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By Joël P. T. Kapusta

Although Peirce-Smith converting remains the workhorse in matte converting, the copper and nickel industries are still confronted with production hindrances such as tuyere blockage, excessive refractory wear and limits in the oxygen enrichment levels of the blast air. The knowledge acquired on high-pressure gas injection technology as well as the invention of the concentric tuyere for steelmaking led to the development of the Air Liquide Shrouded Injector (ALSI) technology for copper and nickel converting. Following a technology demonstration in 1997-98 with four shrouded injectors installed in a Peirce-Smith converter, Falconbridge Limited implemented ALSI Technology on a commercial scale in May 1999 as an integral part of its new Slag Make Converter at Sudbury, Ontario, Canada. The paper presents the various aspects of commissioning ALSI Technology, as well as the operating changes and injector design modifications over the five years the shrouded injectors have been in operation.

Jan 1, 2005

By Holcombe R. J, Dobos S. K, Little T. R

Blue amphibole-bearing rocks in the North D'aguilar Block of southeast Queensland occur either as relict pods and lenses within regionally extensive greenschist facies phyllites and schists or as blocks entrained in serpentinite-matrix melange. Epidote + crossite-bearing varieties predominate and formed under conditions consistent with underplating and high P:T metamorphism in a subduction-related tectonic environment. Neither lawsonite nor jadeite has been observed and metamorphic conditions are estimated at 380-4500C for pressures of 0.5-0.8 GPa. High P:T metamorphism occurred during the earliest stages of deformation and was superimposed upon protoliths of inferred Late Devonian - Early Carboniferous age, including mafic volcanics, tuffs and coarse volcaniclastic breccias as well as pelagic and henipelagic sediments, all of which have undergone varying degrees of over-printing to the greenschist facies. Greenschist facies metamorphism occurred during the second phase of deformation and was associated with the formation of mainly flat-lying or subhorizontal structures; it followed the cessation of subduction and occurred in response to either thermal relaxation during uplift or the imposition of regional heating induced by crustal thickening and/or synkinanatic granite emplacement. Uplift and cooling of the high P:T rocks was completed by 260-265 Ma and may have occurred in response to the same extensional processes which gave rise to the onset of rifting in the adjacent Esk Trough.

Jan 1, 1990

By Norbert Asamer

At various stages during the hot rolling process, the different rolled products – blooms, billets, bars, respectively sections, but also slabs or plates – need to be cut. While the cross sections of these products are being reduced during each rolling pass, the lengths are being increased accordingly. Thus, it becomes necessary to cut the products to shorter lengths suitable for the next steps of production by state-of-the-art designed dry abrasive cut-off machines.

Jul 30, 2018

By J. S. Lee

A new high performance adsorbent is synthesized by the sol-gel method and applied to the removal of cadmium and mercury ions from aqueous solutions. Adsorbents based on metal oxides have been developed by immobilizing chelating molecules on the surface of the existing metal oxide networks and show ability for selective metal extraction from aqueous solutions. However, efficiencies of such adsorbents are limited due to low ligand density, and difficulty in pore accessibility. These difficulties are circumvented by synthesizing adsorbents using the sol-gel technique. In one example to be discussed, the sol-precursor possesses an organic moiety that binds cadmium, mercury, and copper ions. The capacities of 1.98mmol Cd(II-/gm and 6.40 mmol Hg/gm of this adsorbent are considerably higher than those of adsorbents prepared by the ligand immobilization technique. The scope of this paper is to discuss the development of the new adsorbent and its applications for cadmium and mercury removal from aqueous solutions.

Jan 1, 1999

By S. B. Breyner, A. Ressler, D. Gregurek, A. Spanring

"The changes in process conditions that frequently decrease the service life of refractory products provided incentive for RHI AG to develop high performance bricks, especially for non-ferrous metal applications. Innovative product development was required to determine suitable refractory products for improving lining life. At the Technology Center in Leoben, Austria, practical corrosion testing methods and facilities, including an induction furnace and rotary kiln, enable detailed comparative analysis of brick wear on a pilot scale. In tests that were carried out using a fayalite type slag, the newly developed RADEX VFG magnesia-chromite grade showed very promising results compared to the standard grades. Based on the test results, optimal refractory solutions can be recommended for this challenging industrial application and field trials can be performed directly at the customer's site.IntroductionThe complexity of metallurgical processes in the non-ferrous metal industry, and especially changes to the process conditions in combination with the diversity of metal processing furnaces ''', requires a precise understanding of each individual system for appropriate refractory product selection l2'. In addition, particular importance is focused on the specific refractory consumption being as low as possible.Another important aspect results from the global shortage of resources, which forces companies to invest in recycling processes. In the base metal industry, recycling operations have resulted in significant changes; for example, operating with two slag chemistries and process temperatures will influence the performance of previously suitable linings. The raw material mix for primary smelters has also changed, including higher levels of secondary raw materials in the smelter feed."

Jan 1, 2012

A construction material based on plasticized sulfur and mineral aggregate, that is superior in corrosion resistance and strength to portland cement concrete. The material can be used in the chemical, metallurgical, and fertilizer industries, and will also provide an attractive market for by-product sulfur resulting from compliance with pollution regulations. How It Is Made Sulfur concrete is thermoplastic material. Plasticized sulfur is mixed with sand and gravel aggregate heated to 375-400° F. The sulfur melts and acts as the binder or cement. The sulfur concrete is poured hot and sets at a temperature of 200° F. Full strength is attained in a few hours, compared to several days for portland cement concretes. Sulfur concrete even pours and sets in freezing weather. Although unmodified sulfur with aggregate will produce a sulfur concrete with good initial properties, it undergoes crystallographic modifications, and deteriorates with time, particularly when exposed to moisture or freeze-thaw conditions. The Bureau of Mines has developed plasticizers which, when reacted with the sulfur, give sulfur concretes with excellent moisture and freeze-thaw resistance. The plasticizers are based on mixtures of dicyclopentadlene (DCPD) and ollgomers of cyclopentadiene. About 5 percent by weight of the plasticizers is reacted with molten sui fur for several hours. The sulfur cement can be used directly or allowed to solidify for easier handling and storage.

Jan 1, 1981

By Takayuki Takasugi, Naoya Masahashi, Yasuyuki Kaneno, Satoshi Semboshi, Yusuke Kadoi

Cu–Ti alloy wires doped with and without a small amount of Ni were fabricated by over-aging and using intense drawing procedures. For both the Cu–Ti alloys with and without Ni doping, the over- aged microstructure was occupied fully with a coarse lamella of Cu solid solution and β-Cu4Ti plates precipitated discontinuously by grain boundary reactions. The full-lamellar microstructure was developed much more rapidly by aging in multi steps at 873 K to 723 K rather than by isothermal aging at 723 K. Ni doping in Cu-Ti alloy was also effective to accelerate the formation of the lamellar microstructure. When drawing the over-aged alloy with inferior hardness but superior electrical conductivity, the strength increased steadily and eventually exceeded that for the wires drawn from the peak-aged alloy. In addition, the electrical conductivity of the wires drawn from the over-aged alloy was always much greater than that from the peak-aged alloy. Eventually, the procedure of over-aging, followed by intense drawing, could enhance both the strength and electrical conductivity of Cu-Ti alloys, whichever they contain a small amount of Ni or not, rather than the conventional peak-aging and drawing process. INTRODUCTION Cu-based alloy wires, which have an excellent combination of strength and electrical conductivity, have attracted extensive attention for highly mechanically stressed electrical devices, such as conductive lead wires and wires in suspension springs. Cu-Be alloys are widely used for such electrical components owing to their combination of strength and electrical conductivity among industrial Cu-based alloys. However, since beryllium is potentially toxic and also a rare element, substitute materials for Cu-Be alloys have been searched for several decades. Age-hardenable Cu–Ti based alloys have been proposed as candidates because their mechanical and physical properties are comparable to those of Cu-Be alloys; however, their electrical conductivity is inferior (Datta & Soffa, 1976; Soffa & Laughlin, 2004). In order to satisfy the requirement of downsizing and streamlining electrical devices, further improvement of the mechanical and electrical properties of Cu–Ti alloy wires is needed. Age-hardenable Cu–Ti alloys, which contain approximately 3 to 6 at.% Ti, are typically prepared using a solid solution treatment above 1100 K and then aging at a moderate temperature of 700 K to 800 K. It has been revealed that the microstructural events during aging progress as follows (Soffa & Laughlin, 2004): (1) compositional modulation of the parent supersaturated Cu solid solution in an initial aging stage (Laughlin & Cahn, 1975), (2) continuous nucleation and growth of fine needle-shaped precipitates of metastable β’-Cu4Ti with a tetragonal structure in a peak-aged stage, and (3) discontinuous precipitation of cellular components laminating the plates of a terminal Cu solid solution and stable β-Cu4Ti with an orthorhombic structure at the grain boundaries in an over-aging stage. It has been also accepted that the highest number density of dispersed fine β’-Cu4Ti needles should contribute to maximal strengthening. On the other hand, decease of the strength in the over-aging stage occurs due to the replacement of the fine β’- Cu4Ti needles with cellular components containing coarse β-Cu4Ti plates, while the electrical conductivity is significantly enhanced due to the depletion of solute Ti in the Cu matrix. This suggests that a combination of strength and electrical conductivity for age-hardenable Cu-Ti alloys is in a trade-off relationship, and that innovative improvement of both properties might be limited to tuning the aging conditions.

Jan 1, 2019

By R F. Hoeberling

"The use of ground penetrating radar (GPR) for geological purposes has been underway for almost two decades. The commercial need for a versatile GPR that can rapidly identify buried objects andunderground voids has been recognized and is an area of research that has already proved useful for several geological activities. Several types of GPR endeavors have been reported in the literature, including exploration of placer deposits (Davis, et al. 1985) and heavy metals (Hammond and Sprenke, 1991), improving oil recovery (Witterholt and Kretzschmar, 1984), investigating coal seams (Coon, et al., 1981), stratigraphic survey (Fisher, et al. 1992), Lunar soils characterization (Olhoeft, et al. 1975 and Strangway, et al. 1977), characterization of rock around mine tunnels (Cook, 1985), location of old mine workings (Scaife, et al., 1992), location of abandoned gas wells in coal seams (Kemerait, 1992) and survey of hazardous waste burial areas (Horton, et al., 1981). Coal seammapping has been developed using a related continuous wave, phase discrimination technique (Stolarczyk, 1990). As the technology for the radar equipment and the onsite computational power has increased, many new applications have become feasible. This article will describe the present status of the GPR technology and indicate some of the exciting possibilities for nearterm prototypes now being constructed."

Jan 1, 1994

By Thomas Camus

"STATE OF THE ART The current situation of ground prediction in TBM is of great concern for tunnelling contractors, and the subject has been quite widely addressed over recent years, for instance by the French Eupalinos 2000 programme, which tested a variety of technological approaches. A number of interesting projects were executed, such as the SOUND and OnSITE projects, part of the German Geotechnologien programme: these projects are focused on seismics, while other techniques such as radar are not considered. Little information and even less industrial applications have been released apart from lab simulations and numerical modelling. A number of field tests in different configurations have been carried out for compression waves, but the results were often not reliable or convincing, and therefore little has been reported in open literature. The advances seem somewhat promising as far as hard rock tunnels are concerned, but ignore the problem raised by concrete lined tunnels such as those bored by a TBM in soft ground. In such tunnels, sending and receiving seismic waves reliably through the lining (and the grouting behind) is quite illusory. A careful analysis of the seismic prediction research results show that the main problem is the source which is poorly controlled and poorly coupled (for instance in concrete lined tunnels, or in approaches that use the TBM cutter head vibrations as a source). Generating waves perpendicular to the tunnel axis is also a problem: aligning with the tunnel axis makes more sense. Radar (Ground Penetrating Radar - GPR) has been used in geotechnical surveys for decades, and also for tunnel inspection. Attempts have been made at using it on a TBM (for example in Japan by Taisei) but mainly using off-the-shelf GPRs, which are not adapted to work in the specific environment of a TBM (because of its huge mass of metal, to start with). Very few results have been published, probably due to the somewhat disappointing performance of such implementations. At present, no TBM has a GPR incorporated in its cutter head that is able to predict ground characteristics while drilling. Another characteristic and drawback of most current methods is that they require dedicated periods of time during which other tunnel construction activities must be stopped. Due to the duration of such operations this leads to performing ground prediction on a weekly basis only, and therefore to a requirement for an investigation range of 100 metres approximately (in order to cover the TBM advance over the coming week). This is not achievable with boreholes made from the TBM, even less if a reasonable accuracy is required, as is usually the case."

Jan 1, 2016

By K. Hausmann, W. Whelchel

The properties of ethylene Ionomer resins for the inner layer of non-electric shock tubes will be discussed in detail, and opportunities for property enhancement will be pointed out. A stiffness program for prediction of shock tube stiffness, as determined by the stiffness of the individual layers, will be presented and discussed.

Jan 1, 2010

By Bolger Witthaus

"High performance production under challenging geological conditions is a product of several parameters. Main factors are the technical equipment and the knowledge in processing. The design and the support system of maingates must also be taken into consideration. The extraction of seams in German underground hard coal mines of RAG in a range of heights between approximately 1.1 and 4.0 m ( 4 and 13 ft) is done by plow and shearer technology. A complete system for quality management of production is required. The process examination of processes begins with procurement of the equipment. Education and training of the engineers and specialists, as well as for the miners are requirements for success as well.This report gives an overview of RAG measures for achieving high performance. Starting with examination of the processes accompanying procurement of equipment, the following important elements are described. Standards in education and training, technical design and elements of automated processing using stateof- the-art in control systems are critical to this system.The application of automation plays a decisive role in modem coal mines. The latest development in German coal mines is the fully-automated shearer system for longwalls. This helps to enhance safety, particularly in difficult ground conditions, by removing the shearer and shield operators from the immediate mining activity.INTRODUCTIONLongwall mining in carboniferous strata in Germany faces various challenges. Different longwall systems are used to mine up to 24 seams, each with a thickness between 1.1 m (3.6 ft) and 4.0 m (13 ft). High stresses due to a depth of up to 1,400 m (4,593 ft) requiring pillars between the panels, require special systems for roadway development, roadway support and reinforcemen.t as well as for longwall advance operations. Two main types of equipment for extraction are shearer and plow systems. While shearers are utilized for seam thicknesses above approximately 1.8 m (6 ft), plow systems can be used for smaller seam thicknesses between 1.8 m (6 ft) and approximately 1.0 m (3 ft)."

Jan 1, 2010

By Salete Martins Alves

The future lubricants must be more environmentally adapted, with a higher level of performance lower total life cycle, cost than currently used lubricants. Environmental friendly, the biodegradable alternatives are available for a large variety of mineral oil based lubricants. Vegetable oils are the major source of these base fluids, although they have lower thermal and oxidation stability and even worse low-temperature behavior than mineral oil. These physical and chemical properties can be improved by chemical modification. The aim of this study was to evaluate physicochemical properties and film formation from modified vegetable oils. The vegetable oil was chemically modified by epoxidation reaction with acetic and formic acid using sunflower oils. Viscosity, iodine value, density, acidity value and thermal stability were determined for epoxidized oils. The film formation was analyzed using a HFRR tribometer. The results showed that epoxidized vegetable oils had excellent properties to be used as lubricant, and their tribological performance is higher than mineral oil.

Jul 31, 2018

Develop a metal substitute which is more plentiful and less expensive than the metals currently being used in high performance, permanent magnets, while maintaining the quality of the magnet. The New Alloy The rare-earth metal used in most high performance magnets is samarium, an expensive metal of limited availability. Cobalt is also used in high performance magnets, but supplies of this metal also are limited because it is not domestically mined and must be imported. The Bureau of Mines embarked on research to find a less costly domestic: metal source for use in industrial magnets. The alloy found most promising consists of mischmetal, a relatively abundant, naturally occurring mixture of rare-earths, which can be used as a replacement for samarium. Additives of copper, magnesium and iron used in combination with mischmetal aid in replacing some of the cobalt needed for the magnets.

Jan 1, 1983

By Katsuyoshi Kondoh

The utilization of silica particles originated in rice husks as reinforcements of magnesium composites was discussed. By using the solid state reaction of rice husk silica particles with magnesium powder, P/M magnesium based composites dispersed with the magnesium silicide (Mg2Si) and magnesium oxide (MgO) were fabricated. High-purity silica particles were originated from rice husks, one of the major agricultural wastes, via the citric acid leaching treatment and combustion in air. The effects of the silica particle characteristics such as size, crystalline and porous structures, on the reactivity of silica and magnesium to synthesize Mg2Si intermetallic were discussed. Amorphous silica was more useful for this reaction than crystalline one. The reactivity of rice husk silica was superior to that of the conventional mineral silica particles because of not only its amorphous structure but the larger specific surface area due to their pore structures. In the case of the green compact of the mixture of the rice husk silica and Mg powder, the silica particle size was not effective on the reactivity because the coarse particles were fractured into fine ones by cold compaction. The distribution of Mg2Si intermetallics of magnesium powder composites consolidated by SPS process was investigated by XRD and SEM-EDS analysis. Their mechanical and physical properties were also evaluated in detail.

Jan 1, 2009

By Allan J. Guse

The primary limiting factor for hoisting capacity from great depths is the self-weight of the typical steel wire ropes used for mine hoisting. Steel wire ropes possess properties making them very suitable for mine hoisting including high strength and durability, but have the negative characteristic of being relatively heavy in comparison with their strength. Also, as hoisting depths increase, the service life of steel wire ropes decreases due to the higher stresses and physical effects on the ropes. The significantly higher strength-to-weight ratio of synthetic ropes compared with steel ropes offers the primary advantage of hoisting a larger payload with a similar size rope and hoisting plant. The beneficial properties of synthetic ropes could be used to improve the overall economics of deep underground mining both for new deep shaft projects and for existing mining operations expanding to deeper orebodies. A research and development program has been initiated to evaluate the suitability of a fully synthetic rope for the mine hoisting application, including rope discard methodology and NDT testing. The three phases/projects are: 1) proof of concept with focus on coilability under load (successfully completed in 2012); 2) high speed and load durability optimization & NDT Development; and 3) in-situ mine trial.

May 1, 2013

By A. J. Guse

The primary limiting factor for hoisting capacity from great depths is the self-weight of steel wire ropes. Steel wire ropes are very suitable for mine hoisting due to their high strength and durability, but have the negative characteristic of a low strength/weight ratio. Also, as hoisting depths increase, the service life of steel wire ropes decreases due to the higher stresses and physical effects on the ropes. The significantly higher strength/weight ratio of synthetic ropes offers the primary advantage of hoisting a larger payload with a similar size rope and hoisting plant. The beneficial properties of synthetic ropes could be used to improve the overall economics of deep underground mining both for new deep shaft projects and for existing mining operations expanding to deeper orebodies. A research and development program has been initiated to evaluate the suitability of a fully synthetic rope for the mine hoisting application.

Feb 23, 2014

By T Goswami, M Edmondson

Henry Walker Eltin (HWE) are the mining contractors for Gloucester Coal at Stratford mine, which is in an environmentally sensitive area in the Avon Valley, NSW, Australia. Normal blasting at Stratford is done in a æstand upÆ or æbox cutÆ mode to suit the truck and shovel operations. Recently an opportunity of doing a throw blast became available when part of a ramp had to be blasted to accommodate changes to the pit design while not damaging the remainder of the ramp. The objective was to maximise throw into the void in order to minimise excavation costs by reducing the amount of overburden to be moved by the excavation fleet. It was necessary that the best result be achieved while staying within the vibration and airblast limits at a neighbouring property and nearby township. Both objectives were achieved through the application of OricaÆs knowledge of blast design, modelling and i-konTM electronic detonators. The i-kon system was used because of its known benefits in cast blasting and environmental control. The i-kon system provides the blaster with much greater accuracy, control and the flexibility to tailor blast designs. It has been found previously to enhance blast throw and provide cleaner high walls (Brent, 2002). The blast was a success, producing a muckpile with a high degree of looseness and consistent fragmentation, with an average throw to final spoil position of 37.5 per cent. This was achieved without any environmental exceedance. In addition, high speed filming showed that the coal edge had remained largely in place, indicating minimal coal loss. The results exceeded the expectations of HWE Stratford and the overall cost savings to HWE Stratford from this blast were recognised to be substantial. Further throw blasting opportunities at Stratford have been followed using the i-kon system to maximise benefits.

Jan 1, 2003

Henry Walker Eltin (HWE) are the mining contractors for Gloucester Coal at Stratford mine, which is in an environmentally sensitive area in the Avon Valley, NSW, Australia. Normal blasting at Stratford is done in a “stand up” or “box cut” mode to suit the truck and shovel operations. Recently an opportunity of doing a throw blast became available when part of a ramp had to be blasted to accommodate changes to the pit design while not damaging the remainder of the ramp. The objective was to maximise throw into the void in order to minimise excavation costs by reducing the amount of overburden to be moved by the excavation fleet. It was necessary that the best result be achieved while staying within the vibration and airblast limits at a neighbouring property and nearby township. Both objectives were achieved through the application of Orica’s knowledge of blast design, modelling and i-konTM electronic detonators.

Jan 1, 2003

By Brian Khalighi, Massimo Franceschi, Giovanni Giacomin, Gianni Porta

Headrace Tunnels and parts of the Access Adit Tunnels of Kárahnjúkar Hydropower project, KAR-14, in Iceland will be excavated using three full-face Robbins Tunnel Boring Machines (TBM). TBM sizes range from 7.23 to 7.63 meters in diameter and the total headrace tunnel length is approximately 40 km. The crushed rock is transported on conveyor belts to disposal areas near each Adit. The estimated average excavation rate is approximately 25 meters per day per machine. Electricity will begin to flow in April 2007, and the project is scheduled for completion in 2009. This paper is divided into four sections. In the PROJECT OVERVIEW section, a short overview of the scope of the project is presented. In the GEOLOGY section, the geological condition along the tunnel drives is briefly introduced. The TBM DESIGN section discusses the various design criteria and the resulting machine specifications. The paper concludes in the TBM OPERATION section with a case history describing the tunneling operation from start-up to the time of the writing of this paper.

Jan 1, 2005

By Joseph J. Diehl, Brian B. Khalighi

This paper discusses the Queens Water Tunnel, No. 3, Stage 2, being driven by a new Robbins High Performance (HP) Tunnel Boring Machine (TBM).The paper is divided into four sections. In the INTRODUCTION section, a short overview of the scope of the project is presented. In the GEOLOGY section, the geological condition along the tunnel drive is briefly introduced. The TBM DESIGN section discusses the various design criteria and the resulting machine specifications. The paper concludes, in the TBM OPERATION section, with a case history describing the tunneling operation from start-up to the time of the writing of this paper.

Jan 1, 1997