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By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

By C. B. Daellenbach

The influence of reduction roasting and thermal shock on the grindability of a refractory low-grade Michigan iron ore was examined in bench scale tests. The quantitative effects of the various treatments were evaluated at three sieve levels: 48, 100, and 400 mesh, using ball mill grindability and work index parameters as response indicators. Data from the testing program were analyzed statistically as a means of isolating the effects of cooling rate, roasting temperature, and ore chemical condition. All three variables were found to have an important influence on the grindability of the treated ore; ore chemical condition and roasting temperature had the most pronounced effects.

Jan 1, 1970

By R. A. Vik, C. B. Daellenbach, W. M. Mahan

The influence of reduction roasting and thermal shock on the grindability of a refractory low-grade Michigan iron ore was examined in bench-scale tests. The quantitative effects of the various treatments were evaluated at three sieve levels, 48, 100, and 400 mesh, with ball-mill-grindability and work-index parameters as response indicators. Data from the testing program were statistically analyzed to isolate the effects of cooling rate, roasting temperature, mesh level, and ore chemical condition. All four variables were found to have an important influence on the grindability of the treated ore. Ore chemical condition and roasting temperature had the most pronounced effects.

Jan 1, 1972

By W. M. Husslage, M. E. Kock, T. Bakker, R. H. Heerema

Permeability in the blast furnace shaft is adversely affected by low-temperature reduction degradation of sinters. The fundamental cause of this is the expansion of the iron oxide phase resulting from the reduction of hematite to magnetite. The present study shows that expansion behavior during the hematite/magnetite reduction .step and the resulting microstructure are strongly influenced by the reduction temperature (partial oxygen pressure), the reducing agent and the nature of the hematite. The reduction rate is of minor importance. A reduction mechanism is proposed that can explain the dilation behavior and the magnetite microstructure. The results provide better insight into the reduction degradation behavior.

Jan 1, 2000

By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

By A. A. el-Geassy

High-grade iron ore fines rejected from the DRl plants (>96%Fe20) were isothermally reduced in 30-60%COIH2 gas mixtures at 973-1273K. The freshly reduced reaction products were then subsequently carburised in either H2/CO or H2/CO/S mixtures at 823-1073K for 30-120 min. The thermogarvimetric technique was used to follow up both of reduction and carburisation reactions as a function of time. The carburised samples were characterized by X-ray and Mossbauer techniques. Chemical and carbon analyses were also applied. The influence of temperature and gas composition on the reduction behavior was investigated. The calculated values of apparent activation energy, application of gas-solid mathematical formulations were correlated with the microstructures to predict the reduction mechanism, The influence of carburization time, temperature, CO contents in H2/CO or H2/CO/S were investigated. A conversion extent of Fe to Fe3C was taken as a measurable index for the efficiency of carburization reaction under the different experimental conditions.

Jan 1, 2003

By A. A. EI-Geassy

High-grade iron ore fines rejected from the DRI plants (>96%Fe2O3) were isothermally reduced in 30-60%CO/H2 gas mixtures at 973-1273K. The freshly reduced reaction products were then subsequently carburised in either Hz/CO or H2/CO/S mixtures at 823-1 073K for 30-120 min. The thermogarvimetric technique was used to follow up both of reduction and carburisation reactions as a function of time. The carburised samples were characterized by X-ray and Mossbauer techniques. Chemical and carbon analyses were also applied. The influence of temperature and gas composition on the reduction behavior was investigated. The calculated values of apparent activation energy, application of gas-solid mathematical formulations were correlated with the microstructures to predict the reduetion mechanism. The influenee of carburization time, temperature, CO contents in H2/CO or H2/CO/S were investigated. A conversion extent of Fe to Fe3C was taken as a measurable index for the efficiency of carburization rcaction under the different experimental conditions.

Jan 1, 2003

By N. Shi, T. C. Lowe, S. J. Zhou, M. L. Lovato, Y. T. Zhu, J. A. Valdez, W. R. Blumenthal, M. G. Stout

"A major problem of short-fiber composites is that the interfaces between the fiber and matrix become a limiting factor in improving mechanical properties such as strength. For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber, thus reducing the ineffective fiber length. However, a strong interface will make it difficult to relieve fiber stress concentration in front of an approaching crack. Stress concentrations result in fiber breakage. We report in this paper an innovative approach to overcome this problem: reinforcement morphology design. Short-fibers with enlarged ends are processed and used to reinforce a polyester matrix. The initial results show that the bone-shaped short-fibers produce a composite with significantly higher strength than can be attained with conventional short, straight fibers.IntroductionThese interfaces between the fiber and the matrix in short-fiber composites play a critical role and, in many cases, become a limiting factor in improving such mechanical properties as strength and toughness of the composites (1-4). For a short fiber, a strong interface is desired to effectively transfer load from matrix to fiber. A stronger interface can reduce the ineffective length at both ends of the fiber and, therefore, can increase the effective length that carries load (5-9). However, with a strong interface it is difficult to relieve fiber stress concentration -in front of an approaching crack; and such stress concentration can result in fiber breakage (10, 11). This effect is particularly severe for ceramic matrix composites, because of their low matrix toughness and lack of plasticity. Even for a composite with a highly ductile matrix, such as plastics, too strong an interface may still cause successive adjacent fiber breakage and subsequently reduce composite toughness (1, 11). On the other hand, a weak interface significantly decreases the fiber load-carrying length due to ineffective load transfer and complete fiber interfacial debonding and pullout during loading. A compromise in the interfacial bond strength will also compromise the load-carrying potential of short fibers."

Jan 1, 1998

By S. T. L. Harrison, M. Smart, C. J. Edward

Biooxidation, a biohydrometallurgical process, utilizes a mixed microbial consortium to mediate the dissolution of refractory gold-bearing ores to enhance gold recovery during cyanidation. Recognition of water as a critical resource has prompted improved water management strategies within mining and minerals processing. Bioremediated wastewater from the cyanidation tailings provides a potential water source to supplement the water required for the biooxidation circuit, reducing freshwater extraction. Gold biomining operations have typically been reluctant to recycle this wastewater due to the potential inhibitory effects of cyanide and thiocyanate (SCN-) on the microbial population. Historical process upsets suggest that the microorganisms are sensitive to SCN- concentrations as low as 1 mg/L. However, effective bioremediation processes resulting in effluents with low or negligible SCN- concentrations may allow gold biomining plants the opportunity to recycle available water. Microbial activity as well as alteration in community structure were monitored as a function of increasing SCN- concentration over the range of 0 mg/L to 5 mg/L to investigate the response of the biooxidation community to potential SCN- spikes resulting from upsets in the remediation process. Appropriate microbial growth and ferrous iron oxidation activity with a nominal shift in community structure were observed at SCN- concentrations up to 1 mg/L. Thiocyanate concentrations above 1 mg/L resulted in the complete inhibition of ferrous iron oxidation activity. This was attributed to Leptospirillum ferriphilum’s sensitivity to SCN-. Exposure to a SCN- concentration of 5 mg/L resulted in a lower cell concentration and a significant increase in growth lag time, and the absence of L. ferriphilum from the microbial population. At. caldus and Ap. cupricumulans were still present at 5 mg/L SCN-, although Ap. cupricumulans was unable to oxidise ferrous iron at this SCN- concentration. It was concluded that recycling bioremediated cyanidation tailings wastewater within the biooxidation circuit is feasible; however, to retain process performance, SCN- concentrations should not exceed 1 mg/L. Keywords: Biooxidation, thiocyanate, water recycling, community structure

Jan 1, 2020

By N. Moelans, I. Bellemans, K. Verbeken

Metallic droplets can remain attached to solid particles within liquid slags, resulting in production losses in several movement of solid particles in the liquid slag in a system, considering the attachment of liquid metal droplets to solid slag and on the resulting microstructures is investigated as a function of the velocity of the particles. For all wetting For the amount of metal attached to the particle, a clear trade-off was found between the speed of motion of the solid particle and the wetting regime.

By Petr Sulovsky, Pavel Leber, Jaroslava Ledererova, Miroslav Svoboda

"The properties of raw materials used for the production of building materials play an essential role in their choice. Industrial waste materials can in some cases improve the performance of new building materials, when compared with classical raw materials. The addition of waste can however negatively impact some of the building material´s characteristics, influencing its stability, service time, durability, and can introduce undesirable variation of certain characteristics over time. It is necessary that each secondary raw material intended for such use be thoroughly investigated in terms of its chemical, physical, and mechanical properties, with special attention paid to the risk components and risk parameters. It is necessary to make many- sided technological tests in relation to the required characteristics of the resulting materials for each chosen application. Moreover, the limit values for the critical (risk) parameters, which the given secondary raw material must satisfy to be used in a specific technology, need to be defined. Introduction The risk components in the industrial waste materials to be used in the production of building materials fall into two groups: - components that pose a risk of development (instant or delayed) of a process deleterious to the utility properties and durability of the resulting materials. Such processes include volume change (expansion as well as shrinkage), alkali-silica reaction, delayed ettringite formation, thaumassite attack, aggressive carbonation, etc. - elements or components that can, if released from the waste-containing building material, pollute the environment. They involve the so called potentially hazardous elements as well as compounds like fenols, PCB, PAHs etc. From the viewpoint of the presence of both groups of risk components, the wastes can be classified as: • environmentally inert waste materials. They are produced in the largest volumes and do not pose a threat to human health. Their physical and/or chemical characteristics fail to satisfy all requirements for utilization in ordinary production. The aim of technology design is to work them into the building products with suitable utility properties. • easier workable waste materials containing toxic components are produced in large volumes. In spite of the content of toxic components, their physical and chemical properties make them suitable for ordinary production, provided that the harmful substances are immobilized by the chosen technology."

Jan 1, 2008

By Tevfik Güyagüler

Airborne dust is one of the important environmental problems in mines. Besides conventional dust control methods, recently, extensive studies have been carried out on the elimination of dust before it has actually been formed. Determining to what extend rock characteristics influence the amount of dust produced during different mining activities are considered as a guide for this purpose. The factors analyzed in this study were main mechanical, physical properties and petrographical constituents, namely free and combined silica. In the study regression analysis techniques were applied to investigate the effectiveness of aforementioned factors. INTRODUCTION Nearly every aspect of mining activity contributes to the air pollution caused by dust. Therefore the harmfull effect of airborne dust has been investigated many years and limit dust concentration levels were determined for various types of mine dust. To keep the dust level below limit value different dust control techniques have been applied in mines. So far, the well known techniques regarding dust control focuses on reducing the amount of airborne dust. However, recently various studies have been carried out to avoid the dust before it has actually been formed (Bhaskar and Gong, 1991). In this respect, influence of rock characteristics on dust formation is regarded as a guide for this purpose. The present contribution describes such a study in which the drilling operation is considered as the source of the dust. In this study drilling and dust sampling process were undertaken in a model gallery that simulates an underground working. The mechanical and physical properties of the rock samples were measured in rock mechanics and ore dressing laboratories. Quartz and combined silica contents of the rock samples, on the other hand, were determined in the laboratories of geological engineenring department. Rock samples used in the research were different types of coal measure rocks, namely, sandstone, shale and conglomerate. The rock characteristics studied in this work are brittleness, toughness, rock strength, hardness and hardgrove index as inherent properties; free silica, and total silica contents of rock samples as petrographical constituents. Although there have been various studies to determine the effect of rock characteristics on the dust formation, still the type and extend of effectiveness have not been understood clearly. LITERATURE REVIEW Most of the studies investigating the effect of rock properties on dust formation concluded that they are effective. In such an investigation, it has been found that inherent rock properties influence dust formation (Das, 1973). In the another study, dustiness of the air was considered as a function of the composition, hardness and moisture content (Panov, 1967). It was also accepted that in a drilling operation more fine dust is produced if the rock to be drilled is hard (Skochinsky and Kamarov, 1969). In some other investigations dust production were considered as a function of hardgrove index (Moore and Bise, 1984) or formulated in terms of brittleness, toughness and hardness (Güyagüler, 1991). The effect of the petrographical properties of coal or rock on dust formation characteristics have also been studied (Baafi, 1979) (Panov, 1967). Because of its importance, various researches were conducted the study to find out the effect of free and combined silica content of dust on dust formation. In one of the study, the relationship between quartz in the coal seam and quartz in the airborne coal dust was investigated (Ramani et al, 1988).

Jan 1, 1993

By M. A. Mahtab

This paper presents the results of a parametric study of the influence of natural features (stress field, rock strength, and strength and orientation of fractures) as well as the influence of induced features (undercut span, boundary slot, and other boundary-weakening measures) on the cavability of an undercut block of ore in mining by the block-caving method. The two-dimensional finite element analysis technique was used for this study. A coarse "mesh," along with linear homogeneous assumptions for rock properties, was used to model the problem of initiation of caving in a block of ore. Interpretation of the test results suggests that weakening the "abutments" of the block as well as certain orientations of natural fractures exercise significant influence on cavability. These findings hold promise for immediate application to known situations in block-caving mines.

Jan 1, 1975

By M. A. Mahtab, J. D. Dixon

The results of a parametric study of the influence of natural features (stress field, rock strength, and strength and orientation of fractures) as well as the influence of induced features (undercut span, boundary slot, and other boundary-weakening measures) on the cavability of an undercut block of ore in mining by the block- caving method are presented. The two-dimensional finite-element analysis technique was used for this study. A coarse "mesh," along with linear homogeneous assumptions for rock properties, was used to model the problem of initiation of caving in a block of ore. Interpretation of the test results suggests that weakening the "abutments" of the block as well as certain orientations of natural fractures exercise significant influence on cavability. These findings hold promise for immediate application to known situations in block-caving mines.

Jan 1, 1977

Stress induced, gravity-assisted failure processes typically dominate long before stress levels approach the strength of the intact rock (at approximately smax > 0.4UCS where smax = 3s1 ? s3 and UCS is the Unconfined Compressive Strength of the intact rock (Martin et al. 1999)). Under these conditions, discontinuities typically become clamped and the failure process becomes brittle. This brittle failure process is dominated by new stress induced fractures growing subparallel to the excavation boundary. While it is possible to identify areas with the potential for brittle failure, for example, using the general assumption that brittle failure will occur in areas at right angles to the major principal stress (Hoek et al., 1995), when the threshold smax > 0.4UCS is reached in areas around the tunnel boundary, or elastic modelling and the Hoek-Brown brittle parameters proposed by Martin et al., (1999) (i.e. m? 0 and s ? 0.11), amongst others, recent observations discussed by Everitt & Lajtai (2004), and Kaiser (2005; 2006) suggest that brittle failure processes are enhanced when structural features such as joints, weakness zones, bedding planes or foliations are preferentially orientated around the excavation boundary creating stress raisers which in turn facilitate the stress-driven rock mass disintegration process (e.g., as illustrated by Everitt & Lajtai (2004) on Figure 1b). Such weaknesses induce stress heterogeneities that thus promote tensile-spalling failure processes (Diederichs 2000). The observations suggest that stress induced damage can occur ?prematurely? depending on the orientation of micro and macro structures in situations where the known stress conditions should not yet initiate brittle failure processes. In general, when structural features (micro and/or macro), especially foliations, are present in a rock mass, the strength is effectively reduced, largely due to tensile strength heterogeneity in areas depending on the orientation of the structural features with respect to the excavation boundary. As a result, stress induced damage could occur in areas not normally considered due to the influence of anisotropy (Figure 1).

May 1, 2009

By Kamran Esmaieli

This paper investigates the behavior of ore pass walls under impact loads caused by material transiting through an ore pass. In particular it considers the influence of foliation in the rock mass surrounding an ore pass as both a triggering and accentuating cause of degradation. Based on empirical observations in several underground mines a numerical experiment was designed to understand the influence of rock mass foliation on impact-induced damage on ore pass walls. The distinct element method, and in particular the Particle Flow Code (PFC2D) was used to simulate three different rock masses surrounding an ore pass. Each simulated rock mass has similar properties but was defined by distinct dominant foliation (70o, 80o, 90o) along the foot wall. The numerical experiments investigated different scenarios whereby the walls were loaded by a projected rock fragment striking the foliated walls at a constant impact angle and velocity. The damage inflicted by the projectile rock fragment, on the foliated rock mass, was quantified using the number of impact-induced micro-cracks initiated on the ore pass wall. The results of the numerical analysis indicated that the presence of foliation resulted in greater damage zones in the surrounding rock mass. In addition, the extent of impact-induced damage to the ore pass wall increased as the angle of interception between the ore pass wall and the rock mass foliations decreases. This is in agreement with qualitative field observations.

Jun 1, 2012

By Z B. Rakisheva

By explosion rock mass behaviour is conditioned by preset complex of rocks natural characteristics. Very important role of blockness, which is percent (share) content at examining massif of natural separatenesses of different dimensions and configurations, separated each from other by the cracks of geological and technogene origin. Besides natural properties of massif the power, detonational characteristics of applied explosives, parameters of explosives charges disposition at massif and technology of explosion influence vastly at lumpiness (granulometric structure) of exploded rocks. The mathematical model of rock mass destruction by explosion had been elaborated and substantiated. It ties mutually the initial data (rocks properties, parameters of the charges disposition) and final results of explosion (granulometric structure of exploded rocks). The program of this complicated problem solving had been compiled. Analysing the received results of the problem solving, one can reveal contribution of each group of influence factors for lumpiness of exploded rocks. This fact creates preconditions for elimination or diminution of negative role of some controlled initial data.

Jan 1, 2003

By Behrouz Ohadi, Kamran Esmaeili, Bibhu Mohanty

In most metalliferrous open pit mines with heterogeneous orebodies, blast-induced rock movement is a crucial outcome that has unfavorable impact on ore and waste segregation in the post-blast muck pile, resulting in either ore loss (the ore is misclassified as waste and sent to the waste rock dump) and/or ore dilution (waste is misclassified as ore and sent to the processing plant). While many studies have been carried out to assess the influence of blast design parameters on blast-induced rock movement, the influence of rock mass characteristics in these studies have been overlooked.

Jan 1, 2018

By Jamal Rostami, Richard Kastner, Ahmad Ramezanzadeh

Improving the accuracy of the performance prediction models for hard rock Tunnel Boring Machines (TBMs) is important in estimation of the schedule and cost of tunnelling in related projects. The effects of rock mass on performance of TBMs has been studied extensively, yet due to the complex nature of the process, impact of many parameters influencing machine advance rate are not very clear and there is still room for improvements. More accurate estimates can be obtained by better understanding of operating parameters in various geological conditions and can lead to matching machine specifications with job conditions, optimizing machine performance, and avoiding long delays and downtime for increased productivity. This paper will offer review of two case histories including Queens Water tunnel in New York and KCRC project in Hong Kong. The analysis of the available field data, including the geological back mapping and results of laboratory testing of rock mechanical properties, machine operational parameters and achieved rate of penetration will be presented. This includes statistical analysis of available field data to provide a better understanding of the influence of rock mass properties on performance of hard rock TBMs as well as related formulas to improve performance estimates.

Jan 1, 2005

By R. Krishna, L. A. Kumar

The paper suggests a new empirical model for predicting mining subsidence. The parameters considered are Lithological Factor, which in this context meant percentage of sandstone, Rock Mass Factor (depending upon the RQD value of drill-hole cores), width: depth ratio and percentage extraction of coal. More than 250 drill-hole cores from seven longwall panels and 11 bord-and pillar (room-and-pillar) workings were analyzed from an extensive data bank of Singareni Collieries Company Ltd. (S.C.Co.), Andhra Pradesh, India. Excellent subsidence agreement was found with the suggested model.

Jan 1, 1993