peter J. Peters

The five tunnel contracts of Milwaukee Northeast Side Relief Sewer System are about 80 percent complete. The tunnels are all excavated for 1.9 meter (6'-0") finish diameter sewers in a variable rock, mixed face, and glacial soil environment. Different contracts were let under two primary types of specifications, performance and prescriptive, which treated aspects of construction, such as primary ground support and groundwater control, differently. Interfacing of design and construction through field personnel allowed the needs of all parties to be met and resulted in savings in time and money to the Milwaukee Metropolitan Sewerage District (MMSD). Interfacing, cooperation and risk sharing allowed resolution of problems such as line and grade variations and potential differing site conditions. It also allowed the parties to pursue constructive changes to construction activities. Thus on one contract prescribed use of compressed air was eliminated, but migration of fines into the tunnels was stopped with filter fabric. Use of an expensive primary support system was dropped, but concern about deterioration of lagging was alleviated by use of special materials.

Jan 1, 1983

By Q. G. Reynolds

The presence of dust and fume suspended in the freeboard region is a common feature of the operation of direct current (DC) plasma smelting furnaces. This occurs primarily as a result of the use of fine feed materials together with the open-arc, open-bath operation of such smelters, and is exacerbated by the high velocities and turbulent mixing of the gas in the vicinity of the arc jet. Dust and fume losses into the furnace off-gas system can be significant in some cases and may have economic, operational, and environmental impacts on the process. A computational modelling study is presented in which the concentration of dust material was considered as a continuous field subject to a governing partial differential equation. Settling behaviour was calculated as a function of particle size, local gas/plasma temperature, and other physical properties. Development of the coupling between the concentration field and a magneto-hydrodynamic description of the arc is shown, and the resulting models were used to compute various aspects of the behaviour of the concentration field in the arc region for a variety of furnace conditions. Time-averaged as well as transient models of the arc were used to generate the results presented. Qualitative case studies produced several practical suggestions for furnace operation, including increased dust capture by the bath when feed ports are located closer to the electrode, and the possible effects of feed segregation in the furnace freeboard based on dust particle size and density.

Jan 1, 2014

By Q. G. Reynolds

The presence of dust and fume suspended in the freeboard region is a common feature of the operation of direct current (DC) plasma smelting furnaces. This occurs primarily as a result of the use of fine feed materials together with the open-arc, open-bath operation of such smelters, and is exacerbated by the high velocities and turbulent mixing of the gas in the vicinity of the arc jet. Dust and fume losses into the furnace off-gas system can be significant in some cases and may have economic, operational, and environmental impacts on the process. A computational modelling study is presented in which the concentration of dust material was considered as a continuous field subject to a governing partial differential equation. Settling behaviour was calculated as a function of particle size, local gas/plasma temperature, and other physical properties. Development of the coupling between the concentration field and a magnetohydrodynamic description of the arc is shown, and the resulting models were used to compute various aspects of the behaviour of the concentration field in the arc region for a variety of furnace conditions. Time-averaged as well as transient models of the arc were used to generate the results presented. Qualitative case studies produced several practical suggestions for furnace operation, including increased dust capture by the bath when feed ports are located closer to the electrode, and the possible effects of feed segregation in the furnace freeboard based on dust particle size and density.

Jan 1, 2015

By Das S. C

A detailed study was undertaken on the effect of Fe+3 in combination with LIX64N during copper electrowinning from sulphate electrolytes. The results show that the presence of Fe+3 not only affects the current efficiency during copper electrowinning but also affects the cathode quality. The effect is enhanced by electrolysis parameters like temperature, circulation rate, current density, etc. No significant effect was found from the presence of Fe+2. The presence of Fe+3 along with LIX64N causes a synergistic effect and results in a drastic fall in current efficiency. Moreover, cathode quality is also affected. A pyramidal structure is favoured in the presence of Fe+3 but the presence of LIX64N along with Fe+3 promotes a ridge structure. Addition of thiourea not only causes modification of cathode deposits, but also a rise in current Efficiency.

Jan 1, 1992