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By A. D. Nicholson

This paper presents an approach to quantitatively calculate the neutralization of acid by silicate minerals, based on the chemical kinetics of acid reacting with silicates. This approach incorporates incongruent dissolution mechanisms and the effects of silicate iron content on net acid consumption, and offers guidelines for considering the extent to which specific silicate minerals will react. This approach differs from previous methods of estimating silicate buffering: it is based more on the fundamental chemistry of acid generation, and less on potentially misleading empirical measurements of acid neutralization.

Jan 1, 2002

By Daniel Rigon Orellana

O emprego de fontes renováveis de carbono encontra nos processos de coqueificação uma forma de reuso de partículas carbonosas finas ou fora das especificações necessárias para utilização em outros processos metalúrgicos, além de reduzir as emissões de carbono. O presente trabalho avalia os principais efeitos da incorporação de um carvão vegetal de eucalipto a uma mistura de carvões para a produção de coques em forno piloto. Para isso, o carvão vegetal foi adicionado em teores de 3%, 5% e 10%, e em duas frações granulométricas, a uma mistura de carvões. A qualidade dos coques gerados foi avaliada e discutida ao longo do trabalho por ensaios de caracterização do coque como, análise imediata, teor de enxofre, reatividade e resistência pós-reação (CRI/CSR), resistência mecânica a frio (DI 150/15) e textura óptica. Foi observado que a adição de 3% de carvão vegetal, na fração mais grosseira, à mistura de carvões resultou no coque de melhor qualidade.

Aug 16, 2017

By Verônica Scarpini Candido

Este trabalho tem o objetivo de avaliar o efeito da incorporação de até 15% em peso de lama de alto forno proveniente de uma siderúrgica do estado do Pará, na massa argilosa composta de argila forte e argila fraca para a produção de telhas. O resíduo e as argilas, forte e fraca, foram beneficiados e tiveram sua composição química determinada por meio de fluorescência de Raios-X. Foram preparados corpos de prova por prensagem uniaxial a 20 Mpa para queima em forno de laboratório tipo mufla a 950oC. Foram avaliadas a absorção de água e o módulo de ruptura em flexão dos corpos queimados. Os resultados mostraram que a lama de alto forno é constituída predominantemente por compostos de ferro e que a incorporação de até 15% em peso pode melhorar as propriedades tecnológicas das cerâmicas queimadas.

Oct 30, 2017

By Alessandra Savazzini dos Reis

A crescente preocupação em relação às áreas de proteção ambiental e ao alto consumo de argila, matéria-prima da cerâmica vermelha, ocasiona a indisponibilização progressiva de reservas de argilas no Brasil. Com isso, vê-se a necessidade de incorporar resíduos na massa argilosa para confecção de produtos de cerâmica vermelha. A indústria de cerâmica vermelha brasileira consome cerca de 10 milhões de toneladas de argila ao mês para produção de telhas e blocos. Na própria olaria são gerados resíduos, tal como, o resíduo de massa cerâmica crua originado na etapa de conformação das peças. Este trabalho visa incorporar o resíduo de massa cerâmica crua na massa argilosa usada em cerâmica vermelha. O resíduo foi caracterizado por meio de ensaios de FRX, DRX, limites de Atterberg e distribuição de tamanho de partículas. Corpos de prova feitos com massa argilosa e resíduo em teores variando de 10% a 90% (massa) foram conformados, secos à 110ºC, queimados à 900ºC em forno industrial e submetidos a ensaios de absorção de água, porosidade aparente, massa específica aparente e resistência à compressão. Os resultados evidenciaram que as propriedades cerâmicas avaliadas nos corpos de prova da massa argilosa incorporada com o resíduo atendem aos valores das argilas-padrão brasileiras para cerâmica vermelha.

Aug 17, 2017

By Artur Camposo Pereira

Cerâmicas argilosas foram processadas com adição de até 30% em peso de resíduos de pedra ornamental e queimadas a 900, 950, 1000 e 1050°C. Esta adição contribuiu para ajustar a plasticidade do corpo da argila e aumentar a densidade seca aparente, que ocasiona um empacotamento mais elevado das partículas. A cerâmica adicionada diminuiu sua retração linear com a quantidade de resíduos e evita assim alterações dimensionais excessivas nos produtos finais. Outra vantagem foi a diminuição na absorção de água com resíduos adicionados. As resistências à flexão e à compressão sofreram uma diminuição associada à adição de resíduos. Isto foi atribuído à grande quantidade de quartzo nos resíduos, que gera rachaduras e enfraquece o produto final. No entanto, até 30% em peso de adição a resistência mecânica, de acordo com a norma ASTM, é ainda satisfatória para utilização como cerâmica de pavimentação.

Oct 30, 2017

By E. A. Devuyst

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by Borberly et al. (1984). The process uses S0, (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst that can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops waste waters. The S02/Air process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore, alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful byproducts species exist. Consequently, final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By Leonardo Araújo Peruch, José Fagundes, Henrique Carneiro Pinto, Marco Túlio Costa, Nayara Coutinho, José Fabiano Martins Assunção

The objective of this project was to increase the hot charge by reducing reheating energy consumption and raising the productivity of ArceloMittal Tubarão's hot strip mill by changing the HSM’s schedule process with optimization of the relocation process of slabs after HSM’s chance with focus on slab temperature in reheating time. The project began with the revision of metallurgical rules for the relocation of materials, definition of criteria temperature setting (hot / cold), definition of restrictions of the process and review of modus operandi scheduling process. With the implementation of the process / system it is expected to achieve a 10% increase in the hot charge index in slabs reheating furnaces and increase productivity of the ArcelorMittal Tubarão hot strip mill

Oct 3, 2019

By Emma Arakelova

An increase in concentration of a Zn-containing volatile complex for synthesis of ZnO films was investigated when processing their target by ultraviolet radiation emitted by mercury lamp. The experiments were carried out using a flow-type quartz reactor. ZnO tableted target was preliminarily irradiated during 2 to 7 hours. H2O2 (98%) vapor at 25Pa passed through the reactor with ZnO target at 373K. As substrate material, five subsequent quartz cylinders were used at 423K. The experiment lasts 4 hours. H2O2 decomposition on ZnO surface was accompanied by formation of a Zn-containing volatile complex which passed in gas phase and decomposed on the substrates with isolation of final ZnO. The concentration of the Zn-containing volatile complex (N) in gas phase increases with UV pre-irradiation time (t) (without irradiation N = 1.05 1011 particles/cm3; after t=2 hours, N = 5.19 1011 particles/cm3, after t=4 hours, N = 9.95 1011 particles/cm3; after t=7 hours, N = 1.86 1012 particles/cm3.

Jan 1, 2006

By L. Szecowka, M. Poskart, Siwka M. . J.

Oxides of nitrogen, created during combustion, are the most hazardous components of atmospheric pollution. However, it is possible to limit the negative influence of hazardous components on the natural environment. An experimental appartatus was built to determine the influence of the following "primary methods" on the reduction in concentration of NOx: air staging, reburning and flue gas recirculation. The influence of the simultaneous usage of the primary methods on reduction in NOx emissions was also examined. A significant increase in the efficiency of NOx reduction was achieved in two cases.

Jan 1, 2004

By Victor Munoz, Jorge Oliva, Gonzalo Marias

Cerro Vanguardia is a known gold and silver deposit located in the province of Santa Cruz, Argentina. The mine has been in operation since 1998 and is thought to be one of the most important mines in Patagonia. More than 102 epithermal quartz veins have been identified in the area, with variable lengths, thicknesses, orientations and dips that constitute what is possibly one of the most extensive outcropping vein systems on earth.

Jan 1, 2019

By Paul J. Axtell

The results of in-situ geophysical cross-hole tests on improved soil by soil mixing (SM) and jet grouting (JG) are described. This testing was conducted on soil improved by SM and JG columns constructed in the downstream free-field of Tuttle Creek Dam near Manhattan, Kansas as part of the seismic retrofit. Results of similar geophysical testing performed on untreated soil in the vicinity of the Downstream Test Program (DTP) area, as well as beneath the embankment at several locations, are also described and used for comparison purposes. In-situ shear moduli are also compared with those determined in laboratory resonant column tests. The increase in stress wave velocities and associated shear moduli by SM and JG treatment are presented for use in liquefaction potential and seismic deformation analyses of SM or JG treated soil. This data is required to determine the decrease in liquefaction potential and earthquake-induced permanent deformations due to SM or JG with respect to that of untreated soil.

Jan 1, 2008

By Fumio Hashiuchi, Yushiro Hirai, Masatoshi Maeda, Toshihiro Nagata

"Increase in the copper smelting capacity at Saganoseki Smelter & Refinery was attained through various improvements in the PSconverters and the flash furnace. Two of the major innovations in the converting process were: a new operational technology which avoids increase in the copper content in the converter slag even when higher copper grade matte (65%) are treated in the slag making stage and a technology which shortens the operational interruption time which is caused by coolant charging. The latter was realized by introducing a new automated coolant charging system with which it was made possible to charge the coolant without stopping the blowing into the converter. These improvements brought about a remarkable increase in · the production capacity per converter and an annual production of 450,000 tons of copper without adding new furnaces was made possible. In addition, good results have been obtained of the tests with modified tuyeres to further increase the production.IntroductionIn a bid to renovate its Saganoseki Smelter & Refinery and to establish a leading production unit in terms of global competitiveness, Nippon Mining & Metals undertook major restructuring efforts since 1994. One of its themes was the shift from· a two-flash furnaces operation to a single-flash furnace operation. The shift was successfully completed in 1996 while maintaining the production at the same level (330,000 tons per annum of copper). Then, the productivity was enhanced to 450,000 mtpy without adding new furnaces through technological and operational improvements. It is now planned to increase the smelting capacity further to 470,000 mtpy this year.Some technological and operational improvements in the matte converting process and the new plan resulted from the tests with modified tuyeres are presented in this paper."

Jan 1, 2000

By Y. G. Yaroshenko, V. Y. Baldin, Y. M. Gordon

The manufacture of sulphuric acid from the off-gas of pyrometallurgical processes in the production of heavy metals is one of the common methods of effective recycling of sulfuric anhydrite. The new Impact-Inertial Devices with the rectangular contact channels (IIRCh) and the internal circulation of liquid allow the injection of an absorber into the phase's interactive cell by utilizing the gas stream energy and by this way increasing the sulphuric acid yield and reducing the power consumption. These devices have the following advantages: simplicity of design, smaller size, low capital expenses, absence of irrigating system, high operational reliability, simultaneous cleaning of solid, gaseous and liquid impurities and also cooling of gases etc. The IIRCh efficiency is almost 18 % higher and they require 1.3-2 times lower energy when compared with Venturi Absorbers. Also the elevation of spraying nozzles or injectors is 1.5 times lower in the IIRCh case.

Jan 1, 2004

By C. B. Piazzarollo

Ceramic materials exhibit dispersion results after being subjected to various levels of stress, from the point of view of mechanical strength. With the focus on sustainable development and to improve the strength of these material, was incorporated ornamental rock waste into clay in up to 10% in mass to conform some samples, that was fired to 750ºC, 850ºC and 950ºC and submitted to technological tests. This paper presents an analysis of the technological properties of the samples through the use of Weibull statistic to determine which the best firing temperature for these red ceramic materials. The Weibull Modulus indicates a greater homogeneity for samples with 10R at 950ºC.

Jan 1, 2015

By A. P. Yovanovic, P. Bonadia, M. N. Moraes, C. F. Matos

"The magnesite flotation operation of Magnesita Refractories, in Brumado – Brazil, has four parallel ball mills working in closed circuit with hydrocyclones to grind the ore for the reverse flotation of silicates in mechanical cells. The modification proposed here opens the circuit for three of the ball mills so that their products are collected together to feed a high frequency screen. The oversize of the screen feeds the fourth ball mill in closed circuit for secondary comminution. The product reports to dewatering and flotation. The undersize undergoes desliming and subsequent flotation operation. According to pilot tests performed, the modification on the magnesite flotation operation will promote a 20% increase in the productivity, 8.5% increase in mass recovery and a 26% reduction in water consumption. The gains are due to the fact that the silicates in the feed are concentrated in the smaller particles (<100µm) with over grinding in the existing closed comminution circuit, making it impossible to take advantage of this natural selectivity. The combination of open circuit, more selective milling, and the high frequency screen, ensures high efficiency particle size classification. This renders the process more effective, both to the screen undersize with its high contents of silicates and fines, and to the screen oversize, which is almost without fines and has a higher magnesite grade. This situation allows for the setting of specific parameters for the flotation of both the primary milling undersize and the secondary milling product.INTRODUCTIONMagnesita Refractories, with its operations site in Brumado, is the largest producer of high purity dead burned magnesia (DBM) in Latin America. The magnesite ore is extracted from an open pit mine, named Pomba, after which it is crushed and handpicked. Due to the presence of disseminated silicate the ore has to be ground and concentrated by means of reverse flotation, before feeding the high temperature kilns for sintering and conversion to DBM.The magnesite flotation unit has an impact crusher to reduce the size of the feeding ore, which is transported to the mills by conveyor belts. The milling operation is composed of four ball mills in closed circuit with hydrocyclones. The closed circuit generates a high circulating load with excess fines, which is detrimental to the selectivity of the desliming and flotation operations, reducing both mass andmetallurgical recovery.In the current scenario, the capacity of the flotation plant is insufficient to meet the demand of the DBM kilns, forcing the operation to work with high purity ores in order to attain the highest possible mass recovery in the concentration process. This is not an ideal situation as it requires the mining site to work with higher stripping ratios.The objective of this work was to improve the magnesite flotation unity to increase its productivity. After a detailed analysis, the milling was identified as the limiting process, which made the authors to focus on this operation."

Jan 1, 2016

By T. A. Toney, L. R. Fish, P. J. Bethell

With new lightweight designs, spirals have become standard equipment in coal preparation plants worldwide. To their credit, spirals typically show very low coal losses to the refuse stream under most operating conditions. However, spirals do tend to separate at cut points in excess of 1.80 S.G. Attempts to obtain lower cut points have typically resulted in coal losses to middlings. Middlings retreatment with secondary spirals is therefore becoming common place. Other forms of retreatment with water-only cyclones, hydrosizers and recirculation have been attempted with some success. This paper reports on a novel (patent applied for) approach to retreating spiral middlings in a heavymedia cyclone circuit.

Jan 1, 2000

By T. A. Toney

With new lightweight designs, spirals have become standard equipment in coal preparation plants worldwide. To their credit, spirals typically show very low coal losses to the refuse stream under most operating conditions. However, spirals do tend to separate at cut points in excess of 1.80 S.G. Attempts to obtain lower cut points have typically resulted in coal losses to middlings. Middlings retreatment with secondary spirals is therefore becoming common place. Other forms of retreatment with water-only cyclones, hydrosizers, and recirculation have been attempted with some success. This paper reports on a novel (Patent Applied For) approach to retreating spiral middlings m a heavy-media-cyclone circuit.

Jan 1, 1998

By M. Townsend, E. L. Petsonk, H. Abrons, E. Daniloff, K. Kinsley

Workers exposed to certain inhaled dusts may show increased levels of nonspecific airways responsiveness (AR). In some studies, cigarette smokers have also been reported to have increased levels of AR. As part of an ongoing study, we compared the results of preshift methacholine inhalation challenge, spirometry, and smoking and occupational histories, in 191 under-ground bituminous coal miners (M) and 215 non-mining control workers· (C) . All M and c were selected to have normal baseline% predicted FEVI (PPFEV). Mining tenure was recorded as years worked underground (YRUG) and at the coal face (YRFC). AR was assessed as the% decrease in FEVI from baseline divided by the dose of methacholine delivered. M reported similar years smoked (YRSM) but fewer pack-years* (PY) than c~ Overall, both increasing YRSM and PY were associated with more AR*. Smoking C* but not M showed increased AR with increasing PY. In smoking and nonsmoking M, baseline AR and PPFEV showed no association with YRUG. The level of AR was inversely related to YRFC*, possibly representing selection away from dustier jobs. AR was inversely correlated with PPFEV*. In this study, AR and baseline PPFEV were not significantly associated with mining tenure, but cigarette smoking was related to both baseline lung function and level of AR. * p < 0.05 (Supported in part by Grant Gll35142, us Bureau of Mines, Generic Mineral Technology Center for Respirable Dust.)

Jan 1, 1989

By W. Boas, R. Silva, D. Yumi, L. Steffen

The continuity of the flow and stages within the mining process is essential to achieve success in its operation and results, especially when it comes to a gold mine. During the first seven months of 2022, crushing at the Morro do Ouro Mine had 19 stops in the primary crusher due to equipment blockage/obstruction, this could be due to the size of the material that was blasted with explosives and fed. The feeding of coarse material to the crushing plant impacts the operation in several ways, for example, premature wear of the equipment, reduction in the supply of the remainder of the beneficiation, reduction of the buffer pile and damage to the conveyed belt. In a mine located far from the community, the fragmentation improvement is mainly related to load increments or some other relatively simple change. However, when it comes to a mine located close to communities, alterations of this type must be analyzed in detail, as it can have an impact mainly in relation to vibration and flyrock. Aiming to improve the efficiency of the blasting, mainly in relation to the result of fragmentation, a project was created to improve the efficiency of the blasting with a focus on reducing the crushing stoppage and reducing the amount of material discarded due to inadequate granulometry. During the evolution of the project, several improvement solutions were proposed, for example adjustment of the power factor in relation to the geological characteristics of the rock mass, drainage, blasting geometry, vibration reduction techniques and several operational improvements. By using the techniques and methods identified as improvements during the project, it was possible to observe and quantify improvements in relation to the fragmentation of the blast. During the months of January to July 2022 there were 19 events. It was estimated that at this rate there would be 14 more blockage events, but there were only 3 events and that meant a 79% reduction in blockage. In addition to the reduction in crushing shutdown events, there was also a 53% reduction in the amount of ore that is discarded due to inadequate granulometry and, with that, the feed rate of the grinding system was able to reach the maximum feed limit due to the material being fed to the mill well fragmented, contributing to increase the production and productivity of the beneficiation process at the Morro do Ouro Mine in Paracatu-Minas Gerais-Brazil.

Jan 1, 2024

By B. P. Spigarelli

To meet the growing need for CO2 capture and storage technology, Michigan Technological University is researching CO2 capture and storage using carbonate solutions. The objective of the present study was to increase the absorption rate of CO2 into the carbonate solution without reducing the absorption capacity of the solution. This approach used a polypropylene glycol methyl ether (PPGME) as a surfactant to chemically alter the gas bubble size. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations of 0, 0.12, 0.24, 0.36, and 0.48 g/L. Results showed that as the concentration of surfactant increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 mmol/min CO2 at 0g/L PPGME to 3.92 mmol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in absorption capacity of the solution.

Feb 27, 2013